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Custom 465<sup></sup> Stainless

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Custom 465 Stainless


Identification
U.S. Patent Number 5,681,528 UNS Number S46500 DIN Number 1.4614 5,855,844

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Type Analysis
Single figures are nominal except where noted.
Carbon (Maximum) Phosphorus (Maximum) Silicon (Maximum) Nickel Titanium 0.02 % 0.015 % 0.25 % 10.75 to 11.25 % 1.50 to 1.80 % Manganese (Maximum) Sulfur (Maximum) Chromium Molybdenum Iron 0.25 % 0.010 % 11.00 to 12.50 % 0.75 to 1.25 % Balance

General Information
Description Custom 465 stainless is a premium melted, martensitic, age-hardenable alloy capable of ultimate tensile strength in excess of 250 ksi in the overaged (H 950) condition. This alloy was designed to have excellent notch tensile strength and fracture toughness in this condition. Overaging to the H1000 condition provides a superior combination of strength, toughness and stress corrosion cracking resistance compared with other high-strength PH stainless alloys such as Custom 455 stainless or Carpenter 13-8 stainless. Applications Custom 465 stainless has been used in a wide variety of applications including: - Aerospace: landing gear components, slat components, torque tubes, pneumatic cylinders, braces, struts, fuse pins, gimbals, and other structural elements - Automotive: suspension coil springs, engine valve springs, torsion bars and instrumented wheel sensors - Medical: endoscopic instruments, scrapers, cutters, and suture needles - Oil field: drive shafts, mud motors, and other downhole drilling tools - Sporting goods: golf club faceplates, wire face shields for field sports, and big-bore firearms cylinders - High performance racing: speed boat propellers

Corrosion Resistance
The general corrosion resistance of Custom 465 stainless approaches that of Type 304 stainless. Exposure to 5% neutral salt spray at 95F (35C) (per ASTM B117) caused little or no rusting after 200 hours regardless of condition (i.e., annealed or H900-H1100 conditions). Double-cantilever-beam tests conducted in 3.5% NaCI (pH 6) show Custom 465 stainless to possess inherently good resistance to stress corrosion cracking which improves with increasing aging temperature. Important Note:The following 4-level rating scale is intended for comparative purposes only. Corrosion testing is recommended; factors which affect corrosion resistance include temperature, concentration, pH, impurities, aeration, velocity, crevices, deposits, metallurgical condition, stress, surface finish and dissimilar metal contact.
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Nitric Acid Phosphoric Acid Sodium Hydroxide Sea Water

Moderate Restricted Moderate Restricted

Sulfuric Acid Acetic Acid Salt Spray (NaCl) Humidity

Restricted Restricted Good Excellent

Properties
Physical Properties Density Annealed/CT Condition H 900 Condition H 950 Condition H 1000 Condition H 1050 Condition H 1100

0.2822 0.2825 0.2829 0.2832 0.2832 0.2840

lb/in! lb/in! lb/in! lb/in! lb/in! lb/in!

Mean CTE 77 to 212F, Annealed/CT 77 to 392F, Annealed/CT 77 to 572F, Annealed/CT 77 to 752F, Annealed/CT 77 to 932F, Annealed/CT 77 to 1112F, Annealed/CT 77 to 212F, Condition H 900 77 to 392F, Condition H 900 77 to 572F, Condition H 900 77 to 752F, Condition H 900 77 to 932F, Condition H 900 77 to 1112F, Condition H 900 77 to 212F, Condition H 1000 77 to 392F, Condition H 1000 77 to 572F, Condition H 1000 77 to 752F, Condition H 1000 77 to 932F, Condition H 1000 5.72 x 10-6 in/in/F 6.00 x 10-6 in/in/F 6.06 x 10-6 in/in/F 6.17 x 10-6 in/in/F 6.06 x 10-6 in/in/F 5.48 x 10-6 in/in/F 5.78 x 10-6 in/in/F 6.17 x 10-6 in/in/F 6.33 x 10-6 in/in/F 6.50 x 10-6 in/in/F 6.67 x 10-6 in/in/F 6.22 x 10-6 in/in/F 5.89 x 10-6 in/in/F 6.17 x 10-6 in/in/F 6.39 x 10-6 in/in/F 6.50 x 10-6 in/in/F 6.67 x 10-6 in/in/F

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Custom 465<sup></sup> Stainless

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77 to 1112F, Condition H 1000 77 to 212F, Condition H 1100 77 to 392F, Condition H 1100 77 to 572F, Condition H 1100 77 to 752F, Condition H 1100 77 to 932F, Condition H 1100 77 to 1112F, Condition H 1100

6.78 x 10-6 in/in/F 6.28 x 10-6 in/in/F 6.67 x 10-6 in/in/F 6.89 x 10-6 in/in/F 7.06 x 10-6 in/in/F 7.17 x 10-6 in/in/F 7.28 x 10-6 in/in/F

Thermal Conductivity 73F, Annealed/CT 212F, Annealed/CT 392F, Annealed/CT 572F, Annealed/CT 752F, Annealed/CT 932F, Annealed/CT 1112F, Annealed/CT 73F, Condition H 900 212F, Condition H 900 392F, Condition H 900 572F, Condition H 900 752F, Condition H 900 932F, Condition H 900 1112F, Condition H 900 73F, Condition H 1000 212F, Condition H 1000 392F, Condition H 1000 572F, Condition H 1000 752F, Condition H 1000 932F, Condition H 1000 1112F, Condition H 1000 73F, Condition H 1050 212F, Condition H 1050 392F, Condition H 1050 572F, Condition H 1050 752F, Condition H 1050 932F, Condition H 1050 1112F, Condition H 1050

97.60 108.6 122.9 134.4 148.7 165.5 178.7 103.0 117.2 133.3 145.5 156.0 170.1 182.6 109.8 125.0 140.5 150.6 163.4 177.5 191.6 109.6 125.5 141.7 152.6 163.1 175.5 186.7

BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F BTU-in/hr/ft"/F

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Custom 465<sup></sup> Stainless

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Modulus of Elasticity (E) Condition H 1000 Condition H 1100 28.8 x 103 ksi 28.4 x 103 ksi

Electrical Resistivity 70F, Annealed/CT 70F, Condition H 900 70F, Condition H 1000 70F, Condition H 1100

569.0 496.0 494.0 464.0

ohm-cir-mil/ft ohm-cir-mil/ft ohm-cir-mil/ft ohm-cir-mil/ft

Magnetic Properties

Saturation Flux Density Annealed/CT H900 H950


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13400.0 G 13800.0 G 13600.0 G


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H1000 H1050 H1100 Coercivity Annealed/CT H 900 H 950 H 1000 H 1050 H 1100 Typical Mechanical Properties

13300.0 G 12400.0 G 10100.0 G 25.5 23.3 24.0 28.1 34.2 53.0 Oe Oe Oe Oe Oe Oe

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Heat Treatment
Solution Treatment Condition A (Solution Annealed) Heat to 1800F15F (982C8C), hold one hour at heat and cool rapidly. Sections up to 12" can be quenched in a suitable liquid quenchant. Sections over 12" should be cooled rapidly in air. For optimum aging response, solution annealing should be followed by refrigerating to -100F (-73C), holding eight hours, then warming to room temperature (CT). Subzero cooling should be performed within 24 hours of solution annealing. Custom 465 stainless normally will be supplied from the mill in the solution annealed/cold treated condition (annealed/CT), ready for the one-step hardening treatment. Billet product will be provided in the hot finished condition.

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Custom 465<sup></sup> Stainless

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Age Condition H 900, H 950, H 1000, H 1050 and H 1100 The high strength levels of Custom 465 stainless are derived from a single age hardening step consisting of heating to a selected temperature between 900/1150F (482/621C) and holding for four to eight hours. A water or oil quench is suggested for optimum toughness. Slower cooling methods are not preferred, and are likely to result in reduced toughness. Aging temperature will depend upon the desired combination of strength, toughness and stress corrosion cracking resistance. While the alloy does develop maximum strength after a 900F age, it is not recommended because toughness is significantly degraded compared to aging at higher temperatures. The best combination of properties is obtained after aging at 950F (482C) and above and quenching in a suitable liquid, the severity of which should in part be based on the geometry and complexity of the part being aged. Condition H 1150M While the alloy typically will be machined in the annealed/CT condition, optimum machinability of Custom 465 stainless can be achieved by overaging to the H 1150M condition. Material is heated to 1400F15F (760C 8C) for two hours, air cooled, then reheated to 1150F15F (621C8C) for four hours and air cooled. If this practice is used, parts must be reannealed at 1800F (982C), cold treated at -100F (-73C) and aged at a selected temperature.

Workability
Hot Working Custom 465 stainless typically is forged within the temperature range of 1850/2000F (1010/1093C), followed by air cooling. Forgings must be solution annealed prior to age hardening. Cold Working Because of a relatively low annealed yield strength and low work hardening rate, Custom 465 stainless can be readily cold formed by drawing or rolling. Single step aging of cold worked material results in enhanced strengthening response as illustrated in the hyperlink entitled "Effects of Cold Work and Aging on Yield and Ultimate Tensile Strengths".

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Machinability Custom 465 stainless can be machined in both the solution-treated and various age-hardened conditions. In Condition A the alloy gives good tool life and surface finish when machined at speeds 20 to 30% lower then those used for Carpenter Custom 630 (17Cr-4Ni) or 20 to 30% lower than used for Stainless Types 302 and 304. The machinability as age-hardened will improve as the hardening temperature is increased. Condition H 1150M provides optimum machinability. Having procured Condition H1150M for best machinability, higher mechanical properties can be developed only by solution treating and heat treating at standard hardening temperatures. Following are typical feeds and speeds for Custom 465 stainless.

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Additional Machinability Notes When using carbide tools, surface speed feet/minute (SFPM) can be increased between 2 and 3 times over the high-speed suggestions. Feeds can be increased between 50 and 100% Figures used for all metal removal operations covered are average. On certain work, the nature of the part may require adjustment of speeds and feeds. Each job has to be developed for best production results with optimum tool life. Speeds or feeds should be increased or decreased in small steps. Weldability Custom 465 stainless can be satisfactorily welded by the GTA process using matching filler metal. When the GMA process is employed, Pyromet X-23 alloy filler metal is suggested to provide high strength and avoid weld-bead cracking associated with this higher-heat-input process. Welds should be fabricated employing the minimum amount of heat-input required to achieve complete
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penetration. If lower strength can be tolerated, Custom 450 stainless or Custom 630 stainless filler metal may be used. Oxyacetylene welding is not recommended, since carbon pickup in the weld may occur. Preheating is not required to prevent cracking during the welding of this alloy. The material has been welded satisfactorily in the overaged or solution annealed/cold treated condition. Welding in the overaged (H1150M) condition requires subsequent solution annealing with cold treating and aging. Direct aging of weldments on annealed base metal is possible, but hardness throughout the weld is not uniform. The optimum combination of properties is obtained by solution annealing and cold treating the weldment and then aging.

Other Information
Applicable Specifications AMS 5936 ASTM A693 MMPDS-01 Forms Manufactured Bar-Flats Bar-Squares Strip Technical Articles ASTM A564 ASTM F899

Bar-Rounds Billet Wire

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Disclaimer: The information and data presented herein are typical or average values and are not a guarantee of maximum or minimum values. Applications specifically suggested for material described herein are made solely for the purpose of illustration to enable the reader to make his/her own evaluation and are not intended as warranties, either express or implied, of fitness for these or other purposes. There is no representation that the recipient of this
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literature will receive updated editions as they become available. Unless otherwise specified, registered trademarks are property of CRS Holdings Inc., a subsidiary of Carpenter Technology Corporation. Copyright 2013 CRS Holdings Inc. All rights reserved. Edition Date: 5/17/13 Contact our U.S. Sales Office or one of our International Sales Offices for more information.

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