AMMONIA-UREA AND SYNGAS-BASED PRODUCTS ENGINEERING AND CONSTRUCTION

PROJECT REFERENCES

AMMONIA-UREA AND SYNGAS-BASED PRODUCTS

INDEX

SAIPEM TODAY

SAIPEM ENGINEERING & CONSTRUCTION 6 AMMonIA-UrEA And SyngAs-BAsEd Products SYNGAS PRODUCTIONCAPACITY SNAMPROGETTItM UREA TECHNOLOGY INTHEWORLD AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES SNAMPROGETTItM UREA TECHNOLOGY REVAMP rEfErEncEs UREA PLANTS BASED ON CONVENTIONAL AND I.D.R. PROCESSES OTHER FERTILIZERS, RELATED UNITS AND GAS-BASED PRODUCTS

8 12

14

16

44

50

56
3

Saipem today
SAIPEM todAy Is A world lEAdEr In thE gloBAl suPPly of EngInEErIng, ProcurEMEnt, ProjEct MAnAgEMEnt, constructIon AND DRILLING sErVIcEs wIth dIstInctIVE cAPABIlItIEs In thE dEsIgn And EXEcutIon of lArgE-scAlE offshorE And onshorE ProjEcts.

Saipem has a strong bias towards oil and gas frontiers, namely activities in harsh and remote areas, in deep waters as well as in extremely cold and hot environments, applying significant technological competences in many diverse fields such as gas monetization and heavy oil exploitation. Saipem is organized in two Business Units: Engineering & Construction and Drilling.

Saipem ENGINEERING & CONSTRUCTION

FOLLOWING AN AGGRESSIVE GROWTH STRATEGY, WHICH INCLUDED IN THE LAST DECADE THE ACQUISITION OF MANY CONSTRUCTION, TECHNOLOGY AND ENGINEERING COMPANIES, MOST PROMINENTLY OF SNAMPROGETTI, BOUYGUES OFFSHORE, SOFRESID AND MOSS MARITIME, SAIPEM HAS BECOME ONE OF THE WORLD LARGEST AND MOST COMPLETE ENGINEERING AND CONSTRUCTION COMPANIES IN THE GLOBAL OIL AND GAS MARKETS, ONSHORE AND OFFSHORE.

Ever since its initial steps in the fifties as the construction division of Snam, the pipeline company of the Eni Group in Italy, Saipem has pursued a systematic growth strategy, based on the development of internal assets, expertise and skilled resources, as well as on the acquisition of other players with their own asset bases, such as Micoperi in late eighties, and many others. In the last decade, Saipem has continued its growth by acquiring Bouygues Offshore and Sofresid in France, Moss Maritime in Norway, IdPe in India and Snamprogetti in Italy, and by carrying out a multibillion investment program into the expansion of its offshore construction and drilling fleets. Since the year 2000, Saipems market capitalization has grown more than sixfold and its revenues tenfold.(*) The organizational integration of this considerable asset base, namely the network of engineering centres, fabrication and support yards in several continents as well as the offshore construction fleet, has been completed gradually over the years - most recently with the creation of a unified Business Unit Engineering & Construction, an entity with over 30,000 employees (excluding corporate and BU Drilling staff) from over 100 nationalities, with over 60 permanent establishments

and numerous project execution centres around the globe, and with yearly revenues exceeding 10 billion /y; all held together by outstanding project management skills. Through the involvement of our global EP(I)C hubs in Milan, Rome and Fano (Italy), Paris (France) and Chennai (India), which operate in connection with a growing number of medium size and smaller regional engineering and project execution centres employing altogether over 7,000 engineers, Saipem balances high project execution quality with a competitive cost and - most importantly - with a major emphasis on local know-how and content. This well-integrated multicenter approach provides a consistent design and robust execution philosophy on all our projects worldwide. Top priority is provided throughout to all HSEQ aspects. Saipem therefore offers a complete range of project definition and execution services, offshore and onshore, particularly for the complex mega-projects required by the market today: from feasibility and conceptual studies to complex integrated solutions combining design, engineering, procurement, field construction, fabrication and offshore

installation; also revamps, upgradings, maintenance, decommissionings, reclamations and decontaminations. Saipem today operates in virtually every world market, often in remote locations with harsh environmental conditions and challenging logistics, leveraging on its proven experience across the most significant product lines in the oil and gas production onshore, offshore, in deepwater; gas and oil transportation via offshore and onshore pipeline systems; midstream, refining, chemicals, power generation from fossil as well as from renewable sources; environmental industries, maritime works and infrastructure. This new series, therefore, outlines Saipems integrated references in engineering and construction markets offshore and onshore, according to individual business and technology lines.

(*) Until Dec. 31, 2010

7

Ammonia-Urea and Syngas-based Products

ThE IndustrIAl APPlIcAtIon of syngAs-BAsEd chEMIcAl ProcEssEs hAs BEEn onE of thE stAlwArts of SnAMProgEttI, rEcEntly IntEgrAtEd Into SAIPEM, AlMost sIncE Its EArlIEst dAys MAny dEcAdEs Ago.

We have designed and built hundreds of plants, including more than twenty fully integrated complexes, in every remote corner of the world, mostly based on the world leading and proprietary licensed SnamprogettiTM Urea Technology as well as on third party syngas generation, ammonia and methanol synthesis technologies. In the Ammonia-Urea process sequence, Saipem is a recognized world leader: 127(*) Urea Technology licensed plants. In the quest for the economies of scale, following the design and construction of the largest single train urea unit in operation for a long time (Profertil, Bahia Blanca Fertilizer Complex in Argentina), which achieved an average yearly

production of 3,558 Tons per Day (T/D) in 2006 and has become the reference for the subsequent design and construction of todays biggest single train urea plants, at the end of 2010 Saipem has completed and put on stream the world largest single train unit, namely the Daharki Ammonia-Urea Complex for Engro in Pakistan, with the design production capacity of 3835 T/D of urea. Three more such units, with the capacity of 3850 T/D, are at various stages of design and construction in Qatar and in India. Design and construction in 20022005 of the largest ammonia-urea single project, namely Omifco in Oman, with the total urea design capacity of 5,060 T/D; in 2008 the plant achieved the capacity peak of 6,000 T/D.

Continuous Urea Technology improvements and upgrading. To name just a few most recent achievements: - the new OmegabondTM Advanced Tubing Technology (Ti/Zr metallurgically coextruded) for improved stripper performance developed in collaboration with ATI WahChang; - focus on plant reliability and availability concepts applied on the 5,000+ T/D single train for which a design is available; - the adoption of continuously improved environmental impact reduction and energy saving schemes.

(*) Until Dec. 31, 2011

8

Moron Fertilizer Complex - Venezuela 1972

10

In addition to a large number of integrated ammonia-urea complexes based on natural gas and light naphthas as feedstocks, in 2002 Saipem has placed on stream in Nanjing, P.R. China, a complex utilizing coal-like Eureka pitch as feedstock. This feedstock is gasified by means of a GE (former Texaco) gasification technology to produce syngas, subsequently converted into 1,000 T/D of ammonia and 1,700 T/D of urea. Our project reference list has been enriched with the award a few years ago of the multibillion Gas-to-Liquids project in Escravos, Nigeria from Chevron Nigeria Ltd., to be started up shortly. The goal of this new investment is the conversion of natural gas into 33,000 BPSD of top quality middle distillates for transportation fuels via the new process technology licensed by Sasol. The first steps in the process sequence, namely the syngas production, are based on a technology which is very similar to the one applied in large scale ammonia and methanol synthesis.

Among other technological novelties, this project will see one of the first applications on a very large scale of Haldor Topses ATR Auto Thermal Reformer process technology. With a capacity of 560,000 Nm3/h of each of the two ATRs, this will be one of the largest syngas production units in the world. Saipem has been traditionally a leading player in the design and execution of Methanol Synthesis plants, based on different process technologies, with the more recent focus on Haldor Topses e.g. the 3,000 T/D Bandar Imam plant in Iran a world class plant at the time of its start-up in 2004 and, more recently, the Front End Design of the 10,000 T/D VIVA Methanol Project in Nigeria. This last one could become the largest methanol synthesis and syngas generation plant ever built.

11

Syngas Production Capacity

SyngAs ProductIon CAPAcIty In REcEnt SAIPEM DEsIgns.

Project

Syngas Production Capacity per Train (dry basis), kNm3/h

Syngas Generation Technology

N. Type 1 ATR

VIVA METHANOL,(b) NIGERIA ESCRAVOS GTL,(c) NIGERIA QAFCO 5,(a) QATAR ENGRO,(a) PAKISTAN OMIFCO,(a) OMAN FERTINITRO,(a) VENEZUELA PROFERTIL,(a) ARGENTINA BANDAR IMAM,(b) IRAN NANJING,(a) CHINA
0 100 200 300 400 500 600 700 800 900 1000 1100

ATR

Primary and secondary Air Blown Reformer Primary and secondary Air Blown Reformer Primary and secondary Air Blown Reformer Primary and secondary Air Blown Reformer Primary and secondary Air Blown Reformer One step reformer

Gasifier

(a) Ammonia (b) Methanol

Synthesis including Nitrogen

Synthesis (c) Gas-to-Liquids

12

13

SNAMPROGETTI UREATECHNOLOGY INTHEWORLD

TM

CANADA

U.S.A.

SPAIN ALGERIA

MEXICO VENEZUELA

TRINIDAD & TOBAGO

NIGE

G PERU

SAIPEM todAy Is A MArkEt lEAdEr In thE AMMonIA-urEA ProcEss chAIn, wIth 127 snAMProgEttITM UrEA TEchnology lIcEnsEs worldwIdE, wIth MorE thAn 20 IntEgrAtEd AMMonIA-urEA coMPlEXEs And nuMErous IndIVIduAl ProcEss unIts dEsIgnEd And BuIlt In EVEry contInEnt. SAIPEM holds A lEAdIng shArE of thE totAl InstAllEd cAPAcIty worldwIdE.
14

ARGENTINA

RUSSIA TATARSTAN GERMANY KAZAKHSTAN AUSTRIA ITALY BULGARIA IRAQ SAUDI ARABIA OMAN SOMALIA MALAYSIA IRAN PAKISTAN BAHRAIN QATAR INDIA P.R. CHINA BANGLADESH VIETNAM INDONESIA

ERIA

GABON

15

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

SAIPEM IS THE OWNER OF THE SNAMPROGETTITM UREA TECHNOLOGY. LOCATION
Country, Location Saudi Arabia, Al Jubail China, Ordos, Inner Mongolia Malaysia, Sabah Gabon, Port Gentil Nigeria, Agenebode, Edo State Tatarstan, Mendeleevsk Nigeria, Escravos SAUDI ARABIA FERTILIZER Co. SAFCO-5 ORDOS YIDING COAL CHEMICAL Co, Ltd. PETRONAS CHEMICAL FERTILISER SABAH Snd. Bhd. GABON FERTILIZER COMPANY DANGOTE FERTILIZER Ltd. AMMONI CHEVRON NIGERIA Ltd. (CNL)

Technologies
AMMONIA
License Capacity T/D

CLIENT

UREA
SnamprogettiTM Technology Capacity T/D 3250 1740 3500 3850 2x 3850 2050

ESCRAVOS GAS-TO-LIQUIDS PROJECT - NIGERIA

In addition to being one of the first applications of the Gas-to-Liquids technology on a world-class scale (process technologies by Sasol, Chevron, Haldor Topse and others), the design and construction of this complex had several elements of originality, such as the harsh and remote site environment. In order to simplify local construction on the site in Escravos, Nigeria, many plant sections were designed and built in an U.A.E. fabrication yard as modules, then shipped to the site. Modularization design: the biggest Saipem modularized plant of all times (pipe rack modules of over 1,000 tons each, process modules of over 2,000 tons each) Erection - Reactors Size: World Class Record 2008

16

GRANULATION
License Capacity T/D UFT 3250

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK

ON STREAM

Licences/Engineering/Procurement/Supervision License / PDP / Tech. Assistance

Under Exec. Under Exec. Under Exec. Under Exec. Under Exec. Under Exec.

UFT UFT UFT UFT

3500 3850 2x 3850 2050 Gas-to-Liquids (Sasol, Chevron, Haldor Topse A/S)

Licenses / PDP / Tech. Assistance License / PDP / Tech. Assistance FEED License / PDP / Tech. Assistance

2 x 17000 BPSD

Engineering / Procurement / Construction

Under Exec.

17

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION ClIENT AMMONIA
Country, Location Vietnam, Bac Giang HABAC NITROGENOUS FERTILIZER & CHEMICALS COMPANY Ltd. TATA (FERTILIZER DIVISION) CHEMICALS Ltd. CNSG ANHUI HONG SIFANG Co., Ltd. MATIX FERT. & CHEM. Ltd. CF INDUSTRIES Inc. QATAR FERTILIZER COMPANY QAFCO-6 Project SHAANXI POPULAR JURASSIC (GROUP) Co., Ltd. INNER MONGOLIA TALENT CHEMICAL FERTILIZER Co., Ltd. ALGERIA OMAN FERTILIZER COMPANY PETROVIETNAM VIETNAM NATIONAL CHEMICAL CORP. (VINACHEM) VIVA METHANOL License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D 1000 3850 1000 3850 3850 3850 1760 1760 2x 3500 2385 1760

India, Babrala China, Hefei, Anhui India, Panagarh, West Bengala Peru, San Juan De Marcona Qatar, Mesaieed China, Fugu, Shaanxi China, Jungar, Inner Mongolia Algeria, Arzew Vietnam, Ca Mau Vietnam, Ninh Binh Nigeria, Lekki Peninsula (Lagos)

18

GRANulATION OTHERS SCOPE OF WORK ON STREAM

License Capacity T/D Plant (License) Capacity T/D License / PDP / Tech. Assistance License / PDP / Engineering / Tech. Assistance License / PDP / Tech. Assistance License / PDP / Engineering / Tech. Assistance UFT UFT 3850 3850 Licenses / PDP / Tech. Assistance Licenses / PDP / Tech. Assistance License / PDP / Tech. Assistance License / PDP / Tech. Assistance License / PDP / Tech. Assistance License / PDP / Tech. Assistance License / PDP / Tech. Assistance Methanol (Haldor Topse A/S) 10000 Front End Engineering Under Exec. Under Exec. Under Exec. Under Exec. Under Exec. Under Exec. Under Exec. Under Exec. Under Exec. Under Exec. Under Exec.

19

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Qatar, Mesaieed QATAR FERTILIZER COMPANY QAFCO-5 Project

CLIENT
License

AMMONIA
Capacity T/D Haldor Topse A/S 2x 2300

UREA
SnamprogettiTM Technology Capacity T/D 3850 2640

China, Korla, Xinjiang Uyugur

PETROCHINA TARIM PETROCHEMICAL COMPANY

QAFCO 5 FERTILIZER COMPLEX - QATAR

The Qafco 5 Fertilizer Complex, with a total capacity of 4,600 T/D of ammonia partially converted into 3,850 T/D of granular urea, will be the largest single train urea project inside the largest fertilizer complex in the world. The project is also characterized by a common utilities and offsites complex to feed subsequent development of Qafco as fertilizer producer as well as by an excess of ammonia production capacity for other applications.

20

GRANULATION
License Capacity T/D UFT 3850

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK

ON STREAM

Licenses / Engineering / Procurement / Supervision License / PDP / Tech. Assistance

2012 2011

21

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Pakistan, Daharki ENGRO FERTILIZERS Ltd.(EFL) (formerly ENGRO CHEMICAL PAKISTAN Ltd.) Sohar International Urea & Chemical Industries SAOC (SIUCI)

CLIENT
License

AMMONIA
Capacity T/D Haldor Topse A/S 2194

UREA
SnamprogettiTM Technology Capacity T/D 3835 2x 1750

Oman, Sohar

DAHARKI AMMONIA-UREA COMPLEX - PAKISTAN

The Daharki Ammonia-Urea Complex, with an ammonia capacity of 2,194 T/D and an urea capacity of 3,835 T/D, is today the largest single train urea plant on stream in the world. The complex is characterized by the world tallest urea prilling tower.

22

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK

ON STREAM

License / Engineering / Procurement / Supervision License / PDP / Tech. Assistance

2010 2009

23

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Oman, Sur OMIFCO

CLIENT
License

AMMONIA
Capacity T/D Haldor Topse A/S, Giammarco Vetrocoke

UREA
SnamprogettiTM Technology Capacity T/D

2x 1750

2x 2530

Iran, Bandar Imam (Razi)

PETROCHEMICAL INDUSTRIES DEVELOPMENT MANAGEMENT Co.

OMAN INDIA FERTILIZER COMPLEX - OMAN

At the time of the start-up in 2005, the Omifco Fertilizer Complex was the largest ammonia-urea project in the world, supplying granular urea. The plant was implemented under limited recourse of project financing, including the involvement of Italian and French ECA. The project was built quickly and started up smoothly: First gas into the ammonia plant 32 months after project financial closure, 35 months after EPC contract signature First production in 18 days and 1 day for ammonia-urea train one; 12 days and 1 day for train two

24

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK

ON STREAM

UFT HydroAgri

2x 2530 1800

Utilities & Offsites

License / Engineering / Procurement / Construction Engineering / Procurement / Construction

2005 2004

25

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Iran, Bandar Imam FANAVARAN PETROCHEMICAL Co.

CLIENT
License

AMMONIA
Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D

Vietnam, Phu-My China, Nanjing, Jiangsu

PETROVIETNAM SINOPEC NANJING CHEMICAL INDUSTRIAL Co., Ltd. Haldor Topse A/S,Texaco, Linde, Ici

2200

1000

1750 1725

Indonesia, Bontang-Utara

P.T. PUPUK KALIMANTAN TIMUR

BANDAR IMAM THIRD METHANOL PLANT - IRAN

At the time of the design in 2001, the Bandar Imam Third Methanol was the largest methanol project in the world, supplying methanol high quality grade (AA).

26

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D Methanol (Haldor Topse A/S) 3030

SCOPE OF WORK

ON STREAM

License / Engineering / Procurement License / Basic / Tech. Assistance

2004 2004

License / Engineering / Procurement License / Basic / Tech. Assistance

2002 2002

27

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Bahia Blanca, Argentina PROFERTIL S.A.

CLIENT
License

AMMONIA
Capacity T/D Haldor Topse A/S, Basf 2050

UREA
SnamprogettiTM Technology Capacity T/D 3250 400 400

China, Hefei, Anhui China, Qingzhen, Guizhou

HEFEI SIFANG GROUP GUIZHOU FERTILIZER Co., Ltd.

BAHIA BLANCA FERTILIZER COMPLEX - ARGENTINA

At the time of completion in 2001, the Bahia Blanca Fertilizer Complex included the largest single train urea plant in the world, with the design granular urea production capacity of 3,250 T/D. It was the first plant to break the 3,000 T/D production target in single stream urea. In 2006 it produced 1,280,718 tons in a full year of operation, achieving in 360 days of operation an average daily production of 3,558 T/D, with a maximum peak of 3,700 T/D.

28

GRANULATION
License Capacity T/D HydroAgri 2x 1850

OTHERS
Plant (License) Capacity T/D Utilities & Offsites

SCOPE OF WORK

ON STREAM

Licenses / Engineering / Procurement / Construction License / Basic / Tech. Assistance License / Engineering / Procurement

2001 2001 2001

29

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION
Country, Location Venezuela, Jose FERTINITRO C.E.C.

CLIENT
License

AMMONIA
Capacity T/D Haldor Topse A/S, Giammarco Vetrocoke

UREA
SnamprogettiTM Technology Capacity T/D

2x 1800

2x 2200 900 600 400 400 400 1800

China, Huainan, Anhui China, Anyang, Henan China, Hechi, Guangxi China, Huaxian, Shaanxi China, Pingdingshan, Henan Malaysia, Gurun, Kedah

ANHUI HUAINAN CHEMICAL GROUP Co., Ltd. ANYANG CHEMICAL INDUSTRIAL GROUP Co., Ltd. GUANGXI HECHI CHEMICAL Co., Ltd. SHAANHUA FERTILIZER Co., Ltd. PINGDINGSHAN FEIXING CHEMICAL GROUP Co., Ltd. PETRONAS FERTILIZER Sdn Bhd

JOSE FERTILIZER COMPLEX - VENEZUELA

With the design production of 4,400 T/D of urea in two lines, the Jose Fertilizer Complex is still today the largest ammonia-urea complex in Latin America.

30

GRANULATION
License Capacity T/D

OTHERS
Plant (License) Capacity T/D

SCOPE OF WORK

ON STREAM

HydroAgri

2x 2200

Utilities & Offsites

License / Engineering / Procurement / Construction License / Engineering / Procurement License / Engineering / Procurement License / Engineering / Procurement License / Engineering / Procurement License / Basic / Tech. Assistance License / Basic / Tech. Assistance

2001 2000 1999 1999 1999 1999 1999

31

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION ClIENT AMMONIA
Country, Location Bahrain, Sitra Island GULF PETROCHEMICAL INDUSTRIES Co. License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D 1700 (941 uninterrupted production days between turnarounds) 400

China, Zhanyi, Yunnan India, Kakinada, A.P.

YUNNAN ZHANYI CHEMICAL Co., Ltd. NAGARJUNA FERTILIZERS AND CHEMICAL CORP. Haldor Topse A/S, Giammarco Vetrocoke

900

1500

Venezuela, Jose China, Lanzhou, Gansu India, Phulpur, U.P. India, Vijaipur, M.P. China, Chishui, Guizhou China, Dongfang, Hainan China, Hejiang, Sichuan China, Hohhot, Inner Mongolia China, Jining, Shandong China, Jiujiang, Jiang-Xi India, Aonla, U.P. China, Baoji, Shaanxi

SUPERMETANOL CA PETROCHINA LANZHOU PETROCHEMICAL Co. INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd. NATIONAL FERTILIZERS Ltd. GUIZHOU CHITIANHUA GROUP Co., Ltd. CNOOC CHEMICAL Ltd. SICHUAN TIANHUA Co., Ltd. INNER MONGOLIA TIANYE CHEMICAL GROUP Co., Ltd. JINING CHEMICAL FERTILIZER PLANT SINOPEC JIUJIANG PETROCHEMICAL COMPANY (JPC) INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd. SHAANXI BAOJI NITROGEN FERTILIZER PLANT 1760 2x 1100 2x 1100 500 1765 1765 1760 400 1760 2x 1100 400

32

GRANulATION OTHERS SCOPE OF WORK ON STREAM

License Capacity T/D Plant (License) Capacity T/D

License / Basic / Tech. Assistance License / Basic / Tech. Assistance

1998 1998

License / Engineering / Supervision Methanol (Kvaerner) from 2000 to 2250 Engineering / Procurement / Constr. Mngmt License / Engineering / Procurement License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Engineering / Procurement License / Engineering / Procurement License / Engineering / Procurement License / Basic / Tech. Assistance License / Engineering / Procurement License / Basic / Tech. Assistance License / Basic / Tech. Assistance

1998 1998 1997 1997 1997 1996 1996 1996 1996 1996 1996 1996 1995

33

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION ClIENT AMMONIA
Country, Location India, Babrala, U.P. TATA (FERTILIZER DIVISION) CHEMICALS Ltd. License Capacity T/D Haldor Topse A/S, Giammarco Vetrocoke

UREA
SnamprogettiTM Technology Capacity T/D

1350

2x 1125 2x 1100

India, Shahjahanpur, U.P. India, Gadepan, Ra.

KRIBHCO SHYAM FERTILIZERS Ltd. (KSFL) CHAMBAL FERTILIZERS AND CHEMICALS Ltd. Haldor Topse A/S, Giammarco Vetrocoke

1350

2x 1125

Venezuela, Jose China, Fuling, Sichuan China, Jinxi, Liaoning Pakistan, Goth Machhi

SUPERMETANOL CA CHONGQING JIANFENG CHEMICAL C OMPLEX JINXI NATURAL GAS & CHEMICAL Co., Ltd. FAUJI FERTILIZER COMPANY Ltd. Haldor Topse A/S, Basf 1100 1750 1760 1925 1700 400 400 Haldor Topse A/S, Giammarco Vetrocoke

Bangladesh, Tarakandi China, Luoyang, Henan China, Yuanping, Shanxi India, Kakinada, A.P.

JAMUNA FERT. COMPANY Ltd. LUOYANG ZHONGHAO CHEMICAL INDUSTRIAL Co., Ltd. SHANXI YUANPING CHEMICAL INDUSTRY Co., Ltd. NAGARJUNA FERTILIZERS AND CHEMICALS Ltd.

900

1500

Italy, Ferrara

ENICHEM AGRICOLTURA S.p.A.

34

GRANulATION OTHERS SCOPE OF WORK ON STREAM

License Capacity T/D Plant (License) Capacity T/D

License / Engineering / Supervision License / Basic / Tech. Assistance

1995 1995

License / Engineering / Supervision Methanol (Ici) 2000 Engineering / Procurement / Constr. Mngmt License / Basic / Tech. Assistance License / Basic / Tech. Assistance Utilities & Offsites License / Engineering / Procurement / Construction License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Basic / Tech. Assistance

1994 1994 1993 1993 1993 1992 1992 1992

License / Basic / Tech. Assistance Deep Hydrolysis (SnamprogettiTM)

1992

1700

Engineering / Procurement / Construction

1992

35

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION ClIENT AMMONIA
Country, Location China, Beijing China, Xuanhua, Hebei China, Puyang, Henan Italy, Nera Montoro BEIJING CHEMICAL EXPERIMENTAL PLANT HEBEI XUANHUA FERTILIZER GROUP Co., Ltd. HENAN ZHONGYUAN DAHUA GROUP Co., Ltd. TERNI INDUSTRIE CHIMICHE S.p.A. License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D 400 400 1760

Saudi Arabia, Al Jubail Bahrain, Sitra Island

NATIONAL CHEMICAL FERTILIZER Co. (IBN AL-BAYTAR) GULF PETROCHEMICAL INDUSTRIES Co. Uhde from 1000 to 1200

1500

Venezuela, Zulia

PEQUIVEN

India, Aonla, U.P.

INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd.

Haldor Topse A/S, Benfield (UC) Haldor Topse A/S, Giammarco Vetrocoke

1350

2x 1100

India, Jagdishpur, U.P.

INDO GULF Co., Ltd.

1350

2x 1100 2x 1100

India, Vijaipur, M.P. United Kingdom, Immingham

NATIONAL FERTILIZERS Ltd. NORSK HYDRO FERTILIZERS Ltd.

36

GRANulATION OTHERS SCOPE OF WORK ON STREAM

License Capacity T/D Plant (License) Capacity T/D License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Engineering / Procurement Kaltenbach Thuring S.A. 400 Engineering / Procurement / Construction License / Basic / Tech. Assistance Methanol (Ici) Deep Hydrolysis (SnamprogettiTM) from 1000 to 1200 License / Engineering / Procurement 1991 1991 1990 1990 1990 1989 1989 2x 1200

License / Engineering / Supervision License / Engineering / Procurement

1988 1988

License / Engineering / Supervision Ammonium Nitrate (HydroAgri) Calcium Ammonium Nitrate Granulation (HydroAgri) 1800

1988

3000

Engineering Services

1988

37

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION ClIENT AMMONIA
Country, Location Pakistan, Multan Bahrain, Sitra Island India, Hazira, Gu. India, Thal Vaishet, Ma. Somalia, Mogadishu Mexico, Pajaritos Bulgaria, Vratza Canada, Red Water, Alberta Spain, Castellon de la Plana PAKARAB FERTILIZERS Ltd. GULF PETROCHEMICAL INDUSTRIES Co. KRISHAK BHARATI COOP. Ltd. RASHTRIYA CHEMICALS FERTILIZERS Ltd. MINISTRY OF NATIONAL PLANNING AGRO NITROGENADOS S.A. CHIMCO AGRIUM U.S. Inc. PROQUIMED Uhde 1000 4x 1100 3x 1500 150 1500 600 1500 License Capacity T/D

UREA
SnamprogettiTM Technology Capacity T/D 300

Trinidad and Tobago, Point Lisas PCS NITROGEN India, Bharuch, Gu. India, Trombay, Ma. GUJARAT NARMADA VALLEY FERTILIZERS Co., Ltd. RASHTRIYA CHEMICALS FERTILIZERS Ltd. Haldor Topse A/S, Benfield (UC) Haldor Topse A/S, Benfield (UC)

1620 1800

900

1000

Libya, Marsa El Brega

NATIONAL PETROCHEMICAL Co. (NAPETCO)

1000

1500 1500

Mexico, Pajaritos

AGRO NITROGENADOS S.A.

38

GRANulATION OTHERS SCOPE OF WORK ON STREAM

License Capacity T/D Plant (License) Capacity T/D License / Basic / Tech. Assistance Methanol (Ici) 1000 Engineering / Procurement / Construction License / Engineering / Supervision License / Engineering / Supervision License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Basic / Tech. Assistance Ammonium Sulphate (Struthers Wells) 366 Engineering / Procurement / Construction License / Engineering / Procurement Licence / Engineering / Procurement 1986 1985 1985 1985 1985 1984 1983 1983 1983 1983 1982

License / Engineering / Procurement Engineering / Procurement / Construction

1982 1982

License / Basic / Tech. Assistance

1982

39

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION ClIENT AMMONIA
Country, Location Pakistan, Goth Machhi FAUJI FERTILIZER COMPANY Ltd. License Capacity T/D Haldor Topse A/S, Benfield (UC)

UREA
SnamprogettiTM Technology Capacity T/D

1000

1725 2x 1500 1550

CIS, Togliattigrad India, Phulpur, U.P. Pakistan, Mirpur Mathelo

TOGLIATTI AZOT INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd. FAUJI FERTILIZER COMPANY Ltd. Haldor Topse A/S, Benfield (UC)

1000

1740 250 1500 1000 2x 1600 1000 1000 1300 1000 600

USA, Borger, Texas CIS, Novomoskovsk Germany, Bsterreichische Iraq, Khor Al-Zubair Italy, Manfredonia Austria, Linz Iraq, Basrah USA, Memphis, Tennessee USA, Lawrence, Kansas Italy, Ravenna

AGRIUM U.S. Inc. NOVOMOSKOVSK AZOT YARA BSTERREICHISCHE GmbH MINISTRY OF INDUSTRY AND MINERALS ENICHEM AGRICOLTURA S.p.A. AGROLINZ MELAMIN GmbH MINISTRY OF INDUSTRY AND MINERALS PCS NITROGEN FARMLAND FERTILIZER/Ag CHEMICAL ANIC S.p.A.

40

GRANulATION OTHERS SCOPE OF WORK ON STREAM

License Capacity T/D Plant (License) Capacity T/D

License / Engineering / Supervision License / Engineering / Procurement License / Engineering / Supervision

1982 1980 1980

License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Engineering / Procurement License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Engineering / Supervision License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Basic / Tech. Assistance License / Basic / Tech. Assistance Ammonium Sulphate (Ici) Calcium Nitrate (Pintsch Bamag) 1400 200 License / Basic / Tech. Assistance

1980 1980 1979 1979 1979 1978 1977 1976 1975 1974

1973

41

AMMONIA-UREA AND SYNGAS-BASED PROJECT REFERENCES

Technologies
LOCATION ClIENT AMMONIA
Country, Location Italy, Manfredonia ENICHEM AGRICOLTURA S.p.A. License Capacity T/D Haldor Topse A/S, Giammarco Vetrocoke

UREA
SnamprogettiTM Technology Capacity T/D

1200

1000 750 300 750 300

Venezuela, Moron Italy, Nera Montoro Mexico, Minatitlan Spain, Puertollano Syria, Homs

SERVIFERTIL TERNI INDUSTRIE CHIMICHE S.p.A. FERTIMINA S.A. EMPRESA NACIONAL DE FERTILIZANTES S.A. GENERAL ORGANIZATION FOR EXECUTING INDUSTRIAL PROJECTS (GOEIP) ENICHEM AGRICOLTURA S.p.A. V/O TECHMASHIMPORT Air Liquide, Ammonia Casale 430 Ici 150 MT/D

Italy, Gela Russia, Tula

70

Italy, Pisticci

ANIC S.p.A.

Romania, Victoria

INDUSTRIAL IMPORT

42

GRANulATION OTHERS SCOPE OF WORK ON STREAM

License Capacity T/D Plant (License) Capacity T/D

License / Engineering / Supervision NPK (Dorr Oliver) 920 Engineering / Procurement / Construction License / Engineering / Supervision License / Engineering / Procurement License / Engineering / Procurement Engineering / Procurement / Construction License / Engineering / Procurement Methanol (Ammonia Casale) Methanol (Ammonia Casale) Methanol (Ammonia Casale) from 720 MT/D Engineering / Procurement

1972 1972 1971 1971 1971 1971 1966 1966

170

Engineering / Supervision

1964

90

Engineering / Procurement

1963

43

Snamprogetti Urea Technology ReVamp references

TM

WIth thE oBjEctIVE of IMProVIng thE EconoMIcs And EnVIronMEntAl IMPAct of PlAnts BuIlt EArlIEr Mostly on SnAMProgEttITM UrEA TEchnology, SAIPEM hAs IntroducEd sEVErAl NEW solutIons In ordEr to EXPAnd thEIr ProductIon cAPAcIty, ModErnIzE thEIr hArdwArE And EnhAncE thEIr oPErABIlIty And rElIABIlIty.

Main revamp undertakings: Updated process scheme Energy optimization Improvement of product quality Reduction of emissions Improved metallurgy Saipem has developed a successful revamp methodology to meet clients expectations: Continuous assistance during the development of the project and the lifetime of the plant. Identification of clients needs through feasibility studies. Definition of the appropriate and economically viable revamp process scheme.
44

Development of a process design package and supply of the relevant services (licensor technical assistance during detailed engineering, commissioning and start-up) to allow an effective implementation. Based on this approach, almost twenty revamps have been implemented during the last few years, mainly in India, Pakistan and P.R. China, resulting in a typical capacity increase between 30 and 70%, as well as in a significant reduction in energy consumption.

45

SnamprogettiTM Urea Technology ReVamp references

LOCATION ClIENT ORIGINALPROCESS O

Country, Location India, Jagdishpur, U.P. India, Thal Vaishet, Ma. Iraq, Khox Al-Zubair India, Vijaipur, M.P. India, Hazira, Gu. India, Babrala, U.P. China, Hejiang, Sichuan India, Kakinada, A.P. India, Aonla, U.P. India, Bharuch, Gu. India, Gadepan, Ra. India, Phulpur, U.P. India, Phulpur, U.P. Pakistan, Mirpur Mathelo India, Namrup India, Namrup India, Thal Vaishet, Ma. INDO GULF Co., Ltd. RASHTRIYA CHEMICALS FERTILIZERS Ltd. STATE COMPANY OF FERTILIZER NATIONAL FERTILIZERS Ltd. KRISHAK BHARATI COOP. Ltd. TATA (FERTILIZER DIVISION) CHEMICALS Ltd. SICHUAN TIANHUA Co., Ltd. NAGARJUNA FERTILIZERS AND CHEMICAL CORP. INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd. GUJARAT NARMADA VALLEY FERTILIZERS Co., Ltd. CHAMBAL FERTILIZERS AND CHEMICALS Ltd. INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd. INDIAN FARMERS FERTILIZERS COOPERATIVE Ltd. FAUJI FERTILIZER COMPANY Ltd. HINDUSTAN FERTILIZER COMPANY Ltd. HINDUSTAN FERTILIZER COMPANY Ltd. RASHTRIYA CHEMICALS FERTILIZERS Ltd. SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM Montedison Montedison SnamprogettiTM

46

 ORIGINALNOMINAL CAPACITY CAPACITY AFTER REVAMPING ON sTrEAm

(MT/D) 2x 1500 1900 2x 1600 4x 1100 4x 1300 2x 1125 1765 2x 1500 4x 1100 2350 2x 1125 1550 2x 1100 1740 2x 500 1167 3x 1500 (MT/D) 2x 1700 2300 2x 2080 2x 1515 and 2x 1615 4x 1660 2x 1900 2300 2x 2350 4x 1515 2350 energy efficiency improvement 2x 1750 2115 2x 1515 2175 2x 500 1167 3x 1900 Year Under Exec. Under Exec. Under Exec. Under Exec. Under Exec. Under Exec. Under Exec. 2009 2008 2008 2008 2008 2008 2008 2005 2002 2002

47

SnamprogettiTM Urea Technology ReVamp references

LOCATION ClIENT ORIGINALPROCESS O

Country, Location India, Hazira, Gu. India, Jagdishpur, U.P. Canada, Red Water, Alberta Pakistan, Goth Machhi Spain, Puertollano Germany, Brunsbttel India, Bharuch, Gu. Pakistan, Multan USA, Memphis, Tennessee USA, Lawrence, Kansas Austria, Linz Italy, Nera Montoro KRISHAK BHARATI COOP. Ltd. INDO GULF Co., Ltd. AGRIUM U.S. Inc. FAUJI FERTILIZER COMPANY Ltd. EMPRESA NACIONAL DE FERTILIZANTES S.A. YARA BRUNSBUTTEL GmbH GUJARAT NARMADA VALLEY FERTILIZERS Co., Ltd. PAKARAB FERTILIZERS Ltd. PCS NITROGEN FARMLAND FERTILIZER/Ag CHEMICAL AGROLINZ MELAMIN GmbH TERNI INDUSTRIE CHIMICHE S.p.A. SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM Inventa SnamprogettiTM SnamprogettiTM SnamprogettiTM SnamprogettiTM

48

 ORIGINALNOMINAL CAPACITY CAPACITY AFTER REVAMPING ON sTrEAm

(MT/D) 4x 1100 2x 1100 1500 1725 300 1000 1800 150 1000 600 1000 300 (MT/D) 4x 1300 2x 1500 2100 2105 400 1400 2350 300 1250 720 1300 360 Year 2001 2001 1996 1992 1991 1990 1990 1986 1983 1982 1980 1980

49

UREA PLANTS BASED on conVentional and i.d.r. PROCESSes

SAIPEM IS THE OWNER OF THE FORMER MONTEDISON UREA TECHNOLOGy. COMPANY
ZAKLADY AZOTOWE PULAWY AGRIMONT C.N.C.C.C. TECHMASHIMPORT QUIMIGAL FERTIMONT. TECHMASHIMPORT THE FERTILIZER CORP. OF INDIA Ltd. THE FERTILIZER CORP. OF INDIA Ltd. THE FERTILIZER CORP. OF INDIA Ltd. THE FERTILIZER CORP. OF INDIA Ltd. TECHMASHIMPORT THE FERTILIZER CORP. OF INDIA Ltd. MONTEDISON

LOCATION
Poland, Pulawy Italy, Ferrara China, Luzhou Russia, Berezniki Portugal, Lavradio Italy, San Giuseppe di Cairo Russia, Kemerovo India, Ramagundam India, Talcher India, Sindri India, Haldia Ukraine, Gorlovka India, Nangal Italy, Ferrara

CAPACITY t/d Urea

1700 1700 750 1500 Rev. to 270 300 1500 1500 1500 1000 500 1500 1000 1500

START-UP
1994 1989 1988 1982 1982 1981 1981 1979 1979 1979 1979 1979 1978 1977

50

COMPANY
THE FERTILIZER CORP. OF INDIA Ltd. THE FERTILIZER CORP. OF INDIA Ltd. KIROVAKAN CHIM THE FERTILIZER CORP. OF INDIA Ltd. THE FERT. & CHEM. TRAVANCORE C.N.A. (Compagnie Neerlandaise de lAzote) MONTEDISON C.N.A. (Compagnie Neerlandaise de lAzote) MONTEDISON VETROCOKE NEYVELI LIGNITE C.N.A. (Compagnie Neerlandaise de lAzote)

LOCATION
India, Nampur India, Rarauni Russia, Kirovakan Chim India, Durgapur India, Cochin The Netherlands, Sluiskil Italy, Castellanza The Netherlands, Sluiskil Italy, San Giuseppe di Cairo Italy, Porto Marghera India, Neyveli The Netherlands

CAPACITY t/d Urea

1000 1000 54 1000 1000 1100 450 700 450 250 500 330

START-UP
1976 1976 1973 1973 1973 1970 1968 1968 1967 1967 1965 1965

51

UREA PLANTS BASED on conVentional and i.d.r. PROCESSes

COMPANY
NISSAN CHEM. IND. COLOMBIANA DE FERTILIZANTES OESTERREISCHICHE STICKSTOFFWERKE MINISTRY OF MINES FERT. CORP. MONTEDISON MONTEDISON UNIAO FABRIL AZOTO IST. VENEZOLANO DE PETROQUIMICA OFFICE NATIONAL IND. DE LAZOTE PIERREFITTE STE GENERALE DENGRAIS ET PRODUITS CHIMIQUES AZOLACQ VETROCOKE C.N.A. (Compagnie Neerlandaise de lAzote) C.N.A. (Compagnie Neerlandaise de lAzote)

LOCATION
Japan, Toyama Colombia, Barranca Austria, Linz Iran, Shiraz Italy, Novara Italy, Novara Portugal, Lisboa Venezuela, Moron France, Toulouse France, Pierrefitte France, Pardies Italy, Porto Marghera The Netherlands, Sluiskil

CAPACITY t/d Urea

60 30 80 120 70 43 150 50 200 120 120 125 200

START-UP
1965 1964 1963 1963 1963 1963 1963 1963 1962 1962 1962 1962 1962

The Netherlands, Sluiskil

180

1962

52

COMPANY
ARMOUR SUN OLIN CHEM. SPENCER CHEM. FINALENS BEFU CHEM. OESTERREISCHICHE STICKSTOFFWERKE SINDRI FERTILIZERS MITSUBISHI CHEM. TOKAI AMM. SULPH. MITSUBISHI CHEM. UBE IND. NISSAN CHEM. SPENCER CHEM. OFFICE NATIONAL IND. DE LAZOTE MONTEDISON

LOCATION
U.S.A., Cherokee U.S.A., North Claymont U.S.A., Henderson France, La Bass Japan, Befu Austria, Linz India, Sindri Japan, Kurosaki Japan, Yekkaichi Japan, Kurosaki Japan, Ube Japan, Toyama U.S.A., Vicksburg France, Toulouse Italy, Ferrara

CAPACITY t/d Urea

45 200 100 70 100 40 70 60 200 60 100 50 30 100 200

START-UP
1962 1960 1959 1959 1959 1958 1958 1958 1958 1957 1957 1957 1957 1956 1956

53

UREA PLANTS BASED on conVentional and i.d.r. PROCESSes

COMPANY
MITSUBISHI CHEM. KIOWA HAKKO SHELL CHEM. NISSAN CHEM. MONTEDISON MONTEDISON STAATSMIJINEN HOLZVERZUCHERRUNGS MONTEDISON STOCK, SUPERFOSFAT MONTEDISON

LOCATION
Japan, Korodaki Japan, Ube U.S.A., Ventura Japan, Toyama Italy, Ferrara Italy, Novara The Netherlands, Lutterada Switzerland, Ems Italy, San Giuseppe di Cairo Sweden, Ljiungavark Italy, Novara

CAPACITY t/d Urea

60 80 100 50 100 120 2 10 30 2 6

START-UP
1956 1956 1956 1953 1953 1953 1945 1945 1939 1938 1935

54

55

OTHER FERTILIZERS, RELATED UNITS AND GAS-BASED PRODUCTS

SAIPEM HAS FURTHER REFERENCES IN DESIGNING AND BUILDING PLANTS TO PRODUCE OTHER FERTILIZERS AND ASSOCIATED PRODUCTS.

AMMonIuM NItrAtE AMMonIuM SulPhAtE GrAnulAtEd CAlcIuM AMMonIuM NItrAtE CO ProductIon DIAMMonIuM PhosPhAtE (DAP) HydrogEn ProductIon NItrIc AcId NPK PhosPhAtE GrAnulAtIon PhosPhAtE Rock GrIndIng PhosPhorIc AcId SulPhurIc AcId TrIPlE SuPEr PhosPhAtE

56

People, Skills, Equipment.

Saipem S.p.A. Via Martiri di Cefalonia, 67 - 20097 San Donato Milanese, Milan - Italy Tel. +39.02.520.1 - Fax +39.02.520.44415 saipem.com - A subsidiary of Eni S.p.A.

02.2012