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MS 200s AY2009 52
Name: t,oqy
hT /"ty T2-
(ruesotol)
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l.
What is the absolute uncertainty in 15.34 (+/- 0.07) + 10.80 (+/- 0.04)? (3 marks)
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,L
(#l'nGffi'
sg= ts'lv x
[s
(tl-
o.CIt)
to
o.ooG
An-indicator with pKa 4.1 is best used for which type of titration: ;zfsnongacid - weak base b) strong acid - strong base c) weak acid - strong base d) weak acid - weak base
t/
3.
1s- , r'5 What volume of 0.05 M NaOH is required to neutralise 35 mL of 0.1 M NazHPO+
t.
solution? 35..tLxo.tM
V
4.
a o.osrrtxvr r} = 35nrL
25%o
40.^^U
ffi#ffi#;Jffi;;;;:i"i';h,i;#;F;;:& V.
What will be the potential when
E0r.3*rFrr*
Cea*
:0.767 V.
E=o:,6'r"F.(Hl)
E0c"avc"t+
1.7
(3 marks)
vo,arccq{
u'J Gtr.r G*t ' J1r( *rl e g-r,rJ-rrrl I ' *\ * e*..-rs tr\t = o.r = ,,,,.-. . o.oos I $L,, ,r,-t.+ c.e = o-oos o o.o>S I
,.^a
9"}r
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o-r*
| *,fr-}.;*r,*ifu
^) 'll,-
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t"
*
5.
:ffir--1,*+.*\"\
2Lc
6.
If a I.23 x
lO's M solution in a I cm cell shows 29%o transmittance at254 nm, calculate the molar absorptivity (units are L/mol cm)? (3 marks)
/= &ht
I = 4r-t+ ).;J.rl ,,*(;
( t'zcxro-r)1 1.,'.,
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7.
How many signals do you expect to see in the co*no-urds? ,,.. ;_\
.;1"
t3C
4 g"l'T5,
t!
ll-,3E l
{c)
b 3.r h5.
g.
\, )
What happens to the height of a theoretical plate as the velocity of the mobile phase is increased? $ &c'urclrJ 'flr,rrr. i*.ar-.r*q"r ro ./ Rc-dr^cA * rt What is a contact angle?
9.
i\/ -{--<,'
Ll
(2 marks)
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tt8t\u
a$C
r"'\r'ictn.
t^'r-* usg\ er nol I !e,^\ h^s.d^ 1\* q'AaJ vlrr., *ll[ Ia rrV.+r a Srt\36n11 pll o^{e aniwr (3*,
.rfiil\rqo.
'.*a)
10.
11.
An increase in co4tact angle means the height a liquid rises in a capillary will: d) cannot tell a) increase ufi d""rease c) remain the same
A\=
=
ffi
3' I O rlQ{
r'nr'
4rz-t
3roAi/
,i
Which of the following surfactants will have the highest Critical Micelle
Concenffatiop? a) CrzHzsPO+Nag
'
c)
C rzHzs(O
"diCrrHrrsoNa
s\
v6'"t
z'Pda'lu'
F, s"ito." fr '{
ioric )
1on' torrC
(V't "ao"tl
13.
For,a polarcompound being eluted through a polar stationary phase which of the following will increase the retention time? lncreasing thepolarity of the mobile r5 t b) Increasing the polarity of the stationary c) Increasiag dre vclocity of the mobile phase d) All of the above
,;f,
t4.
If ltrc u ewl#
c a slrface freshly cut under vacuum to air what happens to its surface
gt'r*'c.
t.ill
&c'..garq-
Cts.
-WE:<**
Appcudir
JR=
sl +s3+sZ
*=m
.=iq+)
=f--L-)' " (A/. +V" )
A = 2-lodToT)
A=ebc
H=4 l6t:
r\
tr,B'tr,A
--
2N,
wE+w^
0.5{w,
+*o)
fA
\,,1'
HLB mix =
X IILBAI + [(l-lA.) X
HLBBI H: L/N
a(m2lmorecure)=;-tiffi
E=Eo*RTo,
t=-#[#)
[=- 2vws0
prg
oH = ol(a+loq [A'] -tHA]
nF
[oxJ
[Red]
H=A
+ B/u+Cu
R=8.314JK'l msfr
F=96500Cmol'r
q/
...f.f
F-,
/'
'i).
1.
Which ofthe following is true about chemical adsorption? Its entropy (AS) is negative It enthalpy (AlI) is usually greater than for physisorption i It may be reversible at high temperature.l All of above
a) b) c) d) a) b) c) d)
(d\
"/
2.
Which of the following is not true about physical adsorption? It has negative entroPY (AS). r It produces multilayers. It is reversible at high temperature. -r None ofthe above.
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J.
Is a surfactant with a low HLB better for stabilizing o/w or w/o emulsions?
U{o cr^,.r,tlstqw9
4.
What mixtute of 2 surfactants with HLBs of 6.3 and 15.9 is needed to make a mixture with HLB of 9.5? Q.t. d.:Pq + ls-t - rs.t pr d) l:2 c) 1:l a)2:l r(\4rs
b)3:2
C4
5.
J/-o'BG fu,
N's (r1) + >c-
6'rp1
tt$
-q.r
I
{-t
CalculatethecellpotentialforthefollowingGalvaniccellat25"C:>
NilNiSO+ (aq,0.004M)llAgNOr (aq,0.02
M)lAg (3 marks)
N;fd->
AJ"C5)
N'Lt (^1)+
)f
eb = -b->5V
-)
Pc.\
-Eort
f-D(v
[ -o->S v)
ft.
t-os
B.3l
C?AS)
>-'Q6S*e
)^1"-..--or1-
u-w\
(\/ *
l-ozV
/
I
)L
6.
Which way are the electrons flowing in the Galvanic cell CulCuSO+ (aq, I M)llNiSO4 (aq, I M)lNi? q^ g'?rJ V a) From left to right in the external circuit -o.>sr/ b) From right to left in the external circuit c) From left to right across the salt bridge G'oll -o'>sv d) From right to left across the salt bridge
Ni
ct) /
-o'3{y'
-o.s? of
7.
How much silver Mw Ag = 107.9 g/mol) will be deposited from a solution AgNOI in an electrolytic cell using a current of 35 A for 2.5 minutes. (3 marks)
b*oJe-'{o atao&
&--
tt = nz'F
:
tt
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rSoS
e&4"1
t xq6f,co
x
/
lo7't
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-8.
S.E1o
S ,/
9.
hJaJ ebd,,t&/aggro tY-:ra/.-l dkbqJ v-{o6fiD.. 16 ,leruv$e Why do batteries give a steady current whereas an ordinary Galvanic rrl6o-.rt"ttor*u not? ( 2 marks)
Frr{
electroplating? \ r^!es do at n-t 6rc{,^q[<-m e\G{$Acs.I 4\c (sl,lcCr t 4.C..^1, *4 T\ahS 'ac"n-^p.
[.,. r$tc*trJ r dl^. n*-adcA A
""tiu\ i\
f'e
:[,t
]ste;i 0 L=
E"
cov$r-a*
$''r"svrr
electrode?
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a-rr$*-f, #"--rtvP
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*[, tt^^
ocr^crg-ott
L '"..ry'e.,*ut
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marks)
= )l ;.ltl
f*o"{
,/
_
( Go =-o'XV) >; - ni (s) I ( v) bX) -o'43 = )fizo *,>a- J ,{,- 5) + )^f A 'tt"\"+/e * n %"s'"' \\" :*t ptr*tt l + wtcbc\ Yt v'\ro\^\ fstlii{e r
gu
(2 -r lH 'r ) -z H, (o V ) L fo s.w^a"rt
.
6o .odrlt1 .
Cs v\^o\a-
T*F"CI
12.
Define the exchange current density for an electrode and describe how you can determine its value (3 marks)
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arJ-
13.
t4.
l*f-,ra . , Jt eoato6 1o q."dtse e*ot oorrrod*t. A c.*^g$a t.ooh.n1 r.ritl pcarbb a' ****. *rt& 6^ tcr.\b*.lv \vq4, *|\ia\4 sovr i*+l O O"+D" lvcvant \ +-\^ Ccdorisrl . F",*,ar., ..C... t\
Describe how electriciry is produced in a hydrogen-oxygen tuel? (3
l-n = -O-qqV <- cosrqr .!o s;irtasft"f) \).,' - Fots) ("+ Ni b) Nix r >f / : *o-z5N .l.r.orA taas o o^o\^e rnrprtrve go *rcl*c-r.r^t +{r.n ilcch.et -rU*{uru ,0
3*r ceo.gad
o,,.ct
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H,0
APPeadir
t(U{)
X HLBBI
E=Eo*RTtn
nF
[Ox]
tRed]
R=8.314JK'r mol'r
E = Eo
F=965@Cmofr
-IlmO nF
l
Q=It=nzF
-$FnlRI)l }
q = a+ blogi
AG: - nF4cn
Standard Reduction Potentials
Reaction
Ni"(aq)*2e +Ni(s)
CV)
-0.83
-0.4
-0.25
Reaction
sr
I j-
'i
I
,.r
'l