Chemical Products Precious Metal Compounds and Homogeneous Catalysts

Heraeus Your Partner for High-Quality Precious Metal Compounds and Homogeneous Catalysts

Heraeus has more than 160 years experience in the handling of precious metals. From founding the company by Wilhelm Carl Heraeus in 1851, mechanical and chemical processing as well as the recovery of precious metals have been the core business of our family-owned firm. Now as ever, Heraeus precious metal chemicals are used in a multitude of key technologies all over the world. Whether in the production, R&D or analytical departments of the chemical, pharmaceutical, automotive, plating and electronic industries, Heraeus precious metal chemicals enjoy unanimous level of acceptance. Besides an extensive number of inorganics and their solutions, we also synthesize large-scale organometallics and homogeneous catalysts that the markets require commercially. Heraeus close relationship to customers especially in the fields of petrochemistry, electronics and the anode industries has been growing continuously. This has led us to extend our product range to include selected non-precious metal compounds. So, today rhenium and its compounds are a regular part of Heraeus total competence.

Abbreviation
_ acac cod _ Cp* dba dppe dppf dppp en Et Me nbd _ OAc Ph

Formula
_ C5H7O2 C8H12 _ C10H15 C17H14O C26H24P2 C34H28FeP2 C27H26P2 C2H8N2 C2H5 CH3 C7H8 C6H5
relating to anhydrous compound

Meaning
acetylacetonate(1-) cycloocta-1,5-diene pentamethylcyclopentadienyl(1-) dibenzylideneacetone [= 1,5-diphenylpenta-1,4-diene-3-one] [= ethane-1,2-diylbis(diphenylphosphane)] [= pentane-2,4-dionate(1-)]

1,2-bis(diphenylphosphano)ethane

1,1-ferrocenylbis(diphenylphosphane) 1,3-bis(diphenylphosphano)propane ethylenediamine ethyl methyl norborna-2,5-diene acetate(1-) phenyl [= bicyclo(2.2.1)hepta-2,5-diene] [= propane-1,3-diylbis(diphenylphosphane)]

[= ethane-1,2-diamine]

_ C2H3O2

a.c.

Atomic Number Atomic mass (IUPAC 2007)

Symbol (*radioactive isotopes only) Electronegativity (Allred-Rochow)

Chemical Products Core Competence of Heraeus

We are able to adjust packaging to our customers requirements. The complete handling of our products, which are almost entirely hazardous goods, is done in strict adherence to the ruling safety regulations from the time of production until delivery at our customers premises. All over the world we are in close touch with our clients. A tightly knit, global sales network as well as the local production sites in the fast growing industrial centers provide short distances to our customers, rapid flow of information and comprehensive local service. Moreover, in most countries one can find Heraeus sales offices with skilled staff for local support. In addition to product expertise we are also skilled in the field of precious metal management. In close collaboration with Heraeus own metal trading company we offer our customers tailor-made concepts for procuring precious metals and their subsequent positioning. Full cycle operations for the recovery of precious metals, and the administration of precious metal weight accounts, are an integral part of our daily business. In this brochure our commercially available precious metal chemicals are described.

The latest equipment for top-quality compounds

We are continuously developing and expanding our product range in line with market demand. Heraeus welcomes direct contact for custom synthesis and new compounds enquiries. Heraeus Chemical Products your reliable partner for sophisticated precious metal chemistry. You will find our latest news at our website: www.heraeus-chemicalproducts.com Enquiries for supported or heterogeneous precious metal catalysts should be directed to our colleagues of Heraeus Catalysts on phone: +49 (61 81) 35 42 39 or at: www.heraeus-catalysts.com

The Precious Metal Cycle

Recycling

Ore / Primary Metals

Precious Metal Trading

Precious Metal Bearing Scraps and Residues

Automotive

Chemistry

Electronics

Glass and Ceramics

Lighting Technology

Medical Technology and Pharmaceuticals

Key Markets

Precious Metal Refining Highest Quality through the Most Modern Equipment

Precious metal catalysis with recycling of spent catalysts! Thermal reduction is a key step in the treatment of precious metal containing materials. This process ensures the drying of material and the increase of precious metal concentrations and is therefore an essential foundation for the homogenization and sampling of spent materials. Typically spent heterogeneous catalysts such as carbon catalysts, resins and sludges as well as precious metal containing items from the electronics, glass or decorative coating industries are treated in this way. Heraeus has recently invested into capacity expansion at its facilitites in Hanau/Germany, Wartburg/Tennessee, and Taicang/China and thus has significantly increased the range of treatable materials. In Hanau we have comissioned the HeraCYCLE process for thermal processing.
HeraCYCLE: A highly flexible and robust technology for thermal treatment of refining materials

This process is focused on the treatment of catalysts from the chemical, petrochemical or pharmaceutical industries from homogeneous catalysis in particular. The technology used in this robust unit is based on our substantial experience in the treatment of precious metals and is designed to facilitate treatment of materials with more and more complex and ever changing matrices. We can ensure a professional treatment of all intake materials regardless of their consistency. Our proprietary process meets all regulatory and environmental standards and has been permitted without problems. All material is treated in a batch process ensuring that each customers lot is treated separately and that the precious metals contained can be balanced correctly. Heraeus is ready to convert your recovered metal into the precious metal compounds and homogeneous catalysts you need for your process.

Spent homogeneous catalysts

Close your precious metal loop now with Heraeus!

Innovative Technologies Precious Metal Compounds for the 21st Century

Also in the 21st century precious metal compounds are indispensable. Besides classical applications like catalysis and electroplating, the reduction in use of raw materials and fossil energy is the clear focus in technological progress worldwide. This includes innovative technologies for illumination, for miniaturization in the field of electronics, and for the industrial usage of renewable energies. LEDs (Light-Emitting Diodes) are seen in everyday life. For example LEDs are found in flashlights, automotive dashboards and cell phones. Advantages of LEDs are a substantial saving of energy, no maintenance, adjusted coloring, flexible arrangements, and in particular they take up less space. The increasing miniaturization of electronic components in line with requirements for highest purity levels need innovative solutions for ultra-thin metal layers. PLEDs are based on organic polymers and are perfect for use for flexible films. For example, a new application is the so-called E-Paper. PLEDs are normally manufactured with homogeneous catalysis using palladium (C-C coupling reaction). Heraeus offers you a wide range of homogeneous catalysts.

The latest developments for the manufacture of blue emitters for screens are based on organic or organometallic materials (OLEDs, Organic-Light-Emitting Diodes), e.g. highly sophisticated precious metal complexes of iridium. Here, the established sputter technologies are often not precise enough. However, MOCVD (Metal-Organic Chemical Vapor Deposition) offers decisive advantages: high-purity deposition of metals from the gas phase on a nm scale. In this field the term ALD (Atomic Layer Deposition) is used, too. Also recently platinum group metals complexes, e.g. Ruthenium, with organic ligands have been applied to MOCVD. Solar cells of the 3rd generation are based on deepcolored metal complexes which absorb light energy and so generate electric voltage by using physical-chemical processes. They are called DSCs (Dye-Sensitized Cells), or simply Solar Dyes. Ruthenium in particular has proven to be very efficient for this application.

Gold Tradition in Jewelry for Milleniums

Gold Compounds Formula Chloro(triphenylphosphane)gold(I) Gold(III) hydroxide Hydrogen tetrachloroaurate(III) hydrate Chloroauric Acid, Gold Chloride Yellow Hydrogen tetrachloroaurate(III) solution Chloroauric Acid Potassium dicyanoaurate(I) Gold Salt, Potassium Gold Cyanide Potassium tetrachloroaurate(III) Potassium tetracyanoaurate(III) Sodium tetrabromoaurate(III) [AuCl(PPh3)] Au(OH)3 H[AuCl4] nH2O H[AuCl4] K[Au(CN)2] K[AuCl4] K[Au(CN)4] Na[AuBr4] Code 103 105 106 107 108 109 110 112 Metal Contained approx. 39% 80% 50% up to 40% 68.2% 52% 58% 33% CAS 14243-64-2 1303-52-2 16903-35-8 16903-35-8 13967-50-5 13682-61-6 14263-59-3 52495-41-7 Color colorless orange-brown orange orange colorless yellow colorless black-purple

Silver Element for Photography and the Manufacture of Mirrors

Silver Compounds Formula Potassium dicyanoargentate(I) Potassium Silver Cyanide Silver(I) acetate Silver(I) carbonate Silver(I) chloride Silver(I) cyanide Silver(I) nitrate Silver(I) oxide Silver(II) oxide Silver(I) sulfate Code Metal Contained approx. 54% 64% 78% 75% 80% 63% 93% 87% 69% CAS Color

K[Ag(CN)2] Ag(OAc) Ag2CO3 AgCl AgCN AgNO3 Ag2O AgO Ag2SO4

201 202 203 204 205 206 207 208 209

506-61-6 563-63-3 534-16-7 7783-90-6 506-64-9 7761-88-8 20667-12-3 1301-96-8 10294-26-5

colorless colorless yellow colorless colorless colorless brown black colorless

Platinum Catalytic Refining of Petrochemical Raw Materials

High-octane fuels for petrochemical refineries

Platinum Compounds Formula Ammonium hexachloroplatinate(IV) Ammonium tetrachloroplatinate(IV) Bis(acetylacetonato)platinum(II) cis-Diamminedichloroplatinum(II) cis-Diamminedinitritoplatinum(II) ammoniacal solution cis-Diamminedinitritoplatinum(II) nitric-acid solution cis-Diamminedinitritoplatinum(II) suspension cis-Dibromobis(triphenylphosphite)platinum(II) Dibromo(cycloocta-1,5-diene)platinum(II) Di--chloro-bis[chloro(cyclohexene)platinum(II)] cis-Dichlorobis(triphenylphosphane)platinum(II) Dichloro(cycloocta-1.5-diene)platinum(II) Dihydrogen hexachloroplatinate(IV) hydrate Chloroplatinic Acid, CPA Dihydrogen hexachloroplatinate(IV) solution (1) Chloroplatinic Acid, CPA Dihydrogen hexachloroplatinate(IV) solution in isopropanol Speiers Catalyst Dihydrogen hexahydroxoplatinate(IV) Hydroxoplatinic Acid Dihydrogen dinitritodisulfitoplatinate(IV) solution "Pt DNS" 2-Hydroxyethylammonium hexahydroxoplatinate(IV) solution Pt EA Platinum(II) chloride Platinum(IV) chloride Platinum(0) divinyltetramethylsiloxane complex (2) Karstedt Concentrate
(1) Also available in organic solvents upon request (2) Also available as tailor-made blends upon request

Code 301 302 303 305 306 307 308 309 310 311 312 313 314 315 316 317 318 319 320 321 322

(NH4)2[PtCl6] (NH4)2[PtCl4] [Pt(acac)2] cis-[PtCl2(NH3)2] cis-[Pt(NO2)2(NH3)2] cis-[Pt(NO2)2(NH3)2] cis-[Pt(NO2)2(NH3)2] cis-[PtBr2{P(OPh)3}2] [PtBr2(cod)] [{PtCl(C6H10)}2(-Cl)2] cis-[PtCl2(PPh3)2] [PtCl2(cod)] H2[PtCl6] nH2O H2[PtCl6] H2[PtCl6] / i-PrOH H2[Pt(OH)6] H2[Pt(NO2)2(SO3)2] (HOC2H4NH3)2[Pt(OH)6] PtCl2 PtCl4 [Pt2(C8H18OSi2)3]

Metal Contained approx. 44% 52% 50% 65% up to 5 % 10% up to 10 % 20% 42% 55% 24% 52% 40% up to 32 % up to 15% 56% up to 5% up to 12% 73% 58% 19%

CAS 16919-58-7 13820-41-2 15170-57-7 15663-27-1 14286-02-3 14286-02-3 14286-02-3 41871-81-2 12145-48-1 12176-53-3 10199-34-5 12080-32-9 26023-84-7 16941-12-1 26023-84-7 51850-20-5 68958-85-0

Color yellow red yellow yellow yellow yellow beige pale yellow pale yellow beige colorless beige orange orange orange yellow yellow pale yellow light brown reddish brown yellow

10025-65-7 13454-96-1 68478-92-2

10

Platinum Curing Catalyst for the Manufacture of Silicones

Dental impression materials

Platinum Compounds Formula Platinum(II) nitrate Platinum(II) nitrate solution Platinum(IV) oxide hydrate Adams Catalyst Platinum sulfite solution Potassium hexachloroplatinate(IV) Potassium hexahydroxoplatinate(IV) solution Potassium hexahydroxoplatinate(IV) Potassium tetrachloroplatinate(II) Potassium tetranitritoplatinate(II) or: Potassium tetranitroplatinate(II) Sodium hexachloroplatinate(IV) hydrate Sodium tetrachloroplatinate(II) solution Tetraammineplatinum(II) chloride hydrate TPC Pt Tetraammineplatinum(II) chloride solution TPC Pt Tetraammineplatinum(II) hydrogencarbonate TPHC Pt Tetraammineplatinum(II) hydrogenphosphate solution Tetraammineplatinum(II) hydroxide solution TPH Pt Tetraammineplatinum(II) nitrate solution TPN Pt Tetraammineplatinum(II) nitrate low pH solution TPN Pt Tetrakis(triphenylphosphane)platinum(0) Pt(NO3)2 Pt(NO3)2 PtO2 nH2O Pt(SO3)x K2[PtCl6] K2[Pt(OH)6] K2[Pt(OH)6] K2[PtCl4] K2[Pt(NO2)4] Na2[PtCl6] nH2O Na2[PtCl4] [Pt(NH3)4]Cl2 nH2O [Pt(NH3)4]Cl2 [Pt(NH3)4](HCO3)2 [Pt(NH3)4]HPO4 [Pt(NH3)4](OH)2 [Pt(NH3)4](NO3)2 [Pt(NH3)4](NO3)2 [Pt(PPh3)4] Code 323 324 325 326 327 328 329 330 331 332 334 336 337 338 339 340 341 342 343 Metal Contained approx. 58% up to 30% 80% up to 10 % 40% up to 20% 52% 47% 42% 35% up to 8 % 55% up to 6 % 51% up to 2 % up to 10 % 3% up to 4 % 15% CAS 18496-40-7 18496-40-7 52785-06-5 61420-92-6 16921-30-5 12285-90-4 12285-90-4 10025-99-7 13815-39-9 19583-77-8 10026-00-3 13933-32-9 16971-49-6 123439-82-7 127733-98-6 38201-97-7 20634-12-2 20634-12-2 14221-02-4 Color orange-brown orange-brown brown yellow yellow yellow yellow red colorless red red yellowish yellowish colorless colorless colorless pale yellow pale yellow yellow

11

Palladium Active in Hydrogenation Catalysts for the Chemical Industries

Petrochemistry requires supported palladium catalysts for selective hydrogenations.

Palladium Compounds Formula Ammonium hexachloropalladate(IV) Ammonium tetrachloropalladate(II) Bis(acetonitrile)dichloropalladium(II) Bis(acetylacetonato)palladium(II) Palladium Acetylacetonate trans-Bis(benzonitrile)dichloropalladium(II) Bis(dibenzylideneacetone)palladium(0) Bis(ethylenediamine)palladium(II) chloride Diamminedichloropalladium(II) Diamminedinitritopalladium(II) ammoniacal solution Palladium P Salt Solution Dichloro[1,2-bis(diphenylphosphano)ethane]palladium(II) or: Dichloro[ethane1,2-diylbis(diphenylphosphane)]palladium(II) Dichloro[1,3-bis(diphenylphosphano)propane]palladium(II) or: Dichloro[propane-1,3-diylbis(diphenylphosphane)]palladium(II) Dichlorobis(triphenylphosphane)palladium(II) Dichloro(cycloocta-1.5-diene)palladium(II) Dichloro[1,1'-ferrocenylbis(diphenylphosphane)]palladium(II) Dichloro[1.1-ferrocenylbis(diphenylphosphane)]palladium(II) dichloromethane Dihydrogen tetrachloropalladate(II) solution Palladium Chloride Solution Palladium(II) acetate Palladium(II) bromide Palladium(II) chloride Palladium(II) nitrate hydrate Palladium(II) nitrate solution Palladium(II) sulfate solution (NH4)2[PdCl6] (NH4)2[PdCl4] [PdCl2(MeCN)2] [Pd(acac)2] [PdCl2(PhCN)2] Pd(dba)2 [Pd(en)2]Cl2 [PdCl2(NH3)2] [Pd(NO2)2(NH3)2] Code 401 402 403 404 405 406 407 408 409 Metal Contained approx. 30% 37% 41% 35% 27% 20% 35% 50% up to 18 % CAS 19168-23-1 13820-40-1 14592-56-4 14024-61-4 14220-64-5 32005-36-0 13963-53-6 14323-43-4 14708-52-2 Color reddish brown green yellow yellow yellow reddish brown beige yellow yellow

[PdCl2(dppe)]

410

18%

19978-61-1

off-white

[PdCl2(dppp)] [PdCl2(PPh3)2] [PdCl2(cod)] [PdCl2(dppf)] [PdCl2(dppf)] CH2Cl2 H2[PdCl4] Pd(OAc)2 PdBr2 PdCl2 Pd(NO3)2 nH2O Pd(NO3)2 PdSO4

411 412 413 414

18% 15% 37% 13%

59831-02-6 13965-03-2 12107-56-1 72287-26-4

off-white yellow yellow red

415 416 417 418 419 420 421 424

13% up to 20% 47% 40% 60% 41% up to 17% up to 12 %

95464-05-4 7647-10-1 3375-31-3 13444-94-5 7647-10-1 10102-05-3 10102-05-3 13566-03-5

red brown yellowish brown violet brown yellowish brown yellowish brown brown

12

Palladium Homogeneous Catalysts for Liquid Crystal Technologies

Palladium Compounds Formula Palladium(II) trifluoroacetate Potassium hexachloropalladate(IV) Potassium tetrachloropalladate(II) Sodium tetrachloropalladate(II) Sodium tetrachloropalladate(II) solution Tetraamminepalladium(II) chloride TPC Pd Tetraamminepalladium(II) chloride solution TPC Pd Tetraamminepalladium(II) hydrogencarbonate TPHC Pd Tetraamminepalladium(II) hydroxide solution TPH Pd Tetraamminepalladium(II) nitrate TPN Pd Tetraamminepalladium(II) nitrate solution TPN Pd Tetraamminepalladium(II) sulfate solution Tetrakis(triphenylphosphane)palladium(0) Tris(dibenzylideneacetone)dipalladium(0) Tris(dibenzylideneacetone)dipalladium(0) dibenzylideneacetone Pd(CF3CO2)2 K2[PdCl6] K2[PdCl4] Na2[PdCl4] Na2[PdCl4] [Pd(NH3)4]Cl2 Code 425 426 427 428 429 431 Metal Contained approx. 32% 27% 32% 36% up to 15 % 42% CAS 42196-31-6 16919-73-6 10025-98-6 13820-53-6 13820-53-6 13815-17-3 Color light brown red brown brown brown yellow

[Pd(NH3)4]Cl2 [Pd(NH3)4](HCO3)2 [Pd(NH3)4](OH)2 [Pd(NH3)4](NO3)2 [Pd(NH3)4](NO3)2 [Pd(NH3)4]SO4 [Pd(PPh3)4] Pd2(dba)3 Pd2(dba)3 dba

432 433 434 435 436 438 439 440 441

up to 10% 35% up to 5 % 35% up to 6 % up to 4 % 9% 20% 20%

13815-17-3 134620-00-1 68413-68-3 13601-08-6 13601-08-6 13601-06-4 14221-01-3 52409-22-0 51364-51-3

yellow cream yellowish pale yellow light brown yellow yellowish green reddish brown reddish brown

13

Rhodium Homogeneous Catalysis for the Production of Acetic Acid and Oxo Aldehydes

Rhodium Compounds Formula (Acetylacetonato)carbonyl(triphenylphosphane)rhodium(I) ROPAC Acetylacetonato(cycloocta-1,5-diene)rhodium(I) (Acetylacetonato)dicarbonylrhodium(I) CARAC Ammonium hexachlororhodate(III) Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate Carbonylchlorobis(triphenylphosphane)rhodium(I) Carbonylhydridotris(triphenylphosphane)rhodium(I) RODRIDO Chlorotris(triphenylphosphane)rhodium(I) Wilkinsons Catalyst Di--acetato-bis[acetatorhodium(II)] Green Rhodium Acetate Di--chloro-bis[chloro(pentamethylcyclopentadienyl)rhodium(III)] Di--chloro-bis[(cycloocta-1.5-diene)rhodium(I)] Code Metal Contained approx. 21% 33% 40% 27% 25% appr. 15 % 11% 11% 46% 33% 42% CAS Color

[Rh(acac)(CO)(PPh3)] [Rh(acac)(cod)] [Rh(acac)(CO)2] (NH4)3[RhCl6] [Rh(cod)2]BF4 [RhCl(CO)(PPh3)2] [RhH(CO)(PPh3)3] [RhCl(PPh3)3] [{Rh(OAc)}2(-OAc)2] [{RhClCp*}2(-Cl)2] [{Rh(cod)}2(-Cl)2]

501 502 503 504 508 510 511 512 513 515 516

25470-96-6 12245-39-5 14874-82-9 15336-18-2 35138-22-8 13938-94-8 17185-29-4 14694-95-2 15956-28-2 12354-85-7 12092-47-6

yellow yellow red - green red reddish brown yellow yellow red green reddish brown yellow

14

Rhodium Emission Control and Brilliant Surfaces

Rhodium Compounds Formula Hexaamminerhodium(III) chloride solution Hexaamminerhodium(III) hydroxide solution Rhodium acetate Rhodium acetate acetic solution Rhodium(III) chloride Rhodium(III) chloride hydrate Rhodium(III) chloride solution Rhodium 2-ethylhexanoate solution in 2-ethyl hexanol Rh 2-EH Rhodium(III) iodide Rhodium(III) nitrate hydrate Rhodium(III) nitrate solution Rhodium(III) phosphate solution Rhodium(III) sulfate solution Rhodium sulfite solution [Rh(NH3)6]Cl3 [Rh(NH3)6](OH)3 Rh(OAc)x Rh(OAc)x RhCl3 RhCl3 nH2O RhCl3 Rh2(C8H15O2)4 RhI3 Rh(NO3)3 nH2O Rh(NO3)3 RhPO4 Rh2(SO4)3 Rh(SO3)x Code 520 521 523 524 527 528 529 530 531 532 533 535 536 537 Metal Contained approx. up to 2 % up to 8% 39% up to 8% 49% 38% up to 20% up to 2 % 21% 40% up to 13% up to 3 % up to 12% up to 6 % CAS 13820-96-7 42204-14-8 26105-49-7 42204-14-8 26105-49-7 10049-07-7 20765-98-4 13569-65-8 20845-92-5 15492-38-3 13465-43-5 10139-58-9 67859-71-6 10489-46-0 Color colorless pale yellow brown brown red red red reddish brown black brown brown yellow - red brown brownish yellow

15

Ruthenium Essential to High-Capacity Hard Disks

CI Ru

CI CI

Ru CI

Picture: Dyesol

Ruthenium Compounds Formula Ammonium hexachlororuthenate(IV) Ammonium -nitrido-bis[aquatetrachlororuthenate(IV)] Carbonyldihydridotris(triphenylphosphane)ruthenium(II) Di--chloro-bis[chloro(p-cymene)ruthenium(II)] Dichloro(cycloocta-1.5-diene)ruthenium(II) Dichlorotris(triphenylphosphane)ruthenium(II) Ruthenium acetate Ruthenium(III) chloride hydrate Ruthenium(III) chloride solution Trinitratonitrosylruthenium(II) Trinitratonitrosylruthenium(II) solution Trinitratonitrosylruthenium(II) technical solution Tris(acetylacetonato)ruthenium(III) Ruthenium Acetylacetonate Ruthenium acetate solution (NH4)2[RuCl6] (NH3)4[{RuCl4(H2O)}2(-N)] [Ru(H)2(CO)(PPh3)3] [{RuCl(C10H14)}2(-Cl)2] [RuCl2(cod)]n [RuCl2(PPh3)3] Ru(OAc)x RuCl3 nH2O RuCl3 [Ru(NO3)3(NO)] [Ru(NO3)3(NO)] [Ru(NO3)3(NO)] [Ru(acac)3] Ru(OAc)x Code 701 702 703 704 705 706 708 710 711 715 716 717 718 719 Metal Contained approx. 31% 34% 11% 33% 35% 10% 47% 40% up to 20% 30% up to 15% up to 15% 25% up to 8% CAS 18746-63-9 27316-90-1 25360-32-1 52462-29-0 50982-12-2 15529-49-4 55466-76-7 14898-67-0 10049-08-8 34513-98-9 34513-98-9 34513-98-9 14284-93-6 55466-76-7 Color brown red cream reddish brown brown reddish brown black brownish black brown reddish brown claret brown red dark green

16

Iridium Anodes for the Production of Chlorine and Sodium Hydroxide Solution

Manufacture of anodes for industrial electrolysis

Molecular structure of di--chloro-bis[(cycloocta-1.5-diene)iridium(I)]

Iridium Compounds Formula Ammonium hexachloroiridate(IV) Bis(cycloocta-1,5-diene)iridium(I) tetrafluoroborate Di--chloro-bis[chloro(pentamethylcyclopentadienyl)iridium(III)] Di--chloro-bis[(cycloocta-1.5-diene)iridium(I)] Dihydrogen hexachloroiridate(IV) hydrate Chloroiridic Acid; CIA Dihydrogen hexachloroiridate(IV) solution Chloroiridic Acid; CIA Iridium acetate Iridium(III) chloride hydrate Iridium(III) chloride hydrate, Type G Iridium(III) chloride solution Iridium(IV) chloride hydrate Iridium(IV) oxide Potassium hexachloroiridate(III) Potassium hexachloroiridate(IV) Ir black Tris(acetylacetonato)iridium(III) Iridium Acetylacetonate Iridium acetate solution (NH4)2[IrCl6] [Ir(cod)2]BF4 [{IrClCp*)2(-Cl)2] [{Ir(cod)}2(-Cl)2] H2[IrCl6] nH2O H2[IrCl6] Ir(OAc)x IrCl3 nH2O IrCl3 nH2O IrCl3 IrCl4 nH2O IrO2 K3[IrCl6] K2[IrCl6] Ir [Ir(acac)3] Ir(OAc)x Code 602 603 604 605 606 607 608 610 611 612 613 614 617 618 619 621 622 Metal Contained approx. 43% 38% 48% 57% 43% up to 25% 48% 54% 54% up to 10 % 53% 85% 37% 39% 98% 37% up to 8 % CAS 16940-92-4 35138-23-9 12354-84-6 12112-67-3 16941-92-7 16941-92-7 52705-52-9 14996-61-3 14996-61-3 10025-83-9 10025-97-5 12030-49-8 14024-41-0 16920-56-2 7439-88-5 15635-87-7 52705-52-9 Color black dark purple orange-red orange-red black brown green green green dark brown black deep blue dark green black black yellowish green teal

17

Osmium Fixing Agent for Modern Microscopy

Osmium Compounds Formula Ammonium hexachloroosmate(IV) Osmium(III) chloride hydrate Osmium(VIII) oxide Osmium(VIII) oxide solution Potassium hexachloroosmate(IV) Potassium tetrahydroxodioxoosmate(VI) Potassium Osmate Sodium hexachloroosmate(IV) hydrate (NH4)2[OsCl6] OsCl3 nH2O OsO4 OsO4 K2[OsCl6] K2[Os(O)2(OH)4] Na2[OsCl6] nH2O Code 901 902 903 904 905 906 907 Metal Contained approx. 43% 55% 75% up to 3 % 39% 52% 39% CAS 12125-08-5 14996-60-2 20816-12-0 20816-12-0 16871-60-6 10022-66-9 1307-81-9 Color red-black black yellow yellow red violet red-black

OsO4 solution of highest purity

OsO4 crystals in ampules

18

Rhenium High-Speed Turbines for Todays Air Traffic Worldwide

Rhenium Compounds Formula Ammonium tetraoxorhenate(VII) Ammonium Perrhenate Hydroxotrioxorhenium(VII) solution Perrhenic Acid Potassium tetraoxorhenate(VII) Rhenium pellets Rhenium powder Code Metal Contained approx. 69% up to 60 % 64% min. 99.9 % min. 99.9 % CAS Color

NH4[ReO4] [HReO4] K[ReO4] Re Re

801 802 803 804 805

13598-65-7 13768-11-1 10466-65-6 7440-15-5 7440-15-5

colorless colorless colorless grey grey

Rhenium pellets

19

Heraeus Chemical Products all over the World

Germany Heraeus Precious Metals GmbH & Co. KG Chemicals Division Business Unit Chemical Products Heraeusstr. 12 14 63450 Hanau Germany Phone +49 6181.35-9774 Fax +49 6181.35-8760 chemicals@heraeus.com U.S.A. Heraeus Precious Metals North America, LLC Chemicals Division 15524 Carmenita Road Santa Fe Springs, CA 90670 United States Phone +1 562.921-7464 Fax +1 562.926-5333 chemicals_america@heraeus.com www.heraeus-hpmn.com

Ireland Heraeus Metal Processing Ltd. Bay 75 Shannon Industrial Estate, County Clare Ireland Phone +353 61.47-2099 Fax +353 61.47-2734 andrew.walsh@heraeus.com

South Africa Heraeus South Africa (Pty) Ltd 6 7 Oddy Place Perseverance, Port Elizabeth P. O. Box 1987, Port Elizabeth 6000 South Africa Phone +27 41.404-2808 Fax +27 41.463-3372 hza-info@heraeus.com

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All solutions in this brochure are aqueous as far as not specified otherwise. Formulae in quotation marks ( ) represent the idealized composition of empirical compounds. Of course besides the precious metal chemicals, homogeneous catalysts and their solutions in this brochure Heraeus supplies you with the respective precious metals in highest purity and certified qualities. Please do not hesitate to contact us.

India Ravindra Heraeus Private Ltd. A-196 (A), F-Road Mewar Industrial Area, Madri 313 003 Udaipur, India Phone +91 294.249-0029 or +91 294.249-2027 Fax +91 294.249-2177 or +91 294.249-1825 info@ravindraheraeus.com Hong Kong Heraeus Ltd. Business Unit Chemical Products Heraeus Technology Centre 30 On Chuen Street On Lok Tsuen, Fanling, N. T. Hong Kong Hong Kong Phone +852 2675.1280 Fax +852 2682.3220 mike.fu@heraeus.com

Shanghai Heraeus Materials Technology Shanghai Ltd. No. 1 Guang Zhong Road Zhuanqiao Town Minhang District 201108 Shanghai P. R. China Phone +8621 3357.5352 Fax +8621 3357.5699 hmts@heraeus.com

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Heraeus Precious Metals GmbH & Co. KG Chemicals Division Business Unit Chemical Products Heraeusstr. 12 14 63450 Hanau, Germany Phone +49 (6181) 35 9774 Fax +49 (6181) 35 8760 chemicals@heraeus.com www.heraeus-chemicalproducts.com

The data given here is correct as of November 2012. We reserve the right to make technical alterations.

E PDF 11.2012/VN Layout 5TC, Friedberg