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B + X K3
→S Where X is the unstable intermediate compound,
a) Derive an expression for rate of disappearance of A
b) Explain how the rate constants can be evaluated using the rate low.
4. Pure gaseous reactant A with CAo = 100 millimole/liter is fed at steady rate into a
mixed reactor, where it dimerizes, 2 A R with rate equation,
-rA = 2 (liter/m.m.hr) CA2 . 60 % conversion takes place in this reactor, all else
remaining unchanged. What will be the conversion if this reactor is changed
with,(i) mixed reactor, 5 times as large (ii) plug flow reactor of equal size.
6. The following multiple reaction scheme is taking place in a steady state PFR
K1 K 3
R
A B
K4
K2 S
If the desired product is B, calculate the optimal residence time to yield maximum
of CB. Also find CB max value,
Date : CAO = 50 CBO = 5.0 CRO = 0 CSO = 0K mole
m3
K1 = 2.0 K2 = 1.0 K3 = 0.2 K4 = 0.6 hr-1
8. Write short notes on (a) Batch and flow reactors (b) Law of mass action.
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Code No: 320802 Set No.
2.a) Calculate the expansion factor for the reaction A 4R with 30% inert present
in the feed. Derive the equation you use for calculating expansion factor.
b) Sketch the energies involved in the transformation of reactants to products in an
elementary reaction.
c) An elementary vapour phase homogeneous reaction 2A R is carried out under
isothermal and isobaric condition. The reaction mixture initially contains 80% of
A and 20 % of inerts. Calculate the % volume charge of reaction mixture for
50% conversion of A.
A+B X
K2
A + X K3
→R
For the reaction 2A + B R, show that the rate of formation is one half of the
rate of disappearance of A.
Contd..2
Code No:320802 -2- Set No.2
8. Write brief notes on (a) Series and parallel reactions (b) Multiple reactor network.
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Code No: 320802 Set No.
Contd..2
Code No:320802 -2- Set No.3
a) What are the fractional yield expressions φ(R/A) and φ(R/B) for this system.
b) How should we operate a mixed reactor so as to maximize the production
of R from a single feed consisting CAO = CBO = 1 mol/lit.
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Code No: 320802 Set No.
III B.Tech. II-Semester Supplementary Examinations, November-2003
CHEMICAL REACTION ENGINEERING -I
(Chemical Engineering )
4
Time: 3hours Max.Marks:80
Answer any FIVE questions
All questions carry equal marks
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1. The following multiple chemical reactions occur in the reduction of carbon
C(s)+2H2(g)⇄ CH4(g) ; KP1 =0.132 and C(s)+CO2(g)⇄2CO(g) ; KP2 =1.072
The feed consists of 70% hydrogen and 30% carbon monoxide, and the reactions
occur at 700°C temperature and 1atm. pressure. Calculate the equilibrium
composition
suggested is A + B S+X
K2
K1
B+X S+Y
K2
B + Y → K5
R+S
a) Derive the rate law Show how the rate law transforms when each of the
mechanism steps controls the rate.
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