SPM Trial 2012 Chemistry Qa Selangor

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C B B D C C C C A C D C C D B C B B A C C D D B D
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SKEMA JAWAPAN KERTAS KIMIA 3 (4541/3) PPPA SPM 2012 MARKING SCHEME OF PAPER 3 (4541/3) PPPA SPM 2012
Question 1 (a) (i) (ii) (iii)
Description [Able to give a definition correctly] The temperature at which solid turns to liquid [Able to state the boiling point correctly] 136 0C [Able to explain the reasons correctly] Heat energy is absorbed and used to overcome the force of attraction between particles // Heat is absorbed to overcome the intermolecular force between molecule r: ion/atom [Able to state the process correctly ] Diffusion [Able to explain the observations correctly - Potassium manganate(VII)is made up of tiny particles - The spaces between particles in gel are smaller than in water//vice versa - Potassium manganate (VII) particles diffuse slower in gel // vice versa 1 1 1 1 1
Marks ......1 ......2
......2
(b)
(i) (ii)
.1 1 1 1 .3 9
Question (a) (b) (c) (d) (i) (ii)
Description Form complex ion/ Act as a catalyst/Form coloured ion or compound/exhibit different oxidation numbers in compounds The outermost shell of atom R has already achieved stable octet electron arrangement/ Atom R has 8 valence electron T2 + H2O HT + HOT T Atomic size of atom T is smaller than atom S Strength of the nucleus/nuclei attraction to attract electron of atom T is stronger than atom S Covalent bond -
Mark 1 1 1 1 1 1 1 ....1 .....1 .....1 .....1 .....2 .....1
(e)
(i) (ii)
Diagram showing correct sharing of electrons between four atoms S and 1 one atom Q with label/nucleus Correct number of electrons in each shell 1 Total
.....2 9
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Question 3 (a) (i) (ii) (b) (c) (i) (ii) Description Colourless solution turns blue // Some of black solid dissolves 1 Copper(II) sulphate To ensure all acid react completely Double decomposition// precipitation Pb2+ + SO42- PbSO4 Correct formulae of reactants and product Balanced equation (iii) (iv) 0.5 x 20 1000 (v) = = 0.01 mol 1 Lead (II) sulphate 1 1 1 ....2 ....1 1 1 1 .....1 .....1 .....1 Marks .....1
From eq: 1 mol SO42- produce 1 mol PbSO4 // 0.01 mol SO42- produce 0 .01 mol PbSO4 = 0.01 X 303 = 3.03 g 1 .....2 10 1
Question 4 (a) (i) (ii) (b) (i) Contact Process Sulphur // oxygen// water Ammonium sulphate (NH4)2SO4 (ii) Percentage of nitrogen = = (c) (i) (ii) (iii) (iv) Analgesic
Description 1
Marks ......1 1 ........1 1 1 ........2
14 x 2 132 21.21 %
100%
1 1 1 1 1
Total
.....2 .....1 .......1 ......1 .....1 10
Relieves aches and pain / reduces inflammation / reduces fever Penicillin / chloramphenicol / erythromycin To reduce depression / tension / worry // to calm a person

Question 5 (a) (i) Description [able to state the Homologous series correctly] compound P - alkene compound Q - alkane (ii) [able to state the general formula of compound R correctly] CnH2n+1OH (iii) [able to state the process correctly] Dehydration process (iv) 1 ........1 1 ........1 1 ........1 Marks
Porcelain chips Glass wool Soaked in R Heat water 1.(functional set up of apparatus, gas is collected by water displacement method) 2. correct labels (b) (i) (ii) Gas X carbon dioxide 1 [able to write a balance chemical equation] C2H4 + 3O2 C2H6 + 7/2O2 (c)

Gas P
1 1 ........2
........1
2CO2 + 2H2O / 2CO2 + 3H2O
1 ........1 1
[able to state observation] Effervesence occurs
(d)
[able to draw the structural formula of product formed and name correctly]
H H C
H
H C H
H
O
H C H H
C H
Ethyl propanoate
.......2
Total
11

6 Question (a) (b) (i) Description Heat of precipitation is the heat change when one mole of a precipitate is formed from its ion in aqueous solution The heat released = mc =(50 + 50) x 4.2 x 3.5 =1470 J Number of moles of Ag+ = (50 x 0.5) = 0.025 mol 1000 Number of moles of Cl= (50 x 0.5) = 0.025 mol 1000 0.025 mole of Ag+ reacts with 0.025 mole of Cl- to form 0.025 mole of AgCl Number of moles of AgCl = 0.025 mol = x 1470 J =58 800 J Heat of precipitation of AgCl = -58.8 kJ mol-1 (c)
Energy Ag+ + Cl-
Mark 1 .....1
1 1
.....1
(ii)
1 ......2 1 .......1 1 1 ......2
(iii)
(iv)
H = -58.8kJmol-1 AgCl
1. Label axes 2. Energy levels of reactants and products correct with formula of reactants and products 3. Heat of precipitation written (d) Ag+ + Cl-AgCl Total
1 1 1 1 ......1 10 ......3

Question 7 (a) (i) (ii) J, K, Cu, L [Able to state the negative terminal with correct explanation ] 1. Negative terminal is K 2. Because K is more electropositive than L/above L in Electrochemical Series [ Able to predict voltage value of cell K/L] 3. Voltage value is 1.80V [Able to state the factors that determine the products formed at electrode X] The type of electrode [Able to explain the reactions at each electrodes] Electrode Ion attracted Half equation Observation (iii) Anode / Electrode X SO42-, OHCu Cu2+ + 2e Copper electrode become thinner Cathode/ Electrode Y Cu2+, H+ Cu2+ + 2e Cu Brown solid deposited Description 1 1 1 1 3 Marks 1
(b)
(i)
(ii)
1+ 1 1+ 1 1+ 1 6
[Able to state the product at Electrode X with correct explanation] 1. Oxygen gas is formed. 2. SO42- and OH- ions attracted to Electrode X. 3. OH- ion is selected for discharge because it is lower in position than SO42- ion in Electrochemical series. 4. Half equation : 4OH- O2 + 2H2O + 4e - Correct formula- 1 - Balance equation - 1 [Able to arrange the three metals according to their increasing electropositivity] The order of the three metals in ascending order of electropositivity R , P , Q
1 1 1 1+1 5
(i) (c)
1 electropositivity increases [Able to state the strongest reducing agent with correct explanation] (ii) 1. Q is the strongest reducing agent. 2. The easier the metal atom to release electron, the higher the tendency of metal to act as stronger reducing agent. 3. Q is the most electropositive metal, so it has highest tendency to release electron. Total 1 1 1 3 1
20
Question 8 (a)
Description 1. Total surface area of smaller pieces wood is larger/bigger/ greater than the bigger pieces of wood 2. Larger surface area of smaller pieces wood exposed to air for burning Substance that can alter (change) the rate of reaction but the substance itself does not change chemically 2H2O2 2H2O + O2 1 1 1 1 1
Marks
.....2
(b)
(i)
......1
(ii)
1. Correct formulae of reactants and product 2. Balanced equation (iii)

Energy
.......2
Ea 2H2O2
Ea
2 H2O + O2
(i)
Axis with correct label Curve without catalyst, Ea, Curve with catalyst , Ea Position energy level of reactant Label H Heat absorb during breaking of bond in the ractaant is lower than heat release during formation of bond in the product. 6. Energy content of reactant is higher than energy content of product 7. The reaction is exothermic 8. In the presence of catalyst/ manganese(IV) oxide provide an alternative path/ lower activation energy 9. Frequency of effective collision between hydrogen peroxide molecules increases any 7 Zn + 2HCl ZnCl2 + H2 No. of mol HCl = 50 X 0.5 // 0.025 1000 Based on the chemical equation; 2 mol HCl : 1 mol H2 0.025 mol HCl : 0.0125 mol H2 Volume of H2 = 0.0125 x 24 // 0.3dm3
1. 2. 3. 4. 5.
1 1 1 1 1 1 1 .....7
1 1
......4

(ii) 1. Pour /measure 12.5 cm3 of 1 mol dm-3 hydrochloric acid . 2. Add excess zinc powder 3. At the same temperature OR 1. Pour/measure 25 cm3 of 0.5 mol dm-3 hydrochloric acid 2. Add excess zinc powder 3. At the higher temperature (iii) 1 1 1 1 ....3 1 1 1
Because the number of mol of hydrochloric acid used is half
....1 20
Question 9 (a) (i)
Description Acid P : Nitric acid/hydrochloric acid (any strong acid) r : sulphuric acid Acid Q : ethanoic acid (any weak acid) Sample answer: 2HCl + CaCO3 CaCl2 + H2O + CO2 // 2HNO3 + CaCO3 Ca(NO3)2 + H2O + CO2 Acid P 1. Acid P is a strong acid/Ionises completely in water/ HCl H+ + Cl2. Concentration of H+ is higher 3. The rate of reaction higher Zinc oxide Acid Q 1. Acid Q is a weak acid/Ionises partially in water/CH3COOH CH3COO- + H+ 2. Concentration of H+ is lower 3. The rate of reaction lower 1 1
Marks
.....3
(ii)
3+3
.....6
(b)
(i) (ii)
.....1
Zinc carbonate powder
1. Functional diagram 2. Label
1 1
.....2

(c) 1. 2. 3. 4. 5. Add excess nitric acid/hydrochloric/sulphuric acid to zinc carbonate Pass gas through lime water Lime water turns cloudy/ chalky/ milky shows the presence of CO32- ion Pour solution produced into 2 test tubes 1 1 1 1 1
Test tube 1 6. Add aqueous sodium hydroxide until excess, shake. 7. If white precipitate formed and dissolves in excess NaOH, Zn2+ or Al3+ or Pb2+ ions present Test tube 2 8. Add aqueous ammonia, NH3 until in excess shake. 9. If white precipitate formed and dissolves in excess NH3, Zn2+ ions present
1 1
1 1 Max 8
...8 20
Question 10 (a) (i) (ii) (iii)
Description Magnesium, Aluminium, Y, Copper Iron/Tin/Lead [Able to write a balanced chemicla equation] 4 Al + 3 O2 2 Al2O3 1. Correct formula of reactants and product 2. Balanced equation 3. Oxidation number of aluminium increases from 0 to +3. [Able to draw a labelled diagram] Potassium Glass wool Metal powder manganate(VII)/ chlorate(V)
Marks 1 1 1 1 1 3
(iv)
Heat
Heat
(b)
1. Able to name potassium manganate(VII) or potassium chlorate(V) 2. Diagram complete and functional 3. Labels correct [Able to write the procedure] 1. A crucible and its lid is weighed and its weight is recorded. 2. A 10 cm length of magnesium ribbon is cleaned with sand paper and coiled loosely.The magnesium coil is placed in the crucible. 3. The crucible with its lid and content are weighed again and the weight is recorded. 4. The crucible is heated strongly without its lid. 5. When the magnesium starts to burn, the crucible is covered with its lid. 6. Using a pair of tongs, the lid is lifted at intervals. 7. When the burning is completed, the lid is removed and the crucible is heated strongly for 2 minutes. 8. The crucible is allowed to cool to room temperature. 9. The crucible and its lid and content are weighed again and its weight is recorded.
1 1 1
1 1 1 1 1 1 1 1 1

10. The processes of heating, cooling and weighing are repeated until a constant mass is obtained. [Able to show tabulation of data] Mass (g) Crucible + lid a .......1 Crucible + lid + magnesium b Crucible + lid + magnesium oxide c [Able to show calculation ] Element Magnesium Mass(g) b-a Number of moles b-a/24 of atoms Simplest ratio of x moles Empirical formula = MgxOy 1 Max 8
Oxygen c-b c-b/16 y
.......1
.......1
.......1
12 20

SKEMA JAWAPAN KERTAS KIMIA 3 (4541/3) PPPA SPM 2012 MARKING SCHEME OF PAPER 3 (4541/3) PPPA SPM 2012
Question 1(a) (i)
Rubric [Able to record all readings accurately to one decimal point with unit] Sample answer:
Score
Experiment I II III # Accept unit mm :
Copper 3.2 cm 2.9 cm 3.2 cm 1 cm = 10 mm
Bronze 2.0 cm 2.3 cm 2.0 cm 3
[Able to record all readings accurately with correct decimal point or unit ]
readings to one decimal point without unit readings to two decimal point with unit
Sample answer: Experiment I II III Copper 3.2 2.9 3.2 Or Experiment I II III Copper 3.20 cm 2.90 cm 3.20 cm Bronze 2.00 cm 2.30 cm 2.00 cm 1 0 Bronze 2.0 2.3 2.0 2
[Able to record three to five readings correctly] [No response given or wrong response]

Question 1 (a) (ii) Rubric [Able to show calculations of both average diameter correctly] Sample answer: Copper : 3.2 + 2.9 + 3.2 = 3.1 cm 3 Bronze : 2.0 + 2.3 + 2.0 = 2.1 cm 3 # Accept calculation in mm : 1 cm = 10 mm 2 1 0 Score Score
[Able to show calculation of any one average diameter correctly] [Able to give idea of calculation of average diameter] [No response given or wrong response] Question 1(a) (iii) Rubric [Able to construct a table to record the diameters of the dents and average diameters for copper and bronze with the following aspects] 1. Correct titles 2. Readings and unit Sample answer: Material 1 Copper Bronze 3.2 2.0 Diameter of dents (cm) 2 2.9 2.3 3 3.2 2.0 Average Diameter (cm) 3.1 2.1
[Able to construct a less accurate table to record the diameters of the dents and average diameters for copper and bronze with the following aspects] 1. Title 2. Readings Sample answer: Diameter of dents 1 Copper Bronze 3.20 2.00 2 2.90 2.30 3 3.20 2.00 Average Diameter 3.10 2.10 2
[Able to construct a table with at least one title/ reading] Sample answer: Diameter of dents 1 Copper Bronze [No response given or wrong response] 0 2 3 1
Question 1( b)
Rubric [Able to state the observation correctly ] Sample answer: The diameter of dents made on bronze/ copper is smaller/bigger than copper/bronze. [Able to state the observation less correctly] Sample answer: The diameter of dents made o bronze/ copper is smaller/bigger. [Able to state an idea of the observation] Sample answer: The diameter of dent for bronze is small/ /The diameter of dent for copper is big. [ No response or wrong response]
Score 3
Question 1(c)
Rubric [Able to state the inference correctly] Sample answer: Bronze/ copper is harder/softer than copper/bronze. [Able to state the inference less correctly] Sample answer: Bronze/ copper is harder/softer. [Able to state an idea of the inference] Sample answer: Bronze/ copper is hard/soft. [No response or wrong response]
Score 3
Question 1(d)
Rubric [Able to state three variables correctly] Sample answer: Manipulated variable:
Score
Different types of materials/block//copper and

3
bronze
Responding variable: Size / diameter of dent// hardness of the block Constant variable: Mass of the weight// Height from which weight is released// Size of steel ball bearing [Able to state any two variables correctly ] [Able to state any one variable correctly ] [No response or wrong response]
2 1 0
Question
1(e)
Rubric
[Able to state the relationship between the manipulated variable and the responding variable with direction correctly] Sample answer:
Score
Bronze is harder than copper // Copper is softer r than bronze //Bronze has smaller size / diameter of dent than copper// alloy is harder than its pure metal Able to state the relationship between the manipulated variable and responding variable
Sample answer:
When the size / diameter of dent is smaller, the material is harder

[Able to state the idea of hypothesis] Sample answer:
Different materials have different diameter/size of the dent

[No response or wrong response] 0
Question 1(f)
Rubric [Able to state the operational definition for hardness of material block correctly ] Sample answer:
Score
When weight is dropped on the surface of the block/when force is applied. the material that has a smaller dent is the alloyr
[Able to state the operational definition less accurately] Sample answer: 2
The material that has smaller size / diameter of dent is the alloy.
[Able to state an idea of the operational definition] Sample answer: 1 0
Bronze is alloy.
[ No response or wrong response]
Question 1(g)
Rubric [Able to state the relationship accurately] Sample answer: The smaller the diameter of the dent, the harder the material/block. // The bigger the diameter of the dent, the softer the material/block. [Able to state the relationship less accurately] Sample answer: The smaller the diameter of the dent, the stronger the material/block. [Able to state an idea of the relationship] Sample answer:
Score 3

Different material/block produce different diameter of dent [No response or wrong response] 0
Question
Rubric [Able to give all three explanations correctly] Sample answers: 1. Atoms in copper are in orderly arrangement. 2. Atoms in bronze are not in orderly arrangement./ Arrangement of atoms in bronze is disrupted. 3. Layers of atoms in bronze difficult to slide on each other when force is applied [Able to give any two explanations correctly] [Able to give any one explanations correctly] [No response or wrong response]
Score
1(h)
2 1 0
Question 1(i)
Rubric [Able to classify all the six materials correctly] Sample answer: Pure metal Aluminium Tin Iron [Able to classify any four materials correctly] [Able to classify any two materials correctly] if reverse score 1 Sample answer: Pure metal Brass Pewter Stainless steel [No response or wrong response] Alloy Copper Tin Iron Alloy Brass Pewter Stainless steel
Score
Question 2(a)
Rubric [Able to state the problem statement correctly] Sample answer: Do salt A and salt B soluble/insoluble salt? dissolve in water ?// Are salt A and salt B
Score
[Able to state the problem statement less accurately] Sample answer: Does salt A/B dissolve in water? //To identify the solubility of salt A and

salt B [Able to give an idea of the problem statement] Sample answer: Can salt A and salt B mix with water? [No response or wrong response] Question 2(b) Rubric [Able to state the three variables correctly] Sample answer: Manipulated variable Salt A and Salt B Responding variable Solubility of salt Constant variable Quantity Water / quantity of salt / temperature of water [Able to state any two variables correctly] [Able to state any one variable correctly] [No response or wrong response] 1 0 Score 3
2 1 0
Question 2(c)
Rubric [Able to state the relationship correctly between the manipulated variable and the responding variable with direction] Sample answer:
If salt A and salt B dissolve in water , salt A and B are soluble salt soluble/insoluble salt // [Able to state the relationship between the manipulated variable and the responding variable with direction]
Score
Sample answer: Salt A/Salt B is soluble/insoluble salt [Able to state the idea of hypothesis] Sample answer: Salt A/Salt B can mix with water [No response or wrong response]
1 0
Question 2(d)
Rubric [Able to give complete list of substances and apparatus] Sample answer: Substances Salt A, salt B and distilled water Apparatus Beaker, glass rod, spatula [Able to give a list of substances and apparatus but less complete] Sample answer: Substances Salt A, salt B and water Apparatus Beaker/test tube, glass rod [Able to give at least two substance and at least one container] Sample answer : Substances
Score

Salt A, salt B and water Apparatus Any container [No response or wrong response]
Question 2(e)
Rubric [Able to list all the steps correctly] Sample answer:
Score
1. 2. 3. 4. 5.
Put one spatula of salt A in a beaker . Add distilled water until half full . Stir the mixture using glass rod. The solubility of salt A is recorded/record the observation. Repeat step 1 to 4 by replacing the salt A with salt B
[Able to list down steps 1, 2, 4 and 5] (no step 3) [Able to list steps 1, 2 and 5] [No response or wrong response]
2 1 0
Question 2(f)
Rubric [Able to tabulate the data with the following aspects]
Score
1. Correct titles 2. List of substances

Sample answer: Type of salt Salt A Salt B Observation / Solubility of salt 2
[Able to construct table at least one title] Sample answer: Type of salt Observation / Solubility of salt 1 or Type of salt Salt A Salt B
[No response or wrong response or empty table]

SPM Trial 2012 Chemistry Qa Selangor

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http://www.chngtuition.blogspot.

Google Search : mr sai mun PPPA SPM 2012

4541@ Kertas PPPA(2) Kimia SPM

MARKING SCHEME OF PAPER 1 (4541/1) PPPA SPM 2012

END OF MARKING SCHEME SKEMA JAWAPAN TAMAT

4541 @ Hakcipta Jabatan Pelajaran Negeri Selangor http://www.chngtuition.blogspot.com

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Question 1 (a) (i) (ii) (iii)

Marks ......1 ......2

Question (a) (b) (c) (d) (i) (ii)

Mark 1 1 1 1 1 1 1 ....1 .....1 .....1 .....1 .....2 .....1

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Marks ......1 1 ........1 1 1 ........2

.....2 .....1 .......1 ......1 .....1 10

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2CO2 + 2H2O / 2CO2 + 3H2O

[able to state observation] Effervesence occurs

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1 ......2 1 .......1 1 1 ......2

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1. Correct formulae of reactants and product 2. Balanced equation (iii)

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Because the number of mol of hydrochloric acid used is half

Question 9 (a) (i)

Zinc carbonate powder

1. Functional diagram 2. Label

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Question 10 (a) (i) (ii) (iii)

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Oxygen c-b c-b/16 y

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Question 1(a) (i)

Experiment I II III # Accept unit mm :

Copper 3.2 cm 2.9 cm 3.2 cm 1 cm = 10 mm

Bronze 2.0 cm 2.3 cm 2.0 cm 3

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Different types of materials/block//copper and

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When the size / diameter of dent is smaller, the material is harder

Different materials have different diameter/size of the dent

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Rubric [Able to list all the steps correctly] Sample answer:

Rubric [Able to tabulate the data with the following aspects]