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Review of IC Fabrication Technology

MICROELECTRONIC ENGINEERING ROCHESTER INSTITUTE OF TECHNOLOGY

A Review of IC Fabrication Technology


Dr. Lynn Fuller
Webpage: http://people.rit.edu/lffeee Microelectronic Engineering Rochester Institute of Technology 82 Lomb Memorial Drive Rochester, NY 14623-5604 Tel (585) 475-2035 Email: Lynn.Fuller@rit.edu Department webpage: http://www.microe.rit.edu

Rochester Institute of Technology Microelectronic Engineering

1-7-2013 Review.ppt
Page 1

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

ADOBE PRESENTER This PowerPoint module has been published using Adobe Presenter. Please click on the Notes tab in the left panel to read the instructors comments for each slide. Manually advance the slide by clicking on the play arrow or pressing the page down key.

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 2

Review of IC Fabrication Technology

OUTLINE Constants Periodic Table Material Properties Oxide Growth Diffusion Resistivity, Sheet Resistance, Resistance Mobility pn Junction MOSFET Vt Ion Implantation Conclusion

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 3

Review of IC Fabrication Technology

CONSTANTS
Electronic charge Speed of light in vacuum Permittivity of vacuum Free electron Mass Planck constant Boltzmann constant Avogadros number Thermal voltage q c o mo h k Ao kT/q 1.602 E -19 Coulomb 2.998E8 m/s 8.854 E -14 F/cm 9.11E-31 Kg 6.625E-34 J s 1.38 E-23 J /K = 8.625E-5 eV/K 6.022E23 molecules/gm- mole @ 300 K = 0.02586

PLAY

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 4

Review of IC Fabrication Technology


1
1.0079

H
0.0899 Hydrogen

PERIODIC TABLE OF THE ELEMENTS


4
9.01218

4.0026

He
0.1787 Helium 14.0067 8 15.9994 9 18.9984

6.914

Li
0.53 Lithium

Be
1.85 Beryllium 24.305

Atomic Number Density g/cm3


14
20.086

Atomic Weight Symbol Name


27 58.9332 28 29 30

10.81

12.011

10

20.179

B
2.34 Boron

C
2.62 Carbon

N
1.251 Nitrogen

O
1.429 Oxygen

F
1.696 Fluorine

Ne
0.901 Neon

1122.9898 12

Si
2.33 Silicon

13

26.9815

14

20.08615 30.97376 16

32.06 17 35.453 18 39.948

Na
0.97 Sodium

Mg
1.74 Magnesium 47.90

Al
2.70 Aluminum 63.546 65.238

Si
2.33 Silicon

P
1.82 Phosphorous

S
2.07 Sulfur

Cl
3.17 Clorine

Ar
1.784 Argon

19 39.0983 20 40.08 21 44.9559 22

K
0.86 Potassium

Ca
1.55 Calcium

Sc
3.0 Scandium

23 50.941 24

51.996

25

54.938

26

55.847

58.70

31

69.72

32

72.59

33 74.9216 34

78.96 35 79.904 36 83.80

Ti
4.50 Titanium

7.43 7.19 5.8 Vanadium Chromium Manganese

Cr

Mn
43
98

Fe
7.86 Iron

Co
8.90 Selenium

Ni
8.90 Nickel 106.4

Cu
8.96 Copper

Zn
7.14 Zinc 112.41

Ga
5.98 Gallium

Ge
5.32 Germanium

As
5.72 Arsenic

Se
4.80 Selenium

Br
3.12 Bromine

Kr
3.74 Krypton

37

85.468 38 87.62

39

88.906 40 91.22

41

92.906 42 95.94

44

101.07

45 102.9055 46

47

107.868 48

49

114.82

50

118.69 51 121.75 26 55.847 26 127.60 54 131.30

Rb
55

Sr Ba
3.5 Barium

Y
4.5 Yttrium

Zr
6.49 Zirconium

Nb Ta
16.6 Tantalum

Mo W
19.3 Tungstem

Tc Re
21.0 Rhenium

1.53 2.8 Rubidium Strontium

8.55 10.2 11.5 Niobium Molybdenum Technetium

Ru
12.2 Rhodium

Rh
12.4 Rhodium

Pd
12.0 Palladium

Ag
10.5 Silver

Cd
8.65 Cadmium

In
7.31 Indium

Sn
7.30 Tin

Sb
6.68 Antimony

Te
6.24 Tellurium

Fe
7.86 Tellurium

Xe
5.89 Xenon

132.9056 137.3357 138.906 58 178.49 59 180.95 60 183.85 61 186.207

76

190.2

77

192.22

78

195.09 79 196.9665

80

200.59

Cs
1.87 Cesium

La
6.7 Lanthanum

Hf
13.1 Hafnium

Os
22.4 Osmium

Ir
27.16 Iridium

Pt
21.4 IPlatinum

Au
19.3 Gold

Hg
13.53 Mercury

81

204.37

82

207.2

83

206.980 84 209

85

210

86

222

Tl
11.85 Thallium

Pb
11.4 Lead

Bi
9.8 Bismuth

Po
9.4 Polonium

At
??? Astatine

Rn
9.91 Radon

87

223

88

226.02 89 227.02

104 261 105 262 106 263

Fr
??? Francium

Ra
5 Radium

Ac

10.07 ???? Unnilpentium ???? ActiniumUnnilquadium Unnilhexium

Unq Unp Ce Th

Unh Pr Pa

PLAY
144.24

58 140.12 59 140.91 60

61 145

62 150.4 63 151.96 64 157.25

65 158.92 66

162.5

67 164.93 68 167.26 69 169.93 70

173.04

71

174.97

Nd U

Pm
93 237

Sm
94
237

Eu
95 243

6.78 6.77 7.00 6.475 7.54 Cerium Praseoymium NeodymiumPromethium Samarium

5.26 7.89 Europium Gadolinium

Gd

Tb
8.27 Terbium

Dy
8.54 Dysprosium

Ho
8.90 Holmium

Er
9.06 Erbium

Tm
9.33 Thulium 258

Yb
6.98 Ytterbium

Lu
9.84 Lutetium

90 232.0 91 231 92 238.02

96

247

97 247

98

251

99 252

100 257 101

102

259

103

260

Np

Pu Am

11.7 15.4 18.90 20.4 19.8 13.6 Rochester of Technology Thorium Institute Protactinium Uranium Neptunium Plutonium Americium

Cm
13.511 Curium

Bk
???? Berkelium

Cf
???? Californium

Es
???? Einsteinium

Fm

Md

No
???? Nobelium

Lr
???? Lawrencium

Microelectronic Engineering

???? ???? Fermiumr Mendelevium

January 7, 2013 Dr. Lynn Fuller, Professor

Page 5

Review of IC Fabrication Technology

MATERIAL PROPERTIES
Symbol Atoms per unit cell Atomic Number Atomic weight Lattice constant Atomic density Density Energy Gap 300K Relative permittivity Index of refraction M elting point Specific heat Thermal diffusivity Coefficient expansion Intrinsic carrier conc Electron M obility Hole M obility Density of States conduction Density of States valance Breakdown Electric Field Effective mass electron Effective mass hole Electron affinity Z MW ao No d Eg r n Tm Cp K Dth ni n p Nc Nv E mn*/mo mp*/mo qX Units g/g-mole nm cm-3 g cm-3 eV Si 8 14 28.09 0.54307 5.00E22 2.328 1.124 11.7 3.44 1412 0.70 0.87 2.5E-6 1.45E10 1417 471 2.8E19 1.04E19 3E5 1.08 0.81 4.05 Ge 8 32 72.59 0.56575 4.42E22 5.323 0.67 16.0 3.97 937 0.32 0.36 5.7E-6 2.4E13 3900 1900 1.04E19 6.0E18 8E4 0.55 0.3 4.00 GaAs 8 31/33 144.64 0.56532 2.21E22 5.316 1.42 13.1 3.3 1237 0.35 0.44 5.9E-6 9.0E6 8800 400 4.7E17 7.0E18 3.5E5 0.068 0.5 4.07 GaP 8 31/15 100.70 0.54505 2.47E22 4.13 2.24 10.2 3.3 1467 0.004 5.3E-6 300 100 SiO2 14/8 60.08 2.20E22 2.19 8~9 3.9 1.46 1700 1.4 0.32 5E-6 20 10E-8 6~9E6 0.5 0.5 4.3 1.0 Si3N4 14/7 140.28 0.775 1.48E22 3.44 4.7 7.5 2.0 0.17 2.8E-6

C J (gK)-1 w(cmK)-1 K-1 cm-3 cm2/Vs cm2/Vs cm-3 cm-3 V/cm eV

Rochester Institute of Technology Microelectronic Engineering

From Muller and Kamins


Page 6

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

OXIDE GROWTH

Oxide Thickness Xox

0.46 Xox

Original Silicon Surface Silicon Consumed

PLAY
Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 7

Review of IC Fabrication Technology

WET OXIDE GROWTH CHART


10

1 Xox ,(um) 10-1

10-2 1
Rochester Institute of Technology Microelectronic Engineering

10

t, Time, (min)

100

PLAY
Page 8

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

DRY OXIDE GROWTH CHART


10

1 xox ,(um) 10-1

10-2 10

100 t, Time, (min)


Rochester Institute of Technology Microelectronic Engineering

1,000

PLAY
Page 9

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

OXIDE GROWTH CALCULATOR

OXIDE.XLS

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 10

Review of IC Fabrication Technology

EXAMPLES 1. Estimate the oxide thickness resulting from 50 min. soak at 1100 C in wet oxygen.

2. If 1000 of oxide exists to start with, what is resulting oxide thickness after an additional 50 min. soak at 1100 C in dry oxygen.

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 11

Review of IC Fabrication Technology

OXIDE THICKNESS COLOR CHART


Thick ness 500 700 1000 1200 1500 1700 2000 2200 2500 2700 3000 3100 3200 3400 3500 3600 3700 3900 4100 4200 4400 4600 4700 Color Tan Brown Dark Violet - Red Violet Royal Blue Blue Light Blue - Metallic Blue Metallic - very light Yellow Green LIght Gold or Yellow - Slightly Metallic Gold with slight Yellow Orange Orange - Melon Red Violet Blue - Violet Blue Blue Blue Blue - Blue Green Light Green Green - Yellow Green Yellow Green Yellow Light Orange Carnation Pink Violet Red Red Violet Violet Blue Violet Thickness 4900 5000 5200 5400 5600 5700 5800 6000 6300 6800 7200 7700 8000 8200 8500 8600 8700 8900 9200 9500 9700 9900 10000 Color Blue Blue Blue Green Green Yellow Green GreenYellow

Blue

Yel low -"Yel lowish "(at times app ears to b e Lt gray o r matelli c)

Light Orange or Yellow - Pink Carnation Pink Violet Red "Bluish"(appears violet red, Blue Green, look s gray ish) Blue Blue Blue Green - Green "Yellowish" Orange Salmon Dull, LIght Red Violet Violet Blue Violet Blue Blue Blue Blue Green Dull Yellow Green Yellow - "Yellowish" Orange Carnation Pink

Nitride Thickness = (Oxide Thickness)(Oxide Index/Nitride Index) Eg. Yellow Nitride Thickness = (2000)(1.46/2.00) = 1460 Rochester Institute of Technology
Microelectronic Engineering

PLAY
Page 12

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

DIFFUSION FROM A CONSTANT SOURCE PLAY STOP N(x,t) = No erfc (x/2 Dt ) N(x,t) Solid Solubility Limit, No Wafer Background Concentration, NBC Xj
Rochester Institute of Technology Microelectronic Engineering

p-type

n-type x into wafer

January 7, 2013 Dr. Lynn Fuller, Professor

Page 13

Review of IC Fabrication Technology

ERFC FUNCTION
Concentration/Surface Concentration = N/No
10-0 10-1 10-2 10-3 10-4 10-5 10-6 10-7 10-8 10-9 10-10 10-11 0.0 1.0 2.0 3.0 4.0

= x / 4Dt

Rochester Institute of Technology Microelectronic Engineering

PLAY
Page 14

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

DIFFUSION CONSTANTS AND SOLID SOLUBILITY

DIFFUSION CONSTANTS
BORON PHOSPHOROUS PHOSPHOROUS BORON PHOSPHOROUS

TEMP 900 C 950 1000 1050 1100 1150 1200 1250

DRIVE-IN 1.07E-15 cm2/s 4.32E-15 1.57E-14 5.15E-14 1.55E-13 4.34E-13 1.13E-12 2.76E-12

PRE 2.09e-14 cm2/s 6.11E-14 1.65E-13 4.11E-13 9.61E-13 2.12E-12 4.42E-12 8.78E-12

SOLID SOLUBILITY NOB 7.49E-16 cm2/s 4.75E20 cm-3 3.29E-15 4.65E20 1.28E-14 4.825E20 4.52E-14 5.000E20 1.46E-13 5.175E20 4.31E-13 5.350E20 1.19E-12 5.525E20 3.65E-12 5.700E20

DRIVE-IN

SOLID SOLUBILITY NOP 6.75E20 cm-3 7.97E20 9.200E20 1.043E21 1.165E21 1.288E21 1.410E21 1.533E21

PLAY
Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 15

Review of IC Fabrication Technology

TEMPERATURE DEPENDENCE OF DIFFUSION CONSTANTS Temperature Dependence:


D = D0 Exp (-EA/kT ) cm2/sec Boron D0 = 0.76 EA = 3.46 k = 8.625E-5

PLAY
eV/K T in Kelvins

Phosphorous D0 = 3.85 EA = 3.66

Temperature Dependence of the Solid Solubility of Boron and Phosphorous in Silicon


NOB = 3.5E17T + 1.325E20 cm-3 NOP = 2.45E18T - 1.53E21 cm-3
Rochester Institute of Technology Microelectronic Engineering

T in Celsius T in Celsius

January 7, 2013 Dr. Lynn Fuller, Professor

Page 16

Review of IC Fabrication Technology

DIFFUSION FROM A LIMITED SOURCE N(x,t) = QA(tp) Exp (- x2/4Dt) Dt for erfc predeposit QA (tp) = QA(tp)/Area = 2 No PLAY for ion implant predeposit QA(tp) = Dose
Rochester Institute of Technology Microelectronic Engineering

PLAY (Dptp) / = Dose

Where D is the diffusion constant at the drive in temperature and t is the drive in diffusion time, Dp is the diffusion constant at the predeposit temperature and tp is the predeposit time
Page 17

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

DIFFUSION MASKING CALCULATOR Select Boron or Phosphorous Enter Temperature and Time

Rochester Institute of Technology Microelectronic Engineering

From: Hamilton and Howard


Page 18

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

DIFFUSION MASKING Phosphorous Masking Boron Masking

From: Hamilton and Howard


Rochester Institute of Technology Microelectronic Engineering January 7, 2013 Dr. Lynn Fuller, Professor

Page 19

Review of IC Fabrication Technology

DIFFUSION AND DRIVE IN CALCULATIONS

DIFFUSION.XLS

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 20

Review of IC Fabrication Technology

DIFFUSION FROM A LIMITED SOURCE


GIVEN Starting Wa fer Resistivity Starting Wa fer Type VALUE Rho = n-type = 1 p-type = 1 UNITS 10 ohm-cm 1 1 or 0 0 1 or 0

Pre Deposition Ion Implant Dose Drive-in Temperature Drive-in Time CALCULATE Diffusion Constant at Temperature of Drive-in CALCULATION OF DIFFUSION CONSTANTS Boron Phos phorous CALCULATIONS Substra te Doping = 1 / (q max Rho) RES ULTS Pre deposition Dose xj afte r drive-in = ((4 Dd td/QA) ln (Ns ub ( Ddtd)^0.5))^0.5 average doping Nave = Dos e/xj mobility () at Doping e qual to Nave Sheet Resistance = 1/(q ((Nave))Dos e) Surfa ce Conce ntration = Dose/ (pDt)^0.5 D0 (cm2/s) EA (eV) 0.76 3.46 3.85 3.66

4.00E+15 ions/cm2 1000 C 360 min VALUE UNITS 1.43E-14 cm/se c

IonImplt.xls
VALUE UNITS 4.42E+14 cm-3 VALUE UNITS 4.00E+15 atoms/cm2 1.25 m 3.21E+19 atoms/cm3 57 cm2/V-s 27.6 ohms 1.28E+20 cm-3

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 21

Review of IC Fabrication Technology

EXAMPLE 1. A predeposit from a p-type spin-on dopant into a 1E15 cm-3 wafer is done at 1100C for 10 min. Calculate the resulting junction depth and dose.

2. The spin-on dopant is removed and the Boron is driven in for 2 hours at 1100 C. What is the new junction depth?

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 22

Review of IC Fabrication Technology

RESISTANCE, RESISTIVITY, SHEET RESISTANCE


Resistance = R = L/Area = s L/w Resistivity = = 1/( q nn + q pp) ohms

PLAY I

ohm-cm

Sheet Resistance = s = 1/ ( q (N) N(x) dx) ~ 1/( q Dose) ohms/square

PLAY
L

s = / t
Area

q = 1.6E-19 coul

slope = 1/R

w t

V R
Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 23

Review of IC Fabrication Technology

CALCULATION OF CARRIER CONCENTRATIONS


B h o r ni Nc/T^3/2 Nv/T^3/2 1.11E+03 6.63E-34 Js ec 8.85E-14 F/cm 11.7 1.45E+10 cm-3 5.43E+15 2.02E+15 Nd = Ed= Na = Ea= Temp= 3.00E+16 cm-3 0.049 eV below Ec 8.00E+15 cm-3 0.045 eV above Ev 300 K Donor Concentration Acceptor Concentration

Donor and Acceptor Levels (eV above or below Ev or Ec) Boron 0.044 Phos phorous 0.045 Ars enic 0.049 CALCULATIONS: (this program makes a guess at the value of the fermi level and t rys the charge balance) KT/q Eg=Ego-(aT^2/(T+B)) Nc Nv Fermi Level, Ef free electrons , n = Nc exp(-q(Ec-Ef)KT) Ionized donors , Nd+ = Nd*(1+2*exp(q(Ef-Ed)/KT))^(-1) holes , p = Nv exp(-q(Ef-Ev)KT) Ionized accept ors , Na- = Na*(1+2*exp(q(Ea-Ef)/KT))^(-1) Charge Balance = p + Nd+ - n - NaRochester Institute of Technology Microelectronic Engineering

carrier_conc.xls

to minimize 0.026 Volts 1.115 eV 2.82E+19 cm-3 1.34E+01 cm-3 0.9295 eV above Ev 2.17E+16 cm-3 2.97E+16 cm-3 3.43E-15 cm-3 8.00E+15 cm-3 3.22E+12 cm-3

Click on Button to do Calculation Button Button

January 7, 2013 Dr. Lynn Fuller, Professor

Page 24

Review of IC Fabrication Technology

RESISTIVITY OF SILICON VS DOPING


1021

Impurity Concentration, N, cm-3

1020 1019 1018 1017 1016 1015 1014 1013 10-4

= 1/(q(N)N)
Because is a function of N and N is the doping, the relationship between resistivity and N is given in the figure shown, or calculated from equations for (N)

Boron

Phosphorous

10-3

10-2

10-1 100

101

102

103

104

PLAY

Rochester Institute of Technology Microelectronic Engineering

Resistivity, ohm-cm
Page 25

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

ELECTRON AND HOLE MOBILITY


Mobility (cm2/ V sec)
1600 1400 1200 1000 800 600 400 200 0

PLAY
electrons
Electron and hole mobilities in silicon at 300 K as Arsenic Boron functions of the total dopant Phosphorus concentration (N). The values plotted are the results of the curve fitting measurements from several sources. The mobility curves can be generated using the equation below with the parameters shown:

holes
10 ^1 9 10 ^1 7 10 ^1 6 10 ^1 4 10 ^1 5 10 ^1 8 10 ^2 0

10 ^1 3

Total Impurity Concentration (cm-3)

PLAY

(N) = mi+
Parameter min max Nref

( max- min) {1 + (N/Nref)}


Phosphorous 68.5 1414 9.20X10^16 0.711 Boron 44.9 470.5 2.23X10^17 0.719

Institute of Technology FromRochester Muller and Kamins, 3rd Ed., pg 33 Microelectronic Engineering

Arsenic 52.2 1417 9.68X10^16 0.680 Page 26

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

TEMPERATURE EFFECTS ON MOBILITY


Derived empirically for silicon for T in K between 250 and 500 K and for N (total dopant concentration) up to 1 E20 cm-3

n (T,N) = 88 Tn-0.57 +

1250 Tn-2.33 1 + [ N / (1.26E17 Tn


2.4)]

^0.88 Tn -0.146

PLAY
p (T,N) = 54.3 Tn-0.57 + 1 + [ N / (2.35E17 Tn 407 Tn-2.33
2.4)]^

0.88 Tn -0.146

Rochester Institute of Technology Microelectronic Engineering

Where Tn = T/300 From Muller and Kamins, 3rd Ed., pg 33


Page 27

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

EXCELL WORKSHEET TO CALCULATE MOBILITY


MICROELECTRONIC ENGINEERING CALCULATION OF MOBILITY 3/13/2005 Dr. Lynn Fuller

To use this spreadsheed change the values in the white boxes. The res t of the s heet is protected and should not be changed unless you are s ure of the consequences. The calculated res ults are shown in the purple boxes. CONSTANTS Tn = T/300 = 1.22 VARIABLES Temp= N total 365 K 1.00E+18 cm-3 n-type p-type <100> CHOICES 1=yes , 0=no 1 0

Kamins , Muller and Chan; 3rd Ed., 2003, pg 33 mobility= 163 cm2/(V-s ec)

Rochester Institute of Technology Microelectronic Engineering

mobility.xls
Page 28

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

EXCELL WORKSHEET TO CALCULATE RESISTANCE

Resistors_Poly.xls

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 29

Review of IC Fabrication Technology

UNIFORMLY DOPED PN JUNCTION


P+ P+ BB+ Phosphrous donor atom and electron Ionized Immobile Phosphrous donor atom Ionized Immobile Boron acceptor atom Boron acceptor atom and hole

Space Charge Layer p = NA


B+ B+ BB-

n = ND

B-

P+

P+ P+

P+ P+

P+ -

P+

+VR

p-type

P+ P+

n-type

charge density, qNA W1 =qND W2 -W1 -qNA Electric Field,

+qND x W2

Potential,
Rochester Institute of Technology Microelectronic Engineering

+VR
Page 30

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

UNIFORMLY DOPED PN JUNCTION


Built in Voltage:

ni = 1.45E10 cm-3 Width of Space Charge Layer, W: with reverse bias of VR volts

= KT/q

ln (NA ND /ni2)

W = ( W1 + W2 )

= [ (2 / q) ( +VR) (1/NA + 1/ND)]1/2 W2 width on n-side W2 = W [NA/(NA + ND)]

W1 width on p-side W1 = W [ND/(NA + ND)] Maximum Electric Field:

- [(2q/ ) ( +VR) (NA ND/(NA + ND))]1/2

Junction Capacitance per unit area:

Cj = r/W

= r/ [(2/ q) ( +VR) (1/NA + 1/ND)]1/2 = o r =8.85E-12 (11.7) F/m = 8.85E-14 (11.7) F/cm
Page 31

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

EXAMPLE Example: If the doping concentrations are Na=1E15 and Nd=3E15 cm-3 and the reverse bias voltage is 0, then find the built in voltage, width of the space charge layer, width on the n-side, width on the pside, electric field maximum and junction capacitance. Repeat for reverse bias of 10, 40, and 100 volts. = Vbi = KT/q ln (NA ND /ni2) = W = (W1 + W2 ) = [ (2 /q) ( +VR) (1/NA + 1/ND)]1/2
W1 = W2 = Emax = Cj =

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 32

Review of IC Fabrication Technology

EXAMPLE CALCULATIONS

PN.XLS

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 33

Review of IC Fabrication Technology

LONG CHANNEL THRESHOLD VOLTAGE, VT


Xox

Flat-band Voltage VFB =

- Qss Cox p-type substrate (n-channel)

ms

1 X (x) dx Cox 0 Xox n-type substrate (p-channel) Qss = q Nss

Bulk Potential : Work Function: Difference

p = -KT/q ln (NA /ni) n = +KT/q ln (ND /ni) M S = M - ( X + Eg/2q + [ p]) M S = M - ( X + Eg/2q - [ n])
4 s[ p] qNa 4 s[ n] qNd 2 s q Na ( 2[ p]) 2 s q Nd ( 2[ n])

Maximum Depletion Width:

(Wdmax)

Threshold Voltage: VT = VFB + 2 [ p] + 1 p-type substrate Cox Threshold Voltage: n-type substrate VT = VFB - 2 [ n] Cox
1

Rochester Institute of Technology Microelectronic Engineering

PLAY
Page 34

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

LONG CHANNEL Vt
Gate work function, n+, p+, aluminum Substrate doping, Nd or Na Oxide thickness, Xox Surface State Density, Nss or Qss also Substrate to Source voltage difference Threshold Voltage +3 +2 +1 250 150 650 +4 +3 +2 +1 0 -1 -2

PLAY

0 -1

n+ poly gate left scale p+ poly gate right scale -2 Qf = 0 Vbs = 0 -3 implant dose = zero
Rochester Institute of Technology Microelectronic Engineering

150 250 650 1014 1015 1016 1017 Substrate doping, Nd or Na


Page 35

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

VT ADJUST IMPLANT Assume that the total implant is shallow (within Wdmax) +/- Vt = q Dose*/Cox where Dose* is the dose that is added to the Si Cox is gate oxide capacitance/cm2 Boron gives + shift Cox = or / Xox Phosphorous gives - shift Example: To shift +1.0 volts implant Boron through 1000 Kooi oxide at an energy to place the peak of the implant at the oxide/silicon interface. Use a Dose = Vt Cox/q =(1.0)(3.9)(8.85E-14)/(1.6E-16)=2.16E11 ions/cm2 but multiply by 2 since 1/2 goes into silicon
Rochester Institute of Technology Microelectronic Engineering

PLAY
Page 36

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

MOSFET THRESHOLD VOLTAGE CALCULATION

MOSFETVT.XLS

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 37

Review of IC Fabrication Technology

ION IMPLANT EQUATIONS


Gaussian Implant Profile concentration cm-3 N -(X-Rp)2 N(x) = exp [ ] 2 Rp 2Rp2 Rp = Range Rp = Straggle N = Dose = After Anneal N N(x) = 2 Rp2 + 2Dt exp
after implant after anneal at 950 C, 15 min

} From Curves

Ni

I mqA dt

Approximation used in Vt calculations

-(X-Rp)2 2(Rp2+Dt)

xi Approximation N = Ni xi

where D is diffusion constant at the anneal temperature t is time of anneal


Rochester Institute of Technology Microelectronic Engineering

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January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

ION IMPLANT RANGE


1 Projected Range, Rp ,(um)

As
10-1

B P
10-2 10

Sb
100 Implantation Energy (KeV)
Rochester Institute of Technology Microelectronic Engineering

1,000

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January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

ION IMPLANT STANDARD DEVIATION


Standard Deviation, Rp ,(um)

0.1

B
0.01

P As Sb

0.001 10
Rochester Institute of Technology Microelectronic Engineering

100 Implantation Energy (KeV)

1,000

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Page 40

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

ION IMPLANT MASKING CALCULATOR


Rochester Institute of Technology Microelectronic Engineering 11/20/2004 IMPLANT MASK CALCULATOR DOPANT SPECIES B11 1 BF2 0 P31 0 Lance Barron Dr. Lynn Fuller

Enter 1 - Ye s MASK TYPE Resist Poly Oxide Nitride

0 - No in white boxe s ENERGY 60

0 1 0 0

KeV

Thickne ss to Ma sk >1E15/cm3 Surface Concentration

4073.011 Angstroms

This calculator is based on Silvaco Suprem simulations using the Dual Pearson model.

In powerpoint click on spread sheet to change settings for a new calculation


Rochester Institute of Technology Microelectronic Engineering

Lance Baron, Fall 2004


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January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

REFERENCES
1. Basic Integrated Circuit Engineering, Douglas J. Hamilton, William G. Howard, McGraw Hill Book Co., 1975. 2. Micro Electronics Processing and Device Design, Roy a. Colclaser, John Wiley & Sons., 1980. 3. Device Electronics for Integrated Circuits, Richard S. Muller, Theodore I. Kamins, Mansun Chan, John Wiley & Sons.,3rd Ed., 2003. 4. VLSI Technology, Edited by S.M. Sze, McGraw-Hill Book Company, 1983. 5. Silicon Processing for the VLSI Era, V ol. 1., Stanley Wolf, Richard Tauber, Lattice Press, 1986. 6. The Science and Engineering of Microelectronic Fabrication, Stephen A. Campbell, Oxford University Press, 1996.

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 42

Review of IC Fabrication Technology

HOMEWORK - REVIEW OF IC TECHNOLOGY


1. If a window is etched in 5000 of oxide and the wafer is oxidized again for 50 min in wet O2 at 1050 C what is the new thickness (where it was 5000 ), the thickness in the etch window, and the step height in the silicon if all the oxide is etched off the wafer. Draw a picture showing original Si surface. 2. A Boron diffusion is done into 5 ohm-cm n-type wafer involving two steps. First a short predeposit at 950 C for 30 min., followed by removal of the diffusion source and a drive in at 1100 C for 2 hours. Calculate the junction depth and the sheet resistance of the diffused layers. Estimate the oxide thickness needed to mask this diffusion. 3. For a pn junction with the p side doping of 1E17 and the n side at 1E15 calculate, width of space charge layer, width on p side, on n side, capacitance per unit area, max electric field. 4. Calculate the threshold voltage for an aluminum gate PMOSFET fabricated on an n-type wafer with doping of 5E15, a surface state density of 7E10, and gate oxide thickness of 150 . What is the threshold voltage if the surface state density is 3E11? 5. Calculate the ion implant dose needed to shift the threshold voltage found in the problem above to -1 Volts.
Rochester Institute of Technology Microelectronic Engineering

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January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

HOMEWORK - EXACT CALCULATION OF SHEET RESISTANCE FOR A DIFFUSED LAYER 1. A Boron p-type layer is diffused into an n-type silicon wafer (1E15 cm-3) at 1100 C for 1 hour. Calculate the exact value of the sheet resistance and compare to the approximate value.
Sheet Resistance = s = 1/ ( q (N) N(x) dx) ~ 1/( q Dose) ohms/square

(N) =

min

for Boron min 44.9 max 470.5 Nref 2.23X10^17 0.719

+ {1 + (N/Nref) }

( max- min)

Let QA(tp) = 5.633E15 cm-2 D= 1.55E-13 cm2/s t = 1 hour

N(x,t) = QA(tp) Exp (- x2/4Dt) Dt


Page 44

Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Review of IC Fabrication Technology

HW SOLUTION - EXACT CALCULATION OF SHEET RESISTANCE FOR A DIFFUSED LAYER Divide the diffused layer up into 100 slices and for each slice find the doping and exact mobility. Calculate the sheet resistance from the reciprocal of the sum of the conductance of each slice. N(x)

NBC xj
Rochester Institute of Technology Microelectronic Engineering

January 7, 2013 Dr. Lynn Fuller, Professor

Page 45

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