Exam

Name___________________________________

MULTIPLECHOICE.Choosetheonealternativethatbestcompletesthestatementoranswersthequestion.
1) Calculatethemass(inng)of2.33x10 20atomsofoxygen.
A) 4.69107 ng

1)

B) 2.25103 ng
C) 6.19106 ng
D) 1.62107 ng
E) 3.73106 ng
2) Amixtureof10.0gofNeand10.0gArhaveatotalpressureof1.6atm.Whatisthepartial
pressureofNe?
A) 1.3atm
B) 0.54atm
C) 1.1atm
D) 0.40atm
E) 0.80atm

2)

3) Howmanyatomsofcarbonarecontainedin47.6gofAl 2 (CO3 )3 ?ThemolarmassofAl 2 (CO3 )3is

3)

233.99g/mol.
A) 3.681023Catoms
B) 1.101024Catoms
C) 2.871025Catoms
D) 1.231023Catoms
E) 2.961024Catoms
4) DeterminetheempiricalformulaforacompoundthatcontainsC,HandO.Itcontains52.14%C
and34.73%Obymass.
A) C2 H6 O
B) CH3 O
C) C4 H13O2
D) CHO
E) CH4 O3

4)

5) Thetemperaturerisesfrom25.00Cto29.00Cinabombcalorimeterwhen3.50gofsucrose
undergoescombustioninabombcalorimeter.CalculateE rxnforthecombustionofsucrosein

5)

kJ/molsucrose.Theheatcapacityofthecalorimeteris4.90kJ/C.Themolarmassofsugaris
342.3g/mol.
A) -1.92x103 kJ/mole
B) 1.92x103 kJ/mole
C) -1.23x103 kJ/mole

D) 2.35x104 kJ/mole

6) Whichofthefollowingquantumnumbersdescribestheshapeofanorbital?
A) magneticquantumnumber
B) principalquantumnumber
C) Schrdingerquantumnumber
D) spinquantumnumber
E) angularmomentumquantumnumber

6)

7) Thetitrationof25.0mLofanunknownconcentrationH 2 SO4 solutionrequires83.6mLof0.12M

LiOHsolution.WhatistheconcentrationoftheH 2 SO4 solution(inM)?

7)

A) 0.40M

B) 0.10M

C) 0.36M

D) 0.25M

E) 0.20M

8) Placethefollowingtypesofelectromagneticradiationinorderofincreasingfrequency.
visiblelight

microwaves

8)

X-rays

A) microwaves<visiblelight<X-rays
B) visiblelight<X-rays<microwaves
C) microwaves<X-rays<visiblelight
D) X-rays<microwaves<visiblelight
E) X-rays<visiblelight<microwaves
9) Whichofthefollowingsubstances(withspecificheatcapacityprovided)wouldshowthegreatest
temperaturechangeuponabsorbing100.0Jofheat?
A) 10.0gFe,CFe =0.449J/gC

9)

B) 10.0gethanol,C ethanol=2.42J/gC
C) 10.0gH 2 O,CH2 O=4.18J/gC
D) 10.0gAu,C Au=0.128J/gC
E) 10.0gAg,C Ag=0.235J/gC
10) Calculatethetemperature,inK,of2.20molesofgasoccupying3.50Lat3.30atm.
A) 337K
B) 5.25K
C) 64.0K
D) 28.0K

10)

11) Accordingtothefollowingreaction,whatmassofPbCl 2 canformfrom235mLof0.110MKCl

11)

solution?AssumethatthereisexcessPb(NO3 )2 .
2KCl(aq)+Pb(NO3 )2 (aq)PbCl2 (s)+2KNO 3 (aq)
A) 3.59g

B) 7.19g

C) 1.30g

D) 5.94g

E) 1.80g

12) Determinetheenergychangeassociatedwiththetransitionfromn=2ton=5inthehydrogenatom.
A) +3.7610-19J

12)

B) +6.5410-19J
C) -1.5310-19J
D) +4.5810-19J
E) -2.1810-19J
13) Calculatetheenergyofthegreenlightemitted,perphoton,byamercurylampwithafrequencyof
5.491014Hz.
A) 2.7510-19J
B) 4.6810-19J
C) 3.6410-19J
D) 1.8310-19J
E) 5.4610-19J

13)

14) DeterminethevolumeofO 2 (atSTP)formedwhen50.0gofKClO 3 decomposesaccordingtothe

14)

followingreaction.ThemolarmassforKClO 3is122.55g/mol.
2KClO 3 (s)2KCl(s)+3O2 (g)
A) 12.3L

B) 14.6L

C) 9.14L

D) 13.7L

E) 8.22L

15) Usingthefollowingequationforthecombustionofoctane,calculatetheamountofmolesof
oxygenthatreactswith100.0gofoctane.Themolarmassofoctaneis114.33g/mole.Themolar
massofcarbondioxideis44.0095g/mole.

15)

Hrxn=-11018kJ

2C8 H18+25O2 16CO2 +18H 2 O

A) 10.93moles
B) 18.18moles
C) 14.00moles
D) 8.000moles
E) 6.997moles

16) ChoosetheorbitaldiagramthatrepresentsthegroundstateofN.
A)

B)

C)

D)

E)

16)

17) Givethesetoffourquantumnumbersthatcouldrepresentthelastelectronadded(usingthe
Aufbauprinciple)totheClatom.
1
A) n=3,l=1,ml=1,ms=+
2
B) n=3,l=0,ml=1,ms=-

17)

1
2

1
C) n=2,l=1,ml=1,ms=-
2
D) n=3,l=2,ml=1,ms=+

1
2

E) n=3,l=2,ml=1,ms=-

1
2

18) Thecompleteelectronconfigurationofargon,element18,is__________.
A) 1s6 2s6 2p2 3s4

18)

B) 1s4 2s4 2p10

C) 1s2 2s2 2p103s2 3p2
D) 1s2 2s2 2p6 3s2 3p6
E) 1s4 2s4 2p6 3s4
19) Howmanyofthefollowingelementshave1unpairedelectroninthegroundstate?
B

Al

A) 2

Cl
B) 4

C) 3

20) Placethefollowinginorderofdecreasingradius.
Te2

19)

D) 1
20)

O2

A) F>Te2 >O2
B) Te2 >F>O2
C) F>O2 >Te2
D) O2 >F>Te2
E) Te2 >O2 >F
21) PlacethefollowinginorderofincreasingIE1 .
K

Ca

21)

Rb

A) Rb<K<Ca
B) Ca<K<Rb
C) Ca<Rb<K
D) K<Ca<Rb
E) Rb<Ca<K

22) Howmanyofthefollowingspeciesareparamagnetic?
Sc3

Mg 2

Br

A) 1

B) 0

22)

Se
C) 2

D) 4

E) 3

23) ChoosethegroundstateelectronconfigurationforZn 2 .
A) [Ar]4s2 3d 8

23)

B) [Ar]3d8
C) [Ar]
D) [Ar]3d10
E) [Ar]4s2 3d 6
24) Whichreactionbelowrepresentsthesecondelectronaffinity ofS?
A) S(g)S(g)+e
B) S(g)+eS(g)
C) S(g)+eS2 (g)

24)

D) S(g)S(g)+e
E) S2 (g)S(g)+e
25) WhichofthefollowingrepresenttheLewisstructureforN?
A)

B)

C)

25)
D)

E)

26) UseLewistheorytodeterminethechemicalformulaforthecompoundformedbetweenAlandO.
A) Al3 O2
B) AlO
C) AlO2
D) Al2 O
E) Al2 O3

26)

27) Placethefollowinginorderofdecreasing magnitudeoflatticeenergy.

27)

KF

MgS

RbI

A) RbI>KF>MgS
B) RbI>MgS>KF
C) MgS>KF>RbI
D) KF>RbI>MgS
E) MgS>RbI>KF
28) UsethedatagivenbelowtoconstructaBorn-HabercycletodeterminetheelectronaffinityofBr.

K(s)K(g)
K(g)K(g)+e
Br2 (l)2Br(g)
1
K(s)+ Br2 (g)KBr(s)
2

H(kJ)
89
419
193
-394

KBr(s)K(g)+Br(g)
A) -325kJ

B) +246kJ

674
C) -885kJ

D) +367kJ

E) -464kJ

28)

29) Placethefollowingelementsinorderofdecreasing electronegativity.

S
Cl
A) S>Cl>Se
B) Cl>S>Se
C) Se>Cl>S
D) Se>S>Cl
E) Cl>Se>S

29)

Se

30) Choosethebondbelowthatismostpolar.
A) F-F
B) C-C
C) C-N

30)
D) C-O

E) C-F

31) ChoosethebestLewisstructureforCH 2 Cl2 .

31)

A)

B)

C)

D)
E)

32) DrawthebestLewisstructureforCH 3 -1 .WhatistheformalchargeontheC?

B) -1

A) 1

C) 0

32)
D) 2

33) Howmanyofthefollowingelementscanformcompoundswithanexpandedoctet?
I
A) 2

Cl
B) 0

33)

Xe
C) 4

D) 3

E) 1

34) Whichcompoundhasthehighestcarbon-carbonbondstrength?
A) CH2 CH2
B) HCCH
C) CH3 CH3

D) allbondstrengthsarethesame

34)

35) Whichofthefollowingprocessesareexothermic?
A) NaF(s)Na(g)+F(g)
B) Cl2 (g)2Cl(g)

35)

C) Li(s)Li(g)
D) Br(g)+eBr(g)
E) Noneoftheaboveareexothermic.
36) UsethebondenergiesprovidedtoestimateH rxn forthereactionbelow.

36)

Hrxn=?

2Br2 (l)+C2 H2 (g)C2 H2 Br4 (l)

BondEnergy(kJ/mol)
193
837
347
276
414

Bond
Br-Br
CC
C-C
C-Br
C-H

A) +407kJ

B) -324kJ

C) -648kJ

D) +573kJ

E) -228kJ

37) Determinetheelectrongeometry(eg)andmoleculargeometry(mg)ofXeF 4 .

37)

A) eg=octahedral,mg=squareplanar
B) eg=trigonalbipyramidal,mg=tetrahedral
C) eg=linear,eg=linear
D) eg=tetrahedral,mg=tetrahedral
E) eg=tetrahedral,mg=bent
38) Placethefollowinginorderofincreasing X-A-Xbondangle,whereArepresentsthecentralatom
andXrepresentstheouteratomsineachmolecule.
HCN

H2 O

38)

H3 O

A) HCN<H3 O<H2 O
B) H3 O<H2 O<HCN
C) H2 O<HCN<H3 O
D) H2 O<H3 O<HCN
E) H2 O<H3 O<HCN
39) Choosethecompoundbelowthatcontainsatleastonepolarcovalentbond,butisnonpolar.
A) ICl3

39)

B) CF 4
C) HCN
D) SeBr4
E) BothBandCarenonpolarandcontainapolarcovalentbond.
40) DrawtheLewisstructureforBrF5 .WhatisthehybridizationontheBratom?
A) sp2

B) sp3 d2

C) sp3

D) sp3 d

40)
E) sp

41) Considerthemoleculebelow.Determinethehybridizationateachofthe2labeledcarbons.

41)

A) C1=sp,C2=sp 2
B) C1=sp 2 ,C2=sp 3 d
C) C1=sp 3 ,C2=sp 3 d
D) C1=sp 3 d,C2=sp 3 d2
E) C1=sp 2 ,C2=sp 3
42) Howmanyofthefollowingmoleculeshavesp 3 dhybridizationonthecentralatom?
SiCl 4
A) 1

BrF5

AsF5
B) 4

42)

BrF3
C) 0

D) 3

E) 2

43) Howmanyofthefollowingmoleculescontainatleastonepibond?
C2 H6
A) 1

Cl2 CO
B) 0

C2 Cl4

43)

SeS3
C) 3

D) 4

E) 2

44) Usethemolecularorbitaldiagramshowntodeterminewhichofthefollowingis moststable.

A) B2 2

B) C2 2

C) C2 2

D) N2 2

44)

E) B2

45) Drawthemolecularorbitaldiagramshowntodeterminewhichofthefollowingisparamagnetic.
A) O2 2

45)

B) Ne2 2
C) F2 2
D) O2 2
E) Noneoftheaboveareparamagnetic.
46) Describewhatchangesoccurduringbetadecay.
A) Themassnumberisunchangedandtheatomicnumberincreases.
B) Themassnumberandatomicnumberdecreases.
C) Themassnumberisunchangedandtheatomicnumberdecreases.
D) Themassnumberandatomicnumberdonotchange.
E) Themassnumberandatomicnumberincreases.

46)

47) Determinetheidentityofthedaughternuclidefromthealphadecayof
A)

206
Pb
82

B)

212
Ra
88

C)

208
Hg
80

D)

210
Po.
84

214
Rn
86

48) Determinetheidentityofthedaughternuclidefromthepositronemissionof
A)

22
Na
11

B)

14
N
7

C)

18
O
8

D)

18
Ne
10

49) Whichofthefollowingnuclidesaremostlikelytodecayviabetadecay?
A) I-131
B) Pb-206
C) F-18
D) Zr-90
50) Thefollowingreactionrepresentswhatnuclearprocess?
235
1
139
94
1
U+ n
Ba+ Kr+3 n
92
0
56
36
0
A) nuclearfusion
B) nuclearfission
C) alphadecay
D) betaemission
E) electroncapture

10

47)
E)

211
At
85

18
F.
9

48)
E)

19
F
9
49)

E) Ar-40
50)