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MEPC 59/24/Add.

ANNEX 2 RESOLUTION MEPC.179(59) Adopted on 17 July 2009 GUIDELINES FOR THE DEVELOPMENT OF THE INVENTORY OF HAZARDOUS MATERIALS THE MARINE ENVIRONMENT PROTECTION COMMITTEE, RECALLING Article 38(a) of the Convention on the International Maritime Organization concerning the functions of the Marine Environment Protection Committee conferred upon it by the international conventions for the prevention and control of marine pollution, RECALLING ALSO that the International Conference on the Safe and Environmentally Sound Recycling of Ships held in May 2009 adopted the Hong Kong International Convention for the Safe and Environmentally Sound Recycling of Ships, 2009 (the Hong Kong Convention) together with six Conference resolutions, NOTING that regulations 5.1 and 5.2 of the Annex to the Hong Kong Convention require that ships shall have on board an Inventory of Hazardous Materials which shall be prepared and verified taking into account Guidelines, including any threshold values and exemptions contained in those Guidelines, developed by the Organization, NOTING ALSO that regulation 5.3 of the Annex to the Hong Kong Convention requires that Part I of the Inventory of Hazardous Materials shall be properly maintained and updated throughout the operational life of the ship, taking into account the Guidelines developed by the Organization, NOTING FURTHER that regulation 5.4 of the Annex to the Hong Kong Convention requires that the Inventory shall also incorporate Part II for operationally generated wastes and Part III for stores and shall be verified, taking into account the Guidelines developed by the Organization, RECALLING that the International Conference on the Safe and Environmentally Sound Recycling of Ships, in its resolution 4, invited the Organization to develop Guidelines for global, uniform and effective implementation and enforcement of the relevant requirements of the Convention as a matter of urgency, HAVING CONSIDERED, at its fifty-ninth session, the draft Guidelines for the development of the inventory of hazardous materials developed by the Working Group on Guidelines for Ship Recycling, 1. ADOPTS the Guidelines for the development of the inventory of hazardous materials as set out in the Annex to this resolution; 2. INVITES Governments to apply the Guidelines as soon as possible, or when the Convention becomes applicable to them; and 3. AGREES to keep the Guidelines under review. ***
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MEPC 59/24/Add.1 ANNEX 2 Page 2 ANNEX GUIDELINES FOR THE DEVELOPMENT OF THE INVENTORY OF HAZARDOUS MATERIALS

1 1.1

Introduction Objectives of the Guidelines

These Guidelines provide recommendations for developing the Inventory of Hazardous Materials (hereinafter referred to as the Inventory) to assist compliance with regulation 5 (Inventory of Hazardous Materials) of the Hong Kong International Convention for the Safe and Environmentally Sound Recycling of Ships, 2009 (hereinafter referred to as the Convention). 1.2 Application of the Guidelines

These Guidelines have been developed to provide relevant stakeholders (e.g., shipbuilders, equipment suppliers, repairers, shipowners and ship management companies) with the essential requirements for practical and logical development of the Inventory. 1.3 Objectives of the Inventory

The objectives of the Inventory are to provide ship-specific information on the actual Hazardous Materials present on board, in order to protect health and safety and to prevent environmental pollution at Ship Recycling Facilities. This information will be used by the Ship Recycling Facilities in order to decide how to manage the types and amounts of materials identified in the Inventory of Hazardous Materials (regulation 9). 2 Definitions

The terms used in these Guidelines have the same meaning as those defined in the Convention, with the following additional definitions which apply to these Guidelines only. Homogeneous material means a material of uniform composition throughout that cannot be mechanically disjointed into different materials, meaning that the materials cannot, in principle, be separated by mechanical actions such as unscrewing, cutting, crushing, grinding and abrasive processes. Product means machinery, equipment, materials and applied coatings on board a ship. Supplier means a company which provides products; which may be a manufacturer, trader or agency. Supply chain means the series of entities involved in the supply and purchase of materials and goods, from raw materials to final product. Threshold level is defined as the concentration value in homogeneous materials.

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MEPC 59/24/Add.1 ANNEX 2 Page 3 3 3.1 Requirements for the Inventory Scope of the Inventory

The Inventory consists of: Part I: Materials contained in ship structure or equipment; Part II: Operationally generated wastes; and Part III: Stores. 3.2 Materials to be listed in the Inventory

Appendix 1 of the Guidelines, Items to be listed in the Inventory of Hazardous Materials, provides information on the Hazardous Materials that may be found on board a ship. Materials set out in appendix 1 should be listed in the Inventory. Each item in appendix 1 of these Guidelines is classified under Table A, Table B, Table C or Table D according to its properties: .1 .2 .3 Table A comprises the materials listed in appendix 1 of the Convention; Table B comprises the materials listed in appendix 2 of the Convention; Table C (Potentially hazardous items) comprises items which are potentially hazardous to the environment and human health at Ship Recycling Facilities; and Table D (Regular Consumable Goods potentially containing Hazardous Materials) comprises goods which are not integral to a ship and are unlikely to be dismantled or treated at a Ship Recycling Facility.

.4

Table A and Table B correspond to Part I of the Inventory. Table C corresponds to Parts II and III and Table D corresponds to Part III. 3.3 Materials not required to be listed in the Inventory

Materials listed in Table B that are inherent in solid metals or metal alloys, provided they are used in general construction, such as hull, superstructure, pipes, or housings for equipment and machinery are not required to be listed in the Inventory. 3.4 Standard format of the Inventory of Hazardous Materials

The Inventory should be developed on the basis of the standard format set out in appendix 2 of these Guidelines: Standard format of the Inventory of Hazardous Materials. Examples of how to complete the Inventory are provided for guidance purposes only. 4 4.1 Requirements for development of the Inventory Development of Part I of the Inventory for new ships

4.1.1 Part I of the Inventory for new ships should be developed at the design and construction stage.
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MEPC 59/24/Add.1 ANNEX 2 Page 4 4.1.2 Checking of materials listed in Table A

During the development of the Inventory (Part I), the presence of materials listed in Table A of appendix 1 should be checked and confirmed; the quantity and location of Table A materials should be listed in Part I of the Inventory. If such materials are used in compliance with the Convention, they should be listed in Part I of the Inventory. Any spare parts containing materials listed in Table A are required to be listed in Part III of the Inventory. 4.1.3 Checking of materials listed in Table B

If materials listed in Table B of appendix 1 are present in products above the threshold levels provided in Table B, the quantity and location of the products and the contents of the materials present in them should be listed in Part I of the Inventory. Any spare parts containing materials listed in Table B are required to be listed in Part III of the Inventory. 4.1.4 Process for checking of materials The checking of materials as provided in paragraphs 4.1.2 and 4.1.3 above should be based on the Material Declaration furnished by the suppliers in the shipbuilding supply chain (e.g., equipment suppliers, parts suppliers, material suppliers). 4.2 Development of Part I of the Inventory for existing ships

In order to achieve comparable results for existing ships with respect to Part I of the Inventory, the following procedure should be followed. The procedure is based on the following steps: .1 .2 .3 .4 .5 collection of necessary information; assessment of collected information; preparation of visual/sampling check plan; onboard visual check and sampling check; and preparation of Part I of the Inventory and related documentation.

The determination of Hazardous Materials present on board existing ships should, as far as practicable, be conducted as prescribed for new ships, including the procedures described in section 6 and 7 of these Guidelines. Alternatively the procedures described in subsection 4.2 may be applied for existing ships, but these procedures should not be used for any new installation resulting from the conversion or repair of existing ships after the initial preparation of the Inventory. The procedures described in subsection 4.2 should be carried out by the shipowner, who may draw upon expert assistance. Such an expert or expert party should not be the same as the person or organization authorized by the Administration to approve the Inventory. Please refer to appendix 4: Flow diagram for developing Part I of the Inventory for existing ships; and appendix 5: Typical example of development process for Part I of the Inventory for existing ships.
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MEPC 59/24/Add.1 ANNEX 2 Page 5 4.2.1 Collection of necessary information (Step 1)

The shipowner should identify, research, request, and procure all reasonably available documentation regarding the ship. Information that will be useful includes maintenance, conversion, and repair documents; certificates, manuals, ships plans, drawings, and technical specifications; product information data sheets (such as Material Declarations); and hazardous material inventories or recycling information from sister ships. Potential sources of information could include previous shipowners, the ship builder, historical societies, classification society records, and ship recycling facilities with experience working with similar ships. 4.2.2 Assessment of collected information (Step 2)

The information collected in Step 1 above should be assessed. The assessment should cover all materials listed in Table A of appendix 1; materials listed in Table B should be listed as far as practicable. The results of the assessment should be reflected in the visual/sampling check plan. 4.2.3 Preparation of visual/sampling check plan (Step 3)

To specify the materials listed in appendix 1 of these Guidelines a visual/sampling check plan should be prepared taking into account the collated information and any appropriate expertise. The visual/sampling check plan based on the following three lists: List of equipment, system and/or area for visual check (any equipment, system and/or area specified regarding the presence of the materials listed in appendix 1 by document analysis should be entered in the List of equipment, system and/or area for visual check); List of equipment, system and/or area for sampling check (any equipment, system and/or area which cannot be specified regarding the presence of the materials listed in appendix 1 by document or visual analysis should be entered in the List of equipment, system and/or area as requiring sampling check. A sampling check is the taking of samples to identify the presence or absence of Hazardous Material contained in the equipment, systems, and/or areas, by suitable and generally accepted methods such as laboratory analysis); and List of equipment, system and/or area classed as potentially containing Hazardous Material (any equipment, system and/or area which cannot be specified regarding the presence of the materials listed in appendix 1 by document analysis may be entered in the List of equipment, system and/or area classed as potentially containing Hazardous Material without the sampling check. The prerequisite for this classification is a comprehensible justification as to the impossibility of conducting sampling without compromising the safety of the ship and its operational efficiency).

Visual/sampling checkpoints should be all points where: the presence of materials to be considered for the Inventory Part I as listed in appendix 1 is likely;

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MEPC 59/24/Add.1 ANNEX 2 Page 6 4.2.4 the documentation is not specific; or materials of uncertain composition were used.

Onboard visual/sampling check (Step 4)

The onboard visual/sampling check should be carried out in accordance with the visual/sampling check plan. When a sampling check is carried out, samples should be taken and the sample points should be clearly marked on the ship plan and the sample results referenced. Materials of the same kind may be sampled in a representative manner. Such materials are to be checked to ensure that they are of the same kind. The sampling check should be carried out drawing upon expert assistance. Any uncertainty regarding the presence of Hazardous Materials should be clarified by a visual/sampling check. Checkpoints should be documented in the ships plan and may be supported by photographs. If the equipment, system and/or area of the ship are not accessible for a visual check or sampling check, they should be classified as potentially containing Hazardous Material. The prerequisite for such classification should be the same prerequisite as in section 4.2.3. Any equipment, system and/or area classed as potentially containing Hazardous Material may be investigated or subjected to a sampling check at the request of the shipowner during a later survey (e.g., during repair, refit or conversion). 4.2.5 Preparation of Part I of the Inventory and related documentation (Step 5)

If any equipment, system and/or area is classed as either containing Hazardous Material or potentially containing Hazardous Material, their approximate quantity and location should be listed in Part I of the Inventory. These two categories should be indicated separately in the remarks column of the Inventory of Hazardous Materials. 4.2.6 Diagram of the location of Hazardous Materials on board a ship

Preparation of a diagram showing the location of the materials listed in Table A is recommended in order to help Ship Recycling Facilities gain a visual understanding of the Inventory. 4.3 Maintaining and updating Part I of the Inventory during operations

4.3.1 Part I of the Inventory should be appropriately maintained and updated, especially after any repair or conversion or sale of a ship. 4.3.2 Updating of Part I of the Inventory in the event of new installation

If any machinery or equipment is added to, removed or replaced or the hull coating is renewed, Part I of the Inventory should be updated according to the requirements for new ships as stipulated in subsections 4.1.2 to 4.1.4. Updating is not required if identical parts or coatings are installed or applied.

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MEPC 59/24/Add.1 ANNEX 2 Page 7 4.3.3 Continuity of Part I of the Inventory

Part I of the Inventory should belong to the ship and the continuity and conformity of the information it contains should be confirmed, especially if the flag, owner or operator of the ship changes. 4.4 Development of Part II of the Inventory (operationally generated waste)

4.4.1 Once the decision to recycle a ship has been taken, Part II of the Inventory should be developed before the final survey, taking into account that a ship destined to be recycled shall conduct operations in the period prior to entering the Ship Recycling Facility in a manner that minimizes the amount of cargo residues, fuel oil and wastes remaining on board (regulation 8.2). 4.4.2 Operationally generated wastes to be listed in the Inventory

If the wastes listed in Part II of the Inventory provided in Table C (Potentially hazardous items) of appendix 1 are intended for delivery with the ship to a Ship Recycling Facility, the quantity of the operationally generated wastes should be estimated and their approximate quantities and locations should be listed in Part II of the Inventory. 4.5 Development of Part III of the Inventory (stores)

4.5.1 Once the decision to recycle has been taken, Part III of the Inventory should be developed before the final survey, taking into account the fact that a ship destined to be recycled shall minimize the wastes remaining on board (regulation 8.2). Each item listed in Part III should correspond to the ships operations during its last voyage. 4.5.2 Stores to be listed in the Inventory

If the stores to be listed in Part III of the Inventory provided in Table C of appendix 1 are to be delivered with the ship to a Ship Recycling Facility, the unit (e.g., capacity of cans and cylinders), quantity and location of the stores should be listed in Part III of the Inventory. 4.5.3 Liquids and gases sealed in ships machinery and equipment to be listed in the Inventory

If any liquids and gases listed in Table C of appendix 1 are integral in machinery and equipment on board a ship, their approximate quantity and location should be listed in Part III of the Inventory. However, small amounts of lubricating oil, anti-seize compounds and grease which are applied to or injected into machinery and equipment to maintain normal performance do not fall within the scope of this provision. For subsequent completion of Part III of the Inventory during the recycling preparation processes, the quantity of liquids and gases listed in Table C of appendix 1 required for normal operation, including the related pipe system volumes, should be prepared and documented at the design and construction stage. This information belongs to the ship, and continuity of this information should be maintained if the flag, owner or operator of the ship changes. 4.5.4 Regular consumable goods to be listed in the Inventory

Regular consumable goods, as provided in Table D of appendix 1should not be listed in Part I or Part II but should be listed in Part III of the Inventory if they are to be delivered with the ship to a Ship Recycling Facility. A general description including the name of item (e.g., TV set),
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MEPC 59/24/Add.1 ANNEX 2 Page 8 manufacturer, quantity and location should be entered in Part III of the Inventory. The check on materials provided for in paragraphs 4.1.2 and 4.1.3 of the Guidelines does not apply to regular consumable goods. 4.6 Description of location of Hazardous Materials on board

The locations of Hazardous Materials on board should be described and identified using the name of location (e.g., second floor of Engine-room, Bridge DK, APT, No.1 Cargo Tank, Frame number) given in the plans (e.g., General Arrangement, Fire and Safety Plan, Machinery Arrangement or Tank Arrangement). 4.7 Description of approximate quantity of Hazardous Materials

In order to identify the approximate quantity of Hazardous Materials, the standard unit used for the of Hazardous Materials should be kg, unless other units (e.g., m3 for materials of liquid or gases, m2 for materials used in floors or walls) are considered more appropriate. An approximate quantity should be rounded up to at least two significant figures. 5 5.1 Requirements for ascertaining the conformity of the Inventory Design and construction stage

The conformity of Part I of the Inventory at the design and construction stage should be ascertained by reference to the collected Suppliers Declaration of Conformity described in section 7 and the related Material Declarations collected from suppliers. 5.2 Operational stage

Shipowners should implement the following measures in order to ensure the conformity of Part I of the Inventory: .1 designate a person as responsible for maintaining and updating the Inventory (the designated person may be employed ashore or on board); the designated person, in order to implement subsection 4.3.2, should establish and supervise a system to ensure the necessary updating of the Inventory in the event of new installation; to maintain the Inventory including dates of changes or new deleted entries and the signature of the designated person; and provide related documents as required for the survey or sale of the ship.

.2

.3

.4 6 6.1

Material Declaration General

Suppliers to the shipbuilding industry should identify and declare whether or not the materials listed in Table A or Table B are present above the threshold level specified in appendix 1 of these Guidelines. However, this provision does not apply to chemicals which do not constitute a part of the finished product.
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MEPC 59/24/Add.1 ANNEX 2 Page 9 6.2 Information required in the declaration

At a minimum the following information is required in the Material Declaration: .1 .2 .3 .4 .5 .6 date of declaration; Material Declaration identification number; suppliers name; product name (common product name or name used by manufacturer); product number (for identification by manufacturer); declaration of whether or not the materials listed in Table A and Table B of appendix 1 of these Guidelines are present in the product above the threshold level stipulated in appendix 1 of these Guidelines; and mass of each constituent material listed in Table A and/or Table B of appendix 1 of these Guidelines if present above threshold level.

.7

An example of a Material Declaration is shown in appendix 6. 7 7.1 Suppliers Declaration of Conformity Purpose and scope

The purpose of the Suppliers Declaration of Conformity is to provide assurance that the related Material Declaration conforms to section 6.2, and to identify the responsible entity. The Suppliers Declaration of Conformity remains valid as long as the products are present on board. The supplier compiling the Suppliers Declaration of Conformity should establish a company policy1. The company policy on the management of the chemical substances in products which the supplier manufactures or sells should cover: .a Compliance with law: The regulations and requirements governing the management of chemical substances in products should be clearly described in documents which should be kept and maintained; and .b Obtaining of information on chemical substance content: In procuring raw materials for components and products, suppliers should be selected following an evaluation, and the information on the chemical substances they supply should be obtained.
1

A recognized quality management system may be utilized.

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MEPC 59/24/Add.1 ANNEX 2 Page 10 7.2 Contents and format

The Suppliers Declaration of Conformity should contain the following: .1 .2 .3 unique identification number; name and contact address of the issuer; identification of the subject of the Declaration of Conformity (e.g., name, type, model number, and/or other relevant supplementary information); statement of conformity; date and place of issue; and signature (or equivalent sign of validation), name and function of the authorized person(s) acting on behalf of the issuer.

.4 .5 .6

An example of the Suppliers Declaration of Conformity is shown in appendix 7. 8 List of appendices Appendix 1: Appendix 2: Appendix 3: Items to be listed in the Inventory of Hazardous Materials Standard format of the Inventory of Hazardous Materials Example of the development process for Part I of the Inventory for new ships Flow diagram for developing Part I of the Inventory for existing ships Example of the development process for Part I of the Inventory for existing ships Form of Material Declaration Form of Suppliers Declaration of Conformity Examples of Table A and Table B materials of appendix 1 with CAS-numbers

Appendix 4: Appendix 5:

Appendix 6: Appendix 7: Appendix 8:

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MEPC 59/24/Add.1 ANNEX 2 Page 11 APPENDIX 1 ITEMS TO BE LISTED IN THE INVENTORY OF HAZARDOUS MATERIALS
TABLE A* Materials listed in appendix 1 of the Annex to the Convention

Inventory No. Materials Part I A-1 A-2 Asbestos Polychlorinated biphenyls (PCBs) CFCs Halons Other fully halogenated CFCs Carbon tetrachloride A-3 Ozone Depleting Substances 1,1,1-Trichloroethane (Methyl chloroform) Hydrochlorofluorocarbons Hydrobromofluorocarbons Methyl bromide Bromochloromethane Anti-fouling systems containing organotin compounds as a biocide x x x x x x x x x x x x Part II Part III

Threshold level no threshold level no threshold level

no threshold level

A-4

2500 mg total tin/kg

TABLE B* Materials listed in appendix 2 of the Annex to the Convention

No. B-1 B-2 B-3 B-4 B-5 B-6 B-7 B-8 B-9

Materials Part I Cadmium and cadmium compounds Hexavalent chromium and hexavalent chromium compounds Lead and lead compounds Mercury and mercury compounds Polybrominated biphenyl (PBBs) Polybrominated diphenyl ethers (PBDEs) Polychlorinated naphthalenes (more than 3 chlorine atoms) Radioactive substances Certain shortchain chlorinated paraffins (Alkanes, C10-C13, chloro) x x x x x x x x x

Inventory Part II Part III

Threshold level

100 mg/kg 1,000 mg/kg 1,000 mg/kg 1,000 mg/kg 1,000 mg/kg 1,000 mg/kg no threshold level no threshold level 1%

For materials in this Table with no threshold level, quantities occurring as unintentional trace contaminants should not be listed in Material Declarations and in the Inventory.

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MEPC 59/24/Add.1 ANNEX 2 Page 12

TABLE C Potentially hazardous items No. C-1 C-2 C-3 C-4 C-5 C-6 C-7 C-8 C-9 C-10 C-11 C-12 C-13 C-14 C-15 C-16 C-17 C-18 C-19 C-20 C-21 C-22 C-23 C-24 C-25 C-27 C-28 C-29 C-30 C-31 C-32 C-33 C-34 C-35 C-36 C-37 C-38 Gas Explosibility/ inflammability Liquid Oiliness Gas Green House Gases Explosives/ inflammables Liquid Oiliness Properties Kerosene White spirit Lubricating oil Hydraulic oil Anti-seize compounds Fuel additive Engine coolant additives Antifreeze fluids Boiler and feed water treatment and test re-agents De-ioniser regenerating chemicals Evaporator dosing and descaling acids Paint stabilizers/rust stabilizers Solvents/thinners Paints Chemical refrigerants Battery electrolyte Alcohol, methylated spirits Acetylene Propane Butane Oxygen CO2 Perfluorocarbons (PFCs) Methane Hydrofluorocarbon (HFCs) Nitrous oxide(N2O) Sulfur hexafluoride (SF6) Bunkers: fuel oil Grease Waste oil (sludge) Bilge Oily liquid cargo tank residues Ballast water Raw sewage Treated sewage Non-oily liquid cargo residues Fuel gas x x x x x x x x Goods Part I Inventory Part II Part III x x x x x x x x x x x x x x x x x x x x x x x x x x x x x

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MEPC 59/24/Add.1 ANNEX 2 Page 13

TABLE C Potentially hazardous items No. C-39 C-40 C-41 C-42 C-43 C-45 C-45 C-46 C-47 C-48 C-49 C-50 C-51 C-52 C-53 C-54 C-55 Solid Properties Goods Part I Dry cargo residues Medical waste/infectious waste Incinerator ash2) Garbage
2)

Inventory Part II x x x x x x x x x x x x x x x x x Part III

Fuel tank residues Oily solid cargo tank residues Oily/contaminated rags Batteries (incl. lead acid batteries) Pesticides/insecticide sprays Extinguishers Chemical cleaner (incl. electrical equipment cleaner, carbon remover) Detergent/bleacher (could be a liquid) Miscellaneous medicines Fire fighting clothing and equipment Dry tank residues Cargo residues Spare parts which contain materials listed in Table A or Table B

2)

Definition of garbage is identical to that in MARPOL Annex V. However, incinerator ash is classified separately because it may include hazardous substances or heavy metals.

TABLE D Regular consumable goods potentially containing Hazardous Materials No. Properties Example Part I Domestic and accommodation appliances Computers, refrigerators, printers, scanners, television sets, radio sets, video cameras, video recorders, telephones, consumer batteries, fluorescent lamps, filament bulbs, lamps Inventory Part II Part III

D-1

This Table does not include ship specific equipment integral to ship operations, which has to be listed in Part I of the Inventory.

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MEPC 59/24/Add.1 ANNEX 2 Page 14

APPENDIX 2 STANDARD FORMAT OF THE INVENTORY OF HAZARDOUS MATERIALS


Part I HAZARDOUS MATERIALS CONTAINED IN THE SHIPS STRUCTURE AND EQUIPMENT

I-1 Paints and coating systems containing materials listed in Table A and Table B of appendix 1 of the Guidelines
Materials (classification in appendix 1)

No.

Application of paint

Name of paint

Location

Approx. quantity

Remarks

1 2

Anti-drumming compound Primer, xx Co., xx primer #300 Hull part Anti-fouling xx Co., xx coat #100 Underwater parts

Lead TBT

35.00 120.00

kg kg

I-2 Equipment and machinery containing materials listed in Table A and Table B of appendix 1 of the Guidelines
Materials (classification in appendix 1) Cadmium Mercury Cadmium Cadmium Lead Approx. quantity

No.

Name of equipment and machinery

Location

Parts where used

Remarks

1 2 3 4

Switch board Diesel engine, xx Co., xx #150 Diesel engine, xx Co., xx #200 Diesel generator (x 3)

Engine control room Engine room Engine-room Engine-room

Housing coating Heat gauge Bearing Bearing Ingredient of copper compounds

0.02 <0.01 0.02 0.01 0.01

kg kg kg kg kg Revised by XXX on Oct. XX, 2008 less than 0.01kg

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MEPC 59/24/Add.1 ANNEX 2 Page 15

I-3 Structure and hull containing materials listed in Table A and Table B of appendix 1 of the Guidelines
Materials (classification in appendix 1) Asbestos Lead Asbestos Parts where used Approx. quantity

No.

Name of structural element

Location

Remarks

1 2 3

Wall panel Wall insulation

Accommodation Engine control room

Insulation perforated plate Insulation

2,500.00 kg 0.01 kg cover for insulation material 25.00 kg under perforated plates

Part II
No. 1 2 3 4 5

OPERATIONALLY GENERATED WASTE


Location1) Garbage locker Bilge tank No.1 cargo hold No.2 cargo hold No.1 ballast tank Sediments 250.00 kg Name of item (classification in appendix 1) and detail (if any) of the item Garbage (food waste) Bilgewater Dry cargo residues (iron ore) Waste oil (sludge) (crude) Ballast water Approx. quantity 35.00 15.00 110.00 120.00 2,500.00 kg m3 kg kg m3 Remarks

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MEPC 59/24/Add.1 ANNEX 2 Page 16

Part III STORES III-1 Stores


No. 1 2 3 4 5 Location1) No.1 fuel oil tank CO2 room Workshop Medicine locker Paint stores Name of item (classification in appendix 1) Fuel oil (heavy fuel oil) CO2 Propane Miscellaneous medicines Paint, xx Co., #600 Unit quantity 100.00 kg 20.00 kg 20.00 kg Figure Approx. quantity 100.00 m3 kg kg Details are shown in the attached list. 100.00 kg Cadmium containing. Remarks2)

50 bottles 5,000.00 10 5 pcs pcs 200.00

III-2 Liquids sealed in ships machinery and equipment


No. Type of liquids (classification in appendix 1) Hydraulic oil Name of machinery or equipment Location Approx. quantity 15.00 200.00 0.55 0.45 0.20 m3 m3 m3 m3 m3 Remarks

Deck crane hydraulic oil system Deck machinery hydraulic oil system Steering gear hydraulic oil system

Upper deck Upper deck and bosun store Steering gear room Engine-room Engine-room

2 3

Lubricating oil Boiler water treatment

Main engine system Boiler

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MEPC 59/24/Add.1 ANNEX 2 Page 17

III-3 Gases sealed in ships machinery and equipment


No. Type of gases (classification in appendix 1) HFC HFC Name of machinery or equipment Location Approx. quantity 100.00 50.00 kg kg Remarks

1 2

AC system Refrigerated provision chamber machine

AC room AC room

III-4 Regular consumable goods potentially containing Hazardous Materials


No. 1 2 Location1) Accommodation Accommodation Refrigerators Personal computers Name of item Quantity 1 2 Remarks

1) 2)

The location of a Part II or Part III item should be entered in order based on its location, from a lower level to an upper level and from a fore part to an aft part. The location of Part I items is recommended to be described similarly, as far as practicable. In column Remarks for Part III items, if Hazardous Materials are integrated in products, the approximate amount of the contents should be shown as far as possible.

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MEPC 59/24/Add.1 ANNEX 2 Page 18 APPENDIX 3 EXAMPLE OF THE DEVELOPMENT PROCESS FOR PART I OF THE INVENTORY FOR NEW SHIPS

Objective of the typical example

This example has been developed to give guidance and to facilitate understanding of the development process for Part I of the Inventory of Hazardous Materials for new ships. 2 Development flow for Part I of the Inventory

Part I of the Inventory should be developed using the following 3 steps. However, the order of these steps is flexible and can be changed depending on the schedule of shipbuilding: .1 .2 .3 3 3.1 collection of Hazardous Materials information; utilization of Hazardous Materials information; and preparation of the Inventory (by filling out standard format).

Collection of Hazardous Materials information Data collection process for Hazardous Materials

Materials Declaration (MD) and Suppliers Declaration of Conformity (SDoC) for products from suppliers (tier 1 suppliers) should be requested and collected by the shipbuilding yard. Tier 1 suppliers may request from their suppliers (tier 2 suppliers) the relevant information if they cannot develop the MD based on the information available. Thus the collection of data on Hazardous Materials may involve the entire shipbuilding supply chain (Figure 1).

List Request
MD

MD

MD

MD

Request
MD

Shipbuilder

Submit

Equipment supplier (tier 1)

Submit

Equipment supplier (tier 2)

MD

MD

MD

MD

Figure 1 Process of MD (and SDoC) collection showing involvement of supply chain

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MEPC 59/24/Add.1 ANNEX 2 Page 19 3.2 Declaration of Hazardous Materials

Suppliers should declare whether or not the Hazardous Materials listed in Table A and Table B in the MD are present in concentrations above the threshold levels specified for each homogeneous material in a product. 3.2.1 Materials listed in Table A If one or more materials listed in Table A are found to be present in concentrations above the specified threshold level according to the MD, the products which contain these materials shall not be installed on a ship. However, if the materials are used in a product in accordance with an exemption specified by the Convention (e.g., new installations containing hydrochlorofluorocarbons (HCFCs) before 1 January 2020), the product should be listed in the Inventory. 3.2.2 Materials listed in Table B If one or more materials listed in Table B are found to be present in concentrations above the specified threshold level according to the MD, the products should be listed in the Inventory. 3.3 Example of Homogeneous Materials

Figure 2 shows an example of four homogeneous materials which constitute a cable. In this case, sheath, intervention, insulator and conductor are all individual homogeneous materials.
Sheath (PVC) Intervention (paper) Insulator (rubber) Conductor (copper)

Figure 2 Example of Homogeneous Materials (cable)

Utilization of Hazardous Materials information

Products which contain Hazardous Materials in concentrations above the specified threshold levels should be clearly identified in the MD. The approximate quantity of the Hazardous Materials should be calculated if the mass data for Hazardous Materials are declared in the MD using a unit which cannot be directly utilized in the Inventory. 5 Preparation of Inventory (by filling out standard format)

The information received for the Inventory, as contained in Table A and Table B of appendix 1of these Guidelines, ought to be structured and utilized according to the following categorization for Part I of the Inventory:

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MEPC 59/24/Add.1 ANNEX 2 Page 20 1.1 1.2 1.3 5.1 5.1.1 Paints and coating systems; Equipment and machinery; and Structure and hull.

Name of equipment and machinery column Equipment and machinery

The name of each equipment or machinery should be entered in this column. If more than one Hazardous Material is present in the equipment or machinery, the row relating to that equipment or machinery should be appropriately divided such that all of the Hazardous Materials contained in the piece of equipment or machinery are entered. If more than one item of equipment or machinery is situated in one location, both name and quantity of the equipment or machinery should be entered in the column. For identical common or mass-produced items, such as bolts, nuts and valves, there is no need to list each item individually. An example is shown in Table 1. Table 1 Example showing more than one item of equipment or machinery situated in one location
Name of equipment Location and machinery Materials
(classification in appendix 1)

No.

Parts where used

Approx. quantity 0.75 0.01 0.03 kg kg

Remarks

Lead Main engine Engine-room Mercury Diesel generator (x 3) Engine-room Mercury

Piston pin bush Thermometer charge air temperature Thermometer

5.1.2

Pipes and cables

The names of pipes and of systems, including electric cables, which are often situated in more than one compartment of a ship, should be described using the name of the system concerned. A reference to the compartments where these systems are located is not necessary as long as the system is clearly identified and properly named. 5.2 Approximate quantity column

The standard unit for approximate quantity of solid Hazardous Materials should be kg. If the Hazardous Materials are liquids or gases, the standard unit should be either m3 or kg. An approximate quantity should be rounded up to at least two significant figures. If the Hazardous Material is less than 10 g, the description of the quantity should read <0.01 kg.

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MEPC 59/24/Add.1 ANNEX 2 Page 21 Table 2 Example of a switchboard


Name of equipment Location and machinery Engine control room Materials
(classification appendix 1) in

No.

Parts where used

Approx. quantity 0.02 kg

Remarks

Cadmium Mercury

Housing coating Heat gauge

Switchboard

<0.01 kg

less than 0.01kg

5.3 5.3.1

Location column Example of a location list

It is recommended to prepare a location list which covers all compartments of a ship based on the ships plans (e.g., General Arrangement, Engine-room Arrangement, Accommodation and Tank Plan) and on other documentation on board, including certificates or spare parts lists. The description of the location should be based on a location such as a deck or room to enable easy identification. The name of the location should correspond to the ships plans so as to ensure consistency between the Inventory and the ships plans. Examples of names of locations are shown in Table 3. Table 3 Examples of location names
(A) Primary classification
All over the ship Hull part

(B) Secondary classification


Fore part Cargo part

(C) Name of location


Bosun store No.1 Cargo Hold/Tank No.1 Garage deck Fore Peak Tank No.1 WBT No.1 FOT Aft Peak Tank Steering Gear Room Emergency Fire Pump Space Accommodation Compass deck Nav. Bridge deck Wheel House Engine Control Room Cargo Control Room Deck House

Tank part

Aft part

Superstructure

Deck house

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MEPC 59/24/Add.1 ANNEX 2 Page 22


(A) Primary classification
Machinery part

(B) Secondary classification


Engine-room

(C) Name of location


Engine-room Main Floor 2nd Floor Generator Space/Room Purifier Space/Room Shaft Space/Room Engine Casing Funnel Engine Control Room Pump-room Superstructure Upper deck Hull shell bottom under waterline

Pump-room Exterior part Superstructure Upper deck Hull shell

5.3.2

Description of location of pipes and electrical systems

Locations of pipes and systems, including electrical systems and cables situated in more than one compartment of a ship, should be described for each system concerned. If they are situated in a number of compartments, the most practical of the following two options should be used: a) b) listing of all components in the column; or description of the location of the system using an expression such as those shown under primary classification and secondary classification in Table 3.

A typical description of a pipe system is shown in Table 4. Table 4 Example of description of a pipe system
Name of equipment Location and machinery Ballast water system Engine-room, Hold parts Materials
(classification in appendix 1)

No.

Parts used

where Approx. quantity

Remarks

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MEPC 59/24/Add.1 ANNEX 2 Page 23 APPENDIX 4 FLOW DIAGRAM FOR DEVELOPING PART I OF THE INVENTORY FOR EXISTING SHIPS
Step1 Step2

Collection of necessary information Analysis and Definition of scope of assessment

*1 *2

*1 : Documents may include any certificates, manuals, ships plans drawings, technical specifications and information from sister and/or similar ships. *2 : The assessment should cover all materials listed in Table A of Appendix 1 of the Guideline; the materials listed in Table B should be listed as far as practicable. It is impossible to assess all equipment and areas including those which are assumed not to contain Hazardous Materials described above. Using analysis of available documents based on knowledge and experience, it must be made clear which equipment and/or area should be included in the scope of the assessment.

Can you recognize what it contains by document (Confirm by visual analysis? check)

YES

NO

(Confirm by sampling check)

Step3

NO
Visual check plan Sampling check plan

Can you exempt sampling analysis according to a criterion?

*3
YES

List of equipment, system and/or area potentially containing Hazardous Material

Preparation of visual/sampling check p lan

*3 : Equipment, system and/or areas which cannot be specified as containing materials listed in appendix 1 of these guidelines on the basis of documents can be listed in the List of equipment, system and/or area classed as potentially containing Hazardous Material without the sampling check. The prerequisite for this classification is a comprehensible justification of the conclusion, such as the impossibility to conduct samplings without compromising ship safety and operational efficiency.

Onboard visual check , sampling check

*4
*4 : Sampling Check. This means sampling and identification of Hazardous Material contained in the equipment, systems, and/or areas, by laboratory analysis. The sampling check should be applied where the presence of Prohibited and Restricted Hazardous Material is assumed but cannot be recognized by analysis of the available documentation.

Was visual checking/sampling actually possible?

*5 NO

Step4

YES
Does it contain Hazardous Material?

NO

Listing not necessary

*5 : When equipment, systems and/or areas of a ship are not accessible for visual check or sampling check, this equipment, system and/or area is classified as potentially containing Hazardous Material.

YES
Equipment, system and/or area classed as containing Hazardous Material Equipment, system and/or area classed as potentially containing Hazardous Material

Step5

Preparation of Inventory Part I


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MEPC 59/24/Add.1 ANNEX 2 Page 24 APPENDIX 5 EXAMPLE OF THE DEVELOPMENT PROCESS FOR PART I OF THE INVENTORY FOR EXISTING SHIPS 1 Introduction

In order to develop Part I of the Inventory of Hazardous Materials for existing ships, documents of the individual ship as well as the knowledge and experience of specialist personnel (experts) is required. An example of the development process for Part I of the Inventory of Hazardous Materials for existing ships is useful to understand the basic steps as laid out in the Guidelines and to ensure a unified application. However, attention should be paid to variations in different types of ships1). Compilation of Part I of the Inventory of Hazardous Material for existing ships involves the following 6 steps which are described in paragraph 4.2 and appendix 4 of these Guidelines. Step 1: Step 2: Step 3: Step 4: Step 5:
___________

Collection of necessary information; Assessment of collected information; Preparation of visual/sampling check plan; Onboard visual/sampling check; and Preparation of Part I of the Inventory and related documentation.

1) The example of a 28,000 gross tonnage bulk carrier constructed in 1985 is used in this appendix.

2 2.1

Step 1: Collection of necessary information Sighting of available documents

A practical first step is to collect detailed documents for the ship. The shipowner should try to collate documents normally retained onboard the ship or by the shipping company as well as relevant documents that the shipyard, manufacturers, or classification society may have. The following documents should be used when available: Ships specification General Arrangement Machinery Arrangement Spare Parts and Tools List Piping Arrangement Accommodation Plan Fire Control Plan Fire Protection Plan Insulation Plan (Hull and Machinery) International Anti-Fouling System Certificate Related manuals and drawings Information from other inventories and/or sister or similar ships, machinery, equipment, materials and coatings Results of previous visual/sampling checks and other analysis If the ship has undergone conversions or major repair work, it is necessary to identify as far as possible the modifications from the initial design and specification of the ship.
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MEPC 59/24/Add.1 ANNEX 2 Page 25 2.2 Indicative list

It is impossible to check all equipment, systems, and/or areas on board the ship to determine the presence or absence of Hazardous Materials. The total number of parts on board may exceed several thousand. In order to take a practical approach, an Indicative list should be prepared that identifies the equipment, system, and/or area on board that is presumed to contain Hazardous Materials. Field interviews with the shipyard and suppliers may be necessary to prepare such lists. A typical example of an Indicative list is shown below: 2.2.1 Materials to be checked and documented

Hazardous Materials, as identified in appendix 1 of these Guidelines, should be listed in Part I of the Inventory for existing ships. Appendix 1 of the Guidelines contains all the materials concerned. Table A shows those which are required to be listed and Table B shows those which should be listed as far as practical. 2.2.2 Materials listed in Table A Table A lists the following four materials: Asbestos Polychlorinated biphenyls (PCBs) Ozone depleting substances Anti-fouling systems containing organotin compounds as a biocide 2.2.2.1 Asbestos

Field interviews were conducted with over 200 Japanese shipyards and suppliers regarding the use of asbestos in production. Indicative lists for asbestos developed on the basis of this research are shown below: Structure and/or equipment Propeller shafting Component Packing with low pressure hydraulic piping flange Packing with casing Clutch Brake lining Synthetic stern tubes Packing with piping flange Lagging material for fuel pipe Lagging material for exhaust pipe Lagging material turbocharger Lagging material for casing Packing with flange of piping and valve for steam line, exhaust line and drain line Lagging material for piping and valve of steam line, exhaust line and drain line

Diesel engine

Turbine engine

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MEPC 59/24/Add.1 ANNEX 2 Page 26

Structure and/or equipment Boiler

Component Insulation in combustion chamber Packing for casing door Lagging material for exhaust pipe Gasket for manhole Gasket for hand hole Gas shield packing for soot blower and other hole

Packing with flange of piping and valve for steam line, exhaust line, fuel line and drain line Lagging material for piping and valve of steam line, exhaust line, fuel line and drain line Exhaust gas economizer Packing for casing door Packing with manhole Packing with hand hole Gas shield packing for soot blower Packing with flange of piping and valve for steam line, exhaust line, fuel line and drain line Lagging material for piping and valve of steam line, exhaust line, fuel line and drain line Incinerator Packing for casing door Packing with manhole Packing with hand hole Lagging material for exhaust pipe Auxiliary machinery (pump, Packing for casing door and valve compressor, oil purifier, Gland packing crane) Brake lining Heat exchanger Packing with casing Gland packing for valve Lagging material and insulation Valve Gland packing with valve, sheet packing with piping flange Gasket with flange of high pressure and/or high temperature Pipe, duct Lagging material and insulation Tank (fuel tank, hot water, Lagging material and insulation tank, condenser), other equipments (fuel strainer, lubricant oil strainer) Electric equipment Insulation material Airborne asbestos Wall, ceiling Ceiling, floor and wall in Ceiling, floor, wall accommodation area Fire door Packing, construction and insulation of the fire door Inert gas system Packing for casing, etc. Air-conditioning system Sheet packing, lagging material for piping and flexible joint
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MEPC 59/24/Add.1 ANNEX 2 Page 27

Structure and/or equipment Miscellaneous

Component Ropes Thermal insulating materials Fire shields/fire proofing Space/duct insulation Electrical cable materials Brake linings Floor tiles/deck underlay Steam/water/vent flange gaskets Adhesives/mastics/fillers Sound damping Moulded plastic products Sealing putty Shaft/valve packing Electrical bulkhead penetration packing Circuit breaker arc chutes Pipe hanger inserts Weld shop protectors/burn covers Fire-fighting blankets/clothing/equipment Concrete ballast

2.2.2.2

Polychlorinated biphenyl (PCBs)

Worldwide restriction of PCBs began on 17 May 2004 as a result of the implementation of the Stockholm Convention, which aims to eliminate or restrict the production and use of persistent organic pollutants. In Japan, domestic control began in 1973, with the prohibition of all activities relating to the production, use and import of PCBs. Japanese suppliers can provide accurate information concerning their products. The Indicative list of PCBs has been developed as shown below:
Equipment Transformer Condenser Fuel heater Electric cable Lubricating oil Heat oil Rubber/felt gaskets Rubber hose Plastic foam insulation Thermal insulating materials Voltage regulators Switches/reclosers/bushings Electromagnets Adhesives/tapes Surface contamination of machinery Oil-based paint Caulking Rubber isolation mounts
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Component of equipment Insulating oil Insulating oil Heating medium Covering, insulating tape Thermometers, sensors, indicators

MEPC 59/24/Add.1 ANNEX 2 Page 28


Equipment Pipe hangers Light ballasts (component within fluorescent light fixtures) Plasticizers Felt under septum plates on top of hull bottom Component of equipment

2.2.2.3

Ozone depleting substances

The Indicative list for Ozone depleting substances is shown below. Ozone depleting substances have been controlled according to the Montreal Protocol and MARPOL Convention. Although almost all substances have been banned since 1996, HCFC can still be used until 2020.
Materials CFCs (R11, R12) CFCs Component of equipment Refrigerant for refrigerators Urethane formed material Blowing agent for insulation of LNG carriers Halons Extinguishing agent Other fully halogenated The possibility of usage in CFCs ships is low Carbon tetrachloride The possibility of usage in ships is low 1,1,1-Trichloroethane The possibility of usage in (Methyl chloroform) ships is low HCFC (R22, R141b) Refrigerant for refrigerating machine HBFC The possibility of usage in ships is low Methyl bromide The possibility of usage in ships is low Period for use of ODS in Japan Until 1996 Until 1996 Until 1996 Until 1994 Until 1996 Until 1996 Until 1996 It is possible to use it until 2020 Until 1996 Until 2005

2.2.2.4

Organotin compounds

Organotin compounds include Tributyl tins (TBT), Triphenyl tins (TPT) and Tributyl tin oxide (TBTO). Organotin compounds have been used as anti-fouling paint on ships bottoms and the International Convention on the Control of Harmful Anti-Fouling Systems on Ships (AFS Convention) stipulates that all ships shall not apply or re-apply organotin compounds after 1 January 2003, and that, after 1 January 2008, all ships shall either not bear such compounds on their hulls or shall bear a coating that forms a barrier preventing such compounds from leaching into the sea. The above-mentioned dates may have been extended by permission of the Administration bearing in mind that the AFS Convention entered into force on 17 September 2008. 2.2.3 Materials listed in Table B For existing ships it is not obligatory for materials listed in Table B to be listed in Part I of the Inventory. However, if they can be identified in a practical way, they should be listed in the Inventory, because the information will be used to support ship recycling processes. The Indicative list of materials listed in Table B is shown below:
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MEPC 59/24/Add.1 ANNEX 2 Page 29

Materials Cadmium and cadmium compounds Hexavalent chromium compounds Mercury and mercury compounds

Component of equipment Nickel-cadmium battery, plating film, bearing Plating film Fluorescent light, mercury lamp, mercury cell, liquid-level switch, gyro compass, thermometer, measuring tool, manganese cell, pressure sensors, light fittings, electrical switches, fire detectors Lead and lead compounds Lead-acid storage battery, corrosion-resistant primer, solder (almost all electric appliances contain solder), paints, preservative coatings, cable insulation, lead ballast, generators Polybrominated biphenyls (PBBs) Non-flammable plastics Polybrominated diphenyl ethers (PBDE) Non-flammable plastics Polychlorinated naphthalenes Paint, lubricating oil Radioactive substances Certain shortchain chlorinated paraffins Fluorescent paint, ionic type smoke detector, level gauge Non-flammable plastics

Step 2: Assessment of collected information

Preparation of a checklist is an efficient method for developing the Inventory for existing ships in order to clarify the results of each step. Based on collected information including the Indicative list mentioned in Step 1, all equipment, systems, and/or areas onboard assumed to contain Hazardous Materials listed in Tables A and B should be included in the checklist. Each listed equipment, system, and/or area on board should be analysed and assessed for its Hazardous Materials content. The existence and volume of Hazardous Materials may be judged and calculated from the Spare parts and tools list and the Makers drawings. The existence of asbestos contained in floors, ceilings and walls may be identified from Fire Protection Plans, while the existence of TBT in coatings can be identified from the International Anti-Fouling System Certificate, Coating scheme and the History of Paint. Example of weight calculation Location/Equipment/ Reference Calculation Component Flat bottom/paint History of coatings Main engine/ Spare parts and tools 250g x 14 sheet = 3.50 kg Exh. pipe packing list Ref. provision plant Makers drawings 20kg x 1 cylinder = 20 kg Batteries Makers drawings 6 kg x 16 unit = 96 kg Engine-room ceiling Accommodation plan

No. 1.1-2 1.2-1 1.2-3 1.2-4 1.3-1

Hazardous Materials TBT Asbestos HCFC Lead Asbestos

When a component or coating is determined to contain Hazardous Materials, a Y should be entered in the column for Result of document analysis in the checklist, to denote Contained. Likewise, when an item is determined not to contain Hazardous Materials, the entry N should be made in the column to denote Not contained. When a determination cannot be made as to the Hazardous Materials content, the column should be completed with the entry Unknown.
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MEPC 59/24/Add.1 ANNEX 2 Page 30


Checklist (Step 2)
ANALYSIS
No .
Tbl A/B Hazardous Materials *1 Location Name of equipment

AND DEFINITION OF SCOPE OF ASSESSMENT FOR


Quan tity
Component Unit (kg) No. Total (kg)

"SAMPLE SHIP"
Result of DOC *2 Procedure Result of of check check *3 *4 Reference/DWG No.

Manu factur er/br and nam e


Paints Co./marine P1000 Unknown AF

I nvent ory Pa rt I- 1 1 2
A A TBT TBT Top side Flat bottom Painting & coating A/F paints 3000m
2

NIL

N Unknown

On Aug. 200X, sealer coat applied to all over submerged a r e a b ef o r e t i n f r e e c o a t i n g .

I nvent ory Pa rt I- 2 1 A Asbestos 2 A Asbestos 3 A Asbestos 4 A HCFC 5 B Lead

Lower deck

Main engine

3rd de ck Aux.boiler Engine room . P i p i n g / f l a n g e 2nd de ck Ref. provision plant


Nav. Br.deck Batteries

E x h . p i p e p a c k i ng Lagging Packing R e f r i g e r a n t ( R 22 )

0.25

14 12 1 16

Diesel Co. Unknown lagging Reito Co. Denchi Co.

20.00 6

Y Unknown PCHM Y Y

M-100 M-300 Maker's dwg E-300

I nvent ory Pa rt I- 3 Upper deck 1 A Asbestos No tes *1 Ha zardo us *2 Re sult of *3 Pr ocedu re *4 Re sult of

Back deck ceilin gs

E n g i n e r o o m c e il i n g

20m

Unknown ceiling

Unknown

O-25

Mat erial s: Mat erial class ifica tion doc ument s anal ysis: Y=Con taine d, N=N ot co ntain ed, of check : V=Vi sual check, S=Sa mpling chec k che ck: Y =Conta ined, N=Not cont ained, PCHM

U nknow n, PCH M=pot ential ly co ntaini ng Ha zardo us Mat erial .

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MEPC 59/24/Add.1 ANNEX 2 Page 31 4 Step 3: Preparation of visual/sampling check plan

Each item classified as Contained or Not contained in Step 2 should be subjected to a visual check on board, and the entry V should be made in the Check procedure column to denote Visual check. For each item categorized as unknown, a decision should be made as to whether to apply a sampling check. However, any item categorized as unknown may be classed as potentially containing Hazardous Material provided comprehensive justification is given, or if it can be assumed that there will be little or no effect on disassembly as a unit and later ship recycling and disposal operations. For example, in the following checklist, in order to carry out a sampling check for Packing with aux. boiler the shipowner needs to disassemble the auxiliary boiler in a repair yard. The costs of this check are significantly higher than the later disposal costs at a Ship Recycling Facility. In this case, therefore, the classification as potentially containing Hazardous Material is justifiable.

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MEPC 59/24/Add.1 ANNEX 2 Page 32


Checklist (Step 3)
A NAL YSI S
No .
Tbl A/B Haz ar dou s Mat er ial s *1 Loc at ion Na me of Eq uip me nt

AN D D EFI NIT ION OF SC OPE OF AS SES SME NT FO R " SAM PLE SH IP"
Q u an t it y
C omp one nt U nit ( kg) No . To ta l ( kg)

M an uf a ct u re r/ B ra n d n a me
P ain ts Co ./ mar ine P 100 0 U nkn ow n A F

R es ult of D OC *2

P roc ed ure Res ult o f che ck of c hec k *3 *4

R efe re nce /DW G No.

I nv e nt or y P a rt I - 1 1 2
A A TB T TB T To p sid e Fl at bo tt om P ain tin g & c oa tin g A/ F pai nts 30 00m
2

N IL

N U nkn ow n

V S

On Au g. 20 0X, se al er co at app li ed to al l o ve r su bme rg ed are a bef or e t in fr ee co ati ng .

I nv e nt or y P a rt I - 2 1 A As bes to s 2 A As bes to s 3 A As bes to s 4 A HC FC 5 B Le ad

Lo we r d ec k

3 r d de c k E n gi ne ro o m 2 n d de c k
Na v. Br .d eck

M ain en gi ne A ux. boi le r P ipi ng/ fl ang e R ef. pr ov isi on pl an t B att eri es

Ex h.p ip e p ac kin g La ggi ng Pa cki ng Re fri ge ran t (R2 2)

0. 25

14 12 1 16

D ies el Co . U nkn ow n l ag gin g R eit o Co. D enc hi Co .

20. 00 6

Y U nkn ow n PC HM Y Y

V S V V V

M-1 00 M-3 00 Mak er 's dw g E-3 00

I nv e nt or y P a rt I - 3 Up pe r d ec k 1 A As bes to s N ot e s * 1 Ha za r do u s * 2 Re su l t o f * 3 Pr oc e du r e * 4 Re su l t o f

B a ck de ck ce i li ng s

En gin e roo m cei lin g

20m

U nkn ow n c ei lin g

U nkn ow n

O-2 5

Ma t er i al s: Ma t er ia l c l as s if ic a ti o n do c um e nt s a na l ys is : Y = Co n ta in e d, N= No t c o nt ai n ed , U nkn ow n , PC H M= p ot en t ia l ly c o nt a in in g H a za rd o us Ma te r ia l of ch e ck : V =V i su al ch e ck , S =S a mp l in g c he c k ch e ck : Y =C o nt a in ed , N = No t c on t ai n ed , P CH M

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MEPC 59/24/Add.1 ANNEX 2 Page 33 Before any visual/sampling check on board is conducted, a visual/sampling check plan should be prepared. An example of such a plan is shown below. To prevent any incidents during the visual/sampling check, a schedule should be established to eliminate interference with other ongoing work on board. To prevent potential exposure to Hazardous Materials during the visual/sampling check, safety precautions should be in place on board. For example, sampling of potential asbestos containing materials could release fibres into the atmosphere. Therefore, appropriate personnel safety and containment procedures should be implemented prior to sampling. Items listed in the visual/sampling check should be arranged in sequence so that the onboard check is conducted in a structured manner (e.g., from a lower level to an upper level and from a fore part to an aft part). Example of visual/sampling check plan XXXXXXXXXX XXXXXXXXXX 28,000 GT xxx.xx xx.xx xx.xx m dd.mm.1987 XXXXXXXXXX XXXXXXXXXX
Tel: XXXX-XXXX Fax: XXXX-XXXX E-mail: abcdefg@hijk.co.net Visual check dd, mm, 200X Sampling check dd, mm, 200X XX shipyard, No. Dock XXXX XXXX XXXX XXXX, YYYY YYYY, ZZZZ ZZZZ Person with specialized knowledge of sampling Wet the sampling location prior to cutting and allow it to harden after cutting to prevent scatter. Notes: Workers performing sampling activities shall wear protective equipment. Sampling of fragments of paints Paints suspected to contain TBT should be collected and analysed from load line, directly under bilge keel and flat bottom near amidships. QQQQ QQQQ Method by ISO/DIS 22262-1 Bulk materials--Part 1: Sampling and qualitative determination of asbestos in commercial bulk materials and ISO/CD 22262-2 Bulk materials Part 2: Quantitative determination of asbestos by gravimetric and microscopic methods. ICP Luminous analysis (TBT) Refer to lists for visual/sampling check

Name of ship IMO Number Gross Tonnage LxBxD Date of delivery Shipowner Contact point (Tel.,Fax, E-mail, address)

Check schedule Site of check In charge of check Check engineer Sampling engineer Sampling method and anti-scattering measure for asbestos

Laboratory Chemical analysis method

Location of visual/sampling check

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MEPC 59/24/Add.1 ANNEX 2 Page 34

Listing for equipment, system and/or area for visual check See attached Analysis and definition of scope of investigation for sample ship

List of equipment, system and/or area for sampling check Equipment, Location machinery and/or Name of parts zone Upper Deck Back deck ceilings Engine-room ceiling Engine-room Exhaust gas pipe Insulation Engine-room Pipe/flange Gasket

Materials Asbestos Asbestos Asbestos

Result of doc. checking Unknown Unknown Unknown

Refer to attached Analysis and definition of scope of investigation for sample ship and Location plan of Hazardous Materials for sample ship List of equipment, system and/or area classed as PCHM Equipment, Location machinery and/or Name of part Material zone Floor Propeller cap Gasket Asbestos Engine-room Air operated shut-off Gland Asbestos valve packing

Result of doc. checking PCHM PCHM

Refer to attached Analysis and definition of scope of investigation for sample ship and Location plan of Hazardous Materials for sample ship This plan is established in accordance with the Guidelines for the development of the Inventory of Hazardous Materials Prepared by XXXX XXXX Tel. YYYY-YYYY E-Mail XXXX@ZZZZ.co.net Document check date/place dd, mm, 200X at XX Lines Co. Ltd. Preparation date of plan dd. mm, 200X

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MEPC 59/24/Add.1 ANNEX 2 Page 35 5 Step 4: Onboard visual/sampling check

The visual/sampling check should be conducted according to the plan. Check points should be marked in the ships plan or recorded with photographs. A person taking samples should be protected by the appropriate safety equipment relevant to the suspected type of hazardous materials encountered. Appropriate safety precautions should also be in place for passengers, crewmembers and other persons on board, to minimize the potential exposure to hazardous materials. Safety precautions could include the posting of signs or other verbal or written notification for personnel to avoid such areas during sampling. The personnel taking samples should ensure compliance with relevant national regulations. The results of visual/sampling checks should be recorded in the checklist. Any equipment, systems and/or areas of the ship that cannot be accessed for checks should be classified as potentially containing Hazardous Material. In this case, the entry in the Result of check column should be PCHM. 6 6.1 Step 5: Preparation of Part I of the Inventory and related documentation Development of Part I of the Inventory

The results of the check and the estimated quantity of Hazardous Materials should be recorded on the checklist. Part I of the Inventory should be developed with reference to the checklist. 6.2 Development of location diagram of Hazardous Materials

With respect to Part I of the Inventory, the development of a location diagram of Hazardous Materials is recommended in order to help the Ship Recycling Facility gain a visual understanding of the Inventory.

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MEPC 59/24/Add.1 ANNEX 2 Page 36


Checklist (Step 4 and Step 5)
AN AL YS IS
N o.
T bl A /B Ha za rd ou s Ma te ri al s *1 L oc at io n N am e of e qui pm en t

A ND D EF IN IT IO N OF S CO PE OF A SS ES SM EN T FO R "S AM PLE S HI P"


Qu a nt i t y
Co mp on en t Un it (k g) No . T ot al ( kg ) NI L 0. 02 30 00m
2

M an u f ac t u re r / br a n d n a me
P ai nt s C o. /m ar in e P1 00 0

Re su lt of DO C *2

P roc ed ur e R es ul t o f ch ec k of c he ck *3 *4

Re fe re nc e/ DWG N o.

I n ve n t or y Pa r t I - 1 1 2
A A TB T TB T T op s id e F la t bo tt om Pa in ti ng & c oa ti ng A/ F pa in ts N Un kn ow n V S N Y 60 .0 0 U nk no wn AF O n Au g. 2 00 X, s ea le r c oa t a pp li ed t o al l ov er s ub me rg ed a re a be fo re t in f re e c oa ti ng .

I n ve n t or y Pa r t I - 2 1 A As be st os 2 A As be st os 3 A As be st os 4 A HC FC 5 B Le ad

L ow er d ec k

3rd deck E n g in e ro o m 2nd deck


N av . Br .d ec k

Ma in e ng in e Au x. bo il er Pi pi ng /f la ng e Re f. p ro vi si on p la nt Ba tt er ie s

Ex h. pi pe p ac ki ng La gg in g Pa ck in g Re fr ig er an t (R 22 )

0. 25

14 12

3 .5 0

D ie se l C o. U nk no wn la gg in g R ei to Co . D en ch i C o.

2 0. 00 6

1 20 .0 0 1 6 96 .0 0

Y Un kn ow n P CH M Y Y

V S V V V

Y N P CH M Y Y

M -1 00 M -3 00 M ak er 's d wg E -3 00

I n ve n t or y Pa r t I - 3 U pp er d ec k 1 A As be st os N o t es *1 H a za r d ou s *2 R e su l t o f *3 P r oc e d ur e *4 R e su l t o f

B ac k de c k c e i li n g s

En gi ne r oo m ce il in g

0. 19

2 0m

3 .8 0 U nk no wn ce il in g

Un kn ow n

O -2 5

Ma t er i a ls : Ma t e ri a l c l as s i fi c a ti o n do c um e n ts a na l y si s : Y = Co n t ai n e d, N =N o t c o nt a i ne d , of ch e c k: V =V i s ua l ch e ck , S= S a mp l i ng ch e c k ch e ck : Y= C o nt a i ne d , N = No t co n t ai n e d, PC H M

U nk n o wn , PC H M =p o te n t ia l l y c o nt a i ni n g H a za r d ou s Ma t er i a l

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MEPC 59/24/Add.1 ANNEX 2 Page 37

Example of the Inventory for existing ships

Inventory of Hazardous Materials for Sample Ship


Particulars of the Sample Ship Distinctive number or letters Port of registry Type of vessel Gross Tonnage IMO number Name of shipbuilder Name of shipowner Date of delivery XXXXNNN Port of World Bulk carrier 28,000 GT NNNNNNN xx Shipbuilding Co. Ltd yy Maritime SA MM/DD/1988

This inventory was developed in accordance with the Guidelines for the development of the Inventory of Hazardous Materials. Attachment: 1: Inventory of Hazardous Materials 2: Assessment of collected information 3: Location diagram of Hazardous Materials
*

Prepared by XYZ (Name & address)( mm/dd/20XX)

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MEPC 59/24/Add.1 ANNEX 2 Page 38

Inventory of Hazardous Materials : Sample Ship


Part I HAZARDOUS MATERIALS CONTAINED IN THE SHIPS STRUCTURE AND EQUIPMENT

I-1 Paints and coating systems containing materials listed in Table A and Table B of appendix 1 of the Guidelines
No. 1 2 3 Application of paint AF paint Name of paint Unknown paints Location *1 Flat bottom Materials (classification in appendix 1) TBT Approx. quantity 60.00 kg Remarks Confirmed by sampling

I-2 Equipment and machinery containing materials listed in Table A and Table B of appendix 1 of the Guidelines
No. 1 2 3 4 5 Name of equipment and machinery Main engine Aux. boiler Piping/flange Ref. provision plant Batteries Location *1 Lower floor 3rd deck Engine-room 2nd deck Navig. Bridge deck Materials (classification in appendix 1) Asbestos Asbestos Asbestos HCFC Lead Parts where used Exh. pipe packing Unknown packing Packing Refrigerant (R22) Approx. quantity 3.50 10.00 50.00 20.00 96.00 kg kg kg kg kg PCHM (potentially containing Hazardous Material) PCHM Remarks

I-3 Structure and hull containing materials listed in Table A and Table B of appendix 1 of the Guidelines
No. 1 2 3
*1 Each item should be entered in order based on its location, from a lower level to an upper level and from a fore part to an aft part.

Name of structural element Back deck ceiling

Location *1 Upper deck

Materials (classification in appendix 1) Asbestos

Parts where used Engine-room ceiling (A class)

Approx. quantity 3.80 kg

Remarks Confirmed by sampling

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MEPC 59/24/Add.1 ANNEX 2 Page 39 Example of location diagram of Hazardous Materials

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MEPC 59/24/Add.1 ANNEX 2 Page 40 APPENDIX 6 FORM OF MATERIAL DECLARATION


<Date of declaration>
Date

<MD ID number>
MD- ID-No.

<Supplier (respondent) information>


Company name Division name

<Other information>
Remark 1 Remark 2 Remark 3

Address Contact person Telephone number Fax number E-mail address SDoC ID no.:

<Product information>
Product name Product number Delivered unit Amount Unit Product information

<Materials information>
Unit This materials information shows the amount of hazardous materials contained in Present above threshold level Yes / No Asbestos Polychlorinated biphenyls (PCBs) Asbestos Polychlorinated biphenyls (PCBs) Chlorofluorocaobons (CFCs) Halons Table A (materials listed in appendix 1 of the Convention) Ozone depleting substance Other fully halogenated CFCs Carbon tetrachloride 1,1,1-Trichloroethane Hydrochlorofluorocaobons Hydrobromofluorocaobons Methyl bromide Bromochloromethane Anti-fouling systems containing organotin compounds as a biocide no threshold level no threshold level no threshold level 1

Piece

kg

m3

litre

Yes

No

(unit: piece, kg, m, m2, m3, etc) of the product.

Table

Material name

Threshold level

If yes, material mass Mass Unit

If yes, information on where it is used

2,500 mg total tin/kg

Table

Material name

Threshold level 100 mg/kg 1,000 mg/kg 1,000 mg/kg 1,000 mg/kg 1,000 mg/kg 1,000 mg/kg no threshold level no threshold level 1%

Present above threshold level Yes / No

If yes, material mass Mass Unit

If yes, information on where it is used

Cadmium and cadmium compounds Hexavalent chromium and hexavalent chromium compounds Table B (materials listed in appendix 2 of the Convention) Lead and lead compounds Mercury and mercury compounds Polybrominated biphenyl (PBBs) Polybrominated dephenyl ethers (PBDEs) Polychloronaphthalenes (Cl >= 3) Radioactive substances Certain shortchain chlorinated paraffins

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MEPC 59/24/Add.1 ANNEX 2 Page 41 APPENDIX 7 FORM OF SUPPLIERS DECLARATION OF CONFORMITY

Suppliers Declaration of Conformity for Material Declaration management

1) Identification number:

__________

2) Issuers name: Issuers address:

3) Object(s) of the declaration:

4) The object(s) of the declaration described above is in conformity with the following documents Document No.: 5) Title: Edition/date of issue

6) Additional information

Signed for and on behalf of:

(Place and date of issue)

7) (Name, function) (Signature)

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MEPC 59/24/Add.1 ANNEX 2 Page 42 APPENDIX 8 EXAMPLES OF TABLE A AND TABLE B MATERIALS OF APPENDIX 1 WITH CAS NUMBERS
*This list is developed with reference to Joint Industry Guide No.101. *This list is not exhaustive; it represents examples of chemicals with known CAS numbers and may require periodical updating. Table Table A (materials listed in appendix 1 of the Convention) Material Category Substances Asbestos Actinolite Amosite (Grunerite) Anthophyllite Chrysotile Crocidolite Tremolite Polychlorinated biphenyls Aroclor Chlorodiphenyl (Aroclor 1260) Kanechlor 500 Aroclor 1254 Trichlorofluoromethane (CFC11) Dichlorodifluoromethane (CFC12) Chlorotrifluoromethane (CFC 13) Pentachlorofluoroethane (CFC 111) Tetrachlorodifluoroethane (CFC 112) Trichlorotrifluoroethane (CFC 113) 1,1,2 Trichloro-1,2,2 trifluoroethane Dichlorotetrafluoroethane (CFC 114) Monochloropentafluoroethane (CFC 115) Heptachlorofluoropropane (CFC 211) Hexachlorodifluoropropane (CFC 212) Pentachlorotrifluoropropane (CFC 213) Tetrachlorotetrafluoropropane (CFC 214) 1,1,1,3-Tetrachlorotetrafluoropropane Trichloropentafluoropropane (CFC 215) 1,1,1-Trichloropentafluoropropane 1,2,3-Trichloropentafluoropropane Dichlorohexafluoropropane (CFC 216) Monochloroheptafluoropropane (CFC 217) Bromochlorodifluoromethane (Halon 1211) Bromotrifluoromethane (Halon 1301) Dibromotetrafluoroethane (Halon 2402) Carbon tetrachloride (Tetrachloromethane) 1,1,1, - Trichloroethane (methyl chloroform) and its isomers except 1,1,2-trichloroethane Bromomethane (Methyl bromide) Bromodifluoromethane and isomers (HBFCs) Dichlorofluoromethane (HCFC 21) Chlorodifluoromethane (HCFC 22) Chlorofluoromethane (HCFC 31) Tetrachlorofluoroethane (HCFC 121) 1,1,1,2-tetrachloro-2-fluoroethane (HCFC 121a) 1,1,2,2-tetracloro-1-fluoroethane CAS Numbers 1332-21-4 77536-66-4 12172-73-5 77536-67-5 12001-29-5 12001-28-4 77536-68-6 1336-36-3 12767-79-2 11096-82-5 27323-18-8 11097-69-1 75-69-4 75-71-8 75-72-9 354-56-3 76-12-0 354-58-5 76-13-1 76-14-2 76-15-3 422-78-6 135401-87-5 3182-26-1 2354-06-5 134237-31-3 29255-31-0 2268-46-4 1599-41-3 4259-43-2 76-17-5 661-97-2 422-86-6 353-59-3 75-63-8 124-73-2 56-23-5 71-55-6 74-83-9 1511-62-2 75-43-4 75-45-6 593-70-4 134237-32-4 354-11-0 354-14-3

Asbestos

Polychlorinated biphenyls (PCBs)

Ozone depleting substances/isomers (they may contain isomers that are not listed here)

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MEPC 59/24/Add.1 ANNEX 2 Page 43


*This list is developed with reference to Joint Industry Guide No.101. *This list is not exhaustive; it represents examples of chemicals with known CAS numbers and may require periodical updating. Table Material Category Substances Trichlorodifluoroethane (HCFC 122) 1,2,2-trichloro-1,1-difluoroethane Dichlorotrifluoroethane(HCFC 123) Dichloro-1,1,2-trifluoroethane 2,2-dichloro-1,1,1-trifluroethane 1,2-dichloro-1,1,2-trifluroethane (HCFC-123a) 1,1-dichloro-1,2,2-trifluroethane (HCFC-123b) 2,2-dichloro-1,1,2-trifluroethane (HCFC-123b) Chlorotetrafluoroethane (HCFC 124) 2-chloro-1,1,1,2-tetrafluoroethane 1-chloro-1,1,2,2-tetrafluoroethane (HCFC 124a) Trichlorofluoroethane (HCFC 131) 1-Fluoro-1,2,2-trichloroethane 1,1,1-trichloro-2-fluoroethane (HCFC131b) Dichlorodifluoroethane (HCFC 132) 1,2-dichloro-1,1-difluoroethane (HCFC 132b) 1,1-dichloro-1,2-difluoroethane (HFCF 132c) 1,1-dichloro-2,2-difluoroethane 1,2-dichloro-1,2-difluoroethane Chlorotrifluoroethane (HCFC 133) 1-chloro-1,2,2-trifluoroethane 2-chloro-1,1,1-trifluoroethane (HCFC-133a) Dichlorofluoroethane(HCFC 141) 1,1-dichloro-1-fluoroethane (HCFC-141b) 1,2-dichloro-1-fluoroethane Chlorodifluoroethane (HCFC 142) 1-chloro-1,1-difluoroethane (HCFC142b) 1-chloro-1,2-difluoroethane (HCFC142a) Hexachlorofluoropropane (HCFC 221) Pentachlorodifluoropropane (HCFC 222) Tetrachlorotrifluropropane (HCFC 223) Trichlorotetrafluoropropane (HCFC 224) Dichloropentafluoropropane, (Ethyne, fluoro-) (HCFC 225) 2,2-Dichloro-1,1,1,3,3-pentafluoropropane(HCFC 225aa) 2,3-Dichloro-1,1,1,2,3-pentafluoropropane (HCFC 225ba) 1,2-Dichloro-1,1,2,3,3-pentafluoropropane (HCFC 225bb) 3,3-Dichloro-1,1,1,2,2-pentafluoropropane (HCFC 225ca) 1,3-Dichloro-1,1,2,2,3-pentafluoropropane (HCFC 225cb) 1,1-Dichloro-1,2,2,3,3-pentafluoropropane(HCFC 225cc) 1,2-Dichloro-1,1,3,3,3-pentafluoropropane (HCFC 225da) 1,3-Dichloro-1,1,2,3,3-pentafluoropropane (HCFC 225ea) 1,1-Dichloro-1,2,3,3,3-pentafluoropropane(HCFC 225eb) Chlorohexafluoropropane (HCFC 226) Pentachlorofluoropropane (HCFC 231) Tetrachlorodifluoropropane (HCFC 232) Trichlorotrifluoropropane (HCFC 233) 1,1,1-Trichloro-3,3,3-trifluoropropane Dichlorotetrafluoropropane (HCFC 234) Chloropentafluoropropane (HCFC 235) 1-Chloro-1,1,3,3,3-pentafluoropropane Tetrachlorofluoropropane (HCFC 241) Trichlorodifluoropropane (HCFC 242) CAS Numbers 41834-16-6 354-21-2 34077-87-7 90454-18-5 306-83-2 354-23-4 812-04-4 812-04-4 63938-10-3 2837-89-0 354-25-6 27154-33-2; (134237-34-6) 359-28-4 811-95-0 25915-78-0 1649-08-7 1842-05-3 471-43-2 431-06-1 1330-45-6 1330-45-6 75-88-7 1717-00-6; (25167-88-8) 1717-00-6 430-57-9 25497-29-4 75-68-3 25497-29-4 134237-35-7 134237-36-8 134237-37-9 134237-38-0 127564-92-5; (2713-09-9) 128903-21-9 422-48-0 422-44-6 422-56-0 507-55-1 13474-88-9 431-86-7 136013-79-1 111512-56-2 134308-72-8 134190-48-0 134237-39-1 134237-40-4 7125-83-9 127564-83-4 134237-41-5 460-92-4 134190-49-1 134237-42-6

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MEPC 59/24/Add.1 ANNEX 2 Page 44


*This list is developed with reference to Joint Industry Guide No.101. *This list is not exhaustive; it represents examples of chemicals with known CAS numbers and may require periodical updating. Table Material Category Substances Dichlorotrifluoropropane (HCFC 243) 1,1-dichloro-1,2,2-trifluoropropane 2,3-dichloro-1,1,1-trifluoropropane 3,3-Dichloro-1,1,1-trifluoropropane Chlorotetrafluoropropane (HCFC 244) 3-chloro-1,1,2,2-tetrafluoropropane Trichlorofluoropropane (HCFC 251) 1,1,3-trichloro-1-fluoropropane Dichlorodifluoropropane (HCFC 252) Chlorotrifluoropropane (HCFC 253) 3-chloro-1,1,1-trifluoropropane (HCFC 253fb) Dichlorofluoropropane (HCFC 261) 1,1-dichloro-1-fluoropropane Chlorodifluoropropane (HCFC 262) 2-chloro-1,3-difluoropropane Chlorofluoropropane (HCFC 271) 2-chloro-2-fluoropropane Bis(tri-n-butyltin) oxide Triphenyltin N,N'-dimethyldithiocarbamate Triphenyltin fluoride Triphenyltin acetate Triphenyltin chloride Triphenyltin hydroxide Triphenyltin fatty acid salts (C=9-11) Triphenyltin chloroacetate Tributyltin methacrylate Bis(tributyltin) fumarate Tributyltin fluoride Bis(tributyltin) 2,3-dibromosuccinate Tributyltin acetate Tributyltin laurate Bis(tributyltin) phthalate Copolymer of alkyl acrylate, methyl methacrylate and tributyltin methacrylate(alkyl; C=8) Tributyltin sulfamate Bis(tributyltin) maleate Tributyltin chloride Mixture of tributyltin cyclopentanecarboxylate and its analogs (Tributyltin naphthenate) Mixture of tributyltin 1,2,3,4,4a, 4b, 5,6,10,10adecahydro-7isopropyl-1, 4a-dimethyl-1-phenanthlenecarboxylate and its analogs (Tributyltin rosin salt) Table B (Materials listed in appendix 2 of the Convention) Other tributyl tins & triphenyl tins Cadmium Cadmium oxide Cadmium sulfide Cadmium chloride Cadmium sulfate Other cadmium compounds Chromium (VI) oxide Barium chromate Calcium chromate Chromium trioxide CAS Numbers 134237-43-7 7125-99-7 338-75-0 460-69-5 134190-50-4 679-85-6 134190-51-5 818-99-5 134190-52-6 134237-44-8 460-35-5 134237-45-9 7799-56-6 134190-53-7 102738-79-4 134190-54-8 420-44-0 56-35-9 1803-12-9 379-52-2 900-95-8 639-58-7 76-87-9 47672-31-1 7094-94-2 2155-70-6 6454-35-9 1983-10-4 31732-71-5 56-36-0 3090-36-6 4782-29-0 6517-25-5 14275-57-1 1461-22-9 7440-43-9 1306-19-0 1306-23-6 10108-64-2 10124-36-4 1333-82-0 10294-40-3 13765-19-0 1333-82-0

Organotin compounds (tributyl tin, triphenyl tin, tributyl tin oxide)

Cadmium/cadmium compounds

Chromium VI compounds

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MEPC 59/24/Add.1 ANNEX 2 Page 45


*This list is developed with reference to Joint Industry Guide No.101. *This list is not exhaustive; it represents examples of chemicals with known CAS numbers and may require periodical updating. Table Material Category Substances Lead (II) chromate Sodium chromate Sodium dichromate Strontium chromate Potassium dichromate Potassium chromate Zinc chromate Other hexavalent chromium compounds Lead Lead (II) sulfate Lead (II) carbonate Lead hydrocarbonate Lead acetate Lead (II) acetate, trihydrate Lead phosphate Lead selenide Lead (IV) oxide Lead (II,IV) oxide Lead (II) sulfide Lead (II) oxide Lead (II) carbonate basic Lead hydroxidcarbonate Lead (II) phosphate Lead (II) chromate Lead (II) titanate Lead sulfate, sulphuric acid, lead salt Lead sulphate, tribasic Lead stearate Other lead compounds Mercury Mercuric chloride Mercury (II) chloride Mercuric sulfate Mercuric nitrate Mercuric (II) oxide Mercuric sulfide Other mercury compounds CAS Numbers 7758-97-6 7775-11-3 10588-01-9 7789-06-2 7778-50-9 7789-00-6 13530-65-9 7439-92-1 7446-14-2 598-63-0 1319-46-6 301-04-2 6080-56-4 7446-27-7 12069-00-0 1309-60-0 1314-41-6 1314-87-0 1317-36-8 1319-46-6 1344-36-1 7446-27-7 7758-97-6 12060-00-3 15739-80-7 12202-17-4 1072-35-1 7439-97-6 33631-63-9 7487-94-7 7783-35-9 10045-94-0 21908-53-2 1344-48-5 2052-07-5 (2-Bromobiphenyl) Bromobiphenyl and its ethers 2113-57-7 (3-Bromobiphenyl 92-66-0 (4-Bromobiphenyl) 101-55-3 (ether) 13654-09-6 1163-19-5 (ether) 92-86-4 2050-47-7 (ether) 68928-80-3 59080-40-9 36355-01-8 (hexabromo1,1-biphenyl) 67774-32-7 (Firemaster FF1) 36483-60-0 (ether) 63936-56-1 61288-13-9 32536-52-0 (ether)

Lead/lead compounds

Mercury /mercury compounds

Polybrominated biphenyls (PBBs) and polybrominated diphenyl ethers (PBDEs)

Decabromobiphenyl and its ethers Dibromobiphenyl and its ethers Heptabromobiphenylether

Hexabromobiphenyl and its ethers

Nonabromobiphenylether Octabromobiphenyl and its ethers

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MEPC 59/24/Add.1 ANNEX 2 Page 46


*This list is developed with reference to Joint Industry Guide No.101. *This list is not exhaustive; it represents examples of chemicals with known CAS numbers and may require periodical updating. Table Material Category Substances Pentabromobidphenyl ether (note: commercially available PeBDPO is a complex reaction mixture containing a variety of brominated diphenyloxides. Polybrominated biphenyls Tetrabromobiphenyl and its ethers Polychlorinated naphthalenes Tribromobiphenyl ether Polychlorinated naphthalenes Other polychlorinated naphthalenes Uranium Plutonium Radon Americium Thorium Cesium Strontium Other radioactive substances Chlorinated paraffins (C10-13) Other short chain chlorinated paraffins CAS Numbers 32534-81-9 (CAS number used for commercial grades of PeBDPO) 59536-65-1 40088-45-7 40088-47-9 (ether) 49690-94-0 70776-03-3 7440-46-2 7440-24-6 85535-84-8 -

Radioactive substances

Certain shortchain chlorinated paraffins (with carbon length of 10-13 atoms)

***

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