Documente Academic
Documente Profesional
Documente Cultură
1-7-2013 Review.ppt
Page 1
ADOBE PRESENTER This PowerPoint module has been published using Adobe Presenter. Please click on the Notes tab in the left panel to read the instructors comments for each slide. Manually advance the slide by clicking on the play arrow or pressing the page down key.
Page 2
OUTLINE Constants Periodic Table Material Properties Oxide Growth Diffusion Resistivity, Sheet Resistance, Resistance Mobility pn Junction MOSFET Vt Ion Implantation Conclusion
Page 3
CONSTANTS
Electronic charge Speed of light in vacuum Permittivity of vacuum Free electron Mass Planck constant Boltzmann constant Avogadros number Thermal voltage q c o mo h k Ao kT/q 1.602 E -19 Coulomb 2.998E8 m/s 8.854 E -14 F/cm 9.11E-31 Kg 6.625E-34 J s 1.38 E-23 J /K = 8.625E-5 eV/K 6.022E23 molecules/gm- mole @ 300 K = 0.02586
PLAY
Page 4
H
0.0899 Hydrogen
4.0026
He
0.1787 Helium 14.0067 8 15.9994 9 18.9984
6.914
Li
0.53 Lithium
Be
1.85 Beryllium 24.305
10.81
12.011
10
20.179
B
2.34 Boron
C
2.62 Carbon
N
1.251 Nitrogen
O
1.429 Oxygen
F
1.696 Fluorine
Ne
0.901 Neon
1122.9898 12
Si
2.33 Silicon
13
26.9815
14
20.08615 30.97376 16
Na
0.97 Sodium
Mg
1.74 Magnesium 47.90
Al
2.70 Aluminum 63.546 65.238
Si
2.33 Silicon
P
1.82 Phosphorous
S
2.07 Sulfur
Cl
3.17 Clorine
Ar
1.784 Argon
K
0.86 Potassium
Ca
1.55 Calcium
Sc
3.0 Scandium
23 50.941 24
51.996
25
54.938
26
55.847
58.70
31
69.72
32
72.59
33 74.9216 34
Ti
4.50 Titanium
Cr
Mn
43
98
Fe
7.86 Iron
Co
8.90 Selenium
Ni
8.90 Nickel 106.4
Cu
8.96 Copper
Zn
7.14 Zinc 112.41
Ga
5.98 Gallium
Ge
5.32 Germanium
As
5.72 Arsenic
Se
4.80 Selenium
Br
3.12 Bromine
Kr
3.74 Krypton
37
85.468 38 87.62
39
88.906 40 91.22
41
92.906 42 95.94
44
101.07
45 102.9055 46
47
107.868 48
49
114.82
50
Rb
55
Sr Ba
3.5 Barium
Y
4.5 Yttrium
Zr
6.49 Zirconium
Nb Ta
16.6 Tantalum
Mo W
19.3 Tungstem
Tc Re
21.0 Rhenium
Ru
12.2 Rhodium
Rh
12.4 Rhodium
Pd
12.0 Palladium
Ag
10.5 Silver
Cd
8.65 Cadmium
In
7.31 Indium
Sn
7.30 Tin
Sb
6.68 Antimony
Te
6.24 Tellurium
Fe
7.86 Tellurium
Xe
5.89 Xenon
76
190.2
77
192.22
78
195.09 79 196.9665
80
200.59
Cs
1.87 Cesium
La
6.7 Lanthanum
Hf
13.1 Hafnium
Os
22.4 Osmium
Ir
27.16 Iridium
Pt
21.4 IPlatinum
Au
19.3 Gold
Hg
13.53 Mercury
81
204.37
82
207.2
83
206.980 84 209
85
210
86
222
Tl
11.85 Thallium
Pb
11.4 Lead
Bi
9.8 Bismuth
Po
9.4 Polonium
At
??? Astatine
Rn
9.91 Radon
87
223
88
226.02 89 227.02
Fr
??? Francium
Ra
5 Radium
Ac
Unq Unp Ce Th
Unh Pr Pa
PLAY
144.24
58 140.12 59 140.91 60
61 145
65 158.92 66
162.5
173.04
71
174.97
Nd U
Pm
93 237
Sm
94
237
Eu
95 243
Gd
Tb
8.27 Terbium
Dy
8.54 Dysprosium
Ho
8.90 Holmium
Er
9.06 Erbium
Tm
9.33 Thulium 258
Yb
6.98 Ytterbium
Lu
9.84 Lutetium
96
247
97 247
98
251
99 252
102
259
103
260
Np
Pu Am
11.7 15.4 18.90 20.4 19.8 13.6 Rochester of Technology Thorium Institute Protactinium Uranium Neptunium Plutonium Americium
Cm
13.511 Curium
Bk
???? Berkelium
Cf
???? Californium
Es
???? Einsteinium
Fm
Md
No
???? Nobelium
Lr
???? Lawrencium
Microelectronic Engineering
Page 5
MATERIAL PROPERTIES
Symbol Atoms per unit cell Atomic Number Atomic weight Lattice constant Atomic density Density Energy Gap 300K Relative permittivity Index of refraction M elting point Specific heat Thermal diffusivity Coefficient expansion Intrinsic carrier conc Electron M obility Hole M obility Density of States conduction Density of States valance Breakdown Electric Field Effective mass electron Effective mass hole Electron affinity Z MW ao No d Eg r n Tm Cp K Dth ni n p Nc Nv E mn*/mo mp*/mo qX Units g/g-mole nm cm-3 g cm-3 eV Si 8 14 28.09 0.54307 5.00E22 2.328 1.124 11.7 3.44 1412 0.70 0.87 2.5E-6 1.45E10 1417 471 2.8E19 1.04E19 3E5 1.08 0.81 4.05 Ge 8 32 72.59 0.56575 4.42E22 5.323 0.67 16.0 3.97 937 0.32 0.36 5.7E-6 2.4E13 3900 1900 1.04E19 6.0E18 8E4 0.55 0.3 4.00 GaAs 8 31/33 144.64 0.56532 2.21E22 5.316 1.42 13.1 3.3 1237 0.35 0.44 5.9E-6 9.0E6 8800 400 4.7E17 7.0E18 3.5E5 0.068 0.5 4.07 GaP 8 31/15 100.70 0.54505 2.47E22 4.13 2.24 10.2 3.3 1467 0.004 5.3E-6 300 100 SiO2 14/8 60.08 2.20E22 2.19 8~9 3.9 1.46 1700 1.4 0.32 5E-6 20 10E-8 6~9E6 0.5 0.5 4.3 1.0 Si3N4 14/7 140.28 0.775 1.48E22 3.44 4.7 7.5 2.0 0.17 2.8E-6
OXIDE GROWTH
0.46 Xox
PLAY
Rochester Institute of Technology Microelectronic Engineering
Page 7
10-2 1
Rochester Institute of Technology Microelectronic Engineering
10
t, Time, (min)
100
PLAY
Page 8
10-2 10
1,000
PLAY
Page 9
OXIDE.XLS
Page 10
EXAMPLES 1. Estimate the oxide thickness resulting from 50 min. soak at 1100 C in wet oxygen.
2. If 1000 of oxide exists to start with, what is resulting oxide thickness after an additional 50 min. soak at 1100 C in dry oxygen.
Page 11
Blue
Yel low -"Yel lowish "(at times app ears to b e Lt gray o r matelli c)
Light Orange or Yellow - Pink Carnation Pink Violet Red "Bluish"(appears violet red, Blue Green, look s gray ish) Blue Blue Blue Green - Green "Yellowish" Orange Salmon Dull, LIght Red Violet Violet Blue Violet Blue Blue Blue Blue Green Dull Yellow Green Yellow - "Yellowish" Orange Carnation Pink
Nitride Thickness = (Oxide Thickness)(Oxide Index/Nitride Index) Eg. Yellow Nitride Thickness = (2000)(1.46/2.00) = 1460 Rochester Institute of Technology
Microelectronic Engineering
PLAY
Page 12
DIFFUSION FROM A CONSTANT SOURCE PLAY STOP N(x,t) = No erfc (x/2 Dt ) N(x,t) Solid Solubility Limit, No Wafer Background Concentration, NBC Xj
Rochester Institute of Technology Microelectronic Engineering
p-type
Page 13
ERFC FUNCTION
Concentration/Surface Concentration = N/No
10-0 10-1 10-2 10-3 10-4 10-5 10-6 10-7 10-8 10-9 10-10 10-11 0.0 1.0 2.0 3.0 4.0
= x / 4Dt
PLAY
Page 14
DIFFUSION CONSTANTS
BORON PHOSPHOROUS PHOSPHOROUS BORON PHOSPHOROUS
DRIVE-IN 1.07E-15 cm2/s 4.32E-15 1.57E-14 5.15E-14 1.55E-13 4.34E-13 1.13E-12 2.76E-12
PRE 2.09e-14 cm2/s 6.11E-14 1.65E-13 4.11E-13 9.61E-13 2.12E-12 4.42E-12 8.78E-12
SOLID SOLUBILITY NOB 7.49E-16 cm2/s 4.75E20 cm-3 3.29E-15 4.65E20 1.28E-14 4.825E20 4.52E-14 5.000E20 1.46E-13 5.175E20 4.31E-13 5.350E20 1.19E-12 5.525E20 3.65E-12 5.700E20
DRIVE-IN
SOLID SOLUBILITY NOP 6.75E20 cm-3 7.97E20 9.200E20 1.043E21 1.165E21 1.288E21 1.410E21 1.533E21
PLAY
Rochester Institute of Technology Microelectronic Engineering
Page 15
PLAY
eV/K T in Kelvins
T in Celsius T in Celsius
Page 16
DIFFUSION FROM A LIMITED SOURCE N(x,t) = QA(tp) Exp (- x2/4Dt) Dt for erfc predeposit QA (tp) = QA(tp)/Area = 2 No PLAY for ion implant predeposit QA(tp) = Dose
Rochester Institute of Technology Microelectronic Engineering
Where D is the diffusion constant at the drive in temperature and t is the drive in diffusion time, Dp is the diffusion constant at the predeposit temperature and tp is the predeposit time
Page 17
DIFFUSION MASKING CALCULATOR Select Boron or Phosphorous Enter Temperature and Time
Page 19
DIFFUSION.XLS
Page 20
Pre Deposition Ion Implant Dose Drive-in Temperature Drive-in Time CALCULATE Diffusion Constant at Temperature of Drive-in CALCULATION OF DIFFUSION CONSTANTS Boron Phos phorous CALCULATIONS Substra te Doping = 1 / (q max Rho) RES ULTS Pre deposition Dose xj afte r drive-in = ((4 Dd td/QA) ln (Ns ub ( Ddtd)^0.5))^0.5 average doping Nave = Dos e/xj mobility () at Doping e qual to Nave Sheet Resistance = 1/(q ((Nave))Dos e) Surfa ce Conce ntration = Dose/ (pDt)^0.5 D0 (cm2/s) EA (eV) 0.76 3.46 3.85 3.66
IonImplt.xls
VALUE UNITS 4.42E+14 cm-3 VALUE UNITS 4.00E+15 atoms/cm2 1.25 m 3.21E+19 atoms/cm3 57 cm2/V-s 27.6 ohms 1.28E+20 cm-3
Page 21
EXAMPLE 1. A predeposit from a p-type spin-on dopant into a 1E15 cm-3 wafer is done at 1100C for 10 min. Calculate the resulting junction depth and dose.
2. The spin-on dopant is removed and the Boron is driven in for 2 hours at 1100 C. What is the new junction depth?
Page 22
PLAY I
ohm-cm
PLAY
L
s = / t
Area
q = 1.6E-19 coul
slope = 1/R
w t
V R
Rochester Institute of Technology Microelectronic Engineering
Page 23
Donor and Acceptor Levels (eV above or below Ev or Ec) Boron 0.044 Phos phorous 0.045 Ars enic 0.049 CALCULATIONS: (this program makes a guess at the value of the fermi level and t rys the charge balance) KT/q Eg=Ego-(aT^2/(T+B)) Nc Nv Fermi Level, Ef free electrons , n = Nc exp(-q(Ec-Ef)KT) Ionized donors , Nd+ = Nd*(1+2*exp(q(Ef-Ed)/KT))^(-1) holes , p = Nv exp(-q(Ef-Ev)KT) Ionized accept ors , Na- = Na*(1+2*exp(q(Ea-Ef)/KT))^(-1) Charge Balance = p + Nd+ - n - NaRochester Institute of Technology Microelectronic Engineering
carrier_conc.xls
to minimize 0.026 Volts 1.115 eV 2.82E+19 cm-3 1.34E+01 cm-3 0.9295 eV above Ev 2.17E+16 cm-3 2.97E+16 cm-3 3.43E-15 cm-3 8.00E+15 cm-3 3.22E+12 cm-3
Page 24
= 1/(q(N)N)
Because is a function of N and N is the doping, the relationship between resistivity and N is given in the figure shown, or calculated from equations for (N)
Boron
Phosphorous
10-3
10-2
10-1 100
101
102
103
104
PLAY
Resistivity, ohm-cm
Page 25
PLAY
electrons
Electron and hole mobilities in silicon at 300 K as Arsenic Boron functions of the total dopant Phosphorus concentration (N). The values plotted are the results of the curve fitting measurements from several sources. The mobility curves can be generated using the equation below with the parameters shown:
holes
10 ^1 9 10 ^1 7 10 ^1 6 10 ^1 4 10 ^1 5 10 ^1 8 10 ^2 0
10 ^1 3
PLAY
(N) = mi+
Parameter min max Nref
Institute of Technology FromRochester Muller and Kamins, 3rd Ed., pg 33 Microelectronic Engineering
n (T,N) = 88 Tn-0.57 +
^0.88 Tn -0.146
PLAY
p (T,N) = 54.3 Tn-0.57 + 1 + [ N / (2.35E17 Tn 407 Tn-2.33
2.4)]^
0.88 Tn -0.146
To use this spreadsheed change the values in the white boxes. The res t of the s heet is protected and should not be changed unless you are s ure of the consequences. The calculated res ults are shown in the purple boxes. CONSTANTS Tn = T/300 = 1.22 VARIABLES Temp= N total 365 K 1.00E+18 cm-3 n-type p-type <100> CHOICES 1=yes , 0=no 1 0
Kamins , Muller and Chan; 3rd Ed., 2003, pg 33 mobility= 163 cm2/(V-s ec)
mobility.xls
Page 28
Resistors_Poly.xls
Page 29
n = ND
B-
P+
P+ P+
P+ P+
P+ -
P+
+VR
p-type
P+ P+
n-type
+qND x W2
Potential,
Rochester Institute of Technology Microelectronic Engineering
+VR
Page 30
ni = 1.45E10 cm-3 Width of Space Charge Layer, W: with reverse bias of VR volts
= KT/q
ln (NA ND /ni2)
W = ( W1 + W2 )
Cj = r/W
= r/ [(2/ q) ( +VR) (1/NA + 1/ND)]1/2 = o r =8.85E-12 (11.7) F/m = 8.85E-14 (11.7) F/cm
Page 31
EXAMPLE Example: If the doping concentrations are Na=1E15 and Nd=3E15 cm-3 and the reverse bias voltage is 0, then find the built in voltage, width of the space charge layer, width on the n-side, width on the pside, electric field maximum and junction capacitance. Repeat for reverse bias of 10, 40, and 100 volts. = Vbi = KT/q ln (NA ND /ni2) = W = (W1 + W2 ) = [ (2 /q) ( +VR) (1/NA + 1/ND)]1/2
W1 = W2 = Emax = Cj =
Page 32
EXAMPLE CALCULATIONS
PN.XLS
Page 33
ms
p = -KT/q ln (NA /ni) n = +KT/q ln (ND /ni) M S = M - ( X + Eg/2q + [ p]) M S = M - ( X + Eg/2q - [ n])
4 s[ p] qNa 4 s[ n] qNd 2 s q Na ( 2[ p]) 2 s q Nd ( 2[ n])
(Wdmax)
Threshold Voltage: VT = VFB + 2 [ p] + 1 p-type substrate Cox Threshold Voltage: n-type substrate VT = VFB - 2 [ n] Cox
1
PLAY
Page 34
LONG CHANNEL Vt
Gate work function, n+, p+, aluminum Substrate doping, Nd or Na Oxide thickness, Xox Surface State Density, Nss or Qss also Substrate to Source voltage difference Threshold Voltage +3 +2 +1 250 150 650 +4 +3 +2 +1 0 -1 -2
PLAY
0 -1
n+ poly gate left scale p+ poly gate right scale -2 Qf = 0 Vbs = 0 -3 implant dose = zero
Rochester Institute of Technology Microelectronic Engineering
VT ADJUST IMPLANT Assume that the total implant is shallow (within Wdmax) +/- Vt = q Dose*/Cox where Dose* is the dose that is added to the Si Cox is gate oxide capacitance/cm2 Boron gives + shift Cox = or / Xox Phosphorous gives - shift Example: To shift +1.0 volts implant Boron through 1000 Kooi oxide at an energy to place the peak of the implant at the oxide/silicon interface. Use a Dose = Vt Cox/q =(1.0)(3.9)(8.85E-14)/(1.6E-16)=2.16E11 ions/cm2 but multiply by 2 since 1/2 goes into silicon
Rochester Institute of Technology Microelectronic Engineering
PLAY
Page 36
MOSFETVT.XLS
Page 37
} From Curves
Ni
I mqA dt
-(X-Rp)2 2(Rp2+Dt)
xi Approximation N = Ni xi
PLAY
Page 38
As
10-1
B P
10-2 10
Sb
100 Implantation Energy (KeV)
Rochester Institute of Technology Microelectronic Engineering
1,000
PLAY
Page 39
0.1
B
0.01
P As Sb
0.001 10
Rochester Institute of Technology Microelectronic Engineering
1,000
PLAY
Page 40
0 1 0 0
KeV
4073.011 Angstroms
This calculator is based on Silvaco Suprem simulations using the Dual Pearson model.
REFERENCES
1. Basic Integrated Circuit Engineering, Douglas J. Hamilton, William G. Howard, McGraw Hill Book Co., 1975. 2. Micro Electronics Processing and Device Design, Roy a. Colclaser, John Wiley & Sons., 1980. 3. Device Electronics for Integrated Circuits, Richard S. Muller, Theodore I. Kamins, Mansun Chan, John Wiley & Sons.,3rd Ed., 2003. 4. VLSI Technology, Edited by S.M. Sze, McGraw-Hill Book Company, 1983. 5. Silicon Processing for the VLSI Era, V ol. 1., Stanley Wolf, Richard Tauber, Lattice Press, 1986. 6. The Science and Engineering of Microelectronic Fabrication, Stephen A. Campbell, Oxford University Press, 1996.
Page 42
PLAY
Page 43
HOMEWORK - EXACT CALCULATION OF SHEET RESISTANCE FOR A DIFFUSED LAYER 1. A Boron p-type layer is diffused into an n-type silicon wafer (1E15 cm-3) at 1100 C for 1 hour. Calculate the exact value of the sheet resistance and compare to the approximate value.
Sheet Resistance = s = 1/ ( q (N) N(x) dx) ~ 1/( q Dose) ohms/square
(N) =
min
+ {1 + (N/Nref) }
( max- min)
HW SOLUTION - EXACT CALCULATION OF SHEET RESISTANCE FOR A DIFFUSED LAYER Divide the diffused layer up into 100 slices and for each slice find the doping and exact mobility. Calculate the sheet resistance from the reciprocal of the sum of the conductance of each slice. N(x)
NBC xj
Rochester Institute of Technology Microelectronic Engineering
Page 45