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Outline
Plastic-Nanoclay Technology Commercial Applications Environmental Benefits
Nanotechnology
From composite to nanocomposite:
One continuous phase and at least one discontinuous phase At least one dimension in 100-nm scale
Nanoclay
Nanocomposite Benefits
Mechanical properties improvement Increase stiffness without loss of flexibility Increased dimensional stability Enhanced barrier properties Chemical and thermal stability Flame retardation in combination with FR agents Easy processing and recycling
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Nanoclay
BENTONITE: FDA 21CFR184.1155 GRAS: Generally Recognized as Safe
High aspect ratio Silicate layers 200-300 Possible inner layer chemistry
Nanoclay platelets are one-ten thousandth the diameter of a human hair!!
- H2O
15~25 Microns
Na-Bentonite
Nanos
Water Dispersion
Cationic surfactants
1st Step
Surface Treatment Hydrophilic Hydrophobic
Nanocomposite
Polymerization
Hydrophobic
Compatibilizer
nanoMax
Polyolefin Pellets
Polyolefin Pellets
10
400 nm
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H H H N+ O C C N+ H H H O OH N+ H H H OH O C OH
O C NH e-caprolactam M onom er
C O HN O C H N O C N H
O C NH O C H N O C NH
I.24T L
N+ H H H
N+ H H
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3
O T R (c c m i l / 1 0 0 i n 2 .d a y )
W V T R ( g m il/m
day)
2 1 0 0
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Perpendicular Direction
Testing Sample Nylon 6 B135WP Nano-PA6 %Nano Loading n/a 3% Youngs Modulus (Mpa) 200 380 Yield Strength (Mpa) 16 28 Strain @ break (%) 600 550
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Nanocomposites
Same Tm, Tg ---Same processing Smart design Use less resin ---same strength and barrier
PE//PA6//PE = 40//20//40 PE//nano-PA6// = 40//10//40 10% saving in film weight
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Nanocomposites
Applications of Nano-PA6: Stand-up pouch
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Nanocomposites
Nano-Nylon MXD6
H2NCH2 CH2NH2 + HOOC(CH2)4COOH
MXDA
Adipic acid
HNCH2
CH2NHC(CH2)4C OH O O
n
H2O
Nylon-MXD6
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Units
ccmm/m2dayatm
ccmm/m2dayatm
gmm/m2day
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2.02
2
OTR (cc/m2-day)
1.5
0.97 0.61
Regular nano
< 0.05
0.5
MRE Relative Humidity (%) Specification 0.06 US ARMY NATICK SOLDIER RD&E CENTER. The Science Behind the Warrior: Warrior: Yesterday, Today and Tomorrow
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Nanoclay as FR Additives
Low Nanomer loading level Reduction of Traditional FR Agents Dripping Control Anti-Blooming Good Mechanical Properties Easy Processing Regulation Favorable
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Nanoclay as FR Additives
Brominated systems
Reduce toxicity Metal Hydroxide-MDH, ATH Easy processing, high productivity Intumescing systems Easy processing
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WWW.NANOCOR.COM
Nanocomposite Applications
Wire and Cable Application
Non-Hal, low smoke jacket Slow burning Low heat release rate
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Nanocomposite Applications
Auto Parts
Nano-PP replace GF Filled PP 25% weight reduction, easy processing CP Polymer CRESS-ALON A Nano Nano Resin Brand name - Cress-Alon Injection grade - NE2740, NE6040ST
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Nanocomposite Applications
Marine Fuel Tank
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Nanocomposite Applications
nano Regular
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Nanocomposite Applications
Agriculture Film Application
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Nanocomposite Market
Data Source: BCC Research www.bccresearch.com
$857
$288 $252
2006
2008 year
2010
2012
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Nanocor Markets
Transportation FR Compounds
Packaging
Coating
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Summary
Nanoclays are effective additives to make better
plastics Nanocomposite resins offer same processing and recycle Use of nanocomposite have good environmental impact Lower weight auto parts Less toxic flame retardant compounds Thinner plastic package Durable/impermeable fuel tanks
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Company Information
www.amcol.com (NYSE: ACO)
AMCOL International Corp., through its operating subsidiaries, is a leading international producer and marketer of value-added, specialty minerals and related products. The Companys products serve 12 major markets, includingmetalcasting, detergents, pet products, building materials and personal care. AMCOL operates a transportation segment that acts as a servicing operation for other business segments and outside customers. Headquartered in Arlington Heights, Ill., AMCOL operates 68 facilities in Asia, Australia, Europe and North America. The Company employs 1,750+ employees in more than 26 countries. The Company, established in 1927,
American Colloid
CETCO
ASM/AME
HBS
Nanocor
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Thank You
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