ANDHERI / VILEPARLE / DADAR/CHEMBUR/THANE/CHURCHGATE/NERUL/MIRA ROAD, Tel: 2624 5209/ 2624 5223

INORGANIC CHEMISTR
1. Furnaces are lined with calcium oxide because (A) It gives off oxygen on heating (B) It gives light on heating (C) It is refractory and basic ( ) It is not affected by acids "resence of small im#urities usually ma$es a metal %uite hard because the im#urities (A) Change the lattice structure of metal (B) &educe the number of slide #lanes (C) &educe the number of mobile electrons ( ) &educe the crystal symmetry Crystalline metal can be transformed into metallic glass by (A) Alloying (B) "ressing into thin #lates (C) (low cooling of molten metal ( ) )ery ra#id cooling of a s#ray of the molten metal +he salt which is least li$ely to be found in mineral is (A) Chloride (B) (ul#hate (C) (ul#hide ( ) ,itrate +he metal that cannot be obtained by electrolysis of the a%ueous solution of their salts is (A) Ag (B) .g (C) Cu ( ) Cr +he metal obtained by self reduction #rocess is (A) Cu (B) 0g (C) "b ( ) All the above +he incorrect statement is (A) Calamine and siderite are carbonates (B) Argentite and cu#rites are oxides (C) 2n blende and iron #yrites are sul#hates ( ) .alachite and a3urite are ores of Cu "urest form of the iron is (A) Cast iron (C) (tainless steel (B) 0ard steel ( ) 5rought iron !.

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1.

4.

6.

5hich #rocess is not used in #urification of bauxite (A) 0all7s method (B) bauxite7s method (C) (er#e$s method ( ) Fran$lands method Iron obtained from blast furnace is $nown as (A) (teel (B) Cast iron (C) 5rought iron ( ) "ig iron +he #rocess of calcination and roasting are carried out in (A) Blast furnace (B) .uffle furnace (C) &everbaratory furnace ( ) 9#en hearth furnace 9xidation method is used for refining of (A) "b (B) Cu

18.

11.

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(C) .g 1'.

( ) All the above

In solid hydrogen: the intermolecular bonding is (A) Ionic (B) vander 5aals forces (C) .etallic ( ) Covalent 0!9! converts #otassium ferrocynide to ferricyanide. +he change observed in the oxidation state of iron is (A) Fe!; Fe'; (B) Fe Fe!; (C) Fe'; Fe!; ( ) Fe!; Fe; Among the following: which has minimum solubility in water (A) <90 (B) Cs90 (C) =i90 ( ) &b90 (odium thiosul#hate is formed when (A) ,a90 is neutralised by 0!(9* (C) ,a!(9' is boiled with ,a!( and I! +he com#ound insoluble in acetic acid is (A) Calcium oxide (C) Calcium hydroxide (B) ,a!( is boiled with ( ( ) ,a!(9* is boiled with ,a!( (B) Calcium carbonate ( ) Calcium oxalate

1*.

1-.

1/.

11.

14.

Bleaching action of bleaching #owder is due to the formation of (A) CaCl! (B) Ca(9* (C) 09Cl ( ) Ca(Cl9')! 5hich statement is correct for al$aline earth metals (A) +hey are diatomic and form ions of the ty#e .!> (B) +hey are highly electronegative elements (C) +hey are monoatomic and form ions of the ty#e .!; ( ) +hey are diatomic and form ions of the ty#e .!; B > 0 > B bridge in B!0/ is formed by the sharing of (A) ! electrons (B) * electrons (C) 1 electron ( ) ' electrons An element & is in grou# 1'. 5hich is true with res#ect to & (A) It is a gas at room tem#erature (B) It has an oxidation number ; * (C) It forms an oxide of the ty#e &!9' ( ) It forms a halide of the ty#e &?! 5hich halide is least stable and has a doubtful existence (A) Cl* (B) @el* (C) (nl* 5hich is neutral to litmus (A) 2n9 (C) C9 (B) (n9 ( ) (i9 ( ) "bI*

16.

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5hich is correct statementA (A) ,itric oxide is isoelectrobnic with C9! (B) ,itric oxide is diamagnetic (C) ,itric oxide is an endothermic com#ound ( ) ,itric oxide gas is used as general anaesthetic I! on rubbing with li%uor ,0' forms with ex#losion (A) ,0*I (B) ,!

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(C) ,0*I ; ,! ; I! !/. !1. +here is no ( > ( bond in (A) (!9*!> (C) (!9'!> &eagent used to distinguish 0!9! and 9' is (A) "b( (C) <.n9*

( ) ,I',0! (B) (*9/!> ( ) (!91!> (B) (tarch and iodine ( ) Bleaching #owder

!4.

Bromine can be liberated from #otassium bromide solution by (A) Iodine solution (B) Chlorine solution (C) (odium chloride ( ) "otassium iodide "aramagnetic s#ecies is (A) Cl!9 (C) Cl!91 In the dichromate anion (A) * Cr > 9 bonds are e%uivalent (C) All Cr > 9 bonds are e%uivalent (B) Cl9! ( ) Cl!9/ (B) / Cr > 9 bonds are e%uivalent ( ) All Cr > 9 bonds are nonBe%uivalent

!6.

'8.

'1.

.n 1; involves twoC. and five C. electrons in bond formation (A) 'd: *s (B) *s: 'd (C) *f: 'd ( ) 'd: *f Ammonium dichromate is used in some fire wor$s. +he green coloured #owder blow in air is (A) Cr9' (B) Cr!9' (C) Cr ( ) Cr9(9!) An a%ueous solution of Fe(9*.Al!((9*)' and chrome alum is heated with excess of ,a !9! and filtered. +he materials obtained are (A) A colourless filtrate and a green residue (B) A yellow filtrate and a brown residue (C) A yellow filtrate and a green residue ( ) A green filtrate and a brown residue 5hich of the following has maximum number of un#aired electronsA (A) Fe'; (B) Fe!; !; (C) Co ( ) Co'; 2inc forms basic 3inc acetate (C0 'C99)/2n*9. +he number of C0'C99> ions lin$ed with each 2n atoms are (A) ! (B) ' (C) * ( )/ 9xidation state of #latinum in 9!D"tF/E is (A) ;4 (C) ; / 9uter orbital com#lex is (A) D2n(,0')*E!; (C) DCr(,0')/E'; (B) ;( ) ;1

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(B) DCo(,0')/E'; ( ) DCoF/E'>

'4.

+he number of dBelectrons in DCr(0!9)/E'; is (A) ! (B) ' (C) * ( )0ow many un#aired electrons does the manganese have in D.n(C,)/E*> (A) 1 (B) !

'6.

(C) ' *8. *1.

( )-

5hich of the following does not have tetrahedral structureA (A) Cr9*!> (B) D,i(C,)*E!> (C) D,i(C9)/E ( ) D,iCl*E!> +he reagents ,0*Cl and a%ueous ,0' will #reci#itate (A) Ca!; (B) Al'; (C) .g!; ( ) 2n!; Fe(90)' can be se#arated from Al(90)' by addition of (A) dil. 0Cl (B) ,aCl solution (C) ,a90 solution ( ) ,0*Cl and ,0*90 A yellow #reci#itate obtained in II grou# of the %ualitative analysis was soluble in a%. ,a90 and insoluble in dil. 0,9'. +his shows the #resence of (A) +in (B) Antimony (C) Arsenic ( ) Cadmium 5hich #air would be ex#ected to from #reci#itate when solutions are mixedA (A) <;(9*!> (B) ,a;(!> ; > (C) Ag ,9' ( ) Al';90> A solution of a chemical com#ound ? reacts with Ag,9 ' solution to form a white #reci#itate of F which dissolves in ,0*90 to give a com#lex 2. 5hen 2 is treated with dil. 0,9 ': F rea##ears. +he chemical com#ound ? would be (A) ,aCl (B) ,aBr (C) C0'Cl ( ) ,aI A salt with gives violet va#ours on heating with conc. 0!(9* is (A) A sul#hate (B) A bromide (C) An iodide ( ) A nitrate 5hich of the following anions is not easily removed from a%ueous solutions by #reci#itation (A) Cl> (B) (9*!> > (C) ,9' ( ) C9'!> =ead has been #laced in %ualitative grou# analysis in 1st and !nd grou# because (A) It shows the valency one and two (B) It forms insoluble "bCl! (C) It forms lead sul#hate ( ) It is #artly soluble in water A white salt soluble in ,0*90 but insoluble in water is (A) Ba(9* (B) CaC9' (C) "b(9* ( ) AgCl 5hich one of the following combines with Fe!;to form brown com#lex (A) ,!9 (B) ,9 (C) ,!9' ( ) ,!9-

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ANS!ERS
1. '. -. 1. 6. 11. 1'. 1-. 11. 16. !1. !'. !-. !1. !6. '1. ''. '-. '1. '6. *1. *'. *-. *1. *6 C D B B D C B C D C C C C C B B C B D A B C A C D !. *. /. 4. 18. 1!. 1*. 1/. 14. !8. !!. !*. !/. !4. '8. '!. '*. '/. '4. *8. *!. **. */. *4. -8. B D D D C D A C C A D C D B B B A B B B C D C D B

HINTS " SOLUTION

1/. !!. !-. '8. ,a!( ; I! ; ,a!(9' ,a!(!9' ; !,aI "b;; is strong oxidant: I> is strong reductant hence can7t exist 9n rubbing li%uid ,0' with I! flac$es: a dar$ brown ##t. of ammoniated nitrogen iodide ,0'.,I' is obtained which decom#oses %uic$ly on drying into ,0*I ; I! ; ,! 4,I'.,0' -,! ; 6I! ; /,0*I
!>

9>

>9>

>9

!1. !4. '8.

0!9! decolourises <.n9* but 9' does not Cl! ; !<Br !<Cl ; Br! 9
148 #m

9 Cr

9 9 9

9 9 '!. '*. '-.

Ac

Cr
1/1 #m

(,0*)!Cr!91 G ,! ; *0!9 ; Cr!9' Fe'; is having -Bu#aired electron

2n Ac Ac 2n Ac 2n 9 Ac Ac 2n
Ac acetate

'1. *!. *'. */. *1. *4. *6. -8.

Fluoride is a wea$ ligand Al(90)' will dissolve in excess of ,a90 ,aCl ; Ag,9' AgCl ; ,a,9' )iolet va#ours of iodine is liberated Almost all the nitrates are water soluble "bCl! and "b( both forms #reci#itate 5ith ,0*; silver ion forms com#lex. Fe(9* ; ,9 Fe(9*.,9 (brown)