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P-Block Element Test 1. 2. 3. 4. How many sulphur atoms in polythionic acid ion SnO62 have only SS bonds. (A) n (B) n1 (C) n2 (D) n/2 Phosphorus sulphide P4S3, a well known chemical used in match industry has how many PS bonds? (A) 4 (B) 2 (C) 6 (D) 8 Hybridisation state of Si in SiO2 is (A) sp (B) sp2 (C) sp3 (D) sp3d

An element X which occurs in the first short period has an outer electronic structure s 2p1. What are the formulae and acid-base character of its oxides? (A) XO3, basic (B) XO3, acidic (C) X2O3, acidic (D) X2O3, basic
Cold and dilute NaOH

5.
Cl2

(A) + NaCl + H2O (B) + NaCl + H2O

Hot and conc. NaOH

Compounds (A) and (B) are: (A) NaClO3, NaClO (B) NaClO2, NaClO (C) NaClO4, NaClO3 (D) NaClO, NaClO3 The number of sigma and Pi bonds in one molecule

6. of P4O10 is respectively (A) 8, 4 7.

+

(B) 6, 6

(C) 16, 4

(D) 12, 4
+

When N2 goes N2 , the NN bond distance .. and when O2 goes to O 2 , the OO bond distance (A) increases, decreases (B) decreases, increases (C) increase in both case (D) decrease in both case B H B bridge in B2H6 is formed by the sharing of (A) 2 electrons (B) 4 electrons (C) 1 electron (D) 3 electrons (D) Potassium iodide

8. 9. 10. 11. 12.

Bromine can be liberated from potassium bromide solution by (A) Iodine solution (B) Chlorine solution (C) Sodium chloride Paramagnetic species is (A) Cl2O (B) ClO2 (C) Cl2O7

(D) Cl2O6 (D) N2O5 (D) HNO2 and HCl

Which of the following does not decolorise acidified KMnO4 solution (A) NO2 (B) NO (C) N2O3 NCl3 on hydrolysis gives (A) NO2 and HCl (B) NH3 and HOCl (C) NO and HCl

13.

N-O bond order in NO3 ion is (A) 2 (B) 1

(C) 1.5 (C) HIO4

(D) 1.33 (D) I2O4

14. 15.

On strong heating H5IO6 gives (A) I2O5 (B) I2O7

A silicates having two dimensional sheet structure and having general formula as (Si 2O5)n2n. How many oxygen atoms are shared from one SiO4 tetrahedron unit?

16.

(A) 1 (B) 2 I4O9 is a/an (A) Covalent compound (C) Ionic Compound Tincture of iodine is: (A) Aqueous solution of I2 (C) Alcoholic solution of I2

(C) 3

(D) 4 (B) Coordinate Compound (D) Double salt (B) Solution of iodine in aqueous KI (D) Aqueous solution of KI

17.

18. 19. 20. 21.

HClO4 + P2O5 (A) + (B); (A) and (D) are (A) HClO3, H3PO4 (B) Cl2O6, HPO3 (C) ClO2, H3PO4 Which has maximum pH in aqueous solution? (A) NaClO (B) NaClO2 (C) NaClO3

(D) Cl2O7, HPO3 (D) NaClO4

The number of lone pairs and the number of SS bonds in S8 molecules are respectively: (A) 8, 8 (B) 16, 8 (C) 8, 16 (D) 8, 4 The number of isomers possible for di-substituted Borazine, B3N3H4Cl2 is (A) 3 (B) 4 (C) 5 (D) 6

From Question No. 25 to 30, more than one option may correct. 22. 23. 24. Out of the following oxides of nitrogen, which have N-O-N linkage? (A) N2O4 (B) N2O3 (C) N2O5 When NO2 dissolved in water it can give? (A) HNO2 (B) H2NO2 Which of the following statement is true (A) H3PO3 is tribasic and reducing (C) H3PO4 is tribasic and non-reducing (C) HNO3 (D) N2O (D) None of these

(B) H3PO3 is dibasic and reducing (D) H3PO4 is tribasic and reducing (B) It is acidic and paramagnetic (D) It is less stable than NO+ ion

25.

Which of the following statement(s) is true regarding NO (A) It is absorbed by FeSO4 to from a brown ring complex (C) It is neutral and paramagnetic
H 2 S cannot be dried by passing over conc. H 2 SO4 because

26.

(A) The acid oxidises it (C) Both form complex

27. 28.

(B) The acid combines with H 2 S to form a salt (D) It dissolves in the acid.
(D) N2O5

The nitrogen oxide(s) that contain(s) NN bond(s) is (are) (A) N2O (B) N2O3 (C) N2O4 In the reaction 2X + B2H6 B2H6.2X or [ BH 2 ( X )2 ]+ [ BH 4 ] The amine(s) X is (are) (A) NH3 (B) CH3NH2 (C) (CH3)2NH Which of the following contain coordinate bond? (A) H3O+ (B) BF 4 (C) HF 2

(D) (CH3)3N
+ (D) NH 4

29.

30.

Which of the following process is/are associated with change of hybridization of the underlined compound? (A) Al(OH)3 ppt. dissolved in NaOH (B) B2H6 is dissolved in THF

(C) SiF4 vapour is passed through liq. HF (D) Solidification PCl5 vapour From Q31 to Q34, read the given comprehension for oxyacid of Phosphorous and answer the following Phosphorous form two series of oxaacids namely phosphorous acid and phosphoric acids. Each series contains H3PO2 Hypophosphorus acid H3PO3 Phosphorus acid H4P2O6 Hypophosphoric acid H3PO4 Orthophosphoric acid H4P2O7 Pyrophosphoric acid (HPO3)n Metaphosphoric acid tetrahedral phosphorous atom. e.g. 31. 32. 33. 34. Out of the following acids, which one has P-P linkage? (A) H4P2O6 (B) H4P2O7 (C) (HPO3)3 Number of and bonds in cyclotrimeta phosphate ion, (PO3)33- ? (A) 10, 3 (B) 12, 3 (C) 9, 6 Maximum basicity of Diphosphoric acid, H4P2O6 is (A) 1 (B) 2 (C) 3 Out of the following, which cant act as reducing agent? (A) H3PO4 (B) H3PO3 (C) H4P2O6 (D) None of these

(D) 6, 6 (D) 4 (D) (HPO3)3

From Q35 to Q38, read the given comprehension for oxyacid of Sulphur and answer the following Sulphur forms a number of oxoacids such as H2SO3, H2S2O3, H2S2O4, H2S2O5, H2SnO6 (n = 2 to 12), H2SO4, H2S2O7, H2SO3 Sulphurous aicd H2S2O5 Pyrosuphurous acid H2S2O4 Dithionous acid H2S2O3 Thiosulphuric acid H2S2O7 Pyrosulphuric acid H2S2O6 Dithionic acid H2SnO6 Poythionic acid (n = 2 to 12) H2SO5 Peroxyo monosulphuric acid H2S2O8 Peroxidisulphuric acid be isolated. They are known in aqueous solution or in the form of their salts. H2SO5, H2S2O8. Some of these acids are unstable and cannot

35. 36. 37.

Oxidation state of both the Sulphur atoms in Thiosuphuric acid is (A) +2, +2 (B) +4, 0 (C) +6, 0 Out of the following, which dont have S-S bond? (A) H2S2O6 (B) H2S2O8 (C) H2S4O6 In which of the following oxo acid, -O-O-, peroxide link is present?

(D) +6, -2 (D) None of these

(A) H2SO3 38.

(B) H2SO4

(C) H2S2O6

(D) H2S2O8

Identify the correct sequence of increasing number of -bonds in structures of the following molecules. (i) H2S2O6 (ii) H2SO3 (iii) H2SO5 (A) i, ii, iii (B) ii, iii, i (C) ii, i, iii (D) i, iii, ii

From Q39 to Q41, read the given comprehension for Halogens and answer the following Questions Due to high electronegativity and small size, fluorine forms only one oxoacid, HOF known as hypofluorous acid. The other halogens form several oxoacids. Most of them cannot be isolated in pure state. They are stable only in aqueous solutions or in the form of their salts, as HClO Hypochlorous acid HClO2 Clorous acid HClO3 Chloric acid HClO4 Perchloric acid

When two different halogens react with each other, Interhalogen compounds are formed. They can be assigned general compositions as XX, XX3, XX5 and XX7 where X is halogen of larger size and X of smaller size and X is more electropositive than X. 39. 40. 41. Out of the following, which one is strongest oxidizing agent? (A) KClO4 (B) KClO3 (C) KClO2 Which one out of the following is pseudo halide ion? (A) CH3COO (B) CN (C) OH (D) KClO (D) CH3

Which one out of the following interhalogen compounds has rarest possibility of existence? (A) IF5 (B) IF7 (C) IF6 (D) IF3

From Q42 to Q45, read the given comprehension for Halogens and answer the following Questions A binary compound of oxygen with another element is called oxide. In many cases one element forms two or more oxides. The oxides vary widely in their nature and properties. Oxides can be simple (e.g., MgO, Al 2O3) or mixed (Pb3O4, Fe3O4). Simple oxides can be classified on the basis of their acidic, basic or amphoteric character. An oxide that combines with water to give an acid is termed acidic oxide (e.g., SO 2, Cl2O7, CO2 and N2O5). As a general rule, only non-metal oxides are acidic but oxides of some metals in high oxidation state also have acidic character (e.g., Mn2O7, CrO3, V2O5). The oxides which give a base with water are known as basic oxides (e.g., Na 2O, CaO, BaO). Some metallic oxides exhibit a dual behaviour. They show characteristics of both acidic as well as basic oxides. Such oxides are known as amphoteric oxides. They react with acids as well as alkalies. There are some oxides which are neither acidic nor basic. Such oxides are known as neutral oxides. Examples of neutral oxides are CO, NO and N2O. 42. 42. 44. Which pair of species is referred as suboxides? (A) CO, NO (B) SO2, CaO (C) N2O, CO Which pair of species is referred as paramagnetic? (A) CO, NO (B) KO2, NO2 (C) N2O, BaO2 (D) N2O, C3O2 (D) O3, O2

How many different oxides will be produced on heating white lead, 2PbCO 3.Pb(OH)2 at 430oC (A) 1 (B) 2 (C) 3 (D) 4 Which of the following species has p-d bonding? (A) CO2 (B) NO2 (C) SO2

45.

(D) PbO2

NAME: ________________________________________________ DATE: ____________________

1. 2. 3. 4. 5. 6. 7. 8. 9.

A A A A A A A A A

B B B B B B B B B

C C C C C C C C C

D D D D D D D D D

10. 11. 12. 13. 14. 15. 16. 17. 18.

A A A A A A A A A

B B B B B B B B B

C C C C C C C C C

D D D D D D D D D

19. 20. 21. 22. 23. 24. 25. 26. 27.

A A A A A A A A A

B B B B B B B B B

C C C C C C C C C

D D D D D D D D D

28. 29. 30. 31. 32. 33. 34. 35. 36.

A A A A A A A A A

B B B B B B B B B

C C C C C C C C C

D D D D D D D D D

37. 38. 39. 40. 41. 42. 43. 44. 45.

A A A A A A A A A

B B B B B B B B B

C C C C C C C C C

D D D D D D D D D