Technical Data Sheet

LOCTITE

4471"
January-2007

PRODUCT DESCRIPTION
LOCTTE

4471 provides the following product

characteristics:
TechnoIogy Cyanoacrylate
Chemical Type Ethyl cyanoacrylate
Appearance (uncured) Clear liquid
LMS
Components One part - requires no mixing
Viscosity Medium
Cure Humidity
AppIication Bonding
Key Substrates Wood, Leather and Foamed rubber
LOCTTE

4471 is designed for the assembly of difficult-

to-bond materials which require uniform stress distribution and
strong tension and/or shear strength. n addition to key
substrates referred to above, the product bonds acidic surfaces
such as chromated or freshly plated parts.
TYPICAL PROPERTIES OF UNCURED MATERIAL
Specific Gravity @ 25 C 1.05
Viscosity, Brookfield - RVT, 25 C, mPas (cP):
Spindle 2, speed 20 rpm 500 to 750
LMS
Flash Point - See MSDS
TYPICAL CURING PERFORMANCE
Under normal conditions, the atmospheric moisture initiates the
curing process. Although full functional strength is developed
in a relatively short time, curing continues for at least 24 hours
before full chemical/solvent resistance is developed.
Cure Speed vs. Substrate
The rate of cure will depend on the substrate used. The table
below shows the fixture time achieved on different materials
at 22 C / 50 % relative humidity. This is defined as the time to
develop a shear strength of 0.1 N/mm .
Fixture Time, SO 4587, seconds:
Steel (degreased) 10 to 20
Aluminum 2 to 10
Zinc dichromate 20 to 30
Neoprene <5
Rubber, nitrile <5
ABS 2 to 5
PVC 2 to 5
Polycarbonate 2 to 5
Phenolic 5 to 15
Cure Speed vs. Bond Gap
The rate of cure will depend on the bondline gap. Thin bond
lines result in high cure speeds, increasing the bond gap will
decrease the rate of cure.
Cure Speed vs. Humidity
The rate of cure will depend on the ambient relative humidity.
The following graph shows the tensile strength developed with
time on Buna N rubber at different levels of humidity.
%

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C
Cure Time, seconds
100
75
50
25
0
0 10 20 30 40 50 60
6
0
%

R
H
4
0
%

R
H
2
0
%

R
H
Cure Speed vs. Activator
Where cure speed is unacceptably long due to large gaps,
applying activator to the surface will improve cure speed.
However, this can reduce ultimate strength of the bond and
therefore testing is recommended to confirm effect.
TYPICAL PROPERTIES OF CURED MATERIAL
After 24 hours @22 C
PhysicaI Properties:
Coefficient of Thermal Expansion, SO 11359-2,
K
-1
10010
-6
Coefficient of Thermal Conductivity, SO 8302,
W/(mK)
0.1
EIectricaI Properties:
Dielectric Constant / Dissipation Factor, EC 60250:
0.1-kHz 2.3 / <0.02
1-kHz 2.3 / <0.02
10-kHz 2.3 / <0.02
Volume Resistivity, EC 60093, Dcm 1010
15
Surface Resistivity, EC 60093, D 4010
15
Dielectric Breakdown Strength, EC 60243-1,
kV/mm
25
TYPICAL PERFORMANCE OF CURED MATERIAL
Adhesive Properties
After 24 hours @22 C
Lap Shear Strength, SO 4587:
TDS LOCTTE

4471, January-2007
Steel (grit blasted) N/mm 18 to 26
(psi) (2,610 to 3,770)
Aluminum (etched) N/mm 11 to 19
(psi) (1,595 to 2,755)
Zinc dichromate N/mm 6 to 10
(psi) (870 to 1,450)
ABS N/mm 4 to 8
(psi) (580 to 1,160)
PVC N/mm 4 to 8
(psi) (580 to 1,160)
Polycarbonate N/mm 3.5 to 8
(psi) (508 to 1,160)
Phenolic N/mm 5 to 15
(psi) (725 to 2,175)
Neoprene N/mm 5 to 15
(psi) (725 to 2,175)
Nitrile N/mm 5 to 15
(psi) (725 to 2,175)
After 2 minutes @22 C
Lap Shear Strength, SO 4587:
Steel (grit blasted) N/mm <5.2
LMS
(psi) (<755)
After 10 seconds at @22 C
Tensile Strength, SO 6922:
Buna-N N/mm <6.9
LMS
(psi) (<1,000)
TYPICAL ENVIRONMENTAL RESISTANCE
After 1 week @22 C
Lap Shear Strength, SO 4587:
Mild steel (grit blasted)
Hot Strength
Tested at temperature
%

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C
Temperature, C
100
75
50
25
0
0 50 100 150
Heat Aging
Aged at temperature indicated and tested @22 C

%

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C
Exposure Time, hours
100
75
50
25
0
0 1000 2000 3000 4000 5000
80 C
100 C
60C
ChemicaI/SoIvent Resistance
Aged under conditions indicated and tested @22 C.
% of initiaI strength
Environment C 100 h 500 h 1000 h
Motor oil (ML-L-46152) 40 95 95 95
Gasoline 22 100 100 100
Water/glycol 50/50 22 100 100 100
Ethanol 22 100 100 100
sopropanol 22 100 100 95
Freon TA 22 100 100 100

GENERAL INFORMATION
This product is not recommended for use in pure oxygen
and/or oxygen rich systems and shouId not be seIected as
a seaIant for chIorine or other strong oxidizing materiaIs.
For safe handIing information on this product, consuIt the
MateriaI Safety Data Sheet (MSDS).
Directions for use
1. For best performance bond surfaces should be clean and
free from grease.
2. This product performs best in thin bond gaps (0.05 mm).
3. Excess adhesive can be dissolved with Loctite cleanup
solvents, nitromethane or acetone.
Loctite MateriaI Specification
LMS
LMS dated September-23, 1998. Test reports for each batch
are available for the indicated properties. LMS test reports
include selected QC test parameters considered appropriate to
specifications for customer use. Additionally, comprehensive
controls are in place to assure product quality and
consistency. Special customer specification requirements may
be coordinated through Henkel Quality.
Storage
Store product in the unopened container in a dry location.
Storage information may be indicated on the product container
labeling.
OptimaI Storage: 2 C to 8 C. Storage beIow 2 C or
greater than 8 C can adverseIy affect product properties.
Material removed from containers may be contaminated during
use. Do not return product to the original container. Henkel
Corporation cannot assume responsibility for product which
has been contaminated or stored under conditions other than
those previously indicated. f additional information is required,
please contact your local Technical Service Center or
Customer Service Representative.
Henkel Loctite Americas
+860.571.5100
Henkel Loctite Europe
+49.89.9268.0
Henkel Loctite Asia Pacific
+81.45.758.1810
For the most direct access to IocaI saIes and technicaI support visit: www.Ioctite.com
TDS LOCTTE

4471, January-2007
Conversions
(C x 1.8) + 32 = F
kV/mm x 25.4 = V/mil
mm / 25.4 = inches
m / 25.4 = mil
N x 0.225 = lb
N/mm x 5.71 = lb/in
N/mm x 145 = psi
MPa x 145 = psi
Nm x 8.851 = lbin
Nm x 0.738 = lbft
Nmm x 0.142 = ozin
mPas = cP
Note
The data contained herein are furnished for information only
and are believed to be reliable. We cannot assume
responsibility for the results obtained by others over whose
methods we have no control. t is the user's responsibility to
determine suitability for the user's purpose of any production
methods mentioned herein and to adopt such precautions as
may be advisable for the protection of property and of persons
against any hazards that may be involved in the handling and
use thereof. n light of the foregoing, HenkeI Corporation
specificaIIy discIaims aII warranties expressed or impIied,
incIuding warranties of merchantabiIity or fitness for a
particuIar purpose, arising from saIe or use of HenkeI
Corporation's products. HenkeI Corporation specificaIIy
discIaims any IiabiIity for consequentiaI or incidentaI
damages of any kind, incIuding Iost profits. The discussion
herein of various processes or compositions is not to be
interpreted as representation that they are free from
domination of patents owned by others or as a license under
any Henkel Corporation patents that may cover such
processes or compositions. We recommend that each
prospective user test his proposed application before repetitive
use, using this data as a guide. This product may be covered
by one or more United States or foreign patents or patent
applications.
Trademark usage
Except as otherwise noted, all trademarks in this document
are trademarks of Henkel Corporation in the U.S. and
elsewhere.

denotes a trademark registered in the U.S.

Patent and Trademark Office.

Reference 4
Henkel Loctite Americas
+860.571.5100
Henkel Loctite Europe
+49.89.9268.0
Henkel Loctite Asia Pacific
+81.45.758.1810
For the most direct access to IocaI saIes and technicaI support visit: www.Ioctite.com