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*0710019578*
CHEMISTRY
0620/22
Paper 2
May/June 2011
1 hour 15 minutes
[Turn over
2
1
For
Examiners
Use
electrons
ions
neutrons
solids
[2]
[1]
[Total: 9]
UCLES 2011
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2
temperature / C
2100
425
475
925
For
Examiners
Use
(a) (i) Use the information in the table to arrange aluminium, iron, nickel and zinc in order
of their reactivity.
least reactive
most reactive
[1]
(ii) Suggest why aluminium is extracted by electrolysis rather than by heating with
carbon.
....................................................................................................................................
.............................................................................................................................. [1]
(iii) State the name of the main ore of aluminium.
.............................................................................................................................. [1]
(b) Iron is extracted by heating iron ore with carbon in a blast furnace.
(i) Apart from iron ore and carbon (coke), state the names of two other raw materials
used in the blast furnace for the extraction of iron.
......................................................... and .........................................................
[2]
(ii) Complete this equation for the reaction of iron(III) oxide with carbon.
Fe2O3 + ............CO ............Fe + 3CO2
[2]
(iii) In the blast furnace, carbon dioxide reacts with red hot carbon to form carbon
monoxide.
CO2 + C 2CO
Which substance gets reduced during this reaction? Explain your answer.
....................................................................................................................................
.............................................................................................................................. [2]
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4
For
Examiners
Use
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3
For
Examiners
Use
other gases
(a) (i) What is the percentage of nitrogen in the air?
.............................................................................................................................. [1]
(ii) Apart from nitrogen and oxygen, state the names of two gases present in unpolluted
air.
......................................................... and .........................................................
[2]
(b) The percentage of oxygen in air can be found using the apparatus shown below.
air
copper wire
air
gas syringe
heat
Air is passed backwards and forwards over the heated copper using the syringes. The
copper reacts with oxygen in the air.
copper + oxygen copper(II) oxide
As the experiment proceeds, suggest what happens to
(i) the total volume of air in the gas syringes,
.............................................................................................................................. [1]
(ii) the mass of the wire in the tube.
.............................................................................................................................. [1]
(c) State one use of copper.
..................................................................................................................................... [1]
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6
For
Examiners
Use
copper electrode
steel spoon to
be electroplated
electrolyte
Give a description of this electroplating.
In your answer, refer to:
a suitable electrolyte that can be used;
the anode and the cathode;
changes to the spoon.
...........................................................................................................................................
...........................................................................................................................................
...........................................................................................................................................
...........................................................................................................................................
...........................................................................................................................................
..................................................................................................................................... [3]
[Total: 9]
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4
For
Examiners
Use
H2O
C2H5OH
[2]
(ii) Ethene is an unsaturated hydrocarbon.
Describe a test for an unsaturated hydrocarbon.
test .............................................................................................................................
result .................................................................................................................... [2]
(c) Ethanol can be used as a fuel.
State the names of the products formed when ethanol undergoes complete
combustion.
......................................................... and .........................................................
[2]
functional
homologous
similar
unreactive
unsaturated
[3]
[Total: 12]
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8
5
For
Examiners
Use
diamond
chlorine
= carbon atom
= chlorine atom
diatomic
giant
macromolecule
molecule
structure
diamond ............................................................................................................................
...........................................................................................................................................
...........................................................................................................................................
chlorine .............................................................................................................................
...........................................................................................................................................
..................................................................................................................................... [4]
(b) The structure of a compound containing carbon and chlorine is shown below.
Cl
Cl
Cl
Cl
C
Cl
Cl
Cl
Cl
C
Cl
Cl
Cl
Cl
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For
Examiners
Use
element
boiling point / C
density in liquid
state / g per cm3
colour
fluorine
188
1.51
yellow
chlorine
35
1.56
bromine
iodine
red-brown
+114
4.93
grey-black
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10
6
For
Examiners
Use
[1]
(c) Many centuries ago, sulfuric acid was made from iron(II) sulfate.
Sulfuric acid is a typical acid.
(i) Describe what you would observe when sulfuric acid is added to
blue litmus paper, ......................................................................................................
iron powder. ......................................................................................................... [2]
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(ii) Farmers can add a solution of dilute sulfuric acid to their fields if the soil is too
alkaline.
Explain why farmers do not want their fields to become too alkaline.
For
Examiners
Use
.............................................................................................................................. [1]
(iii) Which one of the following pH values best describes a solution which is slightly
alkaline?
Put a ring around the correct answer.
pH 1
pH 6
pH 7
pH 8
pH 14
[1]
(iv) Give the name of a compound which farmers add to the soil to make it less acidic.
.............................................................................................................................. [1]
[Total: 14]
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7
Smelling salts are sometimes used to wake up people who feel faint.
The main chemical in smelling salts is ammonium carbonate. Ammonium carbonate breaks
down slowly at room temperature to release ammonia gas.
ammonium carbonate ammonia + carbon dioxide + water
(a) A few crystals of ammonium carbonate were put on a bench at the front of a classroom.
ammonium
carbonate
C
B
A
The students in row A could smell the ammonia 10 seconds after the smelling salts
had been put on the bench. The students in row C could smell the ammonia after 40
seconds.
(i) Suggest how long it took the students in row B to smell the ammonia.
.............................................................................................................................. [1]
(ii) Explain these results using ideas about moving particles.
....................................................................................................................................
....................................................................................................................................
.............................................................................................................................. [3]
(b) Ammonium carbonate has the formula (NH4)2CO3.
Calculate the relative formula mass of ammonium carbonate.
[1]
(c) Ammonia is used to make fertilisers such as ammonium sulfate.
(i) State the names of the three chemical elements, essential for plant growth, that are
present in fertilisers.
.............................................................................................................................. [3]
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For
Examiners
Use
13
For
Examiners
Use
(ii) Which one of the following statements about ammonium sulfate is correct?
Tick one box.
When ammonium sulfate is heated with sodium hydroxide, carbon
dioxide is given off.
When ammonium sulfate is added to a solution of barium chloride,
a blue precipitate is formed.
Ammonium sulfate can be made by adding sulfuric acid to ammonia.
Farmers add ammonium sulfate to the soil to make it alkaline.
[1]
(d) Ammonium carbonate is made by heating ammonium sulfate with excess calcium
carbonate.
ammonium sulfate + calcium carbonate ammonium carbonate + calcium sulfate
When 132 g of ammonium sulfate is reacted with calcium carbonate, 96 g of ammonium
carbonate is formed.
Calculate the mass of ammonium sulfate needed to make 240 g of ammonium
carbonate.
[1]
[Total: 10]
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BLANK PAGE
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BLANK PAGE
UCLES 2011
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UCLES 2011
Magnesium
Sodium
Calcium
0620/22/M/J/11
Strontium
89
Key
72
X = atomic symbol
88
Ac
Actinium
Ra
Radium
Fr
Francium
87
Hafnium
Lanthanum
57
178
Hf
40
Zirconium
Zr
91
Titanium
139
Yttrium
22
48
Ti
La
39
89
Scandium
21
227
56
Barium
Caesium
45
Sc
226
55
137
Ba
133
Cs
38
Rubidium
37
88
Sr
85
Rb
20
Potassium
19
40
Ca
39
12
24
Mg
23
Na
Beryllium
Lithium
11
Be
II
Li
93
Ta
181
Niobium
Nb
90
58
73
52
96
Mo
184
Protactinium
Thorium
55
Tc
186
Re
144
Nd
92
60
Uranium
238
Neodymium
75
Rhenium
43
Technetium
25
Manganese
Mn
27
59
28
59
29
64
30
65
Ru
101
Iron
190
Pm
Osmium
Os
93
Np
Neptunium
61
Promethium
76
44
Ruthenium
26
56
Fe
Sm
150
Iridium
94
Pu
Plutonium
62
152
Eu
95
Am
Americium
63
Europium
78
Platinum
195
Pt
192
46
Palladium
Pd
106
Nickel
Ni
Ir
Samarium
77
45
Rhodium
Rh
103
Cobalt
Co
Gd
157
Gold
Au
197
Silver
96
64
Curium
Cm
Gadolinium
79
47
Ag
108
Copper
Cu
201
Bk
Terbium
Tb
159
Mercury
Hg
97
Berkelium
65
80
48
Cadmium
Cd
112
Zinc
Zn
11
Dy
162
Thallium
Tl
204
Indium
98
Cf
Californium
66
Es
Holmium
Ho
165
Lead
Pb
207
Tin
99
Einsteinium
67
82
50
119
Sn
115
32
Germanium
Ge
73
Silicon
In
Gallium
Dysprosium
81
49
31
70
Ga
14
28
Si
Carbon
27
Aluminium
13
12
Al
Boron
14
75
Sb
122
Arsenic
As
Bi
209
Fermium
Fm
Erbium
Er
167
Bismuth
100
68
83
51
Antimony
33
15
Phosphorus
31
Nitrogen
N
8
Se
79
Sulfur
32
Oxygen
Po
169
Md
Thulium
Tm
101
Mendelevium
69
84
Polonium
52
Tellurium
Te
128
Selenium
34
16
16
O
9
Yb
173
Astatine
At
Iodine
127
Bromine
Br
80
Chlorine
No
102
Nobelium
70
Ytterbium
85
53
35
17
Cl
35.5
Fluorine
19
Lr
Lutetium
Lu
175
Radon
Rn
Xenon
Xe
131
Krypton
Kr
84
Argon
Ar
40
Neon
103
Lawrencium
71
86
54
36
18
10
Ne
20
Helium
Hydrogen
VII
VI
He
IV
III
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
91
Pa
Th
232
Praseodymium
Cerium
59
141
Pr
140
74
Tungsten
42
Molybdenum
24
Chromium
Cr
Ce
Tantalum
41
23
Vanadium
51
Group
DATA SHEET
The Periodic Table of the Elements
16
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publisher will be pleased to make amends at the earliest possible opportunity.
University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of
Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.