CODE : RAKHI MODEL/17

VSP-RB /SR-IIT (REG)/06-08-2007 /IIT- A

CHEMISTRY
SECTION-I
Question 21 to 26 are single answer type !or ea"# "orre"t answer $ %ar&s will 'e awar(e( an( ea"# in"orre"t answer 1 %ar& will 'e (e(u"te(
Na2 S 2 O3 excess AgNO3 ( aq ) White ppt Solution Solution of Na2 S 2O3

21.

( B) boiled with water Black Solid ( A) (A) and (B) are respectively a) Ag 2 S2O3 and Ag ( S2O3 ) 2 c) Ag 2 S and Ag ( S2O3 ) 2
3 3

b) AgS2O3 and Ag ( S2O3 ) d) Ag 2 S and Ag ( S2O3 ) d) !)e(#$)*&

22. 23. 2%.

Which of the following would not exist as it is a) !"i(#$)%& b) !'(#$)(& c) !#r(#$)(&

Which of the following will not exhibit geo+etrical iso+eris+ a) !,t (en)2&2- b) !,t(gly)2& c) !,t (".3)2 #l2& d) !,t (".3) (,y) (#l) (Br)& Which of the following co+plex ions absorbs highest fre/uency visible light for d0d transition a) !#o(".3)(&3- b) !#o)(&30 c) !#o(#")(&30 d) !#o(.2$)(&3Which of the following halogens absorbs the visible light of shortest wave length a) )2 b) #l2 c) Br2 d) 12 2he volu+e strength of perhydrol is a) 33 b)133 c)13 d) 3

2*. 2(.

SECTION )II Questions 2* to $+ are %ultiple answer type !or ea"# "orre"t answer $ %ar&s will 'e awar(e( an( ea"# in"orre"t answer 1 %ar& will 'e (e(u"te( 24. Which of the following regarding the co+plex "a2!)e(#")* ("$)& is 5 are correct a) 1ts +agnetic +o+ent is 6ero b) 2he oxidation state of iron is -3 c) 1ts +agnetic +o+ent is %.7 B.8. d) 2he oxidation state of iron is -2

,-SH-T.-RO

CODE : RAKHI MODEL/17

VSP-RB /SR-IIT (REG)/06-08-2007 /IIT- A

29.

Which of the following are inner0orbital co+plex:s a) Ni ( NH 3 ) ( c) Fe ( CN ) (

2+

b) Fe ( H 2O ) ( d) Co ( NH 3 ) (

2+ 3+

27.

Which of the following state+ent(s) is 5 are correct regarding the co+plex !,t (py) (".3) ("$2)(#l) (Br) (1)& a) 1t exist in 1* geo+etrical iso+ers b) All 1* geo+etrical iso+ers are optically active c) All 1* geo+etrical iso+ers are optically inactive d) 1t does not exhibit either geo+etrical or optical iso+eris+ Which of the following does not exhibit optical iso+eris+ a) pt ( dipy ) 3
%+

33.

b) !#r(gly)3& d) CoCl% ( py ) 2

c) !#o(".3)%#l2&-

SECTION )III
Questions $1 to $6 "ontain t#ree "o%pre#ension 'ase( /uestions Ea"# write-up "ontain t#ree /uestion !or e0ery "orre"t answer 1 %ar&s will 'e awar(e( an( ea"# in"orre"t answer 2 %ar&s will 'e (e(u"te( 2RITE-34 ) I 5Q No $1-$$6 #o+pounds containing 80# bonds are called organo+etallic co+pounds of which carbonyls constitute an i+portant part. ;ynergic effect in bonding in the +etal carbonyls +a<es the+ stable species= +etal carbonyls abide by the effective ato+ic nu+ber (>A") rule. 31. Which of the following is not an organ +etallic co+pound Al ( C2 H *O ) 3 a) b) Fr ( C* H * ) 2 c) tCl3 ( C2 H 2 ) 32. 33.

d) Cr ( Co ) (
x

2he value of x in !n ( Co ) * a) 3 b) 2

is c) 1 d) 3

Which of the following is true for the synergic bonding in +etal carbonyls a) 2he #0$ bond length increases b) 2he bond order of #$ increases c) 2he #0$ bond length does not change d) "one of these

,-SH-T.-RO

CODE : RAKHI MODEL/17

VSP-RB /SR-IIT (REG)/06-08-2007 /IIT- A

2RITE-34-II 5Q No $7-$66 'alence bond theory explains the +agnetic bahaviour of coordination species ?epending upon the +agnetic behaviour one can understand whether the inner d0 orbitals or outer d0 orbitals are being used in a particular hybrid station .owever= the colours of coordination species can he explained by the crystal filed theory. 3%. Which of the following co+pounds is dia+agnetic as well as coloured a) Fe ( CN ) ( 3*.
%

b) Ni ( CN ) %

c) Co ( NH 3 ) (

3+

d) All of these

2hough ".3 is a strong filed ligand= in which of the following co+pounds= the d0 electrons are not paired 3+ 2+ a) b) c) Cr NH Ni NH ( ) ( ) 3 3 CrCl3 ( NH 3 ) 3 d) All of these ( ( 2he correct order of para+agnetic +o+ent is given by a) Cu ( NH 3 ) % < [ FeF( ] < Cr ( NH 3 ) (
3 2+ 3+ 3+

3(.

b) [ FeF( ]

< Cu ( NH 3 ) % < Cr ( NH 3 ) (
2+

2+

c) Cu ( NH 3 ) %

< Cr ( NH 3 ) ( < [ FeF( ]

2+

3+

3 3

d) Cu ( NH 3 ) % Cr ( NH 3 ) ( <

3+

< [ FeF( ]

,-SH-T.-RO

CODE : RAKHI MODEL/17

VSP-RB /SR-IIT (REG)/06-08-2007 /IIT- A

SECTION )I,
Question no $* 8 $9 are nu%eri"al type !or ea"# "orre"t answer 7 1 %ar&s will 'e awar(e( T#ere is no negati0e %ar&ing :or t#ese /uestions 34. "itric oxide ("$) react with !)e(#$)*& and for+s !)e(#$)2("$)2& with evolution of carbon +onoxide. 2he effective ato+ic nu+ber (>A") of )e in !)e(#$)2("$)2& is 0000000000000 39. A co+plex co+pound of chro+iu+ (111) with for+ula CrCl3 .( H 2 3 looses 13.*@ of its original weight on treating with concentrated .2;$%. 2he nu+ber of water +olecules present outside the co0ordination sphere of co+plex are 00000000000000000000 (8.W. of co+plex A 2((.*)

SECTION ),
Questions $; 8 7+are %at"# t#e :ollowing type !or ea"# "orre"t answer 6 %ar&s will 'e awar(e( T#ere is no negati0e %ar&ing :or t#ese /uestions T#ere "oul( 'e single or %ultiple answers 37. CO<3MN-1 a) ;$3 b) "$30 c) #l$%0 d) Ce$3 CO<3MN -1 a) !#u(".)3&2b) !"i(#")%&20 c) !"i(#$)%& d) !"i#l%&20 CO<3MN-II p) planar /) sp2 hybridisation r) pB0dB bonding s) sp3 hybridisation CO<3MN-II p) s/uare planar /) para+agnetic r) tetrahedral s) dia+agnetic

%3.

,-SH-T.-RO