UNICOOL R-134a

SAFETY DATA SHEET 1 Identification of the substance or preparation and the supplier
Product Name: Datasheet Number: Use of the substance/preparation: Product Part Number: Name of Supplier: Address of Supplier: UNICOOL R-134a R-134A 1. 0. 0 Refrigerant 905620 (12.5 kg), 905557 (57 kg) Unitor ASA Willem Barentszstraat 50 3165 AB Rotterdam-Albrandswaard, The Netherlands +31 10 4877 777 +31 10 4877 888 Leen de Visser, Corporate Product Safety Manager, Tel.: +31 6 538 63736 UNITOR ASA, Business Group Refrigeration P.O.Box 300, Skyen N-0212 Oslo Norway +47 22 13 14 15 NCEC: +44 1865 407333, CHEMTREC (800) 424 9300 CMA +1 703 527 3887, Greece +30 210 7793777

Telephone: Fax: Responsible Person: Name of Manufacturer: Address of Manufacturer:

Telephone: Emergency Telephone:

2 Composition/information on ingredients
Chemical Name 1,1,1,2-Tetrafluoroethane (R-134a) Concentration 100 CAS Number 811-97-2 EC Number 212-377-0 R Phrases Symbols -

3 Hazards identification
Odour: Sweet ether-like odour Appearance: Liquefied pressure gas Contact with eyes: May cause irritation Contact with skin: Possible frost-bite of affected areas Inhalation: May cause dizziness, confusion, headache or stupor, In cases of severe exposure, anaesthesia may develop Ingestion: Not regarded as a potential route of exposure.

4 First aid measures

Contact with skin - In case of contact with liquid, thaw frosted parts with water. Do not attempt to remove clothing which has stuck to the skin - Burns must be treated by a physician. Contact with eyes - If substance has got into eyes, immediately wash out with plenty of water for several minutes - Obtain immediate medical attention Ingestion Not regarded as a potential route of exposure. Give 200-300mls (half pint) water to drink Never give anything by mouth to an unconscious person Do not induce vomiting Seek immediate medical attention

Date of Last Change 13-05-04

UNICOOL R-134a

4 First aid measures (....)

Inhalation - Remove patient to fresh air - Apply artificial respiration only if patient is not breathing - When in doubt or symptoms persist, seek medical attention General - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) (S45) Notes to Physicians - Do not give andrenalin or equivalent medicines.

5 Fire-fighting measures
Unstable above 250 deg C, Auto-ignition point >700 deg C at 760 mm Hg Non-flammable Decomposition products may include halogen compounds Portable containers should be moved if possible and without risk Keep container(s) exposed to fire cool, by spraying with water Smoke from fires is corrosive. Take precautions to protect personnel from exposure Use water spray or fog to knock down and absorb corrosive fumes Inform Fire Brigade of potential danger of exploding and rocketing cylinders

6 Accidental release measures

Personal Precautions - Shut off source of leak if safe to do so - In poorly ventilated areas or confined spaces, use an airline respirator or self-contained breathing apparatus Environmental Precautions - Dangerous for the ozone layer (R59) - Avoid release to the environment. Refer to special instructions/Safety data sheets (S61) Clean Up Actions - Shut off source of leak if safe to do so - Allow product to evaporate - Ventilate area

7 Handling and storage

Handling Storage - Keep in a cool, dry, well ventilated place - Do not store above 45 C Use only in well ventilated areas (S51) Restricted to professional users Do not smoke Do not breathe vapour (S23)

8 Exposure controls and personal protection

Exposure Limits - TLV (TWA) 1000 ppm (1,1,1,2-Tetrafluoroethane (R-134A)) Exposure controls - The undiluted product must not be used in a confined space without good ventilation

Date of Last Change 13-05-04

UNICOOL R-134a

8 Exposure controls and personal protection (....)

Occupational exposure controls - In poorly ventilated areas or confined spaces, use an airline respirator or self-contained breathing apparatus - Wear safety boots when handling cylinders.

9 Physical and chemical properties

Odour: Sweet ether-like odour Appearance: Liquefied pressure gas pH - not applicable Boiling point -26.1 C at 760 mm /Hg Vapour pressure 470 kPa @ 25 C Vapour density (air = 1) 3.53 Melting point -108 C at 760 mm /Hg Water solubility 1.5 g/l Density 1210 kg/m3 at 20 C Non-flammable Unstable above 250 deg C, Auto-ignition point >700 deg C at 760 mm Hg Log Pow 1.06

10 Stability and reactivity

This article is considered stable under normal conditions Avoid overheating, Keep away from naked flames, incandescent or hot surfaces Avoid contact with magnesium and alloys containing more than 2% magnesium. See Section 5

11 Toxicological information
Toxicological information - Asphyxiant Inhalation - In cases of severe exposure, anaesthesia may develop - May disturb the respiration, heart and nervous system Contact with skin - May cause frost-bite Contact with eyes - May cause frost-bite Ingestion - Not regarded as a potential route of exposure. Carcinogenicity - No evidence of carcinogenic effects

Date of Last Change 13-05-04

UNICOOL R-134a

12 Ecological information
Ecotoxicity - On available data, substance is not harmful to aquatic life Mobility - This substance is volatile - Insoluble in water Persistence and Biodegradability - Volatile portion is significant Bioaccumulation Potential - Bioaccumulation is insignificant Other Adverse Effects Gobal Warming Potential: 1300 (CO2 = 1; 100 years) Ozone Depletion Potential: 0 GWP and ODP values according to IPCC/ASHRAE/ARI. IPCC = Intergovernmental Panel on Climate Control ASHRAE = American Society of Heating, Refrigeration and Air-Conditioning Engineers ARI = American Refrigeration Institute

13 Disposal considerations
Classification - This material and/or its container must be disposed of as hazardous waste Disposal considerations - Do not discharge into drains or the environment, dispose to an authorised waste collection point - Refer to manufacturer/supplier for information on recovery/recycling(S59)

14 Transport information

Non-Flammable Compressed Gas

UN Proper Shipping Name: UN No.: Hazard Class: Road/Rail (ADR/RID) Proper Shipping Name: ADR UN No.: ADR Hazard Class: Sea (IMDG) Proper Shipping Name: IMDG UN No.: Date of Last Change 13-05-04 1,1,1,2-Tetrafluoroethane 3159 2.2 Packing Group: N/A

1,1,1,2-Tetrafluoroethane 3159 2 Tremcard: N/A

1,1,1,2-Tetrafluoroethane 3159 4

UNICOOL R-134a

14 Transport information (....)

IMDG Hazard Class.: IMDG EmS: IMDG labels: Air (ICAO/IATA) Proper Shipping Name: ICAO Un No.: ICAO Hazard Class.: ICAO subrisk: ICAO Flashpoint: 2.2 2-09 2.2 IMDG Pack Group.: IMDG subrisk: IMDG Flashpoint: N/A N/A N/A

1,1,1,2-Tetrafluoroethane 3159 2.2 N/A N/A ICAO Packing Group.: ICAO Labels: N/A 2.2

DOT / CFR (US Department of Transportation DOT Proper Shipping Name: 1,1,1,2-Tetrafluoroethane Hazardous Material: 1,1,1,2-Tetrafluoroethane Hazard Class: Product RQ (lbs): DOT labels: 2.2 N/A 2.2 Identification Number: DOT subrisk: DOT Flashpoint: UN 3159 N/A N/A

15 Regulatory information
Classification and labelling - Not classified as hazardous for supply Risk Phrases - Not applicable Safety Phrases - Not applicable

16 Other information
The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the individual constituents The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in terms of safety requirements and does not signify any warranty with regard to the product's properties The data given here only applies when product used for proper application(s). The product is not sold as suitable for other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s) without seeking advice from manufacturer This Safety Data Sheet is provided in compliance with The Dangerous Substances Directive (67/548/EEC) This Safety Data Sheet is provided in compliance with The Dangerous Preparations Directive (88/379/EEC) This Safety Data Sheet is provided in compliance with The Safety Data Sheets Directive (2001/58EC)

Date of Last Change 13-05-04