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CHEMISTRY
SECTION I
Single Correct Choice Type
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONLY ONE is correct.
1. 1 gm of fuming
2 4
H SO (Oleum is a mixture of conc.
2 4
H SO saturated with
3
SO and having the
formula
2 2 7
H S O is diluted with
2
H O. This solution is completely neutralized by 26.7 mL of 0.8
M NaOH. Find the percentage of free
3
SO in the oleum.
(A) 20.73% (B) 20.93% (C) 18.73 % (D) 19.73 %
2. Given that for propylene
4 . 45
c
P
atmosphere,
. 4 . 91 ., . 180 C t c c V
c
Calculate the
pressure exerted by 1 mole of propylene at C 100 when contained in a vessel of 20.06 litres
using Van der Waals equation ( 082 . 0 R litre-atm.)
(A) 2.52 atm (B) 1.52 atm (C) 3.02 atm (D) 2.02 atm
3.
0
red
E of different half cells are given below:
2 2
0 0
Cu / Cu Zn / Zn
E 0.34V; E 0.76V
+ +
2
0 0
Ag / Ag Mg / Mg
E 0.80V; E 2.37V
+ +
In which cell is G
0
most negative?
(A) Zn | Zn
2+
(1M) || Ag
+
(1M) Ag (B) Cu | Cu
2+
(1M) || Ag
+
(1M) Ag
(C) Ag | Ag
+
(1M) || Mg
2+
(1M) | Ag (D) Zn | Zn
2+
(1M) || Mg
2+
(1M) Mg
4. When a substance A reacts with water it produces a combustible gas B and a solution of a
substance C in water. When another substance D reacts with this solution of C, it also produces
the same gas B on warming, but D can produce B on reaction with dilute sulphuric acid at room
temperature. A imparts a deep golden yellow colour to a smokeless flame of Bunsen burner. A, B,
C and D respectively are
(A) Na, H
2
, NaOH and Zn (B) K, H
2
, KOH and Al
(C) Ca, H
2
Ca(OH)
2
and Sn (D) CaC
2
, C
2
H
2
Ca(OH)
2
and Sn
5. Electrolysis of KCl.MgCl
2
.6H
2
O gives
(A) Mg Only (B) Potassium only
(C) Mg and Cl
2
(D) P and Mg
6. 1-propanol on oxidation with aqueous K
2
Cr
2
O
7
give aldehyde and than acid respectively contains
(A) 3 and 2C atoms (B) 3 and 1C atoms
(C) 3 and 3C atoms (D) 2 and 2C atoms
7. Compound C in the following series is:
alcohol HBr KCN
3 7
KOH alcohol
C H Br A B C:
(A) 2-methyl propane nitrile (B) Propane nitrile
(C) Acetonitrile (D) Ethyl isocynide
1
A
IIT-JEEFull Test 1 (PaperI)
(B)
(D)
SECTION II
Multiple Correct Choice Type
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/are correct.
9. The bond in K
4
[Fe(CN)
6
] are
(A) ionic bond (B) covalent bond
(C) coordinate covalent bond (D) double bond
10. The following reaction attains equilibrium at high temperature.
2 2 2
N (g) 2H O(g) heat 2NO(g) 2H (g) + + +
The yield of NO is affected by
(A) Increasing the nitrogen concentration (B) Decreasing the hydrogen concentration
(C) Compressing the reaction mixture (D) None of these
11. Detection of the chlorine is possible without preparing sodium extract in
(A) (B) CHCl
3
(C) (D)
2 2
CH CHCH Cl
12. NH
3
gas is produced in
(A) ( )
4 4
2
NH SO Slakedlime +
(B)
3
NaNO Al NaOH + +
(C)
2
CaCN Steam + (D) ( )
4 2 7
2
NH Cr O Heat +
13. 2 litre of 1 molar solution of a complex salt CrCl
3
.6H
2
O (mol. wt. 266.5) shows an osmotic
pressure of 98.52 atm. The solution is now treated with 1 litre of 6 M AgNO
3
, which of the
following are correct?
(A) Weight of AgCl precipitated is 861 g
(B) The clear solution will show an osmotic pressure = 98.52 atm
(C) The clear solution will show an osmotic pressure = 65.68 atm
2
A
IIT-JEEFull Test 1 (PaperI)
(D) 2 moles of [Cr(H
2
O)
6
] (NO
3
)
3
will be present in solution
SECTION III
Comprehension Type
This section contains 2 groups of questions. Each group has 3 & 2 multiple choice questions based on a paragraph.
Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct.
Paragraph for Questions Nos. 14 to 15
Perovskite, a mineral containing calcium, oxygen &
titanium crystallizes in the given unit cell
Calcium
Oxygen
Titanium
14. Total number of atom present in a unit cell is
(A) 3 (B) 4
(C) 5 (D) 6
15. The formula of perovskite is
(A) CaTiO (B) CaTiO
2
(C) CaTiO
3
(D) CaTiO
4
Paragraph for Questions Nos. 16 to 18
RNH
2
reacts with HNO
3
(nitrous acid from NaNO
2
and dil. HCl) forming alcohols. Chemist A
wanted to prepare 2-propanol and thus she worked out the synthesis from 2-aminopropane.
Chemist B also wanted to prepare 2-propanol but she could not arrange 2-aminopropane but
instead she tried the synthesis from 1-aminopropane.
16. What was the major product of chemist B?
(A) 1-Propanol (B) 2-Propanol
(C) Propene (D) Cyclopropane
17. What are the most stable intermediates of chemists A and B?
A B
(A)
3 2 2
CH CH CH
3 2 2
CH CH CH
(B)
3 3
CH CHCH
3 2 2
CH CH CH
(C)
3 3
CH CHCH
3 3
CH CHCH
(B)
3
4
(C)
4
(D)
4
31. If x
i
> 0 for 1 i n and
1
n
i
i
x
is
(A) n (B) (C) sin n
n
(D) n
32. If the position vectors of the vertices of an equilateral triangle are 72
56 3 i j + , x
i yj +
(y > 0) and the third vertex is to origin itself, then the values of x and y are respectively
(A) 32, 8 3 (B) 32, 32
2
(C) 48, 64 3 (D) 48, 16 3
33. If a
1
= 1 and a
n
= n(1 + a
n1
) n 2, then the limit
lim
n
1 2
1 1
1 1
a a
_ _
+ +
, ,
..
1
1
n
a
_
+
,
=
(A) e (B) log
e
2 (C) e
1/2
(D) log
2
e
34. The value of the integral
[ ]
[ ]
[ ]
[ ]
0
10
2
3
2
3
x
x x
dx
x
x x
(C) a local minima at certain x = 0 (D) a local minima at certain xR
SECTION II
Multiple Correct Choice Type
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/are correct.
37. Tangent at a point P
1
[other than (0, 0)] or the curve y = x
3
meets the curve again at P
2
. The
tangent at P
2
meets the curve at P
3
and so on. Then
(A) abscissae of P
1
, P
2
, P
3
, P
n
are in A. P.
(B) abscissae of P
1
, P
2
, P
3
, . P
n
form a G. P.
(C) area ( )
2 3 4
P PP
16 area ( )
1 2 3
PP P
(D) area ( )
1 2 3
PP P = 16 area ( )
2 3 4
P P P
38. If
1 2 3
x x x and
1 2 3
y y y be two three digits numbers, the number of pairs of
and
can be
formed that
without borrowing is
(A) 2!10!10! (B) (45)(55)
2
(C) 3
2
.5
3
.11
2
(D) 136125
39. The solution of the equation
2
2
2 cot
dy dy
y x y
dx dx
_
+
,
is
(A) y 0
1 cos
C
x
+
(B)
1 cos
C
y
x
(C) x = 2 sin
1
2
C
y
(D) y = 2cos
1
2
C
y
40. The pth term T
p
of HP is q(p + q) and qth term T
q
is p (p + q) when p > 1, q > 1, (p q) then
(A) p q
T pq
+
(B) pq
T p q +
(C) p q pq
T T
+
>
(D) pq p q
T T
+
>
41. If 1 is a cube root of unity and
100 200 2
101 202
2 100 200
1 2 1
1 1 2
2 2
A
1 + +
1
+ +
1
1
+ +
]
, then
(A) A is singular (B) |A| = 0
(C) A is symmetric (D) A is skewsymmetric
6
A
IIT-JEEFull Test 1 (PaperI)
SECTION III
Comprehension Type
This section contains 2 groups of questions. Each group has 3 & 2 multiple choice questions based on a paragraph.
Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct.
Paragraph for Questions Nos. 42 to 43
The smallest circle touching all the sides of triangle is called its incricle. The center of this circle
is called the incentre. The radius of the incircle of the triangle ABC is denoted by r. Note that the
incentre lies on the point of intersection of internal angular bisectors of its angles. Again the
circle touching the sides BC and the two sides AB and AC produced of a triangle is called
escribed circle opposite to the angle A. The radius of this circle is denoted by r
1
. The center of this
circle is called excentre. Similarly r
2
, r
3
be the radii of the escribed circles opposite to the angles B
and C respectively. The point of intersection of altitudes AK, BL and CM of a triangle is called
orthocentre of the triangle ABC. The triangle KLM is called PEDAL triangle of the triangle ABC.
ABC is pedal triangle of triangle formed by joining three excentres I
1
, I
2
, I
3
and therefore the
incentre I is the orthocentre of the triangle I
1
I
2
I
3
. We will denote the circumcentre and centroid by
O and G respectively. The circumradius of ABC is denoted by R. It is well known that
1
r
s a
Note that the existence of RHS is only sufficient for the existence of LHS. It is not necessary.
Certain limit problems are reducible to the given form by taking logarithms or by simplifying.
44. The value of
tan
0
1
lim
x
x
x
_
,
must be equal to
(A) e (B)
1
e
(C)
1
e
e
e
_
,
(D) 1
45.
cos log( )
lim
log( )
x a
x a
x x a
e e
7
A
IIT-JEEFull Test 1 (PaperI)
(A) cos a (B)
1
e
cos a (C) e cos a (D) none of these
46.
1
2
0
log(1 ) 1
lim
x
x
x
x x
+
_ +
,
must be equal to
(A)
1
2
(B)
1
2
(C) 1 (D) zero
SECTION IV
Integer Answer Type
This section contains 10 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9.
The appropriate bubbles below the respective question numbers in the ORS have to be darkened. For example, if the
correct answers to question numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening
of bubbles will look like the following.
47. Given
1
0
2
x then the value of
2
1 1
1
tan sin sin
2 2
x x
x
1
1 +
' ;
1
]
is ____
48. If d is the distance between the point (1, 5, 10) and the point of intersection of the line
2 1 2
3 4 12
x y z +
with the plane x y + z = 5, then d 10 is equal to ____
49. The number of integral values of a for which the inequality
2
3 x a x > is satisfied by at least
one negative x, must be equal to _____
50. The number of pair (x, y) satisfying 4x
2
4x + 2 = sin
2
y and x
2
+ y
2
3 are ____
51. Let
b
is
o
, then find
15
.
52. A bag A contains 2 white and 3 red balls, and a bag B contains 4 white and 5 red balls. One ball is
drawn at random from one of the bags and it is found to be red. Let p be the probability that it was
drawn from the bag B then find the value of
1
p
1
1
]
where [.] denotes G.I.F.
8
A
IIT-JEEFull Test 1 (PaperI)
53. Let ( ) F x
be a nonnegative continuous function defined on R such that ( )
1
3
2
_
+ +
,
F x F x
and the value of ( )
1500
0
F x dx
is
9000
+
along vertical
(D) moves with velocity
v(M m)
(M m)
+
in horizontal direction
60. An artificial satellite is first taken to a height equal to half the radius of Earth. Let E
1
be the
energy required. It is then given the appropriate orbital speed such that it goes in a circular orbit at
that height. Let E
2
be the energy required. The ratio
1
2
E
E
is
(A) 4 : 1 (B) 3 : 1 (C) 1 : 1 (D) 1 : 2
61. Figure (Five straight lines numbered 1, 2, 3, 4 and 5) shows graph of change in temperature T
versus heat supplied Q for different processes performed on a gas of one mole.
(i) line 4 and 5 (coinciding with Q and T axis respectively)
represent isothermal and adiabatic processes respectively
(ii) line 2 represents isochoric process for diatomic gas
(iii) line 1 and 3 represent isobaric process for a diatomic gas
and isochoric process for a monoatomic gas respectively
(iv) line 2 represents isobaric process for a monoatomic gas.
Correct answers are
(A) (i), (ii), (iii) (B) (ii), (iii), (iv)
(C) (i) and (iv) (D) (i), (ii), (iii), (iv)
62. If nuclei of a radioactive element is produced at constant rate and they decays with decay
constant . At t = 0, number of nuclei is zero than the number of nuclei at time t is
(A)
t
(1 e )
(B)
t
e
(C)
t
e
(D)
t
(1 e )
10
A
IIT-JEEFull Test 1 (PaperI)
63. Consider the YDSE arrangement shown in the figure.
If d = 10 then position of 8
th
maxima is
(A)
y D/ 10
(B)
y D/ 3
(C)
2D
y
3
(D)
4D
y
3
(B)
1
5m
m
4
(B)
0 0
q 2q
,
3 3
(C)
0 0
2q 2q
,
3 3
(D)
0 0
q 4q
,
3 3
73. Potential of B in previous case will be
(A)
0
0
3q
24 R
(B)
0
0
3q
48 R
(C)
0
0
q
24 R
(D)
0
0
3q
16 R
74. If A and C are disconnected with earth and now B is connected to earth, then charge on B will be
(A)
0
2q
3
(B) q
0
(C)
0
q
3
(D) q
0
SECTION IV
Integer Answer Type
This section contains 10 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9.
The appropriate bubbles below the respective question numbers in the ORS have to be darkened. For example, if the
correct answers to question numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening
of bubbles will look like the following.
13
A
IIT-JEEFull Test 1 (PaperI)
75. The period of oscillation of a simple pendulum is T =
L
g
L
2
is about 10 cm and is known to
1 mm accuracy. The period of oscillation is about 0.5 s. The time of 100 oscillations is measured
with a wristwatch of 1 s resolution. What is the accuracy in the determination of g?
76. A stationary
He
+
ion emitted a photon corresponding to the first line of the Lyman series. The
photon liberates electron from a stationary hydrogen atom in the ground state. The velocity of the
liberated electron is
3.1 10
x