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Research Interests
Synthesis of Nanoparticles Synthesis of Nanoparticle-based Nanocomposites Surface Modification of Nanoparticles Optical Spectroscopy of Nanomaterials
A simple route to synthesize highly luminescent semiconductor nanocrystals with core/shell structure was developed.
Absorption
Cu0.2InS2
PL
Cu0.2InS2/ZnS
PL
Absorption
Cu0.2InS2/(Cd,Zn)S
PLE
Absorption
PL
PL intensity
Semiconductor nanocrystals-silica composite particles were synthesized by combination of spray drying and sol-gel processing. White light emitting diodes with high color rendering index were fabricated with nanocomposite particles and inorganic matrix successfully passivated the surface of nanocrystals for highly improved luminescence stability.
QD-SiO2 nanocomposite
50nm
Luminescence of copper indium sulfide nanocrystals was dramatically enhanced by surface modification . Uniform size/shape distribution Wavelength shift by alloyed shwll
PLE
PLE
300
400
500
600
700
800
300
400
500
600
700
800
300
400
500
600
700
800
Wavelength (nm)
Wavelength (nm)
Wavelength (nm)
QY ~ 5%
QY ~ 70~80%
QY ~ 50%
30nm
30nm
30nm
emission (a.u.)
400 450 500 550 600 650 700 750 wavelength (nm)
Stability of emission spectra of LED
Uniform dispersion of nanoparticles in polymer matrix : organic-inorganic hybrid nanocomposite for solar cells
Pristine CdPbSe-P3HT
A simple route to synthesize highly branched semiconductor nanocrystals by alloying Anisotropy of CdSe semiconductor nanocrystals were enhanced by alloying with Pb. No special surfactants (alkylphosphonic acid) are required to synthesize the branched nanocrystals
Anisotropic growth along (001) of wurzite
225oC
x=0
(002)
XRD
(110) (103) (112)
Cd1-xPbxSe
(203)
Surface of nanocrystals were modified with organic ligands and uniform dispersion of nanoparticles in conjugated polymer matrix for hybrid solar cells were realized. The short circuit current densities were enhanced by addition of CdSe tetrapods capped with a new ligands up to 3.39% which is more than 10% increase in efficiency compared with undoped P3HT:PCBM blends.
Ligand-treated CdPbSe-P3HT
100nm
(100)
100nm
(101)
x=0
x=0.05
2 0
J(mA/cm )
2
x=0.05
<001>w
-2 -4 -6 -8 -10
x=0.10 x=0.20
20 30 40 50 60 70
x=0.2
<111>cubic 0.35nm 5nm
LiF/Al
2 theta (deg.)
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 Voltage (V)