Concept Recap Test Mains 5 Sol

AITS-CRT(Set-V)-PCM(S)-JEE(Main)/13
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1

ANSWERS, HINTS & SOLUTIONS
CRT(SetV)

Q. No. PHYSICS CHEMISTRY MATHEMATICS
1.
D D A
2.
D A B
3.
B A A
4.
C C A
5.
C D A
6.
D C B
7.
B A B
8.
A C C
9.
D B C
10.
D A B
11.
A B B
12.
D A B
13.
C D D
14.
C C B
15.
D D D
16.
A A A
17.
B B A
18.
C C B
19.
C D B
20.
D C D
21.
C B C
22.
D C C
23.
D C A
24.
D A C
25.
D B D
26.
C A A
27.
D D C
28.
B A D
29.
C D D
30.
B A C

A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
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S

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2
P Ph hy ys si ic cs s PART I
1. Force
dm
V
dt
=

2. Let
1
and
2
be the speed of the body before and after striking.

1 2
sin cos = (as there is no friction)

1 2
e cos cos
2
| |
=
|
\ .

2 2
1
sin
e tan
cos

= =

3. F
shaded
= M
shaded
A =
M
3
A
A =
F
M

F
shaded
=
F
3
.

5. Use E = M C
2

6. The complete reaction is

236 140 94 1
92 54 38
U Xe Sr 2on + +

7.
1
1 1 1
V 1000 400
+ =

2
1 1 1
V 800 400
+ =

8.
1 1 1
V 20 10
=

V = 20 m = 1
2 mm
O

Co-ordinate is (20 cm, 0.2 cm).

11. Calculate the M.I. of the linear and circular portions separately.
12.
1 k
f
2 m
=
, k = spring constant of the uncut spring.

The time period of the full oscillation = sum of those of two half-oscillations with frequencies f and
2f


3
14. W.D. from ground frame = 6.4 50 = 320 J
From elevator frame, displacement = 0.
37
N=8N
80.8 = 6.4 N
100.8=8N

15. Power abosorbed in purely reactive circuit is zero

16. Use the expression: net CM F M. a

=

17. Applying KVL we get
The current flowing in resistor (R
1
) =
E
R

18. The rate of heat dissipation is given by
H = i
2
R, where i = i
0
e
-t/RC
.

20.
V
E
d
= where V = P.d. between plates.

21. emf,
1
(due to varying B) = B
0 /
vt

2
(due to motion of PQ) = B
0 /
vt.
=
1
+
2
= 2B
0
/ vt

2 2 2 2
0
4B vt
Fv
R R
= =
/

2 2 2 2
0
4B v t
F
R
=
/
.

22. P
in
p =
2S
r

p
in
=
2S
r
+ p

=
2S
r
+ p
o
+ gH
p
in
p
h
p
o

23. As each sphere is in equilibrium, the net force acting on each sphere is zero.

24. Suppose that the temperature of the water in the first vessel is
1
(t) and that of the second is
2
(t),
then

1
1 2
d KA
ms ( )
dt L
= (i)
and
2
1 2
d KA
ms ( )
dt L
= (ii)
from (i) and (ii), we get

4

d 2KA
dt msL

= ,
where =
1

2
.
The time, in which the temperature difference reduces to
1
e
of its initial value, is given by

msL
t
2KA
= .
25. The heat capacity of the solid is

3
dQ
2a 4b
d
= +
.
26. The tangential component of force =
dK
,
ds

the centripetal component
2K
R
= .
27. The angle of projection, w.r.t. the horizontal, are and (90 - ) respectively.

28. For equilibrium
F
,
= 0
,
= 0
N =
3 1
2 2

.(i)
torque about A due to all forces excluding normal
force is found to be zero.

1
2
3
2
x
A
N
3
F=
3
2

29. Taking moments about point B to be zero.

1
T . ib B mg
2
+ =
/
/ /

1
mg 2ibB
T
2
= .
B
mg
T
1
T
2
A


5
C Ch he em mi is st tr ry y PART II

1. Edge not covered by atom = a 2r
Also in BCC, 4r 3a =
Therefore, edge not covered =
3 a 2 3
a a
2 2
| |
=
|
|
\ .

Fraction of edge not covered by atoms
2 3
0.134
2
= =
2. [CoA
6
]
3+
is a absorbing higher energy radiation than [CoB
6
]
3+
, i.e. ligand A is producing larger
crystal field splitting.
3. Assuming new normality of original H
2
O
2
solution = X.
After dilution to 100 ml of 10 ml of this solution

1
X 10 X 100 =

1
X
X
10
=
10 ml of this dilute solution is titrated with 25 ml, 0.0245 KMnO
4
solution.
So, N
1
V
1
= N
2
V
2

X
10 0.0245 5 25 X 3.0625 N
10
= =
New volume strength = 3.0625 5.6 = 17.15 V.
4.
( )
2 2
Pb S PbS black ;
+
+

2
3 3 2
3PbS 8HNO 3Pb 6NO 3S 2NO 4H O
+
+ + + + +
( )
2 2
4 4
Pb SO PbSO white
+
+
( ) ( )
4 3 3 3 4 4
2 2
PbSO 2CH COONH CH COO Pb NH SO + +
BaS and SrS precipitates are not black in colour. Ag
2
SO
4
is white precipitate but does not
dissolve in ammonium acetate.
5. ( )
( )
( )
( )
( )
( ) 1-x x+3y 2x-y
A g B g + 2C g

( )
( )
( )
( )
( )
( ) 2x-y 2y 3y+x
C g 2D g +3B g

1 2 4 13
12 24 7
1 6
eq.
i
n
x y
x y
n
+ +
= = + = (1)

| |
| | ( )
4 2 4
9 1 9
eq.
eq.
C
x y
A x
= =

22 9 4 x y = (2)
Solving (1) & (2), we get x and y.
And solve for
1 2
c c
K &K

1 2
c c
K 0.11&K 0.14 = =
6. ( )
D
d
= 1+
Where D is initial density and d is final density.
7. ( ) ( ) ( ) ( )
10 8 2 2 2
C H s 12O g 10CO g 4H O + + /

g 2 1
n n n 10 12 2 = = =

3
p v g
q q n RT 5138.8 kJ 2 8.314 10 298
= + =
5143.8 kJ =

6
9. ( )
2 4
H SO
2 2
2
CH OEt CH O 2EtOH +

OH
NO
2
+
2 4
1. H SO
2 2. HCl
CH O
OH
NO
2
CH
2
Cl

10.
C H
O
OMe
2
KCN,EtOH
H O
C H
CN
OMe
O
C
CN
OMe
O H
C H
O
OMe
CH
O
OMe
C
O H
NC
OMe
CH
O H
MeO
C
O
NC
OMe
CH
O H
MeO
C
O
OMe
H
+
CN
11. H
+
O
O
Li
O
O H
( ) 3 2
CH CO O
O
OCOCH
3

12. With calomel electrode as reference electrode.

0 0591
o
cell ref
E E
pH
.

=
Hence, E
cell
= 0 0591
o
ref
E . pH +
( ) ( )
1 1
0 0591
o
cell ref
E E . pH ; = + Using solution x
( ) ( )
2 2
0 0591
o
cell ref
E E . pH ; = + Using given buffer solution.
Hence

( ) ( )
( )
1
0 612 0 0591
0 741 0 0591 6 86
o
ref
o
ref
. V E . pH
. V E . .
= +
= +
(reference half-cell is same)

On solving (pH)
1
= 4.68.
13. Acidic aspirine ionize in basic medium in intestine but in acidic medium it is almost unionized.
14.
1
3RT
r.m.s. 1351.67 ms
M

= =

11
h
7.38 10 m
mc

= =
15. Resonance stabilized carbanion.

( ) ( ) ||
3 2 5
O
Ph P CH COC H
+

( ) |
3 2 5
O
Ph P CH COC H
+
=


7
17.
H
C H
3
H
D
H
Br
H
C H
3
CH
3

19. In hydrazine (NH
2
NH
2
) bond order is one, whereas in nitrogen gas bond order is three.

20. Two geometrical and two optically active isomers.

21. Vapour pressure depends on temperature not volume.

22. Complete octet of all the C and N atoms in structure (C).

23. Due to ortho effect and I effect.
24. Rate of CO
2
output = 44 gm/hr
22400
ml / min
60
= = 373.33 ml/min.
Rate of conversion = 600 ml/min.
Fraction of time converter has to work
373.3
0.622
600
= =
25. sp
2
hybridisation due to p d overlap is responsible.

26. Trans-addition of hydrogen.
27.
OH
H
OH
2
CH
3
1 2 if , hydride
shift
H
+
+
CH
2
2
H O
if ring exapansion
occurs
H
+
28.
C
CH
3
O
Ph
O
4
NaIO
O
Ph COOH
2
CO
Ph
O

29. Fluorine does not form any polyhalides as it does not have any d-orbital.

30.
2 2
4 4 4 2
2 MnO MnO e ; MnO MnO e

+ +


8
M Ma at th he em ma at ti ic cs s PART III

1. 12 = 4a + 2b, 2a(2) + b = 0
4a + b = 0
b = 12, a = 3

2. Let the point be (x, x
2
+ 4x + 3) Its distance from 3x y + 2 = 0 is

( )
2
2 3x x 4x 3 2
x x 1
10 10
+ + +
+ +
= is minimum when x =
1
2

The required point is
1 5
,
2 4
| |
|
\ .

3. Let the vertices of the rectangle be (a cos , b sin ), (a cos , b sin ), (a cos , b sin ),
(a cos , b sin ). Its sides are 2a cos , 2b sin . Area = 2ab sin 2 is maximum when
4
=
The required sides are a 2, b 2

4. Required area is
( )
( )
( )
a 1 cos bsin
1
absin 1 cos
a 1 cos bsin 2

=

= ab ( )
sin2
sin f
2
| |
=
|
\ .

( ) ( )
1
f ab cos cos2 0
3
2
= = =
Max area =
3 1 3 3
ab. 1 ab
2 2 4
| |
+ =
|
\ .
sq units.

5. Let r, be the radius and angle of the sector
2r + r = 16
Its area =
( )
( )
2 2 2
16 2r
1 1
r r 8r r f r
2 2 r
= = = ( ) f ' r 8 2r 0 r 4and 2 = = = =
Max area ( )( )
1
16 2 16
2
= square cms.

6. Let P
( )
2
x, x be the point on y = x
2

Distance from ( )
( )
2
2 2
Q o, c is PQ x x c = +

( )
( )
2 2 2 2
PQ x x c f x = + =
( )
( )
2 2
f ' x 2x 4x x c 0 x 0or 1 2x 2c 0 = + = = + =

1
x c
2
=
The required distance = PQ =
1 1 1
c c
2 4 4
+ =

8.
2
2
x
sin
dy x x x x
2
sec tan
x x
dx 2 2 2
2cos cos
2 2
= + = + =
x sinx
1 cosx
+
+


9

9. Go ( ) ( ) ( ) ( ) f x x g' f x f ' x 1 = =
Put x = 1, ( ) ( ) ( ) g' f 1 f ' 1 1 =
( ) ( )
1
g' 8 . 1 g' 8 8
8
= =

10. Let g(x) =
( )
1
tanx
f x x
1
= + = ( )
2
2
1
g' x sec x 0 cosx x
x
= + = =
Clearly only one solution for cos x = x in 0,
2
| |
|
\ .
and ( )
2
3
2
g x 2sec x tanx 0in 0,
2
x
| |
= + >
|
\ .

g(x) has one point of minima, hence f(x)has one point of maxima in 0,
2
| |
|
\ .
.

11. f(x) = ( ) ( )
2/ 3
x 2 2x 1 +
( ) ( ) ( ) ( )
1/ 3 2/ 3
1
2
f x x 2 2x 1 2 x 2
3

= + +
( )
( )
( )
( )
1/ 3 1/ 3
2 2x 1 3x 6 2 5x 5
3 x 2 3 x 2
+ +
= =

the critical points are 1, 2.

12.
2
V r h =
2
2
h
h a
4
| |
=
|
|
\ .

2
2 2
h
and a r
4
= +
3
2
h
a h
4
| |
=
|
|
\ .

2
2
dv 3h 2a
a 0 h
dh 4
3
| |
= = =
|
|
\ .

13.
2
dy 250
2x 0 x 5
dx
x
= = =
the stationary point is (5, 75)

14. ( )
9
f ' x 4x 4 0 x 1 3,
2
(
= = =
(

min f(x) = min ( )
9 47
f 3 , f min 7, 7
2 2
| |
= =
` `
|
\ . ) )

15.

( ) f x cosx cos2x cos3x 2cos2xcosx cos2x ' = + + = +
( ) f x cosx cos2x cos3x 2cos2xcosx cos2x ' = + + = + = ( ) cos2x 2cosx 1 0 + =

1
cos2x 0or cosx
2
= =

3 2
x , ,
4 4 3

=

16. a sin
2
x+ b cos
2
x = b + (a b) sin
2
x b. and a
Max = a; min = b


10
17. ( )
3
4
f ' x 4x 0 x 1, 1
x
= = =
Greatest value of f(x) = ( ) ( ) ( ) ( ) ( ) { }
max f 2 , f 1 , f 1 , f 2 , f 0 = max
17 17
,4,1
2 2

=
`
)

18. Minimum value occurs when x = y =
1
2

Minimum value of x log x + y log y is
1 1
2 log log2
2 2
| |
=
|
\ .

19. Let P = cos x + cos y + 2 cos (x + y) =
2
x y x y x y
2cos cos 2 2cos 1
2 2 2
| | + + | | | | | |
+
| | | |
\ . \ . \ . \ .

Put
( )
x y
cos t t R
2
+
=
( )
2
x y
4t 2cos t P 2 0
2
| |
+ + =
|
\ .

For real roots, D 0 4(P + 2)
2
x y
cos 1
2
| |

|
\ .

9
P
4

Equality hold where x = y

20.
( ) ( )
2 2
cosA sinA 9 + =

( )
( )
2 2
cos A sin A 2 cosAcosB sinAsinB + + +

( )
3 2 cos AB 3 2(3) 9 + + =

Equality holds if A = B = C
ABC is equilateral
infinite many equilateral.

21. As x = 1 is a root, so a + b + c = 0 b = (a + c)
Now, given equation is 4ax
2
+ 3bx + 2c = 0
D 9b
2
32ac
D 9a
2
+ 9c
2
14ac (quadratic expression in a)
D
1
= (14c)
2
81(4c
2
) = 128c
2
D
1
< 0 D > 0

22. Let she writes n items
P (getting an item) =
1
2n

P (she does not get an item) =
1
1
2n

P (she gets no items) =
n
n
1
lim 1
2n
| |
|
\ .
=
( )
n 1 1/ 2n 1 1/ 2
e e

=

23. Suppose a d, a, a + d are roots of the given equation
a d + a + a + d = 6
a = 2
roots are 2 d, 2, 2 + d are the roots and 2 (2 d) + 2 (2 + d) + (2 d)(2 + d) =
1

1
d 12 =

1
= 12 d
2
and 2(2 d)(2 + d) =
2


11

2
= 8 2d
2

Hence
1
+
2
= 20 3d
2

(
1
+
2
)
max
= 17 when d = 1

24. As 2
2
,
4
, 24 are in AP.
So, 2
4
= 2
2
+ 24
4

2
12 = 0

( )( )
2 2
4 3 0 + =
= 2 (As
2
+ 3 0 for any real )
Also, 1,
2
, 6
2
are in G.P.
So,
4
= 1 (6
2
)
4
+
2
6 = 0
(
2
+ 3)(
2
2) = 0 = 2 (As
2
+ 3 0 for any real )
Hence,
2 2 2 2
1 2 1 2
12 + + + =

25. Let be a root of f(x) = 0
f() = 0 and f(f()) = 0
f(0) = 0 b = 0
f(x) = x (x + a) = 0 x = 0 or x = a
f(f(x)) = x(x + a)(x
2
+ ax + a) = 0
x
2
+ ax + a = 0 should have no real root besides 0 and a
D = a
2
4a < 0 0 < a < 4
If the roots of x
2
+ ax + a = 0 is either x = 0 or x = a then a = 0
a [0, 4) a = 0, 1, 2, 3
Number of ordered pairs = 4

26. Inequation (x
2
+ 1) > 0 is satisfies x R
Hence the inequation (a 1)x
2
(a + |a 1| + 2)x + 1 0 is satisfied x R
(a 1)x
2
(a + |a 1| + 2)x + 1 0 x R
So, (a 1) > 0 and disc 0 (a + |a 1| + 2)
2
4(a 1) 0
(As a > 1 |a 1| = a 1)
4a
2
+ 5 0, which is not possible for any real values of a
Hence no such real a exists.

27.
( )
10
10 10 10 10
0 1 10
1 x C C x ..... C x + = + + + .. (1)
Also
( )
10
10 10 10 9 10
0 1 10
x 1 C x C x ..... C = + + .. (2)
Multiplying (1) and (2), we get

( )
( )
10
2 10 10 10 9 10 10
0 1 9 10
x 1 C C ..... C x C x = + + + +
( )
10 10 10 9 10 10
0 1 9 10
C x C x ..... C x C + + .. (3)
Comparing the coefficients of x
10
ln (3), we get

( )
( ) ( ) ( )
2 2 2
5
10 10 10 10
5 0 1 2
C 1 C C C ..... = +
( ) ( )
2 2
10 10
9 10
C C +

28. a
0
C
0
a
1
C
1
+ a
2
C
2
a
3
C
3
+ .. + a
2012
C
2012

= a
0
(C
0
C
1
+ C
2
+ .. + C
2012
) d(C
1
2C
2
+ 3C
3
4C
4
+ ..
2012
C
2012
)
= a
0
(0) d(C
1
2C
2
+ 3C
3

4
C
4
+ ..
2012
C
2012
)
Now (1 + x)
2012
= C
0
+ C
1
x + C
2
x
2
+ .. + C
2012
x
2012

Differentiate and put x = 1
0 = C
1
2C
2
+ 3C
3
4C
4
+ ..
2012
C
2012


12
29.
3
tan9
4
=

sin9 cos9
3 4

= =
Now
( )
3 4 3cos3 4sin3
2
sin3 cos3 2sin3 cos3

=

=
3 4
10 cos3 sin3
5 5
sin6
(

(

=
( )
sin9 cos3 cos9 sin3 sin 9 3
10 10
sin6 sin6
(
=
(

= 10

30. Let x
i
= 2n
i
1 where n
1
, n
2
, n
3
, n
4
1
Hence we have (2n
1
1) + (2n
2
1) + (2n
3
1) + (2n
4
1) = 98
n
1
+ n
2
+ n
3
+ n
4
= 51
giving n
1
, n
2
, n
3
, n
4
each equal to 1
We have n
1
+ n
2
+ n
3
+ n
4
= 47
using beggar
47
3
0 0 0 ..... 0 0 0 0
_
_

50
3
50.49.48 n
C 19600
6 100
= = = =
n
196
100
=

Concept Recap Test Mains 5 Sol

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Drepturi de autor:

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Concept Recap Test Mains 5 Sol

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Drepturi de autor:

Formate disponibile

AITS-CRT(Set-V)-PCM(S)-JEE(Main)/13

, k = spring constant of the uncut spring.

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