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SULIT 4541/1

4541/1
Kimia
Kertas 1
Ogos
2007
1¼ jam
BAHAGIAN SEKOLAH
KEMENTERIAN PELAJARAN MALAYSIA
______________________________________________
PEPERIKSAAN PERCUBAAN SPM 2007

KIMIA

Kertas 1

Satu jam lima belas minit

JANGAN BUKA KERTAS SOALAN INI HINGGA DIBERITAHU

1. Kertas soalan ini mengandungi 50 soalan.


2. Jawab semua soalan
3. Jawab dengan menghitamkan ruangan yang betul pada kertas jawapan
4. Bagi setiap soalan hitamkan satu ruangan sahaja
5. Sekiranya anda hendak menukar jawapan, padamkan tanda yang telah dibuat.
Kemudian hitamkan jawapan yang baru.
6. Rajah yang mengiringi soalan tidak dilukiskan mengikut skala.
7. Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh
diprogramkan.

Kertas soalan ini mengandungi 19 halaman bercetak

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1 Which of the following processes, proved the kinetic theory of matter?

A Diffusion
B Photosynthesis
C Respiration
D Neutralization

2 Which of the following is a chemical formula of ammonium sulphate?

A NH4SO4
B (NH4)2SO4
C (NH3)2SO4
D (NH4)3(SO4)2

3 Elements in the Periodic Table are arranged according to an increase in

A proton number
B nucleon number
C relative atomic mass
D relative molecular mass

4 Which of the following substances is a covalent compound?

A Copper
B Ammonia
C Lead(II) oxide
D Sodium chloride

5 Which of the following substances is an electrolyte?

A Hydrogen chloride in methyl benzene


B Molten aluminium oxide
C Glucose solution
D Copper(II) carbonate powder

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6 Which of the following statements is true about alkali?

A Weak alkali is an alkali that undergoes high rate of ionization.


B Strong alkali has low pH value
C Alkalis are bases that are soluble in water.
D Alkalis are not corrosive

7 Which of the following is a soluble salt?

A Lead(II) iodide
B Copper(II) carbonate
C Barium sulphate
D Sodium hypochlorite

8 The body of the car shown in the diagram below is made of alloy T.

Alloy T

What is alloy T?

A Steel
B Brass
C Bronze
D Duralumin

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9 Which of the homologous series is correctly paired to its functional


group?

Homologous series Functional groups

A Ester

B Alkene

C Alcohol

D Carboxylic acid

10 Which of the following statements correctly explains the meaning of effective collision?

A The collision which takes place before reaction.


B The collision where its energy is less than the activation energy.
C The collision that can causes reaction.
D The collision that has the highest energy.

11
• Bromine water
• Acidified potassium manganate(VII)
• Acidified potassium dichromate(VI)

Which of the following is true about the substances?

A Reducing agent
B Oxidising agent
C Dehydration agent
D Hydration agent

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12 Which of the following processes occurs when ice changes to water ?

A Endothermic
B Exothermic
C Neutralization
D Freezing

13 Paracetamol is used for

A reducing pain
B reducing anxiety
C destroying of bacteria
D controlling the level of glucose in blood

14 The diagram below shows the molecular formula of glucose.

C6H12O6
What is the empirical formula for glucose?

A CH2O
B CH2O2
C C2H4O2
D C6H12O6

7
15 Which of the following is the atomic structure of lithium atom, ?
3
Li
A B

3p 3p

C D

4p 4p

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16 The figure shows three elements in Period 3 of the Periodic Table.

X Y Z

Which of the following is true about the properties of oxide formed?

A The oxide of Z is basic


B The oxide of Y is acidic
C The formula of oxide Y is YO
D The oxide of X reacts with an acid to form salt and water

17 Which of the following substances is made up of ions?

A Sulphur
B Naphthalene
C Sulphur trioxide
D Potassium chloride

18 Which of the following ions are present in copper(II) sulphate solution?

A Hydrogen ions and hydroxide ions


B Copper(II) ions and sulphate ions
C Copper(II) ions ,hydrogen ions, suphide ions and oxide ions
D Copper(II) ions, hydrogen ions, sulphate ions and hydroxide ions

19 Dry hydrogen chloride gas is passed through methyl benzene for a few minutes. Which
of the following statements is true about the liquid produced?

I it has a pH value of less than 7


II it consists of hydrogen chloride molecules
III it changes blue litmus to red
IV it does not conduct electric current

A I and III only


B II and IV only
C I, II and III only
D IV only

20 The diagram shows part of a polymer molecule

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CH3 H CH3 H CH3 H

C C C C C C

H H H H H H

Which is its monomer?


A B

C D

21 Nitric acid will change to nitrate salt when hydrogen ions are replaced by

I copper ion
II hydroxide ion
III carbonate ion
IV ammonium ion

A I and II only
B I and IV only
C II and IV only
D I, III and IV only

22 The graph shows the volume of carbon dioxide gas produced against time for the

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reaction of calcium carbonate and sulphuric acid.

Volume of CO2
gas / cm3

Time / second

The gradient of the graph decreases with time because

A catalyst is not used


B volume of mixture decreases
C temperature of reaction decreases
D concentration of sulphuric acid decreases

23 The equation below shows a chemical reaction.

Based on the equation given, name the reaction.


A Hydrogenation
B Polymerization
C Halogenation
D Substitution

24 The diagram below shows the electrolysis process of copper(II) sulphate solution using

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copper as an electrode.

Copper
Copper(II) sulphate
solution

Which of the following substances are oxidized and reduced in this cell?

Oxidised Reduced
A Hydroxide ion Copper(II) ion
B Hydroxide ion Copper atom
C Copper atom Copper(II) ion
D Copper atom Hydrogen ion

25 The reaction between nitrogen and oxygen can be represented by the following equation:

N2 (g) + O2(g) → 2NO(g) ∆H = +181 kJ

Which of the following energy level diagrams represent the above reaction?

A B Energy
Energy
N2 (g) + O2(g)
2NO(g)
∆H = +181 kJ ∆H = +181 kJ
2NO(g) N2 (g) + O2(g)

C D
Energy Energy
2NO(g) N2 (g) + O2(g)
∆H = +181 kJ ∆H = +181 kJ
N2 (g) + O2(g) 2NO(g)

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26 The diagram shows a label on a bottle of orange juice.

SUKARAMAI ORANGE JUICE

Ingredients: water, sugar, X , sulphur dioxide,


aspartame, vitamin A and D

X is one of the important ingredients to make orange juice last longer.


What is X?

A Sodium nitrite
B Sodium nitrate
C Ascorbic acid
D Benzoic acid

27 The figure shows the arrangement of particles of a substance that undergoes the change
of state through process X

What is process X ?

A Melting
B Boiling
C Freezing
D Sublimation

28 The equation below shows the reaction between sulphuric acid and sodium hydroxide

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solution.

H2SO4 + 2KOH K2SO4 + 2H2O

What is the number of moles of sodium sulphate salt produced if 0.2 mol of sodium
hydroxide is used?

A 0.10 mol
B 0.05 mol
C 0.22 mol
D 0.25 mol

29 The table shows the electron arrangements of atoms of four elements.

Element F Al Cl K
Electron
arrangement 2.7 2.8.3 2.8.7 2.8.8.1

Which of the following is the correct arrangement of the elements according to


increasing order of electronegativity?

A F, Al, Cl, K
B F, Cl, Al, K
C K, Cl, Al, F
D K, Al, Cl, F

30 The number of valence electrons of atoms X and Y are 2 and 7 respectively.


Which of the following chemical formulae and types of bonding are true for the
compound formed between X and Y?

Chemical Formula Type of Bonding


A XY2 ionic
B XY2 covalent
C X2Y ionic
D X2Y covalent

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31 The diagram below shows the set-up of the apparatus for electrolysis of concentrated
solution of sodium chloride

What is the product formed at the anode and cathode?

Anode Cathode
A O2 H2
B Cl2 H2
C Cl2 Na
D O2 Cl2

32 The diagram below shows 5 steps for preparing a standard solution of sodium hydroxide,
NaOH but not in correct order.

P- Transfer the solid sodium hydroxide into volume into the volumetric flask.
Q- Weigh the mass of sodium hydroxide
R- Add distilled water until the graduation mark.
S- Rinse the weighing bottle and pour the solution into the volumetric flask.
T- Shake the volumetric flask.

Which of the following steps is correct?

A Q, S, P, R, T
B R, Q, S, P, T
C Q, P, S, R, T
D R, Q, S, T, P

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33 The diagram below shows the test tubes containing lead(II) nitrate solution and
potassium carbonate solution but without a label. Which of the following solutions can
be used to distinguish both solutions?

Potassium carbonate Lead(II) nitrate


solution solution

I Sodium nitrate
II Sodium iodide
III Dilute nitric acid
IV Potassium sulphate

A I and II only
B II and IV only
C II, III and IV only
D I, II, III and IV

34 Which of the following is the alcohol produced from the alkaline hydrolysis of oil?

A Ethane-1,2-diol
B Glycerol
C Cyclohexanol
D Buthane-2-ol

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35

Volume of H2 gas / cm3

40
36
30

20
18
10

0 60 120 180 240 300 time / s


A group of students carried out an experiment to determine the rate of reaction of zinc
metal with dilute hydrochloric acid. The diagram above shows the graph for the total
volume of gas collected against time. The average rate of reaction for the whole
experiment is :

A 0.3 cm3/s
B 0.25 cm3/s
C 0.17 cm3/s
D 0.13 cm3/s

36 When a mixture of 2-butanol, CH3CHOHCH2CH3 and concentrated sulphuric acid is


heated, gas X is produced. Which of the following is the molecular structure of X?

A CH3CH=CHCH3
B CH3CH=C(CH3)2
C (CH3)2CHCH=CH2
D CH3CH2CH=CH2

37 The diagram below shows the changes of the sulphur in Contact Process.

S SO2 SO3 H2S2O7

Which of the following are the correct changes in the oxidation state of sulphur?

A 0 +4 +6 +6
B 0 +4 +6 +7
C 1 +3 +6 +8
D 1 +4 +6 +6

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38 The following equation shows the formation of water

H2(g) + ½ O2(g) → H2O(l) , ∆H = ─ 287 kJmolˉ¹

Which of the following is true regarding the above equation?

A Activation energy for the reaction is high


B If 1 mole of oxygen reacts 574 kJ of heat energy is absorbed
C Combustion of 1 mole of hydrogen releases 287 kJ of heat energy
D 1 mole of water that is formed in the reaction received 287 kJ heat energy

39
A patient claims he always heard someone says something to him but he
didn’t see anybody around him during the situation.

Which of the following medicines is most appropriate in treating the above symptoms or
disorders?

A Chlorpromazine
B Amphetamine
C Tranquilisers
D Barbiturates

40 Which of the following isotopes is used to detect leakage in a gas pipe.


.
A Carbon – 14
B Cobalt – 60
C Sodium – 24
D Iodine - 131

41 34 g of ammonia consists of
[Relative molecular mass of ammonia = 17, Avogadro constant = 6.02 x 10 23 mol-1]
I 2 mole of nitrogen atoms
II 2 mole of ammonia molecules
III 1.204 X 1024 molecules
IV 5 mole of hidrogen atoms

A I and II only
B I, II and III only
C II, III and Iv only
D I, II, III and IV only

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42 Profesional cyclists usually fill their bicycle tyres with gas X which makes the bicycle
lighter.

X
Y W
Z

Which of the following elements X, Y, W and Z in the Periodic Table is suitable to be


used in bicycle tyres?

A X
B Y
C W
D Z

43 The diagram below shows the symbols of atoms D and E

27 16

D E
13 8

Atom D reacts with atom E to form a compound. Calculate the relative molecular mass
for the compound formed.

A 21
B 43
C 102
D 113

44 Calculate the volume of sodium hydroxide of concentration 0.5 mol dm-3 needed to
neutralize 25.0 cm3 sulphuric acid of concentration 0.20 mol dm-3.

A 10 cm3
B 20 cm3
C 25 cm3
D 50 cm3

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45 The table below shows the potential difference of three simple voltaic cells.

Cell Pair of metal Potential Negative


difference(V) terminal
I Mg and Cu 3.0 Mg
II Mg and Zn 1.5 Mg
III Zn and Fe 0.5 Zn
What is the potential difference of a simple voltaic cell for pair of iron and copper ?

A 0.5 V
B 1.0 V
C 1.5 V
D 2.5 V

46 200 cm3 of 0.1 mol dm-3 sodium chloride solution reacts completely with excess silver
nitrate. Calculate the mass of precipitate produced.
[Relative atomic mass of: Ag, 108; Cl, 35.5]

A 2.78 g
B 2.87 g
C 3.78 g
D 3.87 g

47 The uses of substance X;


• To clean metals.
• To produce detergents.
• To make paints.

What is substances X?

A Nitric acid
B Sulphuric acid
C Ammonia
D Ammonium sulphate

48 Graph represents the decomposition of 25 cm3 hydrogen peroxide of 0.5 mol dm-3 with

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manganese(IV) oxide as a catalyst at a temperature of 30oC.

Which of the following experiments will produce graph II ?

Volume of Concentration of Temperature of


hydrogen peroxide / cm3 hydrogen peroxide/ hydrogen peroxide / oC
mol dm-3
A 15 0.7 30
B 15 0.5 30
C 40 0.7 30
D 40 0.5 20

49 Which of the following equations represents a redox reaction?

A Pb(NO3)2(aq) + CuSO4(aq) PbSO4(s) + Cu(NO3)2(aq)


B CH3COOH(aq) + NaOH(aq) CH3COOH(aq) + H2O(l)
C Mg(s) + CuSO4(aq) MgSO4(aq) + Cu(s)
D C2H4(g) + 3O2(g) 2CO2(g) + 2H2O(l)

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50 The diagram below shows the molecular formulae of two compounds A and B. Substance
X is formed when both compounds react with each other.

Compound A, Compound B,
C2H5OH C2H5COOH

Substance X

Which of the following set represents substance X?

Structural formula Name


A
H O H H H
H C C O C C C H Ethyl propanoate

H H H H

B
H H O H H
Ethyl propanoate
H C C C O C C H
H H H H

C
H O H H H
H C C O C C C H Propyl propanoate

H H H H

D
H H O H H
H C C C O C C H Propyl propanoate
H H H H

END OF QUESTION PAPER

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