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Zalazar et. al.

(2005) the illumination of TiO2 under ultraviolet light changes the energy state of electrons from the valence band to the conduction band to give electron-hole pairs. The hole sat the TiO2 valence band can oxidize water or hydrolyze to produce hydroxyl groups. The hydroxyl radical is a powerful oxidizing agent that attacks organic compounds forming intermediates ( !. These intermediates react with hydroxyl radicals to produce the final product ("!.#ydroxyl radicals can also be consumed by inactive species. S. Bagwasi et. al. (2013) "hotocatalytic technology has been increasingly demonstrating prominent superiority for the decomposition of organic compounds and pollutants coming from many industries. $mong various semiconductor photocatalysts% TiO 2 has been proven to be the most important one due to series of merits such as good photocatalytic activity% good chemical and thermal stability for long term% nontoxicity% and low cost. Thus% it has been widely applied in environmental% optical% and electronic fields.

B. Palanisamy et. al. (2013! &ecently% many studies for improving TiO 2 photocatalytic efficiency have become hot topics' one approach is to dope some kind of transition metals into TiO2% forming doped photocatalyst% which would modify both physical and optical properties of TiO2 but the results are still unsatisfying. $nother one is to couple other oxides in order to achieve higher photocatalytic efficiency% such as (O )% *nO% +iO2% +nO2% ,e2O)% and -oO)% and these studies on this aspect are becoming more and more extensively.

REFERANCE
.ee% /% +ung% 0(% "ark% 1(2 -ultiple e3uilibria of phenothiazine dyes in a3ueous cyclodextrin solutions. 1. "hys. /hem. 4. (5666! 57)% 86). .achheb% #% "uzenat% 9% #ouas% $% :sibi% -% 9laloui% 9% ;uillard% /% #errmann% 1--2 "hotocatalytic degradation of various types of dyes ($lizarin +% /rocein Orange ;% -ethyl &ed%

/ongo &ed% -ethylene 4lue! in water by <=-irradiated titania. $pp. /atal. 42 9nviron. (2772! )6% >?. *alazar% /+% -artin% /$% /assano% $92 "hotocatalytic intrinsic reaction kinetics. 2 9ffects of oxygen concentration on the kinetics of the photocatalytic degradation of dichloroacetic acid. /hem. 9ng. +ci. (277?! @7% A)55. +. 4agwasi% 4. *. Tian% 1. .. *hang% and -. Basir% C+ynthesis% characterization and application of bismuth and boron /o-doped TiO22 a visible light active photocatalyst%D /hemical 9ngineering 1ournal% vol. 25>% (275)! pp. 578E558. 4. "alanisamy% /. -. 4abu% 4. +undaravel% +. $nandan% and =. -urugesan% C+ol-gel synthesis of mesoporous mixed ,e2O)F TiO2 photocatalyst2 application for degradation of A chlorophenol%D1ournal of #azardous -aterials% vol. 2?2% (275)! pp. 2))E2A2.

;. G. 0ang% *. ,. 0an% and T. /. Hiao% C"reparation and characterization of +nO2F*nOFTiO2 composite semiconductor with enhanced photocatalytic activity%D $pplied +urface +cience% vol. 2?8% (2752! pp. 8>7AE8>52. /. 1. &en%(. Iiu% and 0. I. /hen% C"hysicochemical properties and photocatalytic activity of the TiO2F+iO2 prepared by precipitation method%D +eparation and "urification Technology% vol. 57>% (275)! pp. 2@AE2>2. &. "eng% +. 4anerJee% ;. +ereda% and &. T. :oodali% CTiO2-+iO2 mixed oxides2 organic ligand templated controlled deposition of titania and their photocatalytic activities for hydrogen production%D nternational 1ournal of #ydrogen 9nergy% vol. )>% (2752! pp.5>776E5>758.

PHO OCA A!" #C S $%"


The photocatalytic activity of pure TiO2 and $gFTiO2 nanopowder was measured by photocatalytic degradation of methyl orange. -ethyl orange a3ueous solution (5 gF.%5777 ppm! and nanopowder (7.)g% 7.?g% 7.>g in ?7 ppm! was magnetically stirred in a dark condition for )7 min to reach the e3uilibrium of methyl orange with the nanopowder. $fter then% the above sample solution was expose to ultraviolet light (K L ?7> nm!. ? m . dye solution obtained at a specific time intervals was centrifuged to separate the residual nanopowder catalyst. $nd the absorbance intensity of residual methyl orange was measured at ?7> nm.

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