Test paper

Chapters included Haloalkanes and haloarens. Alcohols,phenols and ethers Aldehyde,ketones and carboxylic acids Amines Polymers Chemistry in everyday life

hpXIIC2

Full marks -70 Time 3.h

Q.1.Write the IUPAC name of following compound. (1)

Q.2 .Suggest a reagent for conversion of ethanol to ethanoic acid. Q.3.What is Tollens reagent? Write one usefulness of this reagent. Q.4.How will you convert benzene into aniline. Q.5.Define analgesics.Give one example.

(1) (1) (1) (1)

Q. 6. Give one example of artificial sweetner used by diabetic patients. (1) Q.7.Give one example of elastomer. Q.8.What is monomer of PVC? Q.9.Why is phenol more acidic than ethanol? Q.10.Write the isomers of the compound having formula C4H9Br
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(1) (1) (2) (2)

Q.11.How will you convert ethanol to But-2-enoic acid?

(2)

Q.12.Give simple chemical test to distinguish between Benzaldehyde and acetophenone. (2) Q.13.What is the role of HNO3 in the nitrating used for nitration of benzene (2) Q.14.How will you bring out the following conversion. p-nitroaniline to 3.4,5-tribromobenzene. Q.15.Write the names of and structures of the monomers of the following polymers. (2) (a) Buna-N (b) Dacron Q.16.In Nylon 6,6 what does the designations 6,6 mean. Q.17.What are the main constituents of dettol. Q.18.Complete the following reactions. (a)C2H5NH2+C6H5SO2Cl (i)LiAlH4 (b) )RCONH2+C6H5SO2Cl (ii)H20 Q.19.Of the two bromo derivative C6H5CH(CH3)Br and C6H5CH(C6H5)Br ,which one is more reactive in SN1 substitution reaction. and why? (3) Q.20.Why cant aromatic primary amines be prepared by Gabriel phthalimide synthesis.? Q.21.Both soaps and detergents are used for cleansing purposes but detergents are preferred to soaps.Inspite of their benefits, all the detergents are not biodegradable and hence cause water pollution in rivers and other ways .
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(2) (2) (2)

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Now answer the following questions. (a)What is the difference between soaps and detergents? (b)Why do soaps not work in hard water but detergents do? (c)What type of detergents cause water pollution and what should be done to check it? (3) Q.22.Write the equations for the preparation of iodobutane from (a)1-chlorobutane (b)1-butanol (c) but-1-ene (3)

Q.23.An organic compound (A)having molecular formula C8H16O2 was hydrolysed with dilute sulphuric acid to give a carboxylic acid (B) and a alcohol (C).Oxidation of (C) with chromic acid produced (B).(C) on dehydration give but-2-ene as the major product .Write equations for the reaction involved. (3) Q.24.How do antiseptics differ for disinfectants? Give one example of each. (3) Q.25.Write the structure and one use of each of the following polymers: (a)PVC (b)Urea-formaldehyde resin (c)Bakelite. Q.26.Explain the mechanism of following reaction Conc.H2SO4 2C2H5OH 413K C2H5OC2H5 +H2O (3) (3)

Q.27.Give a brief account of Sandmeyer reaction .In what respect does it differ from Gatterman reaction? (3) Q.28.(a) A chloro compound (A) on reduction with Zn-Cu couple and alchol gives the hydrocarbon (B) with five carbon atoms.When (A) is dissolved in
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ether and treated with sodium 2,2,5,5-tetranethyl hexane is formed. Write the structure of A and B. (b)Although chlorine is electron withdrawing group ,yet it is ortho,para directing in electrophilic substitution reaction why? (c) What are enantiomers? Write the 3-D structure of the enantiomers of 3methylpent-1-ene. (3+1+1=5)

Or (a)An organic compound(A) on treatment with CHCl3 and KOH gives two compounds (B) and (C) .Both (B) and (C) have the same product (D) when distilled with Zn dust .Oxidation of (D) gives (E) having molecular formula C7H6O2.The sodium salt on heating with sodalime gives (F) which may also be obtained by distilling (A) with Zn dust. Identify (A) to F.Write chemical tractions involved in the process. (b)Anisole is less reactive than phenol towards electrophilic substitution reactions. Explain. (3+2=5)

Q.29.A ketone (A) (C4H8O) which undergoes haloform reaction give compound (B) on reduction.(B) on heating with sulphuric acid gives a compound (C) which forms mono ozonide (D).(D) on hydrolysis in presence of zinc dust gives only aldehyde (D).Identify (A) to (E).Write the reactions involved. (5) Or (a)How can aromatic aldehydes and ketones are prepared by the use of Reimer-Tiemann reaction .Illustrate your answer by giving one example. (3) (b)Why is ethanoic acid a weaker acid than benzoic acid. Q.30.(a)Discuss briefly the chemistry of azodye test.
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(2)

(b)How will you distinguish primary ,secondary and tertiary amines by Hinsberg reagent test.Give chemical reaction. (5) Or (a) Write the structures of primary,secondary and tertiary amines having the molecular formula C3H9N. (3) (b)Why is aniline soluble in aq.HCl. (2)