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Topics 1. Thermodynamics vs. kinetics 2. Basic thermodynamics of phase equilibrium 3. Phase diagrams
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G = n
i i
T , P ,n j
(5)
=> A COMMON TANGENT AT xB' (phase 1) and xB''(phase 2) MEANS SAME A AND B FOR BOTH PHASES = EQUILIBRIUM
Mechanical mixture
Solution
Solution
Mechanical mixture
f = mole fraction
A C
Phase rule: F=CP+2 F = no. degrees of freedom C = no. of components P = no. of phases 2 = Temperature and Pressure
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Phase Rule
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(2)
(4) (5)
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(8) (9)
Driving force for crystal growth: = M,gas - M,solid = RT ln[PA-a PBb PCc PDd/K(T)]
(10)
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Deposition diagram for GaxIn1-xAsyP1-y. The dashed line = solutions lattice matched to InP. From Koukitu and Seki, J. Crystal Growth, 49 (1980) p325. A=Cl/(inert gas+H2); B=(III-V)/(inert gas+H2); F=H2/inertgas; R3=GaCl/(GaCl+InCl); R5 =AsH3/(AsH3+PH3)
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