Documente Academic
Documente Profesional
Documente Cultură
N
G
I
N
D
U
S
T
R
Y
|
M
a
y
/
J
u
n
e
2
0
1
3
w
w
w
.
e
n
e
r
g
y
g
l
o
b
a
l
.
c
o
m
May / June 2013
LNG_MayJune_2013_OFC.indd 1 21/05/2013 12:50
www.fmctechnologies.com
Copyright FMC Technologies, Inc. All Rights Reserved.
FMC Technologies invented the rst ofshore LNG loading technology. Today we are
developing new solutions built on proven components. Our Articulated Tandem Ofshore
Loader (ATOL) safely performs high-velocity LNG transfers in severe conditions with
waves up to 18 feet (5.5 meters). Our Ofshore Loading Arm Footless (OLAF) side by
side transfer solution accommodates massive new FLNG freeboards in the range of
82 feet (25 meters). And for tomorrow? Were practically there already.
Meeting
challenges
you havent even thought of yet.
LNG_MayJune_2013_IFC.indd 1 21/05/2013 12:58
LNG Industry is audited by the Audit Bureau of Circulations (ABC).
An audit certificate is available on request from our sales department.
Copyright Palladian Publications Ltd 2013. All rights reserved. No part of this publication may be reproduced,
stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying,
recording or otherwise, without the prior permission of the copyright owner. All views expressed in this journal are
those of the respective contributors and are not necessarily the opinions of the publisher, neither do the publishers
endorse any of the claims made in the articles or the advertisements. Printed in the UK.
CONTENTS
ISSN 1747-1826
O
N
T
H
I
S
M
O
N
T
H
S
C
O
V
E
R
L
N
G
IN
D
U
S
T
R
Y
|
M
/J
2
0
1
3
ener
lo
balco
m
May / June 2013
LNG MayJune 2013 OFC indd 1 21/05/2013 12:50
LNGs LNG s
European core
David Stokes and Oliver Spinks,
Timera Energy, UK, examine
European LNG dynamics in the
context of the global gas market.
MAY/JUN 2013 LNGINDUSTRY 11
T
he global LNGmarket is entering a period of rapid
evolution. Market growth is being driven by a structural
shift towards natural gas as a cleaner fuel, as well as an
increase in gas import dependence in Asia and Europe. In order to
meet this increase in demand, global liquefaction capacity may
need to double by 2030, requiring an estimated US$ 1 trillion of
newinvestment. At the same time, pronounced inter-regional
price differentials and improvements in gas hub liquidity have
been a catalyst for LNGcontract re-negotiation and growth in the
shorter termtrading of cargoes.
Europe will play a central role in shaping this growth phase in
the LNGmarket. In turn, LNGpricing and flows are becoming
increasingly important drivers of the European gas market.
European gas suppliers are diversifying portfolios of pipeline gas
supply to include contracted LNGand access to regasification
capacity. As a result, LNGhas become a key source of
incremental supply into European gas portfolios. LNGimport
volumes are still lowrelative to pipeline imports, but they have a
disproportionate influence on marginal pricing at European gas
hubs.
However, Europe cannot be considered in isolation. In order
to understand European LNGdynamics it is important to take a
step back and consider Europe in a global gas market context.
European interaction with the
global gas market
The global LNGmarket is still in a stage of relative infancy. Only
about 10%of global gas consumption is currently satisfied by
LNG, and only a relatively small volume of LNGsupply has the
contractual flexibility to respond optimally to price dynamics.
The constraints around supply flexibility are reflected in the
current regional price divergence across Asia (tight market
post Fukushima), Europe (broadly tracking oil-indexed contract
MAY/ JUN
2013
10
16 Sea change
Nick Prowse, Scott McCabe and Rod Chooramun,
Norton Rose, look at trends in the LNG shipping industry.
19 Unlocking markets
Cyril Widdershoven and Bas van den Beemt, TNO, the
Netherlands, explain why technical-economic cooperation
is needed between European organisations and Arab gas
producers to kick-start small scale LNG markets in the
Middle East.
22 Jumping the hurdles
Jrgen Harperscheidt, TGE Marine Gas Engineering,
Germany, looks at the technical issues facing LNG bunkering.
29 Membrane market
Julie Sakhrai, Lorenz Claes, Stphane Maillard and
Thomas Crmire, GTT (Gaztransport & Technigaz), France,
describe the benefits of using membrane systems along the
LNG chain.
33 From flare to fuel
David A. Franklin, WorleyParsons, USA, establishes the case
for mini-LNG.
39 Flexible processing
Rebecca Liebert, UOP, a Honeywell Company, provides a
guide to selecting appropriate gas processing technologies.
45 Packing for CO
2
removal
Ralph H. Weiland and Nathan A. Hatcher, Optimized Gas
Treating, Inc. and Jenny Seagraves, INEOS Oxide, USA,
discuss the benefits of choosing the right packing for
absorbers and regenerators in a gas processing facility.
53 Mercury rising
John Markovs, Adsorption Solutions LLC, USA, and
Robert W. Soffel, Selective Adsorption Associates Inc., USA,
examine solutions to mercury problems in LNG plants.
57 The cryogenic challenge
Barry Wilder, Severn Glocon, UK, looks at how to maximise
cryogenic control valve performance.
61 Take the weight off
Femke Schaefer, Bronswerk Heat Transfer, the Netherlands,
looks at size, weight and power reduction of process
equipment in LNG liquefaction and regasification.
64 Good vibrations
Israel Ferreres, Cryoperl Australia Pty Ltd, Australia, outlines
the benefits of vibration prior to operation.
69 Detuning plants
Attilio Brighenti, Systems and Advanced Technologies
Engineering S.r.l. (S.A.T.E.), Italy, and Luigino Vitali, SAIPEM,
Italy, discuss how riser singing generated by inner wall
turbulence of flexible risers can be a severe problem for LNG
offloading and regasification plants.
74 Pulling out the stops
Alfred Hbner, Ultratug, Chile, explains the beginning of LNG
terminal services in Chile and how this has impacted the local
market.
79 Maintaining tension
Blaine Dempke, Markey Machinery Company Inc., USA,
discusses new winch technology that helps to improve tanker
transit safety.
83 Predicting the weather
Olivier Gorieu and Max Nussbaum, GDFSUEZLNG, France,
and Dr Christophe Messager, Extreme Weather Expertises,
France, look at extreme weather conditions generated by
Mesoscale Convective Systems over the Cameroon LNG
production site.
03 Comment
05 LNG news
10 LNGs European core
David Stokes and Oliver Spinks, Timera Energy, UK, examine
European LNG dynamics in the context of the global gas
market.
Qatargas, established
in 1984, pioneered
the LNG industry in
Qatar. Today, Qatargas
is the largest LNG
producing company in
the world, with an LNG
production capacity
of 42 million tpy. It is
through our operating
excellence and our
innovation in global
energy that we are
safely and reliably
delivering LNG to our
customers around the
globe.
LNG_MayJune_2013_01-02.indd 1 23/05/2013 15:02
1
2
1
9
_
e
Whatever the impurity, whatever the composition, Air Liquide Global E&C Solutions
has the right treatment.
, ' _ ' ,_
'
The composition of natural gas varies
tremendously: almost every source
contains a diferent blend of impurities.
The options for treatment are almost
as diverse. That's why ofering a solution
specifcally designed for your gas feld
is crucial. We as your partner of choice
provide solutions for all types of natural gas,
including associated and unconventional
gas, from a single source. Customised
and em cient.
Come and visit us at:
MIOGE 2013, 25 - 28 June
in Moscow, Russia
Pavilion 1 | Booth A 524
www.engineering-solutions.airliquide.com
LNG_MayJune_2013_01-02.indd 2 23/05/2013 12:06
COMMENT
CALLUM OREILLY EDITOR
C
O
N
T
A
C
T
I
N
F
O
R
M
A
T
I
O
N
Managing Editor
James Little
james.little@lngindustry.com
Editor
Callum OReilly
callum.oreilly@lngindustry.com
Editorial Assistant
Peter Farrell
peter.farrell@lngindustry.com
Advertisement Director
Rod Hardy
rod.hardy@lngindustry.com
Advertisement Manager, USA/Canada
Chris Atkin
chris.atkin@lngindustry.com
Advertisement Manager, EMEA
John Baughen
john.baughen@lngindustry.com
Editorial/Advertisement Offices, Palladian Publications Ltd, 15 South Street, Farnham, Surrey, GU9 7QU, ENGLAND,
Tel: +44 (0) 1252 718 999 Fax: +44 (0) 1252 718 992 Website: www.energyglobal.com
Production
Stephen North
stephen.north@lngindustry.com
Website Editor
Callum OReilly
callum.oreilly@energyglobal.com
Circulation Manager
Vicki McConnell
victoria.mcconnell@lngindustry.com
Subscriptions
Laura Cowell
laura.cowell@lngindustry.com
Reprint / Marketing Assistant
Catherine Gower
catherine.gower@lngindustry.com
Publisher
Nigel Hardy
LNG Industry Subscription rates:
Annual subscription: 50 UK including postage
60/d85 overseas (postage airmail)
US$ 85 USA/Canada (postage airmail).
Two year discounted rate: 80 UK including postage
96/d136 overseas (postage airmail)
US$ 136 USA/Canada (postage airmail).
Subscription claims:
Claims for non receipt of issues must be made within
3 months of publication of the issue
or they will not be honoured without charge.
Applicable only to USA & Canada.
LNG INDUSTRY (ISSN No: 1747-1826, USPS No: 006-760) is published six
times per year: February, April, June, August, October and December, by
Palladian Publications and is distributed in the USA by by SPP, 17B S Middlesex
Ave, Monroe NJ 08831. Periodicals postage paid at New Brunswick, NJ.
POSTMASTER: send address changes to LNG INDUSTRY, 17B S Middlesex
Ave, Monroe NJ 08831.
Uncaptioned Images courtesy of www.bigstockphoto.com
S
mall scale LNG was one of the big talking points at this
years LNG 17 Conference in Houston, Texas. In addition
to hosting its own conference session, the topic of LNG
as a transportation fuel was also creating quite a stir in the
exhibition hall. The LNG for transport exhibit pavilion was
bursting to the brim for each of the 20+ presentations that
took place over the three day seminar programme, and the
exhibition floor was full of companies showcasing their latest
technology to meet this rapidly developing sector of the
industry.
Previously, I have written comments alluding to LNG fuel
as the industrys next big thing, and recent developments
would appear to support this line of thought. In the last few
months, several major proponents of this market have started
to aggressively pursue infrastructure development.
In April, Royal Dutch Shell finalised an agreement with
TravelCenters of America (TA) to develop a network of LNG
fuelling stations across the US for heavy-duty road transport
customers. The proposed plans will see the construction of at
least two LNG fuelling lanes and a storage facility at up to 100
existing TA and Petro stopping centres. Shell had previously
announced that it is to invest in two small scale LNG
production units that will form the basis of two LNG transport
corridors in the Great Lakes and Gulf Coast regions. In addition
to this, the company is also developing LNG stations at
Flying J truck stops in Alberta, Canada, and it will charter the
worlds first inland barges that run solely on LNG, set to sail on
the Rhine later this year.
Chinas ENN Group has also put in place plans to establish
a network of natural gas fuelling stations for trucks across the
US. The group has partnered with Utah-based CH4 Energy to
form Transfuels LLC, which operates as Blu LNG. It is reported
that the company will build around 50 natural gas filling
stations this year, roughly equal to the number of stations that
Clean Energy Fuels Corp. is expected to open.
On the tracks, BNSF Railway recently announced that it is
to begin testing a number of locomotives using LNG later this
year, with its Chief Executive, Matthew Rose, describing the
use of LNG as a fuel as a potential transformational change
for [the] industry.
The two main drivers for this recent flurry of activity are
cost and the environment. The abundance of natural gas in
North America has driven prices to ten-year lows, and LNG has
the potential to significantly reduce greenhouse gas emissions.
This latter point is particularly important for the marine
industry, with ship owners in Europe and North America under
pressure to comply with strict emission regulations due to
come into force in 2015. The European Commission has also
put aside 2.1 billion to equip 139 seaports and inland ports
with LNG bunker stations by 2025, as part of the EUs new
clean fuels strategy.
There are, of course, some daunting hurdles to overcome
before this market can really take-off, not least the cost of
building the required infrastructure. However, it seems that the
potential benefits are encouraging companies to push forward
with their strategies ahead of the market, as they attempt to
knock down these hurdles.
This issue of LNG Industry takes a closer look at the topic
of LNG as a transportation fuel, with particular focus on the
marine industry. You can also keep up to date with the latest
developments in this burgeoning market via our website:
www.energyglobal.com.
LNG_MayJune_2013_03-04.indd 3 23/05/2013 15:07
versalis chemistry to evolve
versalis the new face of chemicals
versalis teams up with you over the ever-expanding challenges around the industry.
we stand by you in driving innovative solutions with marketable end alongside
a timely advantage. at versalis we believe that excellence goes beyond delivery;
it reaches out to after-sale assistance.
O 1306 210 297 LNG I d t i i dd 1 22/04/13 11 49
LNG_MayJune_2013_03-04.indd 4 23/05/2013 12:09
LNGNEWS
MAY/JUN 2013 LNGINDUSTRY 5
USA
Freeport LNG receives DOE export approval
T
he Energy Department has conditionally authorised
Freeport LNG Expansion, L.P. and FLNG Liquefaction,
LLC (Freeport) to export domestically produced LNG
to countries that do not have a Free Trade Agreement
(FTA) with the US from the Freeport LNG terminal on
Quintana Island, Texas. Freeport previously received
approval to export LNG from this facility to FTA countries
in February 2011.
Subject to environmental review and final regulatory
approval, the facility is conditionally authorised to
export at a rate of up to 1.4 billion ft
3
/d of natural gas
for a period of 20 years. The Department granted the
first authorisation to export LNG to non-FTA countries in
May 2011 for the Sabine Pass LNG terminal in Cameron
Parish, Louisiana at a rate of up to 2.2 billion ft
3
/d.
Michael S. Smith, Chief Executive Officer of Freeport
LNG, welcomed the news: We applaud the DOE on its
thorough and balanced analysis of the public benefits
of LNG exports to the United States. The overwhelming
evidence in favour of LNG exports generated during the
DOEs two-and-a-half year review, definitively confirms
that the DOE should act swiftly to approve additional
pending LNG export applications.
UK
South Hook Gas welcomes the arrival of its 300
th
cargo
S
outh Hook Gas has cemented its position as the UKs
largest LNG terminal shipper with the arrival and safe
off-loading of its 300
th
cargo. The Umm Slal recently sailed
from the South Hook LNG terminal in Milford Haven.
Sheikh Saoud Al-Thani, South Hook Gas Company
Chairman, said: The arrival of LNG has transformed gas
supply to the UK as it can now access supplies from all
over the world and this has improved energy security.
The arrival of our 300
th
cargo demonstrates our long-term
commitment to the UK.
As a Q-Max vessel, the Umm Slal is one of the biggest
LNG vessels in the world, and can provide enough gas to
meet Londons needs for a week.
South Hook Gas has supplied gas every day since
commencing operations and can supply around 20% of the
UKs gas needs.
Uruguay
GDF SUEZ wins regas terminal contract
G
DF SUEZ has been awarded the contract to build an
LNG regasification terminal in the port of Montevideo
by the government of Uruguay, at an estimated cost of
US$ 1.125 billion. The terminal will have a processing capacity
of up to 10 million m
3
/d of LNG.
The LNG project will consist of a floating LNG regasification
vessel and will also include construction of a breakwater and
works to connect the vessel to Uruguays domestic network of
gas pipelines.
Meanwhile, GDF SUEZ has also entered into a joint venture
agreement with Sempra Energy, Mitsubishi and Mitsui to develop,
finance and build the Cameron LNG liquefaction plant in Louisiana,
Texas, USA. Mitsubishi, Mitsui and GDFSUEZ will all have a 16.6%
equity stake, while Sempra Energy will retain a 50.2% stake.
GDF SUEZ already signed a 20-year liquefaction supply
agreement for 4 million tpy of LNG with Sempra last year and
the three minority stakeholders have collectively subscribed
the full capacity of the three-train facility.
The joint venture agreements are subject to a final
investment decision by each party, to final permit
authorisations, and to securing financing commitments, all
of which are expected by early 2014. The new LNG plant is
expected to start operations in late 2017.
LNG_MayJune_2013_05-09.indd 5 24/05/2013 09:12
LNGNEWS
6 LNGINDUSTRY MAY/JUN 2013
N
E
W
S
H
I
G
H
L
I
G
H
T
S
Scan for the
Energy Global
iPhone/ iPad App
To read more
about these
stories go to:
Get the free mobile app at
http:/ / gettag.mobi
USA
Golden Pass affiliates sign Commercial
Framework Agreement for exports
G
olden Pass Products LLC (GPP) shareholders affiliates
Qatar Petroleum International (QPI) and ExxonMobil
have signed a Commercial Framework Agreement for the
proposed liquefaction project at the Golden Pass LNG
facility.
This agreement establishes the commercial framework
to sell the 16.5 million tpy output of LNG from the facility.
This agreement sets out a highly competitive
commercial blueprint for Golden Pass Products, with a
commitment that builds on the unique combined strengths
of QPI and ExxonMobil throughout the global downstream
LNG value chain, said Bill Collins, president of Golden
Pass Products.
Golden Pass products plans to invest approximately
US$10billion to build the liquefaction facility. The
company has already received US DOE authorisation for
exports to Free Trade Agreement (FTA) countries, and is
awaiting DOE approval to export to non-FTA countries.
Clean Air Power welcomes Gasrecs Bio-LNG station
FMC chooses RINA technology qualification
Approve remaining LNG export permits, urges API
Australia
Severn Glocon wins Ichthys contract
C
ontrol valve specialist Severn Glocon has been awarded
the contract to supply 536 engineered control valves
for the processing plant on the Ichthys project onshore LNG
facilities. Included in the contract are cryogenic valves of up
to 42 in. bore, weighing around 20 t, as well as valves with
pressure ratings of up to 2500 ANSI.
This is the largest and one of the most technically
challenging contracts in the firms 50 year history. The valves
will deal with volatile fluids at temperatures as low as -160 C,
and they need to handle extreme requirements surrounding
cryogenics, thermal dynamics and velocity control.
EPC activities for the project are being undertaken by
the JKC Australia LNG Pty Ltd (JKC). The project is now in the
construction phase and the first valves are being shipped.
Manufacture and supply of valves will continue into 2014.
The scope, scale and harsh demands of this project
command highly-engineered, technically advanced
hardware, says Roger Spiers, Commercial Manager at Severn
Glocon.
LNG_MayJune_2013_05-09.indd 6 23/05/2013 16:51
LNG_MayJune_2013_05-09.indd 7 23/05/2013 16:51
LNGNEWS
8 LNGINDUSTRY MAY/JUN 2013
D
I
A
R
Y
D
A
T
E
S
UK
Gasrec to open UKs first Bio-LNG filling station
G
asrec is opening the UKs first Bio-LNG filling station in
Daventry, which will store enough fuel to fill 700 HGVs a
day. Bio-LNG is Gasrecs proprietary blend of LNG and liquid
biomethane (LBM), which is produced from organic matter
such as household food waste. Gasrec is Europes largest
producer of this fuel.
Daventry is the first site identified by Gasrec as part of its
national Bio-LNG refuelling network planned to be up and
running by the end of 2015.
Transport Minister Norman Baker said: This
announcement represents a significant step towards
achieving carbon and air quality benefits and I am very
pleased that demonstration fleets from the Governments
Low Carbon Truck Demonstration Trial will be refuelling from
this site.
Compared with pure diesel equivalents, Bio-LNG can cut
fuel costs by 20 30% and CO
2
by a minimum of 20%, while
delivering a 90% reduction in NO
x
and particulate matter
emissions.
17 - 19 June 2013
Small-Mid Scale LNG Summit
Amsterdam, the Netherlands
www.smallmidlng.com
3 - 6 September 2013
SPE Offshore Europe 2013
Aberdeen, UK
www.offshore-europe.co.uk
24 - 26 September 2013
LNG Global Congress
London, UK
www.lnggc.com
30 September - 3 October
2013
Pump/Turbomachinery Symposia
Houston, Texas, USA
turbolab.tamu.edu/articles/
pump_turbomachinery_symposia
14 - 16 October 2013
LNG Tech Global Summit
Barcelona, Spain
www.lngsummit.com
18 - 21 November 2013
World LNG Summit
Paris, France
world.cwclng.com
USA
BPC reports on impact of US LNG exports
A
report by the Bipartisan Policy Center (BPC) has
concluded that LNG exports are unlikely to have a great
impact on domestic gas prices in the US.
Levels of LNG exports will be determined by the domestic
price of natural gas, costs for transportation and liquefaction,
and the price and level of demand for natural gas in target
foreign markets. One of the fundamental drivers in this
equation is the US price of natural gas, which will influence
LNG export levels far more than LNG exports will influence
domestic prices.
The BPC estimates LNG exports will range from
26.4billion ft
3
/d by 2030. These estimates take into
account the barriers facing LNG projects, including the high
cost of building facilities, liquefying and transporting natural
gas overseas, and finding US producers willing to enter into
long-term low price contracts. Overall, the US is projected to
become a net exporter of natural gas between 2017 and 2021.
LNG_MayJune_2013_05-09.indd 8 23/05/2013 16:51
LNG_MayJune_2013_05-09.indd 9 23/05/2013 16:51
LNGs LNG s
European core
David Stokes and Oliver Spinks,
Timera Energy, UK, examine
European LNG dynamics in the
context of the global gas market.
LNG_MayJune_2013_10-15.indd 10 20/05/2013 11:00
MAY/JUN 2013 LNGINDUSTRY 11
T
he global LNG market is entering a period of rapid
evolution. Market growth is being driven by a structural
shift towards natural gas as a cleaner fuel, as well as an
increase in gas import dependence in Asia and Europe. In order to
meet this increase in demand, global liquefaction capacity may
need to double by 2030, requiring an estimated US$ 1 trillion of
new investment. At the same time, pronounced inter-regional
price differentials and improvements in gas hub liquidity have
been a catalyst for LNG contract re-negotiation and growth in the
shorter term trading of cargoes.
Europe will play a central role in shaping this growth phase in
the LNG market. In turn, LNG pricing and flows are becoming
increasingly important drivers of the European gas market.
European gas suppliers are diversifying portfolios of pipeline gas
supply to include contracted LNG and access to regasification
capacity. As a result, LNG has become a key source of
incremental supply into European gas portfolios. LNG import
volumes are still low relative to pipeline imports, but they have a
disproportionate influence on marginal pricing at European gas
hubs.
However, Europe cannot be considered in isolation. In order
to understand European LNG dynamics it is important to take a
step back and consider Europe in a global gas market context.
European interaction with the
global gas market
The global LNG market is still in a stage of relative infancy. Only
about 10% of global gas consumption is currently satisfied by
LNG, and only a relatively small volume of LNG supply has the
contractual flexibility to respond optimally to price dynamics.
The constraints around supply flexibility are reflected in the
current regional price divergence across Asia (tight market
post Fukushima), Europe (broadly tracking oil-indexed contract
LNG_MayJune_2013_10-15.indd 11 20/05/2013 11:00
12 LNGINDUSTRY MAY/JUN 2013
supply) and the US (awash with unconventional domestic gas
production).
Only a decade ago the European gas market existed in
relative isolation. But growth in LNG flows and price arbitrage
have connected Europe with the gas markets of the US and Asia.
At the same time, the divergence of European gas hub prices
below oil-indexed contract prices has caused the rapid
development of hub liquidity and market price signals. These
factors have resulted in gas hub pricing becoming the key driver
of commercial decision making across European gas portfolios.
This is despite the fact that the majority of gas is still sourced via
long-term oil-indexed supply contracts.
Europe currently accounts for about 20% of global LNG
demand compared to 70% for Asia. But Europe punches above
its weight when it comes to its impact on global LNG pricing. The
interaction between the European and global gas markets is well
illustrated by looking at the evolution of global price benchmarks
over the last half decade, shown in Figure 1.
Price evolution over this period can be broadly split into three
phases:
Commodity super cycle (2007 2008): global gas prices
tracked oil prices through the boom/bust of the commodity
super cycle. At the same time, there was broad gas price
convergence across Europe, Asia and the US in line with
contract oil-indexation.
Global supply glut (2009 2010): the financial crisis, new
global liquefaction capacity and the US shale gas revolution
rapidly combined to create a global gas supply glut.
European gas hub prices fell below oil-indexed contract
prices as surplus LNG flowed into Europe, driving hub prices
down towards Henry Hub (HH) levels. Spot Asian LNG prices
were strongly influenced by the transport cost differential to
UK NBP.
Fukushima led divergence (2011 2013): a recovery in oil
prices, followed by aggressive Japanese buying of LNG
after the Fukushima disaster, opened up a substantial Asian
LNG price premium. European hub prices reconnected with
oil-indexed contract prices. This was helped by a reduction in
LNG flow into Europe as cargoes were diverted to Asia.
Europe lies in close proximity to the key producers in the
Middle East and Africa, so it is an attractive destination for LNG
sales, given relatively low transport costs. The supply of LNG into
Europe is also relatively flexible compared to Asian supply.
Location and supply flexibility mean that Europe plays an
important role in influencing the marginal pricing of LNG. Liquidity
at traded hubs, such as the UK NBP and Dutch TTF, provide key
price signals to the global gas market.
For the time being, US gas prices are in a world of their own
as robust domestic shale gas production flows into the HH spot
market. However, US and European gas prices are re-converging
on a forward basis, in anticipation of the ramp up of US LNG
exports from the middle of this decade and the potential for US
production costs to rise. The volume of US exports remains
subject to regulatory review, but liquefaction terminal developers
in the Gulf of Mexico are aggressively marketing HH indexed
supply contracts to European buyers. This should increase the
relationship between HH and European gas hub prices, but also
presents some key challenges for European LNG buyers as set
out in the following case study.
Case study: buying LNG supply
from a US exporter
A US export contract provides access to HH indexed gas. The
contract has the advantage of being a supply source that can be
managed (both physically and financially) against a liquid hub
and forward market. But contracting gas from a US exporter will
typically involve paying a premium to hub prices (e.g.115%HH)
as well as a capacity fee. So there is an important value
consideration in signing the contract. There is also an important
risk consideration since the contract involves buying gas on a
different price basis (HH) to European end user demand
(NBP/TTF), e.g. for power stations and retail load.
Contract value is driven by regional price spreads between
the US (HH), Europe (NBP/TTF) and Asia. This is in part a question
of the evolution of global gas market fundamentals. For example,
if the flow of gas out of the US
remains constrained by a lack of US
liquefaction capacity then the
transatlantic price spread (NBP minus
HH) may exceed the transport
differential for sustained periods (i.e.
access to HH gas has intrinsic value).
On the other hand, as US export
capacity becomes less constrained
the correlation between NBP and HH
should increase. But as well as
fundamental considerations there are
also specific portfolio value issues.
From the perspective of a
European supplier, HH indexation
offers a liquid/hedgeable alternative
to oil indexed supply, which can be
attractive if the supplier is constrained
in their ability to buy gas indexed to
NBP/TTF (i.e. the price basis for sale to
end users). A US export contract also
adds hedgeable hub based supply
flexibility to an LNG portfolio that can
unlock portfolio constraints; e.g.the
Figure 1. Key global gas price benchmarks (source: Timera Energy).
LNG_MayJune_2013_10-15.indd 12 23/05/2013 10:19
OIL-FREE . MAX MTBO
LABY
2
0
1
3
W
e
a
t
h
e
r
f
o
r
d
.
A
l
l
r
i
g
h
t
s
r
e
s
e
r
v
e
d
.
I
n
c
o
r
p
o
r
a
t
e
s
p
r
o
p
r
i
e
t
a
r
y
a
n
d
p
a
t
e
n
t
e
d
W
e
a
t
h
e
r
f
o
r
d
t
e
c
h
n
o
l
o
g
y
.
Drilling
Evaluation
Completion
Production
Intervention
Pipeline & Specialty Services
Precommissioning
Commissioning
Ha|ntenance
- Pigging
- Cleaning
- Inspection
- Surveying
- Repairs
- Clamps
Shutdowns
Decommissioning
Turn to Weatherford for all of your process pipe services, including:
Bund|ed services save you money, whi|e sing|e-source efciency
shortens project duration and avoids costly reworking.
Enjoy the convenience and advantages of having a single point of
contact and accountabilityalong with a single contract and invoice.
Weatherford offers complete solutions for process pipe service
projects of any size, anywhere in the world. A recent success in
Yemen reduced the original duration projection by 14 days.
For more information on this success or any of our services, email
pss@weatherford.com. To view our full line of Pipeline & Specialty
Services offerings, visit us online at weatherford.com/pss.
Bo|ting
Va|ve testing
Chemica| c|eaning
F|ange management
Nitrogen services
Hydrostatic testing
Pneumatic testing
He|ium |eak detection
Delivering Quality Under Pressure
SM
LNG_MayJune_2013_45-52.indd 49 21/05/2013 11:44
50 LNGINDUSTRY MAY/JUN 2013
mass transfer coefficients and, therefore, the same chemical
reactions affect mass transfer rates to different extents.
Table 1 describes the raw gas common to all the cases in
the study. The solvent was 50 wt% GAS/SPEC* CS-1160*
solvent flowing at 204 m
3
/h and 50 C. The regenerator
contained 13.7 m of type FLEXIPAK 3X structured packing in
all cases. The absorber contained 15.25 m of various crimp
sizes of FLEXIPAC structured packing as described above. In
all cases, both columns were sized for 70% flood regardless
of the packing. The regenerator was 1875 mm diameter
while the absorber ranged from 2825 mm diameter with the
finest packing (1X) to 1885 mm diameter with the coarsest
(4X). Reboiler duty was held constant at 13.5 MW and the
molar stripping ratio was typically 1.2 at the regenerator
overhead.
Table 2 is a synopsis of the simulated treating
performance with 15.25 m of each packing size. The lowest
size designation has the largest specific (dry) area and also
treats the gas to the lowest CO
2
level. Note that although
there is an inverse relationship between area and treated gas
CO
2
content (just as one should expect), it is anything but
inversely linear, treated gas quality is a very strong function
of dry area, i.e., packing size. As ever coarser packing is used,
the temperature bulge moves closer to the top of the
column. What may be surprising is that it also grows in size
until it starts to fall again at very large packing sizes. It may
also be interesting to note that the ratio of wetted area to dry
area of the packing grows with packing size, and can exceed
unity by a considerable fraction. The same liquid flow has a
much larger area to spread across for small packings, thus
leaving more of the packing in the dry state. But for large
packings, the available area for spreading is more restricted.
The wetted area can exceed the dry area because all liquid
flow is not restricted just to the mechanical surface of the
packing when the film becomes thick. A thick film becomes
quite disrupted, large waves form and a certain amount of
sparging of the gas through the liquid probably occurs.
In many ways, tray performance is close to the
performance of the smallest packing, but this is definitely not
because of higher surface area for mass transfer. Indeed, in
this case, equivalent wetted surface area in the biphase
based on the volume between any two trays is
approximately 130m
-1
whereas the column-average wetted
area for 1X packing is twice as high at about 270 m
-1
. Instead,
the intense agitation on the trays gives a mass transfer
coefficient almost four times larger than for the 1X packing
(this also turns out to be true for all the packing sizes in the
FLEXIPAC family).
Several points emerge from this. First, structured (and
random) packings are no
more challenging to a true
mass transfer rate based
simulation than trays.
Secondly, one cannot
simply scale up the effect
of packing size in any
simple or logical
arithmetic way. Packing
performance is a complex
function of packing size,
hydraulics, and chemical
reaction kinetics. Third, the
effective wetted area
active on a structured
packing is not limited to
the packings dry area, so
scale-up based on dry area
Table 2. Simulated treating performance, bulge temperature and bulge position
FLEXIPAK
2X.
Taking the Guesswork Out of CO
2
Removal
ProTreat Simulation Software
Get Real
Dont Guess!
SYNGAS, LNG AND CARBON CAPTURE
ProTreat accurately predicts column performance.
100% Mass-Transfer-Rate based no ideal stages.
Grassroots? Revamp? Designing for Packing?
Using MDEA with piperazine? HotPot?
Build a virtual plant with the industrys
most advanced gas treating simulator.
www.ogtrt.com +1 281 970 2700 info@ogtrt.com
Learn how state-of-the-art simulation science can benet you.
LNG_MayJune_2013_45-52.indd 51 21/05/2013 11:44
52 LNGINDUSTRY MAY/JUN 2013
so of packing, the gas has to wait until it is nearly half way
up the column before significant absorption rates can
resume. It is the intensified temperature bulge that is
responsible for this type of pinch.
Using structured packing in
gas treating
In the last few years, engineers have shown increasing
interest in using structured packing coupled with specialty
solvents in amine-based gas treating applications.
Consequently, structured packing is being applied more and
more widely. Nevertheless, the idea is still new enough that
questions are often asked as to whether structured packing
should or should not be considered in a given application.
One of the most obvious application areas in which the
use of structured packing is almost mandatory is in columns
subject to periodic tilting motion, as on floating structures
such as FPSO and FLNG platforms. An advantage of using a
specialty solvent such as GAS/SPEC CS-1160 and CS-2020 is
the lower circulation requirement. This can result in a smaller
plant and lower operating costs. Structured packing resists
liquid maldistribution brought about by rocking motion better
than random packing. Trays have very poor resistance to the
sloshing and seiching induced by lateral back and forth
motion (exceptions are trays that rely on confined centrifugal
motion during contacting, e.g., ConSep and ULTRAFRAC
trays, although these kinds of trays tend to be more
expensive). Structured packing should always be considered
in offshore applications, especially in the context of periodic
tilting motion. However, care must be taken to use the right
kind of liquid distributor. The distributor should have no free
liquid surfaces and should be high pressure drop type, not a
gravity flow device such as a trough distributor. This also
mandates that solid amine hygiene be practiced (i.e.,
filtration and corrosion management).
There are very few reasons to exclude structured packing
from consideration. One such reason is fouling. If the system
is a fouling one, the deposits that will inevitably occur on the
surfaces of the packing will be almost impossible to remove
and operations may soon become plagued by plugging
problems. On the other hand, unless structured packing is
used too close to the flood point where liquid holdup
becomes high, it is naturally resistant to foaming. It should
be recognised, however, that if the system is a bad foamer,
structured packing may not be the answer. Instead, the root
cause of the foaming should be determined and alleviated.
Even a good design is no match for poor amine hygiene.
In a revamp for higher capacity, the naturally higher
vapour handling ability of structured packing may
recommend it as a way to achieve higher capacity in the
same shell. Except in tail gas treating and acid gas
enrichment, pressure drop is not usually an issue. However, if
it is, structured packing can almost always be made to work
at lower pressure drop. To that end, the largest possible
crimp consistent with being able to achieve the target
separation within the height of the existing tower shell
should be used. Again, finding out what that crimp size is can
be facilitated greatly by using mass transfer rate based
simulation.
Summary
Packed absorption columns can operate in various modes
of pinching or be mass transfer rate controlled throughout.
There is no way to tell beforehand which mode will prevail,
and with what packing type and size. This makes it almost
impossible to develop a design that is truly as optimised
as it should be in FPSO and FLNG applications using any
approach other than one with a mass transfer rate basis.
A real mass transfer rate model is constructed from
components that are soundly based in fundamental sciences
and engineering, and not on approximations made to avoid
what used to be impossibly complex and arduous hand
computations. The enormous power of desktop and laptop
computers has turned computer time into a non-issue. Rigour
can be achieved for the meager cost of computing times
measured in tens of seconds. The computer models that
result can be accurately described as virtual plants in which it
is quite easy to investigate very involved what-if scenarios.
Because of their wide range of sizes and the somewhat
laterally compartmentalised flows, structured packings offer
a great deal of flexibility in gas treating, which allows them
to be used where conventional trays are very difficult, if not
impossible, to apply. Possibly two of the greatest barriers to
using structured packing in gas treating have been the very
small experience base and the resulting difficulty in
translating the results of more conventional, approximate
calculations into real internals.
References
1. Pilling, M., and Holden, B. S., Choosing Packings
and Trays for Distillation, Chem. Eng. Prog., p. 44,
September 2009.
2. Lewis, J.C., Seibert, A.F., and Fair, J.R., et al.,
Interfacial Area in Irrigated Packings, paper presented
at Annual Meeting of AIChE, San Francisco, CA,
14 November 2006.
Notes
*CO
2
in the treated gas was not limited to a value set by the
lean solvent CO
2
loading (lean end pinched) and it was not
limited to a value set by too low a solvent flow, i.e., limited
by the solvent capacity (rich end pinched).
Figure 5. Actual and equilibrium CO
2
concentrations in the gas
at various positions in the absorber. Packing is FLEXIPAK
4X.
LNG_MayJune_2013_45-52.indd 52 21/05/2013 11:44
MAY/JUN 2013 LNGINDUSTRY 53
M
ercury, which is present
in natural gas almost
everywhere, causes corrosion
damage to aluminium heat exchangers
and cryogenic aluminium cold boxes
in LPG recovery and LNG plants. This
leads to unexpected shutdowns
and requires expensive repairs to
equipment. For safe and reliable
operation of the plant, mercury must
be removed from the gas. There is a
wide variety of commercially available
mercury adsorbent products for use
in fixed-bed mercury removal vessels.
Sulfur-impregnated activated carbon
offers reliable, high-efficiency mercury
removal upstream or downstream of
Mercury rising
John Markovs,
Adsorption
Solutions LLC,
USA, and
Robert W. Soffel,
Selective Adsorption
Associates Inc.,
USA, examine
solutions to
mercury problems
in LNG plants.
the gas driers. It also offers the highest
mercury capacity per unit volume of the
non-regenerable mercury adsorbents.
Regenerable mercury adsorbents offer
additional options to plant designers.
Several reliable mercury analysers are
commercially available, combined with
good gas sampling techniques, these
allow plant operators to monitor the
performance of the plants mercury
removal unit (MRU).
Early approaches
Mercury is present in many geological
formations and thus can be present in
natural gas. It had not posed a serious
problem to natural gas operations until
LNG_MayJune_2013_53-56.indd 53 23/05/2013 10:32
54 LNGINDUSTRY MAY/JUN 2013
the early 1970s when the LNG plant at Skikda, Algeria, was
built. Early in its operation, the aluminium heat exchangers were
destroyed,
1,2
due to corrosion induced by the presence of mercury
in the natural gas. Therefore, the LNG industry became aware that
it needed to remove mercury from the natural gas. In addition, the
industry also realised that it needed the capability to analyse for
mercury and to be able to measure low mercury concentrations.
Soon after the Skikda experience, two new LNG plants were
built in Indonesia at Badak, Kalimantan and Arun, Sumatra. The
management for each of these plants wanted to have protection
from mercury. However, there was no industry precedent on how
best to accomplish the desired removal of mercury. Calgon
Carbon Corp. developed a mercury adsorbent that consisted of
activated carbon granules that were infused with elemental
sulfur. A similar product was developed by Union Carbide Corp.,
except that this product was a zeolite molecular sieve pellet
(extrudate) that was infused with elemental sulfur.
3
Thus, mercury
could be removed from the gas by fixed bed adsorption in much
the same way as water is removed from gas in desiccant beds.
The gas flows through a packed bed of adsorbent particles. The
mercury reacts with the sulfur and is thus fixed inside the
adsorbent particle. The mercury is then retained within the
adsorption vessel. So, there were two commercially available
choices of mercury removal adsorbent. The question was, where
in the LNG process should the mercury removal bed be installed?
Management at the Badak plant decided to use the Calgon
sulfur-impregnated activated carbon mercury adsorbent. The
MRU was installed downstream of the molecular sieve gas driers
and just ahead of the cryogenic unit. The sulfur-impregnated
molecular sieve product was used at the Arun plant. The MRU at
Arun was installed on the plant inlet gas, upstream of the acid gas
removal unit and the gas driers. The MRU at Badak operated
without problems, whereas the MRU at Arun had a number of
problems. The sulfur/molecular sieve adsorbent experienced
problems during start-up and the upstream MRU did not have
any protection from liquid carry-over; it experienced liquid
entrainment resulting in inadequate mercury removal. The
sulfur/molecular sieve adsorbent was replaced with
the sulfur-impregnated activated carbon, and a second MRU was
later installed downstream of the gas driers, loaded with
sulfur-impregnated activated carbon. Since that time, the LNG
plants have generally followed the example of Badak, with the
MRU located downstream of the gas driers.
Subsequent developments
Other mercury removal adsorbents have been made available,
based on metal oxide or metal sulfide as the active component.
Metal oxide or metal sulfide mercury adsorbents are available
in three types, with very different amounts of internal surface
area: agglomerated metal oxide (40 m
2
/g), activated alumina
that is impregnated with metal oxide (250m
2
/g), and activated
carbon that is impregnated with metal oxide (1000 m
2
/g). The
oxide form can be used when there is enough H
2
S in the gas
to convert the oxide to sulfide, in situ. When there is no H
2
S
present, the adsorbent must be installed in the presulfided
form. The metal sulfide, unlike the elemental sulfur, does not
dissolve in liquid hydrocarbons. Improvements have also been
made in the dispersion of elemental sulfur within the activated
carbon particle, resulting in better performance. Maximising the
surface area of sulfur exposed to the mercury greatly improves
the adsorbent performance. In all cases with these products, the
mercury stays and accumulates on the adsorbent. The adsorbent
has to be replaced when it reaches its maximum capacity for
mercury.
In the late 1980s, a new concept in mercury removal was
introduced: regenerative mercury removal. This concept originated
from the observation that when natural gas containing mercury is
dried using conventional, type 4A molecular sieve, there is a peak
of mercury concentration in the spent regeneration gas. Thus, the
molecular sieve adsorbs some mercury. A new, silver-containing
molecular sieve was developed and commercialised as a
regenerable mercury adsorbent. By using some of the silver-
containing molecular sieve in the natural gas drier, both moisture
and mercury are removed from the gas in one unit. During the
drying step, the mercury amalgamates with the silver and stays on
the adsorbent. During the normal regeneration step of the gas
drier, when the adsorbent is heated, the mercury is released and
leaves the vessel with the spent regeneration gas. Mercury has a
fairly high vapour pressure and it condenses to a liquid, so it
behaves similarly to water. If the mercury concentration is high
enough and if the gas gets cool enough, mercury condensation
will take place. Since the regeneration is always carried out under
reducing conditions, there is no oxidation of mercury, so it is easy
to separate the condensed mercury from the condensed water.
One plant operating with some 50 g of Hg/Nm
3
in its feed gas,
was drawing off shiny mercury from the bottom of its existing
regeneration gas water knock-out drum. With regenerative
mercury removal it is possible to remove and recover the mercury.
A non-regenerative MRU can be used to permanently remove the
mercury that remains in the spent regeneration gas that is sent to
fuel or to the sales gas.
Analytical issues
The mercury that damaged the exchangers at Skikda was
elemental mercury. However, mercury can exist in various forms:
elemental, organic (e.g. methyl-mercury), inorganic (e.g. HgCl), or
it can be attached to a solid particle. To date, the form of mercury
that has been detected in natural gas has been elemental
mercury. When natural gas liquids (NGLs) have been analysed, all
forms of mercury have been found.
All of the mercury needs to be removed to maximise
protection of the heat exchangers. This means removal to below
an industry standard mercury concentration that can be measured
in the plant with commercially available instrumentation. The
industry standard concentration of mercury has been < 0.01 g of
mercury/Nm
3
. This equals 10nanograms Hg/Nm
3
and
corresponds to about one part per trillion by volume. The mercury
content of raw natural gas has ranged from non-detectable to
several hundred g/Nm
3
.
Great improvements have been made in mercury analytical
equipment and techniques. There are numerous analysers
available that use a variety of detection mechanisms, including
atomic fluorescence and cold vapour atomic absorbance (CVAA).
However, no analyser can measure the low concentrations of
mercury directly. All the analysers require that a sample gas be
taken and passed through an analytical trap containing a gold
surface. The trap is then desorbed into the analyser and the
mercury peak sent to the detector, which then quantifies the
mercury. The accuracy of any in-plant mercury measurement is
seldom limited by the sensitivity of the detector itself. The design
of the sampling system and the analytical procedure greatly
affects any readout generated by the analyser. All of the gas
analysers measure total mercury, not just elemental mercury,
since gold adsorbs all forms of mercury.
4
LNG_MayJune_2013_53-56.indd 54 21/05/2013 11:51
GAZTRANSPORT & TECHNIGAZ
1 route de Versailles, 78470 Saint-Rmy-ls-Chevreuse - France
Tel: +33 (O)1 30 234 789 - E-mail: commercial@gtt.fr
www.gtt.fr
at the heart of LNG
T
r
a
n
s
p
a
r
e
n
c
y
I
n
n
o
v
a
t
i
o
n
E
x
c
e
l
l
e
n
c
e
T
e
a
m
w
o
r
k
S
a
f
e
t
y
SOLUTIONS
In the short term, the release of polluting
exhaust gases (SO
x
, NO
x
, CO
2
) will be
restricted.
A set of new international regulations are
coming progressively into force, which
will impose the use of cleaner fuels.
LNG, being by far the cleanest and probably the cheapest
of all fuels comes to mind as the most obvious alternative.
GTT, through its experience in the design of LNG
handling and storage systems, both at sea, and on land,
is ideally positioned as the preferred partner for the
implementation of clean, efcient and reliable solutions
at each step of the supply chain.
GTT has solutions for land storage tanks, and bunker
tanks for all types of vessel.
LNG_MayJune_2013_53-56.indd 55 21/05/2013 11:51
Adsorbent characteristics,
performance and process design
Adsorption is a surface-active process. Therefore, to maximise
performance, it is important to maximise the surface area in the
adsorption unit. Sulfur-impregnated activated carbon pellets have
1000 m
2
/g of internal surface area and a bulk density of
560 kg/m
3
, therefore they deliver 560 million m
2
per m
3
of
adsorbent installed in the adsorption vessel. Activated
alumina-based mercury adsorbents have an internal surface
area of 250 m
2
/g and a bulk density of 900 kg/m
3
, thus they
deliver 225 million m
2
per m
3
. Agglomerated metal oxide has an
internal surface area of 40 m
2
/g and a bulk density of 1000kg/m
3
,
thus they deliver 40 million m
2
perm
3
of vessel volume. Not
all sulfur-impregnated activated carbons are equal; the best
have high internal dispersion and retention of sulfur to provide
maximum active surface area of sulfur.
The pellet (extrudate) form of sulfur-impregnated activated
carbon is physically strong and is not affected by oxygen in the
air, so it can be loaded in air the same way that molecular sieves
are loaded into their vessels. The pellets retain their physical
strength even when hit with liquid entrainment. However, the
performance of this adsorbent will be permanently reduced when
hit with liquid hydrocarbons because the elemental sulfur
dissolves in liquid hydrocarbons. Loss of sulfur will result in
reduction in mercury removal capacity and efficiency.
All adsorbents require single-phase flow for high efficiency
contaminant removal. Some manufacturers claim that only their
product can be used in an upstream MRU. However, there is no
magic mercury adsorbent product that provides high
performance when subjected to liquid mists and liquid carry-over.
Agglomerated metal oxides do not have many, if any,
micropores, that is why their surface area is low. Activated
aluminas have micropores, so they have over five times more
surface area per unit of volume as metal oxide. The
sulfur-impregnated activated carbon has 14 times the surface area
compared to the metal oxide.
When an upstream MRU is well-protected from liquids with a
knock-out drum and a filter separator, then the upstream MRU is
reliable and delivers high mercury removal efficiency and high
mercury capacity using a sulfur-impregnated mercury adsorbent.
An additional advantage of an upstream MRU is that it prevents
mercury from getting to the rest of the plant. It also avoids the
necessity of dry-out during start-up that is required when the
MRU is downstream of the gas drier. Placing the MRU upstream
does not really require additional equipment vs. a downstream
MRU, as a knock-out drum and filter separator are usually used to
protect the gas drier.
The metal sulfide adsorbents require loading under a nitrogen
blanket. When exposed to air, the sulfide is converted to the
sulfate, which is inactive for mercury removal.
5
Some metal
sulfide adsorbents have had problems retaining particle strength
when exposed to liquid entrainment. The adsorbent beads
compact into a solid mass, which results in a loss of performance
and makes it difficult to remove the adsorbent from the vessel.
Activated carbon pellets do not lose their strength in water or
liquid hydrocarbons. They are used in water, in amine solution,
and in other liquid streams without any loss of strength. Activated
carbon pellets are the only adsorbents that do not lose strength
when wet.
Metal oxides and activated aluminas are more hygroscopic
than activated carbons. When an MRU is located downstream of
the gas drier, the MRU bed must be dried out during start-up, to
prevent freeze-up of the cryogenic unit. It has been reported that
metal-oxide type product took much longer to dry out than the
sulfur-impregnated activated carbon.
6
Summary
LNG plants have been protecting their aluminium process
equipment from mercury corrosion for over 33 years. In that time,
mercury analysers and analytical techniques have improved to
the point where nanograms of Hg/Nm
3
can be reliably measured
in natural gas. Also, the market now offers several types of
non-regenerable mercury adsorbents and at least one
regenerable mercury adsorbent. Sulfur-impregnated activated
carbon still offers the highest performance of the non-regenerable
products. With proper process design, a MRU can be installed
upstream or downstream of the gas driers and provide high-
efficiency mercury removal, or a regenerable mercury adsorbent
can be used to remove mercury in the gas drying unit itself.
Which option is best depends on the operating philosophy of
plant management.
References
1. Dolle, J., and Gilbourne, D., LNG: Startup of the Skikda
LNG Plant, Chem. Eng. Progress, Vol. 72, p. 39,
January 1976.
2. Leeper, J. E., Mercury LNGs Problem, Hydrocarbon
Processing, November, 1980.
3. Ambrosini R. F., et al., Selective Adsorption of Mercury
from Gas Streams, US Patent 4,101,631.
4. Dumarey, R., Dams, R., and Hoste, J., Comparison of the
Collection and Desorption Efficiency of Activated Charcoal,
Silver, and Gold for the Determination of Vapor-Phase
Atmospheric Mercury, Analytical Chemistry, Vol. 57,
No. 13, November 1985.
5. Baageel, O. M., Gas Plant Solves Hg Problems with Copper-
sulfate Adsorbent, Oil and Gas Journal, 24 May 2010.
6. Mock, J., Hahn, P., Ramani, R., and Messersmith, D.,
Experiences in the Operation of Dehydration and Mercury
Removal Systems in LNG Trains, presented at the 2008
Laurance Reid Gas Conditioning Conference, Norman OK, US.
LNG_MayJune_2013_53-56.indd 56 21/05/2013 11:51
MAY/JUN 2013 LNGINDUSTRY 57
Handling
cryogenic fluid is
inevitably a hazardous
activity, particularly when the
fluid is as vulnerable and flammable as LNG. The
volatility of the refrigeration phase of the LNG
train demands that all equipment meets exacting
technical standards. This includes the valves used
for process control.
The rise of LNG megaprojects has brought a
corresponding rise in high capacity liquefaction
phase compressors. Consequently, larger
diameter valves are needed typical contracts
can include cryogenic control valves of 42 in. and
over. This brings a host of challenges and is driving
new developments in the engineering and testing
of valves for cryogenic applications.
The cryogenic challenge
The -160 C liquefaction phase of LNG production
is particularly challenging for control valves. They
are required to provide repeatable bubble-tight
shut-off in a controlled manner, whilst handling
significant differential thermal dynamics. This
needs to be achieved with minimum heat
leakage, minimum cool-down mass and cold
THE
CRYOGENIC
CHALLENGE
Barry Wilder,
Severn Glocon,
UK, looks at
how to maximise
cryogenic control
valve performance.
LNG_MayJune_2013_57-60.indd 57 21/05/2013 12:02
58 LNGINDUSTRY MAY/JUN 2013
impact strength materials. Valves are designed to operate at
temperatures ranging from +80 C to -196 C, so maximising
their performance and prolonging their life requires dedicated
attention from the brightest engineering minds.
Clearly, when dealing with volatile media and extreme
temperatures, safety is a prime consideration. For LNG
operators, safety and productivity have a symbiotic relationship.
It is widely acknowledged that valves can be a major culprit
when it comes to leakage, both internally and to the
atmosphere. Atmospheric leakage of natural gas is considered a
serious environmental pollutant, so minimising the risk of
fugitive emissions is a key priority in the design of the valve seat,
as well as body and stem sealing systems.
If leakage does occur, the problem can escalate very quickly.
It is not unheard of for a valve-related emissions incident to lead
to 48 hours of plant downtime, bringing serious consequences
for production and supply chain management.
Industry standards and
specifications
In the absence of a dedicated international standard for
cryogenic LNG valves, there are many end-user technical
specifications for valves in cryogenic service. These generally
involve a hybrid of traditional British Standards such as
BS6364:1984 valves for cryogenic service and additional US
or international standards. This amalgamation of standards is
quite appropriate. The UK has a long track record of dealing with
cryogenic processes associated with air separation, whilst most
modern control valves for LNG facilities are constructed from US
materials.
The harsh demands of cryogenic applications mean that
each and every valve needs to receive a robust, intelligence-led
specification. Severe service valves linked to the compressors,
such as anti-surge, hot gas bypass or Joule Thompson gas
expansion (associated with plant blow-down requirements),
should be precisely tailored in line with the specific operating
conditions they will face. Advanced engineering surrounding
features such as trim design can bring significant operational and
reliability advantages. Engaging all parties, from engineering
contractors to operators to suppliers, at a projects FEED phase
can facilitate the development of innovative solutions for
seemingly insurmountable technical difficulties.
Avoiding liquid lock
One of the special challenges facing valves handling cryogenic
fluids is the liquid lock phenomenon. When a valve closes,
some liquid can become trapped in the valve body. With
cryogenic fluids, as the temperature rises, the trapped liquid
expands and regasification can occur. This can exert enough
pressure to deform or even rupture internal components,
causing a major incident.
A core design feature of valves that may be at risk of liquid
lock is the inclusion of an internal relief path to prevent
over-pressurisation.
Extended bonnet and stem for
LNG valves
Due to low operating temperatures, the typical bonnet and
stem design for LNG valves is the extended bonnet type,
allowing for a vapour space. Calculations usually take account
of the valve size and the operating temperature range. Draft
BS ISO/DIS 28921-1 for industrial valves outlines a minimum
vapour space and lagging length (bonnet extension).
The extended bonnet provides a temperature gradient to
minimise the risk of moisture freezing at the gland sealing
system. It has a minimum wall thickness section, normally
manufactured from tubular section stainless steel due to its heat
insulation properties.
The valve is designed to allow a very small amount of the
cryogenic liquid or vapour to enter the lower part of the
extension bonnet, and this evaporates inside the extended
bonnet. The vapour has a higher temperature than the cryogenic
fluid, which allows the temperature at the gland sealing area to
rise above freezing point. Since control valves are used outside,
the ambient air conditions also have to be considered. If the
gland area is below freezing, any ice that forms may be dragged
down through the gland packing, causing a leak at the gland.
This will allow cryogenic fluid to fill the extended bonnet,
leading to an ice ball forming around the gland, which may stop
the valve from working.
To compensate for this risk, extension bonnets can be
supplied with an insulation collar/drip plate.
This collar/drip plate is either welded or
clamped to the extension bonnet with any
bolting on the upper side to enable easy
adjustment. The gap between the collar/
drip plates is sealed to prevent
condensation entering the insulated area.
Draft ISO/DIS 28921-1 outlines positioning
and fixing details for collar/drip plates.
It is essential that no product leakage
enters the valves thermal insulation or the
atmosphere, so stem and body sealing
undergoes a fugitive emission test. This
involves the use of a mass spectrometer
and helium gas to comply with the fugitive
emission requirements of ISO 15848
and/or the customers own specific
requirements. Non-destructive examination
and pressure tests are also carried out in
accordance with ASME V Appendix IV and
ASME B16.34 and/or end-user
specifications.
Figure 1. The extended bonnet and stem design reduces the risk of moisture freezing
at the gland sealing system.
LNG_MayJune_2013_57-60.indd 58 23/05/2013 10:35
Find out through our reader survey
measuring the NOV / DEC issue of
FOR MORE INFORMATION PLEASE CONTACT
JOHN BAUGHEN or CHRIS ATKIN:
E: john.baughen@lngindustry.com
E: chris.atkin@lngindustry.com
T: +44 (0)1252 718999
Is your advertising
campaign ticking
all the right boxes?
LNG_MayJune_2013_57-60.indd 59 23/05/2013 16:13
60 LNGINDUSTRY MAY/JUN 2013
The importance of trim design
Modifying trim design can have a significant impact on a
valves ability to perform well in a given application. If the trim
arrangement is not correctly specified it can increase the risk of
leakage and poor process control, whereas adapting it to suit the
operating conditions will enhance performance.
High-output LNG plants tend to have high-capacity trains,
which require larger diameter pipes, thereby increasing the flow
speed of the cryogenic fluid. Any high-velocity process medium
can cause cavitation, erosion and abrasion of internal valve
components, which can result in poor control and premature
valve failure. Simply using harder trims or pipe lagging cannot
solve the problem, it needs to be dealt with at source.
Equipping valves with multi-labyrinth trims (MLTs) can
significantly reduce the velocity of the cryogenic fluid. This is
achieved by splitting the flow into many smaller streams via
multiple passageways, with each flow stream made up of many
right angle flow turns. Every flow turn achieves a pressure or
velocity reduction. This tortuous path removes the kinetic energy
from the fluid whilst lowering pressure in a controlled manner.
The number of required turns is calculated precisely by taking
into account the expected fluid velocity at the inlet, and the ideal
velocity at the outlet. This enables the flow speed to be
accurately controlled in each flow passage so the valves
operation can be well managed over its full service range.
Unlike other severe service trim options, the MLT is fully
pressure-balanced within the stack. This helps hold the valve
plug in the centre of the stack, giving good stability and avoiding
plug vibration, which extends the service life of the trim. As well
as prolonging valve life and improving control performance,
using an MLT ensures the valve produces lower noise levels than
valves using alternative trims, such as multi-cage devices. It also
offers simple, quick change-out, which reduces maintenance
costs.
Valve trim seat sealing and pressure balance seal design at
cryogenic temperatures are critical to the performance of LNG
valves. Attention to detail in the design, manufacture and
machining methods, together with the correct actuator selection,
are vital to provide the degree of repeatable seat leak tightness
required by the industry, typically ANSI/FCI 70-2 Class V or VI.
Application spotlight:
compressor anti-surge
The MLT solution is especially suited to compressor anti-surge
valves. This demanding application is greatly enhanced by a
reduction in the velocity of cryogenic fluid. It facilitates
control and decreases the vibration and noise typically
associated with compressors.
Improving reliability and performance of the
anti-surge valves is cost efficient on multiple levels. Even
minimal leakage of anti-surge valves results in significant
wasted energy, as the fluid returns to the suction side of
the compressor, meaning it has to work harder. Achieving
repeatable bubble-tight shut-off prevents this leakage. In
addition, the precise flow control means there is no need
for additional by-pass valves, and the reduced vibration
extends the life of the trim.
Testing and installing
Valves destined for LNG applications require test
temperatures of -196 C to ensure they can operate
safely and effectively at temperatures as low as
-160 C in the field. Selecting a provider who can conduct
cryogenic testing on even the largest valves in-house enhances
turnaround time and facilitates better project management.
Since many LNG megaprojects now employ time-sensitive
modular construction methods, this capability is advantageous
for all parties.
Typically, LNG valves are supplied with a two-year
warranty, but conducting a detailed pre-commissioning site
survey, then cross-checking the eventual installation, can
underpin an extended warranty of up to four years. This
provides peace of mind and can help reduce the total lifetime
cost of each valve. It also demonstrates confidence on the
suppliers part in terms of the quality and durability of the
valves, as well as the high standard of the specification, design
and manufacture.
Key areas of concern for engineers checking
post-construction valve installations on greenfield sites include:
pressure testing, hydrostatic line tests and calibration checks.
They also verify that the valves have not been damaged in
transit, have been reassembled correctly and are installed at the
correct upstream/downstream orientation, which is of particular
importance for valves that have an extended bonnet design to
overcome liquid lock. Cleanliness is also vital throughout the
installation phase and during ongoing operations:
BSEN12300:1999 and in-house standards and procedures are
followed to ensure product safety and functionality.
Insisting on a thorough best-practice approach to testing and
installation can reduce start-up time and enhance long-term
performance.
Ongoing maintenance
Once a valve is operational, the big question is how often it
requires attention. In many processing industries, a regular
annual or bi-annual assessment is adequate for most valves.
However, a timetabled procedure for testing and management
across the valve population is not best practice for LNG
processing, where closer control is needed. A more dynamic,
intelligence-led approach optimises safety and performance, and
can ultimately be far more cost-effective than static methods
alone.
Whilst valves are a relatively small component in
themselves, they are associated with all the major assets in the
liquefaction process. Cryogenic valves are never just a
commodity. They are a highly-engineered component that has
considerable bearing on plant performance.
Figure 2. In-house cryogenic testing enables better project management.
LNG_MayJune_2013_57-60.indd 60 23/05/2013 10:36
MAY/JUN 2013 LNGINDUSTRY 61
T
he current situation in the LNG industry can be brought back to one simple equation: Weight reduction + size reduction +
power reduction = operational cost reduction. For the production of LNG there are four main licensed processes. The most
commonly used is probably the Cascade liquefaction process. Figure 1 shows an overview of the process and the required
equipment.
Liquefaction
This article focuses on the cooling side of the process. For cooling of the refrigerants, very large coolers are needed, both air cooled
and/or water cooled. These are major cost factors. However, by taking a closer look at cooling and utilising new equipment, large
cost savings can be realised.
In the present overall design, a large number of coolers are needed for the various refrigerant cycles; very heavy and large
equipment is used, especially for offshore applications. Hence, huge plot spaces are needed, with the high power consumption of
Femke Schaefer,
Bronswerk Heat Transfer,
the Netherlands, looks at size,
weight and power reduction of process
equipment in LNG liquefaction and regasification.
LNG_MayJune_2013_61-63.indd 61 22/05/2013 09:39
62 LNGINDUSTRY MAY/JUN 2013
the air coolers having a major influence on the CAPEX.
Onshore, the inter stage compression cooling of the
refrigerants is conventionally done by air coolers, and
offshore by means of water cooled shell and tube heat
exchangers.
High efficiency air coolers
Geothermal plants also use a huge number of air cooled
coolers. Although a different industry, a similar challenge is
posed and solved by using the latest available technology;
the high efficiency air cooled cooler. For a geothermal site in
Germany, the onshore air cooled condensers were reviewed.
The installed turbine had a power of 25 MW, the refrigerant
used was R134a and the capacity of the air cooled coolers
was 68 MW. The original design of this geothermal plant
was based on standard, conventional air cooled coolers with
an absorbed electrical power of 1143 KW, a required plot
space of 4224 m
2
and a resulting noise power emission of
101B(A).
The advanced design was based on the high efficiency air
cooled coolers with an absorbed electrical power of 528 KW,
and a required plot space of 2974 m
2
, resulting in noise power
emissions of only 94 dB(A).
The benefits of the advanced design are an area reduction
of 1250 m
2
, equaling 29%. Additionally, a noise reduction of
7dB(A) is realised and the power consumption is reduced by
615KW, equaling 53%. For the OPEX, this results in a saving
of 492000/y (based on an electrical power price of
0.10/KWh), excluding the savings on maintenance, CAPEX
reduction due to reduced E&I, foundations and auxiliaries.
Water cooling
It has been demonstrated that air cooled coolers can help
reduce costs. An additional example of cost/space savings
for advanced compressor water cooling with compact
shell and tube heat exchangers for offshore applications
is used, especially on a FPSO. Two examples of high
pressure offshore gas compressor coolers for an FLNG
facility off the coast of Australia are detailed here. The
mediums are acidic gas and cooling water. For the fourth
stage compressor after cooler the design for pressure gas
is 215 bar and the design for temperature is 160C. For the
final reinjection compressor after
cooler the design for gas pressure
is 295 bar and the design for
temperature is 160 C.
The original design was based
on conventional B type high
pressure shell and tube heat
exchangers, where the fourth stage
compressor after cooler has a
weight of 17000kg and the required
space is approximately 10 m
2
. The
final reinjection compressor after
cooler has a weight of 28000 kg
and the required space is
approximately 15 m
2
. In addition to
the conventional types, Bronswerk
has also made an advanced design
for the same process conditions,
based on a new high pressure shell
and tube heat exchanger
technology called the compact header design. In the
advanced design, the fourth stage compressor after cooler
has a weight of 10 500 kg and the required space is
approximately 8.5 m. The final reinjection compressor after
cooler has a weight of 14 000 kg and the required space is
approximately 13 m
2
.
The advanced design reduces the size and weight of the
equipment. The benefits of these solutions are a volume
reduction of approximately 3.5 m
2
(15%) and a weight
reduction of 20 500 kg (46%). A well known EPC contractor
indicated that an equipment weight saving of 1000 kg will
save 5000 kg of supporting steel structure. An estimate of at
least ten high pressure heat exchangers on each ship, each
costing US$ 500 000, results in an equivalent of
US$5million less CAPEX.
The new Compact Header
m
is close to the self sustained fluid acoustic resonance.
However, this occurrence is not strictly necessary for a
fatigue rupture, as this can occur even with only the above
singing lock on.
Finally, the mechanical ring frequency of the riser
carcass may interact with the system self excitation, but it
is not the primary cause of excitation of the fluid acoustic
resonance, which also arises in infinitely rigid pipes.
7
Onset velocity
The onset velocity of the fluid to excite riser singing
depends on the ratio between the momentum thickness of
the boundary layer and the cavity gap of the corrugation
pattern. This yields the following equation
6
, derived from
the work of S. Belfroid
6
and others on side cavities and
dead branches, with parameters referring to Figure 2.
Where:
a Boundary layer growth coefficient (--) (equal to 5,
for a flat plate
9
).
c
1
Ratio of momentum boundary layer thickness to
boundary layer thickness (--) ( 0.13 for flat plate
6,9
).
c
crit
Critical ratio of momentum boundary layer thickness
to cavity gap (--) = 0.0005.
Fluid absolute viscosity (Pa s).
Fluid density (kg/m
3
).
U Fluid velocity (m/s).
W Cavity gap (m).
x Boundary layer growth length (m) given by:
Figure 2. Definition of riser carcass geometry patterns.
Table 1. Data for the real riser base case design example
Minimum inner diameter D 356 mm
Corrugation pitch P 39 mm
Cavity depth H 12 mm
Cavity width W 8 mm
Cavity upstream radius R
up
6 mm
Cavity downstream radius R
down
6 mm
Gas density 50 kg/m
3
Gas absolute viscosity
1.16 x 10
-5
Pa s
Gas flowing velocity U 8 20 m/s
LNG_MayJune_2013_69-73.indd 71 22/05/2013 10:20
72 LNGINDUSTRY MAY/JUN 2013
a
1
Constant (--) (found to be equal to 0 from
experiments).
a
2
Constant (--) (found to be equal to 0.4 from
experiments).
R
up
Cavity upstream radius (m).
R
down
Cavity downstream radius (m).
L Cavity plateau length (m).
For the very long corrugated lengths found in flexible
riser systems these boundary layer equation conditions are
alone sufficient to determine and sustain the phenomenon.
It is only for much shorter tubes, as typically used in
experimental research works, that the boundary conditions
at the pipe ends are also important and can determine
much lower onset velocities.
Example of findings
As an example of the above procedure, the flexible riser
of a real case considered by the authors had the data
summarised in Table 1 (see also Figure 2 and profile a in
Figure 3).
The resulting cavity plateau length L is given by:
The boundary layer growth length x then is:
The riser singing onset velocity U
min
is:
y
min
g q
It is clear that no riser singing can occur with this
carcass profile under these conditions, since the onset
velocity exceeds by far the maximum fluid velocity.
Instead, if the riser carcass geometry were like profile b in
Figure 3, e.g. with a shorter pitch (28 mm) but broader
cavity width (10 mm) and radii (9 mm) and no plateau, yet
with the same depth, the onset velocity would be 22 m/s,
under the same gas state. At higher gas pressure, with a
gas density of 75 kg/m
3
, the onset velocity would
decrease to 15 m/s, well within the operational range.
The minimum and maximum riser singing frequencies
would be, in this latter case and with a gas velocity right at
the onset value of 15 m/s:
The first of the two values would be very close to a
resonating mode of the turret piping of the floating facility
considered. In such a case, acoustic lock on would occur
with consequent excitation of high pressure pulsations
around the frequency of 250 Hz (Figure 4).
The absolute dimensions or the scale factor for a same
carcass shape also have an important effect on the onset
velocity, as can be understood from the equations and
shown in Figure 3, which means that with larger diameter
risers the likelihood of riser singing increases.
Conclusion
The phenomenon of riser singing should be carefully
addressed in floating storage and offloading systems
design, particularly of LNG offloading and regasification
facilities, as the consequences of the generated pressure
pulsations may be severe. The phenomenon is very
sensitive to the corrugation geometry, scale factor and
fluid properties such that even apparently marginal
changes of these quantities may yield completely different
results and change the onset possibilities.
References
1. Ltveit, S. A., et al., Flow induced vibrations in
flexible pipes, proceedings of OMAE 2003, the 22
nd
International Conference on Offshore Mechanics and
Arctic Engineering Cancun, Mexico, OMAE2003-
37194, 2003.
2. Nakamura, Y., and Fukamachi, N., Sound generation
in corrugated tubes, Fluid Dynamics Research 7,
pp. 255 261, 1991.
3. Nakiboglu, G., et al., Whistling behavior of periodic
systems: Corrugated pipes and multiple side branch
system, International Journal of Mechanical Sciences
52, pp. 1458 1470, 2010.
4. Swindel, R, and Belfroid, S. P. C., Internal flow
induced pulsation of flexible risers, Offshore
Technology Conference, Houston, Texas, Ref.
OTC18895, 30 April 3 May 2007.
5. Tonon D., et al., Whistling of a pipe system with
multiple side branches: Comparison with corrugated
Figure 3. Sensitivity of the singing onset velocity to riser
carcass shape, scale factor and density.
LNG_MayJune_2013_69-73.indd 72 22/05/2013 10:20
pipes, Journal of Sound and Vibration 329,
pp. 1007 1024, 2010.
6. Belfroid, P.C., et al., Flow induced pulsations
caused by corrugated tubes, Proc. of
PVP2007, ASME Pressure Vessels and Piping
Division Conference, San Antonio, Texas,
22 26 July 2007.
7. Belfroid, S. P. C., et al., Flow induced pulsation
due to flexible risers, Offshore Technology
Conference, Houston, Texas, Ref. OTC19904,
4 7 May 2009.
8. Bruggeman, J.C., et al, Self-sustained aero-
acoustic pulsations in gas transport systems:
experimental study of the influence of closed
branches, Journal of Sound and Vibration 150(3),
pp. 371 393, 1991.
9. Batchelor, G.K., An introduction to fluid
dynamics, Cambridge Mathematical Library,
Cambridge University Press, 1967 2000,
11
th
printing.
10. Brighenti, A., and Osti, P., ACUSYS - Application
of MATLAB-SIMULINK for the simulation of
acoustic pulsation in plants (Italian), 1
st
Italian
MATLAB Conference, Bologna, 14 October 1994.
11. Brighenti, A., and Pavan, A., ACUSCOMP and
ACUSYS A powerful hybrid linear/non linear
simulation suite to analyze pressure pulsations
in piping, ISMA 2002 International Conference
on Noise and Vibration Engineering, Leuven,
Belgium, 16 18 September 2002.
Figure 4. Acoustic transfer function of the turret piping from
the riser to the connection with the topside plant at 250 Hz under
one of the operating cases considered (by ACUSYS
10, 11
).
www. ener gygl obal . com/ news
READ about the latest
developments in the LNG
industry on Energy Global
LNG_MayJune_2013_69-73.indd 73 23/05/2013 11:21
74 LNGINDUSTRY MAY/JUN 2013
D
uring the middle of the previous decade, Chiles energy
matrix was highly dependant on the supply of Argentinian
natural gas, which was supplied through three pipelines that
crossed the Andean mountains.
This supply was suddenly interrupted by the Argentinian
government due to a shortage of natural gas availability, creating a
big problem for Chilean electricity production, which had to be
replaced by thermolectrical electricity generation fed by huge diesel
oil imports. This affected the cost of energy to the Chilean industry
and households.
At the same time, the country has developed quickly and needed
a reliable and independent source of energy at market prices that
could successfully compete with other fuels.
Quintero LNG facility
As a result of this situation, in May 2004 the Chilean government
decided to push for the construction of an LNG reception facility
to be built at Quintero, a port located 180km away from Santiago,
where demand for LNG is greatest. The state owned oil company
Enap was entrusted to lead the design and construction of the LNG
regasification terminal.
The main
energy operators
in the country were
invited to participate
in the construction of the
Quintero LNG facility,
which finally led to the
creation of a consortium formed
by Enap, Endesa Chile and
Metrogas, each with an equal share.
This partnership was later expanded to
include BG Group, one of the largest
producers and distributors of natural gas in
the world, giving birth to GNL Quintero. Its
mission was to build the LNG reception, storage
and regasification terminal in time to start bringing
gas into Chile in the winter of 2009.
The project was initially expected to start operations
in mid-2007 at an investment cost of US$ 700 million. The
final cost of this project was almost double the initial estimate,
and the start-up date of this facility was April 2009.
Figure 1. LNG carrier Celestine River approaching the Quintero terminal.
LNG_MayJune_2013_74-78.indd 74 22/05/2013 10:26
MAY/JUN 2013 LNGINDUSTRY 75
PULLING OUT
THE STOPS
Alfred Hbner,
Ultratug, Chile,
explains the beginning
of LNG terminal
services in Chile and
how this has impacted
the local market.
LNG_MayJune_2013_74-78.indd 75 22/05/2013 10:26
76 LNGINDUSTRY MAY/JUN 2013
The initial throughput capacity of the terminal is
10millionm
3
/d of natural gas, enough to supply 40% of the
countrys natural gas demand. Furthermore, the terminal has
been designed to double this capacity without interrupting its
operations. The jetty is 1878 m long and can unload up to
12000m
3
/h of LNG from the carriers. The offloaded LNG is stored
in three tanks, one small 14 000 m
3
tank and two larger ones with
a capacity of 160 000 m
3
each.
Berthing carriers
As soon as BG Group was integrated into the consortium, it
started to look for reliable companies that could adequately
handle its LNG carriers, which would bring the required LNG to
the Quintero terminal.
Considering the hazardous nature of LNG handling, safety
was considered the most important issue for BG. The project
required careful design and preparation of the berthing and
unberthing manoeuvers for the incoming LNG carriers. The
required services for the ships included the port agency and the
other usual port services, such as pilotage and the timely
availability of tug services. Based on BGs agreement with
GAC Network, Ultramar was the chosen agency in Chile.
Once that aspect had been resolved, BGs main concerns
were for the simulation of a safe berthing and unberthing
manoeuver, the contracting of the necessary tugboats that would
assist these manoeuvers, and the training and preparation of the
port pilots and tug masters that would perform these
manoeuvers.
Considering the risky nature of the operations, and the huge
investment cost of LNG carriers, BG has strict and demanding
procedures for its ship handling. In this case, these included the
training of pilots and tug masters at Wallingford, England, where
manoeuvers were simulated at specifically created replications of
the real sea, wind and swell conditions and forces that the LNG
carriers would face at Quintero.
Prior to that, as these operations also required the timely
availability of an adequate number of powerful and duly fitted
tugboats, BGs international tender included highly demanding
conditions for the bidding parties, both in terms of the required
technical specifications of the tugboats, as well as the
implementation and control of a strict safety, quality and
environment (SQE) system by the performing parties.
Requirements
The specific technical features demanded by BG for the tugboats
included the following:
Four tractor or azimuth type tugs of minimum 50 t bollard
pull. Two of these needed to be fitted with Firefighting (FiFi1)
systems.
Special tube-type fendering for the tugboats that improve
distribution on the ships hull during pushing mode.
Special winches with automatic tension and release meters.
Gas detecting systems and automatic closing devices in the
whole tug accommodation and engine room.
Curtain type of water sprinklers around the bridge.
Use of Dyneema type Kevlar shiplines.
It is important to note that several of these features were
unknown or at least not regularly implemented in the Chilean tug
fleet until that date, but have meanwhile become mandatory in
several ports where the larger container ships are calling.
In addition, BG required that:
All manoeuvers should be directed in technical English
language, so that the ship masters are able to understand any
instructions given by the pilots. This, however, demanded
that the Chilean pilots and tug masters understood English,
which finally proved to be unrealistic and this requirement
was eventually discarded.
Pilots and tugmasters should undergo regular retrainings
either at Wallingford and/or in Quintero, under the
supervision of an international expert designated by BG.
Figure 2. A birds eye view of the Quintero LNG terminal.
LNG_MayJune_2013_74-78.indd 76 22/05/2013 10:26
These latter checks have been carried out twice at Quintero
since the beginning of the operations, whilst the pilots and
tug masters are being retrained at the Humboldt Marine
Training Center in Valparaiso.
Berthing manoeuvers should be carried out in accordance
with the norms and practices of BG, which implies
the incorporation of a computer system that controls
the distances by GPS so as to allow a slow and exact
positioning of the vessels at the jetty, to safeguard the port
installations.
Regular updating and monitoring of the tug operators SQE
system on shore and on board by a BG representative, so as
to make sure that it is properly working. This has also been
carried out in regular intervals with satisfactory results.
Quintero is a port located some 20 miles north of
Valparaiso, which handles most of the liquid, gaseous and dry
bulk cargoes in central Chile. As such, it is an intensely used
port that handles crude oil, petroleum products, LPG,
methanol, coal, copper concentrate and other bulk cargoes. It
is located in a relatively small bay that is opened to the
northwesterly winds during the winter months, and is exposed
to permanent swell. As such, the operation for LNG carriers is
not easy, due to the exposed location of the port, the
permanent swell, and the increasing number of other ships
calling at that port.
Utilisation rates
For many years, Ultratug has held a relevant position in
Quintero, attending a larger share of the shipcalls at the
different terminals located in the bay. The company has had
two tugs permanently stationed in this port, in addition to
another two tugboats in Valparaiso, which occasionally assist
its manoeuvers from that port.
The number of LNG carrier calls was initially projected to
start at 15 calls per year, which may gradually increase up to
24 calls per year.
Due to the high investment that would be needed for the
four required tugboats, and the low utilisation rate that these
tugs would have, it made no sense to use exclusively dedicated
tugboats for the LNG Quintero project. As a result, Ultratug
offered to build two new tugboats of 65 t bollard pull for the
BG tender, which would meet all the technical features required
in the tender specifications. To meet the requirement of four
tugs for each manoeuver, an alliance was formed with two
other local tug operators, providing similar tugs on a per call
basis.
This offer implied that BGs manoeuvers and stand-by
operations would have preference with the required number of
tugs whenever needed, without having to pay for the idle time
of the tugs. This offered a cheaper operation and a more efficient
use of the tugs.
Over time, the LNG Quintero project has expanded to move
LNG regularly to the Concepcion area by truck, which lead to an
increase to 40 LNG calls in 2012.
A key component of the Ultratug strategy is its
comprehensive SQE management system. The companys SQE
standards meet and exceed the strictest international
requirements, including those of the oil majors.
Ultratug is part of the Ultramar Group of companies, which
through their holding company Ultranav operates some
200 vessels: tankers, bulk carriers and gas carriers regularly
undergo vetting procedures by oil majors. Humboldt
Shipmanagement in Valparaiso, which is part of the same
Ultramar Group, provides the technical management, crewing
and SQE management for all vessels and applies the same
standards for the Ultratug harbour tugs.
This was crucial during the tendering process, when BG
evaluated Ultratugs offer and reviewed its SQE system on site,
which included physical visits to the tugs.
Furthermore, Humboldt has also developed a marine
training centre in its Valparaiso facilities, which is oriented to
train pilots and ship masters/engineers in several maritime
matters and for the renewal of several ship certificates. This
centre includes a simulator for the training of tug operations,
which has been approved by the Chilean Maritime Authority and
by BG for the training of LNG tug masters and pilots.
Conclusion
The BG operation has been a successful venture, which has
helped the terminal community, Ultratug and its crews, as
well as the local market to raise its working standards. It
also provides the company with a distinctive and unique
knowledge about harbour towage at LNG terminal operations
in South America. This experience has been key to supporting
other LNG projects in Chile, such as the Suez Energy LNG
terminal in Mejillones, as well as providing services to existing
facilities in Puerto Escobar and Baha Blanca, Argentina,
or sharing knowledge and experience with projects under
development, such as Gas Sayago in Uruguay.
Ult t i dd 1 13/05/2013 09 58
LNG_MayJune_2013_74-78.indd 77 22/05/2013 10:26
SUBSCRIBE ONLINE
A GLOBAL INDUSTRY
REQUIRES GLOBAL
PUBLICATIONS
LNG_MayJune_2013_74-78.indd 78 24/05/2013 10:52
TENSION
Blaine Dempke, Markey Machinery
Company Inc., USA, discusses new
winch technology that helps to
improve tanker transit safety.
Figure 1. The SMBC tug Mexicali, one of four
purpose-built tugs working the Energia Costa
Azul LNG terminal in Ensenada, Mexico.
A
utomated winch technology brings a new level of safety to the world of
tanker escort and emergency towing, a vital part of the LNG supply chain.
Escort tugs generally run with tankers once they reach port, prepared
to assist the large ships if necessary. Tankers also rely on tugs to perform
emergency towing on the rare occasions when ships systems fail and they are
unable to get safely to port under their own power.
It has been said that a tug is essentially just a platform for a winch. Winches,
wires and ropes are indeed fundamental to escort and emergency towing
operations. The winch on the deck of the tug controls the towline connected to a
Maintaining
LNG_MayJune_2013_79-82.indd 79 22/05/2013 10:28
80 LNGINDUSTRY MAY/JUN 2013
ship. In this way, a tug can control a tanker by direct mode,
pulling the tanker behind it in an in-line formation, or by
indirect mode, steering a tanker by pulling the ships stern to
one side or the other (acting as a giant rudder). One of the tug
masters jobs is to maintain even tension on the towline to
avoid line failure due to excessive or spiking payloads. A
parting of the lines means loss of control of a tanker with
potentially disastrous outcomes.
The 1989 Exxon Valdez oil spill in Alaskas Prince William
Sound, and the public outcry that followed, spurred
advancements in environmental and human safety at sea. An
example, specifically benefiting escort and towing operations,
is improvements in electronics that allowed for measuring
tension in the line and gave tug captains the ability to make
far more accurate adjustments.
In the last decade, a second evolution in escort and
towing technology has been prompted by the construction of
LNG terminals in unprotected and challenging ports. Oil
terminals have long been in place, built in ideal locations with
better conditions for ship traffic, often coinciding with
population centres. However, due to current public opinion
and political influences, the more recently built LNG terminals
have had to settle for remote sites, sometimes in exposed
ports with challenging currents and seas. This brought about
the need for tugs and towing systems capable of working in
heavier conditions and the advent of a new class of winches,
generally referred to as automatic line tension winches. These
machines have control systems that automatically adjust line
tension, further reducing the chances of a line failure, allowing
captains to concentrate on driving the tug.
A survey of the latest winch
technology
In August 2012, a report authored by Robert G. Allan and
commissioned by the Prince William Sound Regional
Citizens Advisory Council surveyed the latest technologies in
ship escort and emergency towing systems around the world.
This Escort Winch, Towline, and Tether System Analysis was
used to compare the systems aboard the high-powered tugs
serving the Valdez, Alaska oil terminal to the current best
available technology. The study is equally applicable to LNG
tanker escort and emergency towing, given that there is little
significant difference in technique or equipment whether a tug
is serving an LNG tanker or an oil tanker.
Indeed, because many LNG terminals have been built in
ports characterised by heavier seas, this report examining
tugs in the challenging waters of Prince William Sound is very
relevant. In it, Allan noted: [...] very few places in the world
have such structured escort services as the system that exists
in Prince William Sound. Comparable examples would be
North Puget Sound, Southampton, UK, Milford Haven, UK,
various Norwegian oil terminals (Sture, Mongstad, etc.), and
some Middle East gas terminals. However it is fair to say that
Valdez/Prince William Sound is certainly one of the longest
escort operations in terms of distance, and presents the most
demanding environmental challenges of all of these, save the
fact that the European terminals are generally much busier.
Among others, the report surveyed tug operators
Bukser og Berging AS of Norway, KOTUG of the Netherlands,
IRSHAD of the UAE and Seaspan Marine Corporation of
Canada, as well as winch manufacturers Markey Machinery
Company, Inc. of the US and Rolls-Royce of Norway/Finland.
It found that escort winches have changed more than
anything else in escort technology in the past 10 to 15 years.
Most critically, Allan said, winch braking systems have
evolved to the point where they are the required virtual fuse
in the system, and line tension can be set and controlled quite
accurately.
According to the study, automatic line tension winches at
the appropriate work load rating are a vital part of a modern
escort tugs capabilities, especially one operating in higher
sea-states.
Allan writes: Dynamic loads on a hawser can exceed ten
times the rated Bollard Pull of a tug in extreme sea-states,
and that will far exceed the rated breaking strength of the
towline.
Without automatic line tension capabilities, he continued,
the system is entirely reliant on the skill of the Master to try
to avoid incurring high snatch loads on the towline, but even
the most talented skipper cannot preclude all such events.
Trying to manage towline loads by manoeuvring a 1000 t
vessel is not practical and ultimately leads to less efficient
force application to the attended ship.
Figure 2. A typical big escort winch type DESS-52 on the
Crowley tug Response, which escorts tankers in the Straits of Juan
de Fuca off Washington state in the US.
Figure 3. A tug assists the disabled LNG tanker, Catalunya
Spirit, 33 miles east of Massachusetts, US, in February 2008.
The tankers operator, Teekay Corp., contracted four tugboats
to assist the ship after it lost propulsion and became disabled.
One of the tugs was equipped with a Markey Render/Recover
Hawser Winch and Towing Winch. (Source: US Coast Guard
photo/PA3 Connie Terrell.)
LNG_MayJune_2013_79-82.indd 80 22/05/2013 10:28
Captain Greg Brooks, Principal at Towing Solutions
Inc., described the benefit of this new technology: If an
emergency were to happen and the tug turns to produce
250000 lbs of force, or if it suddenly hits a wave, the
tow line force is not going to be steady. The automatic
line tension feature allows the tug to have a spring
effect.
Brooks worked for Exxon as a tug captain and shore
side manager for 33 years before retiring and becoming a
consultant dedicated to improving the safety and
operational effectiveness of escort systems and general
towing operations. Brooks said that captains cannot
adjust quickly enough in these situations, but the
automated winch controls can. With this new
technology, the captain can increase or decrease the
sensitivity of the winch controls to match the tugs
movement with the period of the sea. For example, when
waves are high and the period between them is short, a
captain could dial up the winchs sensitivity to react more
quickly.
Origins of the automatic line
tension winch
In the mid 1990s, Markey Machinery Company developed
the first winch with automatic line tension in partnership
with Crowley Marine Services. The first Markey
Render/Recover