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2. Hazards identification
Emergency overview Physical state Color Odor Signal word Hazard statements Precautionary measures OSHA/HCS status : : : : : : : Solid. [grease] Red. Mild. Petroleum oil CAUTION! MAY CAUSE EYE AND SKIN IRRITATION. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). : Dermal contact. Eye contact. Inhalation. Ingestion.
Routes of entry Potential acute health effects Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Ingestion : No known significant effects or critical hazards. Skin : Moderately irritating to the skin. NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED.
Validated on 5/14/2012.
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MSDS # : 1756
2. Hazards identification
: Moderately irritating to eyes. NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED. Potential chronic health effects Chronic effects : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Over-exposure signs/symptoms Inhalation : No specific data. Ingestion : No specific data. Skin : Adverse symptoms may include the following: irritation redness Eyes : Adverse symptoms may include the following: irritation watering redness Medical conditions aggravated by overexposure : None known. Eyes
3. Composition/information on ingredients
United States Name propylene carbonate Canada Name propylene carbonate Mexico Name propylene carbonate CAS number 108-32-7 UN number % Not available. 0.5-1.5 IDLH H 2 F 1 Classification R 0 CAS number 108-32-7 % 0.5-1.5 CAS number 108-32-7 % 0.5-1.5
Validated on 5/14/2012.
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MSDS # : 1756
Skin contact
Inhalation
Ingestion
5. Fire-fighting measures
Flammability of the product Extinguishing media Suitable Not suitable Special exposure hazards : No specific fire or explosion hazard. : Use an extinguishing agent suitable for the surrounding fire. : None known. : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. : Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides sulfur oxides : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Environmental precautions
Validated on 5/14/2012.
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MSDS # : 1756
Storage
Exposure limits
Mexico Occupational exposure limits No exposure limit value known. Consult local authorities for acceptable exposure limits. Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation procedures or other control measures and/or the necessity to use respiratory protective equipment. Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Personal protection
Validated on 5/14/2012.
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MSDS # : 1756
Hands
Eyes
Skin
Validated on 5/14/2012.
5/12
MSDS # : 1756
: Under normal conditions of storage and use, hazardous reactions will not occur.
: No known significant effects or critical hazards. : No known significant effects or critical hazards. Result Eyes - Moderate irritant Skin - Moderate irritant Skin - Moderate irritant Species Rabbit Human Rabbit Score Exposure 60 milligrams 72 hours 100 milligrams Intermittent 500 milligrams Observation -
Conclusion/Summary Skin
Eyes
Respiratory Sensitizer Conclusion/Summary Skin Respiratory Carcinogenicity Conclusion/Summary Mutagenicity Conclusion/Summary Teratogenicity Conclusion/Summary Validated on 5/14/2012.
: Moderately irritating to the skin. NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED. : Moderately irritating to eyes. NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED. : Repeated or prolonged exposure to spray or mist may produce respiratory tract irritation.
: No specific information is available in our database regarding the skin sensitizing properties of this product. Sensitization not suspected for humans. : Sensitization not suspected for humans. : There are no data available on the preparation itself. Carcinogenicity not suspected for humans. : There are no data available on the preparation itself. Mutagenicity not suspected for humans. : There are no data available on the preparation itself. Teratogenicity not suspected for humans. 6/12
MSDS # : 1756
: No known significant effects or critical hazards. : No known significant effects or critical hazards. Result Eyes - Moderate irritant Skin - Moderate irritant Skin - Moderate irritant Species Rabbit Human Rabbit Score Exposure 60 milligrams 72 hours 100 milligrams Intermittent 500 milligrams Observation -
Conclusion/Summary Skin
Eyes
Respiratory Sensitizer Conclusion/Summary Skin Respiratory Carcinogenicity Conclusion/Summary Mutagenicity Conclusion/Summary Teratogenicity Conclusion/Summary Reproductive toxicity Conclusion/Summary Mexico Acute toxicity
: Moderately irritating to the skin. NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED. : Moderately irritating to eyes. NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED. : Repeated or prolonged exposure to spray or mist may produce respiratory tract irritation.
: No specific information is available in our database regarding the skin sensitizing properties of this product. Sensitization not suspected for humans. : Sensitization not suspected for humans. : There are no data available on the preparation itself. Carcinogenicity not suspected for humans. : There are no data available on the preparation itself. Mutagenicity not suspected for humans. : There are no data available on the preparation itself. Teratogenicity not suspected for humans. : There are no data available on the preparation itself. Not considered to be dangerous to humans, according to our database.
Validated on 5/14/2012.
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MSDS # : 1756
: No known significant effects or critical hazards. : No known significant effects or critical hazards. Result Eyes - Moderate irritant Skin - Moderate irritant Skin - Moderate irritant Score Rabbit Human Rabbit Score Exposure 60 milligrams 72 hours 100 milligrams Intermittent 500 milligrams Observation -
Conclusion/Summary Skin
Eyes
Respiratory Sensitizer Conclusion/Summary Skin Respiratory Carcinogenicity Conclusion/Summary Mutagenicity Conclusion/Summary Teratogenicity Conclusion/Summary Reproductive toxicity Conclusion/Summary
: Moderately irritating to the skin. NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED. : Moderately irritating to eyes. NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED. : Repeated or prolonged exposure to spray or mist may produce respiratory tract irritation.
: No specific information is available in our database regarding the skin sensitizing properties of this product. Sensitization not suspected for humans. : Sensitization not suspected for humans. : There are no data available on the preparation itself. Carcinogenicity not suspected for humans. : There are no data available on the preparation itself. Mutagenicity not suspected for humans. : There are no data available on the preparation itself. Teratogenicity not suspected for humans. : There are no data available on the preparation itself. Not considered to be dangerous to humans, according to our database.
: There are no data available on the preparation itself. : This product has not been tested for biodegradation. Not readily biodegradable. 8/12
MSDS # : 1756
: There are no data available on the preparation itself. : This product has not been tested for biodegradation. Not readily biodegradable.
Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees.
Validated on 5/14/2012.
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MSDS # : 1756
Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) SARA 313
Product name Form R - Reporting requirements Supplier notification : No listed substance : No listed substance
CAS number
Concentration %
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. State regulations Connecticut Carcinogen Reporting Connecticut Hazardous Material Survey Florida substances Illinois Chemical Safety Act Illinois Toxic Substances Disclosure to Employee Act Louisiana Reporting Louisiana Spill Massachusetts Spill Massachusetts Substances Michigan Critical Material Minnesota Hazardous Substances New Jersey Spill New Jersey Toxic Catastrophe Prevention Act New Jersey Hazardous Substances Validated on 5/14/2012. : : : : : : : : : : : : : : None of the components are listed. None of the components are listed. None of the components are listed. None of the components are listed. None of the components are listed. None of the components are listed. None of the components are listed. None of the components are listed. None of the components are listed. None of the components are listed. None of the components are listed. None of the components are listed. None of the components are listed. None of the components are listed. 10/12
MSDS # : 1756
California Prop. 65 WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer. Ingredient name Cancer Reproductive No significant risk level No. Maximum acceptable dosage level No.
Yes.
No.
Canada WHMIS (Canada) : Class D-2B: Material causing other toxic effects (Toxic). Canadian lists Canadian NPRI : None of the components are listed. CEPA Toxic substances : None of the components are listed. Canada inventory: : All components are listed or exempted. DSL/NDSL This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Mexico Classification : 1 Health 1 Flammability 0 Reactivity Special
Chemical Weapons Convention List Schedule I Chemicals Chemical Weapons : Not listed Convention List Schedule II Chemicals Chemical Weapons : Not listed Convention List Schedule III Chemicals
: Australia inventory (AICS): All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. Japan inventory: Not determined. Korea inventory: All components are listed or exempted. New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Europe inventory : All components are listed or exempted. : Not listed
Validated on 5/14/2012.
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MSDS # : 1756
Validated on 5/14/2012.
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