Documente Academic
Documente Profesional
Documente Cultură
(+46) (0)10 445 95 00 Fax (+46) (0)10 445 95 01 Stena Aluminium A/S Metalvej 10 DK-6000 Kolding, Denmark Tel. (+45) 76 30 56 00 Fax (+45) 76 30 56 01 info@stenaaluminium.com www.stenaaluminium.com
Aluminium alloys for foundries and deoxidization for steel mills Stena Aluminium
When using alloys, many circumstances exist that are outside the control of Stena Aluminium, which is why we cannot assume responsibility for defects that are deemed to have been caused by abnormal handling and use beyond the recommendations described in the brochure.
Stena Aluminium.
Stena Aluminium is the leading producer of recycled aluminium in the Nordic region. Our miss Our mission is to produce and market customized aluminium alloys for foundries and deoxidization for steel mills. Our enterprise today is conducted at two plants, lmhult in Sweden and Kolding in Denmark. The licensed volumes for both plants combined comprise at present 90,000 tons per year. Stena Aluminium has an annual turnover exceeding SEK 1.7 billion with around 140 employees. Stena Aluminium is a part of the Stena Metall Group, which has operations in more than 250 locations and in 13 countries. This means that we are able to guarantee access to raw materials and, no less importantly, dependable deliveries, even for very large quantities.
We think and work with the future in mind. Our task is to help our customers be successful. We do it by forming longterm relationships built on flexibility, the right quality, high delivery performance and availability in products and technical support. In order to help our customers be successful, we work continually on finding new ways to improve. We are constantly developing the unique characteristics of our processes and products. All of Stena Aluminiums operations are certified according to ISO 9001:2000 and ISO 14001:2004. The systems are an active part of our daily work.
In this brochure, we present the European standards for aluminium alloys for foundry purposes. At Stena Aluminium, nearly all alloys are produced in order to fulfil customer-specific requirements. Our customers mainly come from the automotive, electronics, machine shop and furniture industries. At present, we have over 450 different Types of customer-adapted aluminium alloys with varying requirements for electrical conductivity, thermal conductivity, corrosion, resistance, strength, finishing quality, flexural strength, tensile yield limit, cutting property, weldability, etc. Consistently high quality Maintaining consistently high quality and delivering within tolerance limits has become our speciality. Through
the use of large smelters in our smelting process, we are also able to guarantee consistency and high quality for large-volume deliveries. Our large furnaces take up to 30 tons and guarantee consistent analysis, even in large quantities. However, our comprehensive quality controls during the process, from the receiving of the raw materials to final inspection upon delivery, are an even more important guarantee. Our customers must always feel confident that we are delivering the highest possible quality, so they in turn can deliver the same high quality to their customers. Ingots or liquid We were the first in the Nordic region to deliver liquid aluminium to indus-
trial customers, in large thermoses that contain up to eight tons per container. The smelted aluminium is transported in liquid form and is able to be used in the customers production process immediately on arrival. The aluminium will have a temperature that has been adjusted to the needs of the customers own process. We will of course also continue to cast aluminium ingots in the future.
Casting properties Aluminium Solidification range 0 C approx. 600-550 Casting temperature 0 C about 650-700 Fluidity Hot tearing Resistance Shrinkage about % Pressure tightness
Heat treatment
total
EN AB-43400
EN AB-AISiI0Mg (Fe)
9.0-11.0
0.45-0.9 (1.0) 0.45-0.9 (1.0) 0.55 (0.65) 0.6-1.1 (1.3) 0.45-1.0 (1.1) 0.6-1.2 (1.3) 0.6-1.1 (1.3)
0.08 (0.10) 0.08 (0.10) 0.08 (0.10) 2.0-4.0 1.5-2.5 2.0-4.0 0.7-1.2
0.55
0.15
0.15
0.15
0.05
0.15 (0.20) 0.15 0.15 0.20 (0.25) 0.20 (0.25) 0.20 (0.25) 0.15 (0.20)
0.05
0.15
Rest
Excellent
Excellent
0.5-0.8
Good
EN AB-AISiI2 (Fe) EN AB-AISi91) EN AB-AISi9Cu3 (Fe EN AB-AISil ICu2 (Fe) EN AB-AISi9Cu3(Fe)(Zn) EN AB-AISiI2CuI(Fe)
Not age-hardened Not age-hardened Normally not age-hardened. Normally not age-hardened. Normally not age-hardened. Normally not age-hardened.
Note: The value in parentheses is the die casting composition where it differs from ingots.
1) 2)
= Standardized for pressure die casting but normally used for sand and chill casting. Other does not involve material for grain refinement or processing of smelt such as Na, Sr, Sb and P. Mechanical properties of separately cast test bars Older standard State1) Tensile strength Rm MPa2) min. 240 Proof stress Rp0.2 MPa2) min. 140 Elongation A50 % min. 1 Brinell hardness HBS min. 70 Near-eutectic alloy with excellent castability properties and good resistance to hot tearing. Good machinability and high resistance to chemical attack. Eutectic alloy with excellent castability properties, excellent fluidity and high resistance to hot tearing. Good machinability and high resistance to chemical attack. Near-eutectic alloy with excellent castability properties but likely to adhere to the tool. Good resistance to hot tearing and high resistance to chemical attack. Universal alloy with very good castability, particularly suitable for pressure die casting. Slight tendency towards forming surface and internal cavities. Good machinability. Alloy with very good castability, excellent fluidity and good machinability. Universal alloy with very good castability, particularly suitable for pressure die casting. Slight tendency towards forming surface and internal cavities. Very good machinability. Eutectic alloy with excellent castability properties, excellent fluidity and high resistance to hot tearing. Good machinability. For complicated, thin-wall, pressure-tight castings subjected to fatigue loading. Good resistance to corrosion and high strength. For complicated, thin-walled, pressure-tight and corrosion-resistant castings subjected to fatigue loading. Particularly suitable for difficult thin-wall castings with good elongation properties. For castings that require good toughness and resistance to corrosion. For wide range of applications. Also for complicated and thin-wall castings. Particularly Particularly suitable for highly stressed pressure die castings. For wide range of applications. Particularly suitable for thin-wall castings. For wide range of applications. Also for complicated and thin-wall castings. Especially suitable for highly stressed pressure die castings. For complicated, thin-walled, pressure-tight and corrosion-resistant castings subjected to fatigue loading. General description of properties Suitable applications Mechanical and physical properties Density approx. value kg/dm 3) 2.65 Strength Machinability Weldability 3) Resistance to corrosion Satisfactory Satisfactory Satisfactory Poor Decorative anodizing Polishability Linear thermal expansion 293-3730K 0 1 K21x10
-6
Alloys for pressure die casting Alloy designation according to: SS-EN 1780-I numerical EN AB-43400 SS-EN 1780-2 chemical AN AB-AISiI0Mg (Fe) -
DF
Good
Good
Poor
Not recom.
Poor
EN AB-44300
EN AB-AISiI2 (Fe)
DF
240
130
60
2.65
Good
Poor
Not recom.
Poor
-6 20x10
16-22
130-160
EN AB-444001)
EN AB-AISi91)
DF
220
120
55
2.65
Satisfactory Good
Poor
Not recom.
Poor
16-22
130-150
EN AB-46000
EN AB-AISi9Cu3 (Fe)
DF
240
140
<1
80
2.75
Poor
Not recom.
13-17
110-120
EN AB-46100 EN AB-46500
DF DF
240 240
140 140
<1 <1
80 80
2.75 2.75
Good Good
Satisfactory Good
Poor Poor
Poor Poor
14-18 13-17
120-130 110-120
EN AB 47100
EN AB-AISiI2CuI(Fe)
DF
240
140
70
2.65
Good
Satisfactory
Poor
Satisfactory
Not recom.
-6 20x10
15-20
120-150
5
SS = Swedish standard EN = European standard AB = Aluminium ingots 1) = Standardized for pressure die castings, but used normally for sand and chill casting
1)
D = F = 2)1MPa =
3) = The weldability of pressure die castings depends upon the quantity of entrapped gas and in most cases is very poor. With special pressure die casting techniques, satisfactory to good weldability may be obtained.
Alloys for sand and chill casting Alloy designation according to: SS-EN 1780-I SS-EN 1780-2 numerical chemical EN AB-42000 EN AB-A1Si7Mg Older standard
Chemical composition for cast alloys according to SS-EN 1676 (in % weight) Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti Other Each Type 4244 6.5-7.5 0.45 (0.55) 0.40 (0.55) 0.45 (0.55) 0.55 (0.65) 0.55 (0.65) 0.40 (0.55) 0.7 (0.8) 0.7 (0.8) 0.7 (0.8) 0.15 (0.20) 0.03 (0.05) 0.08 (0.10) 0.30 (0.35) 0.10 (0.15) 0.03 (0.05) 2.0-3.5 0.8-1.3 0.35 0.25-0.65 (0.20-0.65) 0.25-0.45 (0.20-0.45) 0.25-0.45 (0.20-0.45) 0.25-0.45 (0.20-0.45) 0.10 0.15-0.55 (0.05-0.55) 0.30-0.65 (0.25-0.65) 0.35 0.15 0.15 0.15 0.05 0.05-0.20 (0.050.25) 0.15 0.05
1)
Gjutegenskaper Aluminium Total 0.15 Rest Solidification range o C about 620-570 o C about Fluidity Hot tearing Resistance o C ca Excellent Shrinkage about % Pressure tightness
Heat treatment
700-750
Good
Good
Solution annealing at 520-530 C for 3-6 hours, after which o it is quenched in water and artificially aged at 150-175 C for 15-5 hours Solution annealing at 520-530 C for 3-6 hours, after which o it is quenched in water and artificially aged at 150-175 C for 15-5 hours Solution annealing at 520-530 C for 3-6 hours, after which o it is quenched in water and artificially aged at 150-175 C for 15-5 hours Solution annealing at 520-530 C for 3-6 hours, after which o it is quenched in water and artificially aged at 150-175 C for 15-5 hours Not age-hardened. Annealed at 520-530 C hours, after which it is quenched in water. Not age-hardened. Annealed at 520-530 C for 3-5 hours, after which it is quenched in water. Normally not age-hardened. Solution annealing at 520-530 C for 3-6 hours, after which o it is quenched in water and artificially aged at 150-175 C for 15-5 hours. Not age-hardened.
3)
EN AB-43000
EN AB-A1Si 10Mg(a)
Type 4253
9.0-11.0
0.45
0.05
0.10
0.05
0.05
0.05
0.15
Rest
600-550
680-750
Excellent
Good
EN AB-43100
EN AB-A1Si 10Mg(b)
Type 4253
9.0-11.0
0.45
0.05
0.10
0.05
0.05
0.15
0.05
0.15
Rest
600-550
680-750
Excellent
S:1-1.2 K:0.8-1 S:1-1.2 K:0.8-1 S:1-1.1 K:0.8-1 S:1-1.1 K:0.8-1 S:1-1.1 K:0.9-1 S:1-1.1 K:0.8-1 S:1-1.1 K:0.8-1
2)
Good
EN AB-43200
EN AB-A1Si 10Mg(Cu)
Type 4253
9.0-11.0
0.55
0.15
0.35
0.10
0.15 (0.20) 0.15 (0.20) 0.15 0.20 (0.25) 0.10-0.18 (0.10-0.20) 0.15 (0.20)
0.05
0.15
Rest
600-530
680-750
Excellent
Excellent
Good
0.15 0.10
EN-AB 47000
EN AB-A1Si 12(Cu)
Type 4260
10.5-13.5
0.9 (1.0)
0.050.55
0.10
0.30
0.55
0.20
0.10
0.05
1)
0.25
Rest
580-530
680-750
Excellent
Excellent
Excellent
Note: The value in parentheses is the die casting composition where it differs from ingots.
Other does not involve material for grain refinement or processing of smelt such as Na, Sr, Sb and P.
Shorter time and/or higher temperature for chill casting. Longer time and/or lower temperature for sand casting. The time is first computed only when the temperature is attained.
7
Good
Good
Good
Good/ Satisfactory
Poor
Satisfactory
EN AB-43000
EN AB-A1Si 1 0Mg(a)
Type 4253
Near-eutectic alloy with excellent castability properties and good resistance to hot tearing. Good machinability, excellent weldability and high resistance to chemical attack.
For complicated, thin-walled, pressure-tight castings subjected to fatigue loading. Very good resistance to corrosion and high strength after heat treatment.
2.65
Good, vid ldr.hrdning mycket Good Good, vid ldr.hrdning mycket Good Good, with artificial ageing very good. Poor
Good
Excellent
Good
Not recom.
Poor
-6 21x10
19-25
150-170
EN AB-43100
EN AB-A1Si 1 oMg(b)
Type 4253
Near-eutectic alloy with excellent castability properties and good resistance to hot tearing. Good machinability, excellent weldability and high resistance to chemical attack.
For complicated, thin-walled, pressure-tight and corrosion-resistant castings subjected to fatigue loading. Good resistance to corrosion and high strength after heat treatment. For complicated, thin-walled, pressure-tight and corrosion-resistant castings subjected to fatigue loading. High strength after heat treatment, but with limited properties concerning resistance to corrosion. For complicated, thin-walled, pressure-tight and corrosion-resistant castings subjected to fatigue loading. Good elongation properties and good resistance to corrosion. For complicated, thin-walled, pressure-tight and corrosion-resistant castings subjected to fatigue loading. Good elongation properties and very good resistance to corrosion. For wide range of applications, also for complicated and thin-wall castings. For wide range of applications, also for complicated and thin-wall castings. For complicated, thin-walled, pressure-tight and corrosion-resistant castings subjected to fatigue loading, but with limitations involving resistance to corrosion and toughness.
2.65
Good
Excellent
Good/ Satisfactory
Not recom.
Poor
-6 21x10
18-25
140-170
EN AB-43200
EN AB-A1Si 1 0 Mg(cu)
Type 4253
Near-eutectic alloy with excellent castability properties and good resistance to hot tearing. Good machinability and excellent weldability.
2.65
Good
Excellent
Satisfactory
Not recom.
Satisfactory
-6 21x10
16-24
130-170
EN AB-44100
EN AB-A1Si 1 2 (b)
Eutectic alloy with excellent castability properties, excellent fluidity and high resistance to hot tearing. Good machinability, excellent weldability and high resistance to chemical attack. Eutectic alloy with excellent castability properties, excellent fluidity and high resistance to hot tearing. Good machinability, excellent weldability and high resistance to chemical attack. Universal alloy with very good castability. Slight Slight tendency towards forming surface and internal cavities. Good machinability and good weldability. Universal alloy with very good castability. Slight tendency towards forming surface and internal cavities. Good machinability and good weldability. Eutectic alloy with excellent castability properties, excellent fluidity and high resistance to hot tearing. Good machinability, excellent weldability.
2.65
Not recom. Not recom. Not recom. Not recom. Not recom.
Poor
-6 20x10
16-23
130-160
EN AB-44200
EN AB-A1Si 1 2 (a)
SF KF
150 170
5 6
50 55
2.65
Poor
Poor
-6 20x10
17-24
140-170
EN AB 46200
EN AB-A1Si8Cu3
SF KF SF KF KT6 SF KF
1 1 1 1 1.5 1 2
60 75 60 75 105 50 55
2.75
Good
Poor
Satisfactory Poor
-6 21x10 -6 21x10
14-18
110-130
EN AB 46400
EN AB-A1Si9Cu 1 Mg
2.65
Excellent
Good
Good
Poor
16-22
130-150
EN AB 47000
EN AB-A1Si 1 2(Cu)
Type 4260
2.65
Poor
Satisfactory
Excellent
Satisfactory
Satisfactory
-6 20x10
16-22
130-150
= Sand cast T6 = Solution annealed and artificially aged. T64 = Solution annealed and artificially aged (underaged). K = Chill cast F = Cast state (The description corresponds to SS-EN 1706) 2) 1MPa = 1N/mm2
1)S
Alloy key.
Alloys for pressure die casting
Europe EN 1706 43400 44300 44400 46000 46100 46500 47100 ISO AISi10Mg(Fe) AISi12 (Fe) AISi9 AISi9Cu3(Fe) AISi11Cu2(Fe) AISi9Cu3(Fe)(Zn) AISi12Cu1(Fe) LM24 LM2 LM24 LM20 A380.0 A413.0 ADC1 B380.0 ADC10 ADC12 226/3 231D 4252 4260 A-S9U3X A-S12U 4525 5079 226 D LM20 ADC2 UK BS US AA Japan JIS Germany DIN 239 D 230 D 4263 4255 4250 A-S12 AS-9 A-S9U3 5075 Sweden SIS France NF Italy UNI
We cannot be held responsible for any possible errors, there is no exactitude in the alloy comparisons, but rather they indicate comparable alloys, Types.
47000
9 11
10
Product description
Descriptions and pictures follow below of our products. All of our products can be delivered in the form of ingots or drops. The casting alloys can also be delivered in liquid form, which is the most cost-effective form of delivery for our customers. Normally, aluminium alloys for casting are delivered as ingots and deoxidization aluminium as drops. The ingots are stacked in lots, where two lots are bundled together for more efficient handlings. Drops are delivered in loose form on loading platforms or in big bags. All dimensions and weights are nominal, deviations may occur.
Chemical composition Material Si Fe Cu Mn Mg Cr Ni Zn Pb Sn Ti Sr Ca P Sb Min. % 8,70 0,50 2,70 0,30 0,35 0,05 0,030 Max % 9,40 0,60 3,30 0,40 0,45 0,30 1,20 0,20 0,10 0,10 0,05 0,003 0,002 0,005
Mechanical properties The standard deviation (1s) is given within parentheses - air-cooled (ac) and water-cooled (wc) for separately cast test bars Proof stress Rp0.2,MPa,min. Ac 220 (22) Wc 226 Tensile strength Elongation Rm,MPa, min A25m,% 361 (25) 352 (6) 2,8 (0,6) 2,6 (0,3) Brinell hardness HBm5/250, r.t N2(1) 118 123 110 107
Drops
Weight, g 70-120 Height, mm 35 Diameter Diameter bottom, mm top, mm 40 30
Ingots
Weight, kg 6,5 Height, mm 60 Length, mm 600 Width, mm 90
Mechanical properties - average value for both air-cooled and water-cooled test bars Proof stress Rp0.2,MPa,min. Ac+Wc 225 (11,3) Tensile strength Rm,MPa, min 357 (9,5) Elongation A25m,% 2,7 (0,26) Q,Rm+150 log A5 422
Other materials each max 0.05 % and in total max. 0.25 %. Note: The Sr content is higher for delivery-state ingots. For castings 150-300 ppm
Deoxidization aluminium.
Stena Aluminium also produces aluminium for deoxidization purposes. These products are also produced on the basis of customer-specific requirements, where the composition is predominantly based upon the aluminium content, for example 96% aluminium. These products are primarily delivered in big bags or on loading platforms.
11
12
Stena Aluminium is the first producer in the Nordic region to be able to deliver aluminium in liquid form, thus further helping our customers to increase their success and competitive strength. The concept of liquid aluminium deliveries involves large environmental and cost-related benefits. The liquid aluminium is delivered in large thermoses that maintain the heat during transport from the smelter to the customer. During transport, heat loss is approx. 5-9 degrees per hour, however, by leaving our smelter at a pre-adjusted temperature, the temperature upon arrival can be at the level the customer requires for his process. The thermoses contain approx. eight tons and in Sweden we can deliver up to three thermoses at a time. By delivering a full load of liquid aluminium, we save approx. 2 tons of greenhouse gas emissions, in comparison with deliver-
ing ingots. This is and will be an increasingly important competitive advantage There are both direct and long-term savings for the customer in using liquid aluminium deliveries instead of ingots, a number of which are mentioned below. Direct savings, effects Diminished metal loss. Diminished energy consumption. Less bound capital. Smaller handling costs. Diminished maintenance costs. Increased environmental savings. Long-term savings, effects. Diminished investment needs. Increased efficiency of existing space. Potential for quality improvements. More consistent metal temperature.
When delivery of liquid aluminium is taken in a thermos, the customer can use it in production directly through the tip station that the thermos is set up in. In this way, it is even possible to replace prior on-site furnaces with the thermos. Heating equipment can be connected up to the tip station to ensure that the temperature is kept at the right level according to the needs of the casting process. It is even possible to connect up magnetic stirring, which ensures that the metal circulates continuously, thereby increasing the homogeneity and consistency of the metal in the heat.
Stena Aluminium is the first producer in the Nordic region to be able to deliver aluminium in liquid form, thus further helping our customers to increase their success and competitive strength.
13 15
12