Unit 6 Study Guide 1. When ignited, a uranium compound burns with a green flame.

The wavelength of the light given off by this flame is greater than that of ! red light. "! infrared light. #! radio waves. $! ultraviolet light. %! none of these &. Which one of the following types of radiation has the shortest wavelength, the greatest energy, and the highest fre'uency( ! ultraviolet radiation "! infrared radiation #! visible red light $! visible blue light %! none because short wavelength is associated with low energy and low fre'uency, not high energy and high fre'uency ). Which form of electromagnetic radiation has the longest wavelengths( ! gamma rays "! microwaves #! radio waves $! infrared radiation %! *+rays ,. Which of the following fre'uencies corresponds to light with the longest wavelength( ! ).-- . 1-1) s/1 "! ,.1& . 1-0 s/1 #! 1.0- . 1-&- s/1 $! 2.1& . 1-1& s/1 %! ).&- . 1-2 s/1 0. Which of the following statements is 3are! true( I. An excited atom can return to its ground state by absorbing electromagnetic radiation. II. The energy of an atom is increased when electromagnetic radiation is emitted from it. III. The energy of electromagnetic radiation increases as its frequency increases. IV. An electron in the n = 4 state in the hydrogen atom can go to the n = 2 state by emitting electromagnetic radiation at the appropriate frequency. 4. The fre'uency and wavelength of electromagnetic radiation are inversely proportional to each other. ! 55, 555, 54 "! 555, 4 #! 5, 55, 555 $! 555, 54, 4 %! 5, 55, 54 Use the following to answer 'uestions 6+67 8rom the following list of observations, choose the one that most clearly supports the following conclusion7 a! emission spectrum of hydrogen b! the photoelectric effect c! scattering of alpha particles by metal foil d! diffraction e! cathode 9rays9 6. %lectrons have wave properties.

6. %lectromagnetic radiation has wave characteristics. 1. The mass of the atom is located mainly in the nucleus. 2. 1-. 11. 1&. toms contain electrons. %lectrons in atoms have 'uanti:ed energies. de "roglie wavelengths. lpha particles

, &< ;e beamed at thin &

metal foil may ! pass directly through without changing direction. "! be slightly diverted by attraction to electrons. #! be reflected by direct contact with nuclei. $! a and c %! a, b, and c 1). =ight can have a wavelength of 0.&2e& nm. The energy of a photon of light is ! 0.&2e/6 > "! 0.66e1, > #! ).66e/12 > $! 1.-0e/)1 > %! &.66e11 >

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Unit 6 Study Guide 1,. 5n an investigation of the electronic absorption spectrum of a particular element, it is found that a photon having @ 0-- nm provides Aust enough energy to promote an electron from the second 'uantum level to the third. 8rom this information, we can deduce ! the energy of the n @ & level. "! the energy of the n @ ) level. #! the sum of the energies of n @ & and n @ ). $! the difference in energies between n @ & and n @ ). %! all of these 10. What is the wavelength of light that is emitted when an e*cited electron in the hydrogen atom falls from n @ 0 to n @ ,( ! &.,6e0 m "! ,.-0e/6 m #! ,.2-e/&- m $! 1.,6e/6 m %! none of these 16. Which of the following is incorrectly paired( ! wavelength / "! fre'uency / #! speed of light / c $! hert: / s/1 %! *+rays / shortest wavelength 16. When a strontium salt is ignited, it burns with a red flame. The fre'uency of the light given off by this flame is greater than ! yellow light "! infrared light #! ultraviolet light $! radio waves %! *+rays 11. What is the wavelength of a photon of red light 3in nm! whose fre'uency is ,.06e1, ;:( 5gnore significant figures for this problem. ! 606 nm "! 1.0&e6 nm #! 10& nm $! ,06 nm %! none of these 12. What is the energy of a photon of blue light that has a wavelength of ,,6 nm( 5gnore significant figures for this problem. ! ,.,6e/6 > "! ,.,,e/12 > #! 6.61e1, > $! 1.11e/)& > %! &.&0e11 > &-. Which of the following is incorrect( ! The importance of the e'uation E @ mc& is that energy has mass. "! %lectromagnetic radiation can be thought of as a stream of particles called photons. #! ll of these are correct. $! The energy of matter is not continuous and is actually 'uanti:ed. %! %nergy can only occur in discrete units called 'uanta.

Use the following to answer 'uestions &1+&)7 #onsider the following portion of the energy+level diagram for hydrogen7 n@, /-.1)61 . 1-/11 > n@) /-.&,&- . 1-/11 > n@& /-.0,,0 . 1-/11 > n@1 /&.161 . 1-/11 > &1. 8or which of the following transitions does the light emitted have the longest wavelength( ! n @ , to n @ ) "! n @ , to n @ & #! n @ , to n @ 1 $! n @ ) to n @ & %! n @ & to n @ 1 &&. 5n the hydrogen spectrum, what is the wavelength of light associated with the n @ & to n @ 1 electron transition( ! 21.& nm "! )60 nm #! 1.&&e6 m $! 1.6)e/11 m %! 1.&&e/6 m &). The wavelength of light associated with the n @ & to n @ 1 electron transition in the hydrogen spectrum is 1.&16 . 1-/6 m. "y what coefficient should this wavelength be multiplied to obtain the wavelength associated with the same electron transition in the =i&< ion( ! 1B2 "! 1B6 #! 1B, $! 1B)

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Unit 6 Study Guide %! 1 &1. 5n "ohrDs atomic theory, when an electron moves from one energy level to another energy level more distant from the nucleus ! energy is emitted. "! energy is absorbed. #! no change in energy occurs. $! light is emitted. %! none of these &2. Which of the following is not determined by the principal 'uantum number, n, of the electron in a hydrogen atom( ! the energy of the electron "! the minimum wavelength of the light needed to remove the electron from the atom. #! the si:e of the corresponding atomic orbital3s! $! the shape of the corresponding atomic orbital3s! %! ll of the above are determined by n. )-. Which of the following statements about 'uantum theory is incorrect( ! The energy and position of an electron cannot be determined simultaneously. "! =ower energy orbitals are filled with electrons before higher energy orbitals. #! When filling orbitals of e'ual energy, two electrons will occupy the same orbital before filling a new orbital. $! Eo two electrons can have the same four 'uantum numbers. %! ll of these are correct. )1. Which of the following statements is true( ! The e*act location of an electron can be determined if we Cnow its energy. "! n electron in a &s orbital can have the same n, l, and ml 'uantum numbers as an electron in a )s orbital. #! Ei has & unpaired electrons in its )d orbitals. $! 5n the buildup of atoms, electrons occupy the ,f orbitals before the 6s orbitals. %! Fnly three 'uantum numbers are needed to uni'uely describe an electron.

&,. When a hydrogen electron maCes a transition from n @ ) to n @ 1, which of the following statements is true( I. nergy is emitted. II. nergy is absorbed. III. The electron loses energy. IV. The electron gains energy. 4. The electron cannot maCe this transition. ! 5, 54 "! 5, 555 #! 55, 555 $! 55, 54 %! 4 &0. Which of the following is a reasonable criticism of the "ohr model of the atom( ! 5t maCes no attempt to e*plain why the negative electron does not eventually fall into the positive nucleus. "! 5t does not ade'uately predict the line spectrum of hydrogen. #! 5t does not ade'uately predict the ioni:ation energy of the valence electron3s! for elements other than hydrogen. $! 5t does not ade'uately predict the ioni:ation energy of the 1st energy level electrons for one+electron species for elements other than hydrogen. %! 5t shows the electrons to e*ist outside of the nucleus. &6. When an electron in a &p orbital of a lithium atom maCes a transition to the &s orbital, a photon of appro*imate wavelength 66-.6 nm is emitted. The energy difference between these &p and &s orbitals is ! &.26&e/&1 > "! &.26&e/12 > #! &.26&e/16 > $! 1.))&e/)1 > %! none of these &6. The energy of the light emitted when a hydrogen electron goes from n @ & to n @ 1 is what fraction of its ground+state ioni:ation energy( ! )B, "! 1B& #! 1B, $! 1B1 %! 1B2

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Unit 6 Study Guide )&. Which of the following statements is false( ! n orbital can accommodate at most two electrons. "! The electron density at a point is proportional to psi& at that point. #! The spin 'uantum number of an electron must be either <1B& or /1B&. $! &p orbital is more penetrating than a &sG i.e., it has a higher electron density near the nucleus and inside the charge cloud of a 1s orbital. %! 5n the usual order of filling, the 6s orbital is filled before the ,f orbital. ;ow many f orbitals have the value n @ )( ! "! ) #! 0 $! 6 %! 1 )1. ;ow many electrons in an atom can have the 'uantum numbers n @ ,, l @ &( ! 1, "! 1& #! 0 $! 1%! 6 )2. 5f n @ &, how many orbitals are possible( ! ) "! , #! & $! 1 %! 6 given set of p orbitals consists of HHHHHH ! "! #! $! %! 1 & ) , 0

)).

,-. orbitals.

),. ;ow many electrons in an atom can have the 'uantum numbers n @ ), l @ &( ! & "! 0 #! 1$! 11 %! 6 )0. ;ow many electrons can be described by the 'uantum numbers n @ ), l @ ), ml @ 1( ! "! & #! 6 $! 1%! 1, )6. Which of the following is incorrect( ! The continuous spectrum of hydrogen contains only four discrete colors. "! $iffraction produces both constructive and destructive interference. #! ll matter displays both particle and waveliCe characteristics. $! Eiels "ohr developed a 'uantum model for the hydrogen atom. %! The lowest possible energy state of a molecule or atom is called its ground state. ;ow many d orbitals have n @ )( ! & "! 0 #! 1$! 6 %! 11

,1. Which of the following is an incorrect designation for an atomic orbital( ! 1s "! )d #! 1p $! ,f %! 6s ,&. The number of orbitals having a given value of l is e'ual to ! &l < 1 "! &n < & #! )l $! l < ml %! the number of lobes in each orbital ,). Which of the following combinations of 'uantum numbers do not represent permissible solutions of the SchrIdinger e'uation for the electron in the hydrogen atom 3i.e., which combination of 'uantum numbers is not allowed!( n l m s3or ms! ! 2 1 +, 1B& "! 1 & & 1B& #! 6 +0 /1 1B& $! 6 0 +0 J %! ll are allowed.

)6.

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Unit 6 Study Guide ,,. Which of the following atoms or ions has ) unpaired electrons( ! E "! F #! l $! S&/ %! Kn&< ,0. The electron configuration for the barium atom is7 ! 1s&&s&&p6)s&)p6)d1-,s& "! LMeN 6s& #! 1s&&s&&p6)s&)p6,s1 $! 1s&&s&&p6)s&)p6,s& %! none of these ,6. The electron configuration for the carbon atom is7 ! 1s&&s&&p& "! L;eN &s, #! LEeN &s&&p& $! 1s&&p, %! none of these ,6. The electron configuration of indium is ! 1s&&s&&p6)s&)p6)d1-,s&,p6,d1-0s&0p10d1"! 1s&&s&&p6)s&)p6)d1-,s&,d1-,p1 #! 1s&)s&&p6)s&)p6,s&,p6,d1-0s&0d1-0p1 $! 1s&&s&&p6)s&)p6)d1-,s&,p6,d1-0s&0p1 %! none of these ,1. 5f l @ ), how many electrons can be contained in all the possible orbitals( ! 6 "! 6 #! 1, $! 1%! 0 ,2. Which of the following combinations of 'uantum numbers is not allowed( n l m3l! m3s! ! "! #! $! %! 1 ) & , , 1 1 ) & -1B& -+1B& +1 +& -1B& 1B& +1B& 0-. Who was the first chemist to recogni:e patterns in chemical properties of the elements( ! Oedeleev "! Eewlands #! Oeyer $! $obereiner %! "ohr 01. The statement that 9the lowest energy configuration for an atom is the one having the ma*imum number of unpaired electrons allowed by the ?auli principle in a particular set of degenerate orbitals9 is Cnown as ! the aufbau principle. "! ;undDs rule. #! ;eisenberg uncertainty principle. $! the ?auli e*clusion principle. %! the 'uantum model. 0&. Which of the following atoms would have the largest second ioni:ation energy( ! Og "! #l #! S $! #a %! Ea 0). The electron configuration of #r)< is ! L rN,s&)d1 "! L rN,s1)d& #! L rN)d) $! L rN,s&)d, %! none of these

0,. n element has the electron configuration LPrN,d1-0s&0p&. The element is a3n! ! nonmetal. "! transition element. #! metal. $! lanthanide. %! actinide. 00. n element E has the electron configuration LPrN,d1-0s&0p&. The formula for the fluoride of E is most liCely ! %81, "! %8, #! %8 $! %86 %! %81

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Unit 6 Study Guide 06. n element with the electron configuration LMeN,f1,0d66s& would belong to which class on the periodic table( ! transition elements "! alCaline earth elements #! halogens $! rare earth elements %! none of the above 06. The electron configuration for #r&< is ! L rN,s&)d, "! L rN,s1)d0 #! L rN)d, $! L rN,s&)d& %! none of these Use the following to answer 'uestion 6&7 Eitrogen has 0 valence electrons. #onsider the following electron arrangements. &s &p a! b! c! d! e! 6&.

01. ll halogens have the following number of valence electrons7 ! & "! ) #! 0 $! 6 %! none of these 02. Ti has HHHHHHHHHH in its d orbitals. ! 1 electron "! & electrons #! ) electrons $! , electrons %! none of these

Which represents the ground state for E(

6). Which represents the ground state for the E/ ion( 6,. 5n which groups do all the elements have the same number of valence electrons( ! ?, S, #l "! g, #d, r #! Ea, #a, "a $! ?, s, Se %! none 60. n atom of fluorine contains 2 electrons. ;ow many of these electrons are in s orbitals( ! & "! , #! 6 $! 1 %! none 66. ;ow many unpaired electrons are there in an atom of sulfur in its ground state( ! "! 1 #! & $! ) %! , 66. ;ow many electrons can be contained in all of the orbitals with n @ ,( ! & "! 1 #! 1$! 11 %! )&

6-. Germanium has HHHHHHHHHH in its ,p orbitals. ! 1 electron "! & electrons #! ) electrons $! , electrons %! none of these 61. 8e has HHHHHHHHHH that is 3are! unpaired in its d orbitals. ! 1 electron "! & electrons #! ) electrons $! , electrons %! none of these

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Unit 6 Study Guide 61. Ff the following elements, which has occupied d orbitals in its ground+state neutral atoms( ! "a "! #a #! Si $! ? %! #l 62. Ff the following elements, which needs three electrons to complete its valence shell( ! "a "! #a #! Si $! ? %! #l 6-. Which of the following electron configurations is correct( ! Ga7 LPrN)d1-,s&,p1 "! Oo7 LPrN0s&,d0 #! #a7 L rN,s1)d1$! "r7 LPrN)d1-,s&,p6 %! "i7 LMeN6s&,f1,0d1-6p) 61. The electron configuration of Ti&< is ! L rN,s& "! L rN,s1)d1 #! L rN)d& $! L rN,s&)d& %! none of these 6,. ;ow many of the following electron configurations for the species in their ground state are correct( 5. 1 s&&s&&p6)s&)p6,s& 55. Og7 1s&&s&&p6)s1 555. 47 L rN )s&)d) 54. s7 L rN ,s&)d1-,p) 4. ?7 1s&&s&&p6)p0 ! 1 "! & #! ) $! , %! 0 60. The number of unpaired electrons in the outer subshell of a #l atom is ! -. "! 1. #! &. $! ). %! none of these 66. 8or which of the following elements does the electron configuration for the lowest energy state show a partially filled d orbital( ! Ti "! Qb #! #u $! Ga %! Pr 66. line in the spectrum of atomic mercury has a wavelength of &0, nm. When mercury emits a photon of light at this wavelength, the fre'uency of this light is ! 1.,6e/16 s+1 "! 6.1&e/12 s+1 #! 1.11e10 s+1 $! 6.61e1 s+1 %! none of these 61. Which statements about hydrogen are true( I. ! has a lower ioni"ation energy than !e. II. !# is smaller than !. III. ! bonds with the halogens to form polar co$alent compounds. IV. ! is always a metal.

6&. 1s&&s&&p6)s&)p6,s&)d& is the correct electron configuration for which of the following atoms( ! #a "! Ti #! Ge $! Kr %! none of these 6). Which of the following atoms has three electrons in p orbitals in its valence shell( ! "a "! Ga #! 4 $! "i %! none of these

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Unit 6 Study Guide 4. ; does not have a second ioni:ation energy. ! "! #! $! %! 5, 4 55, 54 5, 555, 4 55, 54, 4 5, 555, 54, 4 1-. When electron configurations differ from e*pected, it is because orbitals want to be half+filled. ! True "! 8alse 11. Which of the following have 1- electrons in the d orbitals( ! On "! 8e #! #u $! Kn %! two of the above

62. Which of the following electron configurations are different from those e*pected( ! #a "! Sc #! Ti $! 4 %! #r

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Unit 6 Study Guide

Answer %ey
1. &. ). ,. 0. 6. 6. 1. 2. 1-. 11. 1&. 1). 1,. 10. 16. 16. 11. 12. &-. &1. &&. &). &,. &0. &6. &6. &1. &2. )-. )1. )&. )). ),. )0. )6. )6. )1. )2. ,-. ,1. ,&. ,). $ # " $ d! d! c! e! a! d! % # $ " % " " # % " # " " $ # # $ # " $ " # # #

,,. ,0. ,6. ,6. ,1. ,2. 0-. 01. 0&. 0). 0,. 00. 06. 06. 01. 02. 6-. 61.

" $ # $ " % # # " # $ " " $

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Unit 6 Study Guide

6&. a! 6). e! 6,. 60. 66. 66. 61. 62. 6-. 61. 6&. 6). 6,. 60. 66. 66. 61. 62. 1-. 11.

% " # % $ % # " $ " " # # % " %

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