Fulltest IV Main Paper Solution Sol Aits 2013 FT IV Jeem

AITS-FT-IV-PCM-(Sol)JEE(Main)/13
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1

ANSWERS, HINTS & SOLUTIONS
FULL TEST IV
(Main)

Q. No
PHYSICS CHEMISTRY MATHEMATICS
1. B B B
2. D B A
3. B D C
4. B B A
5. C C B
6. C D C
7. C B D
8. C B B
9. C C D
10. C C D
11. D B D
12. D C D
13. D C A
14. B A C
15. A A A
16. C C A
17. C B C
18. D B C
19. B B A
20. C C B
21. D A C
22. C B D
23. C C B
24. C A A
25. D A B
26. A A C
27. A D B
28. C B D
29. D A C
30. D B C
A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
I
E
S

FIITJEE JEE (Main)-2013
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4

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1
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1
0

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2
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,

4
3

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1
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7
5

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T
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2
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1
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9

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T
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R
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3
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2
P Ph hy ys si ic cs s PART I

SECTION A

1. Voltage across L can be greater than 220V. Resultant voltage across R- L or R C can also be
greater than 220V.

2. The particles on the instantaneous axis of rotation have zero velocity.

3.
80 I
0.8I
R 80
=
+

R = 20

4.
3
KQr
E
R
=

R
3
0
KQ KQ
V rdr
2R
R
= =

0
Q
V
8 R
=

5.
0
E

=

0
V ( x)

6. Energy stored in the inductor = heat produced
=
2
0
1
i
2
<
=
2
2
2
1
1
1 E 1 E
2 R 2
R
| |
< = <
|
\ .

7. The net downward force
= weight buoyancy
= mg mg / 2
= mg / 2.
Use the work energy theorem.

8. x and y has same dimensions of velocity. Hence (C) is the correct answer.
9.
2
1
E mv
2
=

2
1
E v
2
= {Since m = 1}
By equation of Trajectory

2
2
g x
y x tan
2
u cos
=
,

3

2
2 2
g R
0 Rtan
2
v cos
=

2
2 2
g R
Rtan
2
v cos
=
;
2
g R
sin
2
v cos
=

2
gR
sin2
v
=

gR
sin2
2E
(
=
(

;
1
0.5sin
=
1
gR
0.5sin
2E
(
=
(

10.

BD BC L 1
DA CA
2L 2
= = =

A
T
T
D
B
C
T
C
2

12. Since U = constant,
P RT
M
=
P = constant since is increasing, therefore V is decreasing.

13. Area under acceleration-time graph gives change in velocity
Hence
total
4 4
A 4 1
2
= = 8 4
V
f
V
i
= 4
V
f
3 = 4
V
f
= 7 m/s

14.
2
0
B
2
=
, so a graph between and B will be a parabola symmetric about axis and passing
through the origin.

15. 0 = u cos 30 g sin 30 t

ucos30
t
gsin30
..(A)

2
1
Hcos30 usin30 t gcos30 t
2
=

By equation (A) and (B), we get

2 2
u cot
H 1
g 2
(
= +
(
(

v = { }
2gH
30
5
=

16. On Rough surface
At any distance from the end

x 0
x
T F 1
L
(
=
(

Hence
x 0
x
T F 1
L
(
=
(

=
1
20 10
2
= newton

17. W
agent
=
0
F
W = F
0
cos .
By conservation of total energy

4

2
0 1
1
F cos mv
2
= ,
1 0
2
v F cos
m
=

18. In region I and IV the magnetic fields are equal and opposite
Hence (D) is the correct answer.

19. 10 emission lines
final state n = 5
If the initial state were not n = 4, in the emission
spectrum some lines with energies less than that of
absorbed radiation would have been observed.
initial state n = 4.
n=5
n=4
n=3
n=2
n=1

20.
min
hc
eV
=
and
deBroglie
h h
2meV
= =
.

21. Since object and image is real
then object distance = x
1

Image distance = x
2

0 1 2
x x x = +
;
2 1
1 1 1
x x f
=

1 2
1 2
x x
x x
f
+ =

1 1
x (x d)
d
f

=
x
1
x
2
x
0

2
0 1
0
1 1
dx x
x 0
x f dx
= =

x
1
= 2f
which means x
2
= 2f
distance between object and image is 4f = 120 cm

22.
eq
1 1 1
0
f 40 40
= = ;
f
eq
= 0 v = u

23. Stress = Y strain
F = YA strain

24. Impulse = change in momentum; moment of impulse about C.M. = initial angular momentum; the
ball moves like a projectile.

25. From the F.B.D. it is clear that we get the equations,
mg sin f = ma
fr = I

a a
I since =
r r
| |
=
|
\ .

Solving

5

2
mgsin
a ;
I
m
r
=
+
the time taken by the bodies to roll down a
distance, is
2
a
.
Using
2
1
I mr
2
= for the solid cylinder and
2
2
I mr
3
= for the
hollow spherical shell we get the required result.
N
f
a
mgsin
mgcos

26. Remember that the time period, T is given by,

m
T 2
k
=
i.e., T
2
m

27. The speed of the transverse waves equals the frequency wavelength
= 200 0.3 m/s = 60 m/s,
and is independent of the frequency.

29. Given
2 2

F (xy )i (x y)j = +

x y
W F dx F dy = +

=
2 2
xy dx x ydy +

2 2
1
d(x y )
2
=

=
4,0
2 2
0,0
x y
2
(
(
(

= 0J

30. Momentum is conserved in the horizontal direction; total K.E. of the two masses equals the P.E.
of the cube at the highest point.

C Ch he em mi is st tr ry y PART II

SECTION A

1. S
N
2 reaction involves only transition state whereas S
N
1 reaction involves intermediate.

2.
2 2 3 3 2
3Br 3Na CO 5NaBr NaBrO 3CO + + +

3 2 4 2 4 2 2
5NaBr NaBrO 3H SO 3Na SO 3Br 3H O + + + +

3.
| || |
2
r k NOBr NO =

| | | || |
2 2
NOBr k NO Br =
| | | |
2
2
r k k NO Br =
| | | |
2
2
r k NO Br =
So when the concentration of [NO] and [Br
2
] in doubled. The rate will become 8 times to the
original rate.
4. The coordination number in K[Cu(CN)
2
] is 3 and exist as [-CNCu(CN)CNCu(CN)-].


6
5.
Step- (i)
O
+
N
H
O O
Step- (ii)
3 2 2
CHCl KOH CCl KCl H O + + +
O
O
CCl
2
O
CHCl
2
2
CCl
H
+
3
H O
Hydrolysis
+
O
CHO

6.
2
2s
give the probability of finding electron at a distance r.
At node the probability of finding electron is zero.
So
2
2
2s
0
r
2 0
a
| |
=
|
\ .

0
2 r
0
a
=
r = 2a
0

7. Fumarate is getting reduced and lactate is getting oxidized

0
cell C A
E E E =
= 0.031 (0.185)
= 0.216 V

8.
O
OLi
( )
( )
2
i R CuLi
ii Hydrolysis
OH
O
R

O
OLi
( )
( )
i RMgX
ii Hydrolysis
OH
O
R

9. (i) H
3
PO
2
is hypophosphorous acid. Here the oxidation number of phosphorous is +1. So it can
show reducing properties.
(ii) H
4
P
2
O
7
is pyrophosphoric acid. It can behave either as dibasic acid or tetrabasic acid.
(iii)
3 2 3 4 3 433 K
2H PO H PO PH
+
(iv)
3 4 10 2
4HPO P O 2H O
+

10.
4 3 2 3
o o o o
CH NH H O NF
Bond angle 109 28 107 48 104 27 102 30
> > >


7
11.
O
O H
O H
N
CH
3
H
H
are chiral carbon centre.

12. Both will undergo Hoffmann bromamide degradation reaction separately.

13. For selection of unit cell the cell boundaries should land up at one of the lattice points.

14. In the PV diagram the isotherm which is above has more temperature than the below one.

15. For a spontaneous reaction.

o o
E 0, G 0, > < K
c
> 1.

16.
2 2 4
SnCl 2HCl I SnCl 2HI + + +

17. Each oxygen atom has 8 electrons. Thus the O
2
molecule contains a total of 16 electrons.
The electrons are arranged in MOs as follow
1s
2
, *1s
2
, 2s
2
, *2s
2
,
2
x
2p ,
{ }
2 2
y y
2p 2p = ,
{ }
1 1
y z
* 2p * 2p =

18. No. of radial nodes = n l 1

19.
2 2
Brown coloured gas
2NO O 2NO +

20. It has a plane of symmetry.

21. For equilibrium given

3
10
a
N H
8
3
a COOH
K
1.6 10
K 4 10
K
4 10
+

= = =

22.
( )
1
n
Ea / RT
1 1
K a T e
=

( )
2
n
Ea/ RT
2 2
K a T e
=

n
1 1
2 2
K T
K T
| |
=
|
\ .
[Ea is zero]

n
1 1
2 2
K T
K T
(
=
(

26. The elimination is E2 elimination. So it require antiperiplanar position of the proton and the
leaving group.

28.
NO
2
NHOH +
NO
2
H NHOH
2
H O
NO
2
NH
HA
NO
2
NH
2


8
M Ma at th he em ma at ti ic cs s PART III

SECTION A

1. The given equation is (1 + z) (1 + z
3
) = 0 the distinct roots being 1, ,
2
which if be
represented by points A, B and C in that order
AB = |1 | = || |
2
1| = |
2
1|
BC = |
2
| = |
2
| |
2
1| = |
2
1|
CA = |
2
1|
The three points represent the vertices of an equilateral triangle.

2. (r a).(a b) 0 =

r.(a b) a.(a b) =

[r ab] 0 =

3. (SIN
2
1)
2
+ (COS
2
1)
2
+ 2(SIN COS)
2
= 0
which is true if sin
2
= 1, cos
2
= 1
and sin = cos
so sin + cos = 2

4. If x and y are both odd then LHS is of the type 8k + 2 however 2008 is not of this type.
So, x = even = 2m, y = even = 2n m
2
+ n
2
= 502.
Now this equation has no integer solution as 502 is neither of the type 8k + 2 nor a multiple of

5. Imposing the conditions;
b
2a
> 2, b
2
48a and f(2) i.e., 2a b + 6 > 0 there is only one solution
for (a, b) (1, 7)

6. a + b + c = 21 b + c > a a + b + c > 2a 2a< 21 a 10. So 1 a, b, c 10
The cases when a > b >c are (10, 9, 2), (10, 8, 3), (10, 7, 4), (10, 6, 5), (9, 8, 4), (9, 7, 5) and
(8, 7, 6). So, number of cases when a, b, c are all distinct is 7 3! = 42.
The cases when a = b > c or a > b = c are (10, 10, 1), (9, 9, 3), (8, 8, 5) and (9, 6, 6). So number
of cases when two same and 1 different is 4 3! /2! = 12.
The cases when a = b = c is (7, 7, 7). The total number of ordered triplets = 42 + 12 + 1 = 55.

7. Total cases are with numbers ending with 3, 5, 7 or 8.
Favourable cases are with numbers ending with 3, 7 or 8.
So, the required probability = 3/4

8. The letters other than vowels are: PRMTTN
Number of permutations with no two vowels together is
6!
2!

7
C
5
5!
Further among these permutations the number of cases in which T's are together is
5!
6
C
5
5!
So the required number =
6!
2!

7
C
5
5! - 5!
6
C
5
5! = 57 (5!)
2

9. 32
33
= 2
165
= 2 16
41
= 2 (17 1)
41
= 2 (17k 1) = 34k 34 + 32
So the remainder is 32.


9
10. The series is
11 11 11 r 1
13 r
r 2
r 0 r 0
C ( 2) 1
C
(r 1)(r 2) ( 2)12 13
+
+
= =
=
+ +

(2)
r+2

=
1
2 12 13
[(1 2)
13

13
C
0
13(2)]
=
1
24
2 12 13

=
1
13
.

11. f(x) = 3
4
(| x | 1)
(| x | 1)
(
+ +
(
+

3 2 4 = 1

12. Normal to y
2
= 4ax and x
2
= 4by in terms of m are y = mx 2am am
3
and
y = mx + 2b +
3
b
m
. For a common normal 2b +
3
2
b
2am am 0
m
+ =
am
5
+ 2bm
3
+
2bm
2
+ b = 0
That means there can be atmost 5 common normals.

13. ( )
3 2
f x 2x 15x 36x k = + +
( )
( )
( )( )
2
f x 6 x 5x 6 6 x 2 x 3 = + =
( ) f x 0 = for x = 2, 3.
The equation has 3 real and distinct roots. This is possible only when ( ) f 2 > 0 and ( ) f 3 < 0.

14. Since f(x) the cubic curve vanishes at
x = 2 therefore we can choose

2
y f(x) (x 2)(ax bx c) = = + + +

2
dy
(x 2)(2ax b) 1.(ax bx c) 0
dx
= + + + + + =
at x = 1 and x = 1/3

1
3
0
x 14 14 14
2a 2x or a
3 3 3 3
(
+ = =
(
(

a = 1, b = 1, c = 1
Hence the cubic function is f(x) =
2
(x 2)(x x 1) + +

16. f(x) = x
2
sin x tan x
f(x) = 2x cos x tan x sin x sec
2
x
= tan x
2x
cosx sec x
tanx
| |

|
\ .
< 0
f(0) = 0
f(x) ( 0 in the nbd of x = 0.
(l = 0)

18. ( ) A adjA A I A 4 = =

( )
( )
2
n 1 n 1 4
n 1
adjA A 16; adj adjA A A 256
adjKA K adjA

= = = = =
=

( )
n
n 1
adjKA K adjA
=

10

6
adj2A 2 .16 = .

19.
1 1 1 1
sin cosx cos sinx cos cosx sin sinx a
2 2

= + =

1 1
sin sinx cos cosx a

=
a 0 x =

20. Area = 36 sq units.

21. Let
2
t x 1 = + , then ( ) t 1 > and ( ) ( )
2
t logt 1
g t g t
logt
log t
= = .
Thus g(t) decreases for | | t 1,e and
increases for | ) ( )
e
t e, ,g e e
loge
= = .
We observe that ( )
t 1
lim g t
+
and ( )
t
limg t

Thus range of g is | ) e, . Hence range of f is | ) e, .

22. x
2
+ 8x = 12y 4
(x + 4)
2
= 12 (y 1)
Parabola with vertex at ( 4, 1) and latus rectum 12
Shift the origin to (4, 1) without changing the direction
of the axes
Equation reduces to x
2
= 12y
Required area
6
2
0
x
6 3 dx 2 24 6k
12

= =
`

)

x
y
x = 6
(0, 3)
s
L
L
k = 4

23. Since coefficient of x
3
is Positive.
local maximum is at x
1
and local minimum is at x
2
.case(i) : If ( )
1
f x 0 < then ( ) ( )
2 1
f x f x 0 < <
then the only real root will be in ( )
2
x , case (ii) : If ( )
2
f x 0 > then ( ) ( )
1 2
f x f x 0 > > then
equation will have only one real root in the interval ( ) , x .

25.
2 2
2
0
0 0
x f (x)dx x f (x)] f (x)dx =

2 =

27. (xy sin xy + cos xy) ydx + (xy sinxy cos xy) xdy = 0
(xy. sinxy (ydx + xdy) + cos xy (y dx x dy) = 0
(tan xy.d(xy) +
dx dy
x y
= 0
(ln | sec xy| + ln |
x
y
| = K
28. (3x + 2y
2
) ydx + 2x (2x + 3y
2
) dy = 0
( 3xy dx + 2y3 dx + 4x2dy + 6xy2dy = 0
( 2(y3 dx + x.3y2dy) + 3xy dx + 4x2dy = 0
( 2d (xy3) + 3xy dx + 4x2dy = 0
( 2(xy3) .d(xy3) + 3x2y4 dx + 4x3 y3dy = 0
( 2. (xy3) .d(xy3) + d(x3.y4) = 0

11
( x2y6 + x3y4 = c

29. ( ) ( )
g f x is continuous x and not differentiable for x 1
2 1
0
-1 -2

30.
( )
5x 15x 3x 5x
cos9x cos6x cos 2cos cos cos
2 2 2 2
dx
5x 5x 15x 5x 5x
2cos5xcos cos cos cos cos
2 2 2 2 2
+
=
+

dx
( ) = +
cos4x cosx dx
1
sin4x sinx c
4
= + +

Fulltest IV Main Paper Solution Sol Aits 2013 FT IV Jeem

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P = constant since is increasing, therefore V is decreasing.

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