PHYSICS m2

Q.1 A jet of water whose cross- section is a, strikes a wall making an angle with normal and elastically rebounds. The velocity of water of density d is v. force exerted on the wall isa! " av" d cos b! av" d cos c! "avd cos d! avd cos Q." A force exerts as im#ulses j on a body which is changing it s#eed from u to $. The force and the motion of the body are along the same line. The work done by the force isa! % v"-u"!&" b! % v'u!&" c! % v-u!&" d! % v"'u"!&" Q.( A bullet is fired from a gun. The force on the bullet is given by- )*+,,-"x1, t -here ) is in newton and t in second. The force on the bullet becomes .ero as soon as it leaves the barrel. The average im#ulse im#arted to the bullet in /ew - ton- second isa! 1.0 b! .ero c! 1 d! ,.1 Q.2 3ix identical steel balls are lined u# in a straight frictionless groove made on a hori.ontal surface. Two similar balls moving with s#eed $ collide elastically with the row of six balls from the lift. Then a! one ball from the row moves with a s#eed "$ other balls remaining at rest. b! Two balls from the row moves with a s#eed $ each other balls remaining at rest. c! all the six balls in the row will move with a s#eed $&+ each and the two incident ball will come to rest. d! all the 0 balls move with a s#eed $&0 each. Q.4 A force of 2x'(x! newton acts on a #artical which dis#laces it from x* "m to x*(m. The work done by the force will be- a! (".0 joule b! (."0 joule c! ,.("0 joule d! .ero Q.+ A ball is dro##ed from a height on a stationary floor and rebounds several times until is sto#s. 5f the coefficent of restitution is e, then total distance covered by the ball the before it sto#s, would bea! e"h b! 1'e&1-e h c! 61'e" 7& 61-e" h7 d! 1'e!" h Q.8 A truck and a car having same kinetic energy are sto##ed by a##lying e9ual retarding forces. Then a! both will sto# at the same distance. b! truck will sto# at greater distance c! car will sto# at lesser distance d! car will sto# a greater distance and truck will sto# at lesser distance Q.0 A moving ball of mass m suffers a #erfectly elastic collision not head on! with a e9ually massive ball initially at rest. After collision, the two balls fly of at an angle between them, then is , :efore ;ollision a! , b! &2 c! &" d! Q.1 A #artical of mass m is made to move with uniform s#eed $ along the #erimeter of a regular #olygon of n sides, inscribed in a circle of radius a. The magnitude of im#ulse a##lied at each corner of the #olygon is < a! "m$ sin &n b! m$ sin =&n c! m$ sin n& d! "m$sin n& Q.1, A ball of mass m moving with a s#eed u undergoes a head on elastic collision with a ball of mass nm initially at rest. The fraction of the incident energy transferred to the heavier ball is a! n&n'1 b! n& n'1!" c! "n & n'1! d! 2n & n'1!" Q.11 A chain is #laced on a frictionless table such that its 1&4#art is hanging down over the edge of the table. if the lenght of the chain be l and the mass be m, then how much work will be done in #ulling u# hanging #art of the chain- a! mgl&4, b! mgl & "4 c! mgl& "4 c! mgl & 8.4 Q.1" A neutron traveling with a velocity v and >.? @?A collides #erfectly elastically head on with the nucleus of an atom of mass number A at rest . The fraction of total energy retained by neutron isa! 6A-1& A'17 " b! 6A'1& A-17 " c! 6A-1& A7" d! 6A'1& A7 " Q.1( The #otential energy between two atoms in a molecule is given by B x!*a&x-b& x,where a and b are #ositibve constants and x is the distance between the atoms. The atom is in stable e9uilibrium when a! x * +C11a & 4b b! x * +Ca & "b c! x*, d! x * +C"a & b Q.12 A rifle bullet loses 1&", of its velocity in #assing through a #lank. The least number of such #lanks re9uiied just to sto# the bullet is - a! 4 b! 1, c!11 d! ", Q.14 A cord is used to lower vertically a block of mass D by a distance d with constant down ward acceleration g&2 work done by the cord block is < a! Dg d&2 b! -(Dg d&2 c! (Dg d&2 d! Dgd

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Q.1+

Q.18

Q.10

Q.11

A thin circular of mass and r radius is roating about its axis with a constant angular velocity . Two objects each of mass m, are attached gently to the o##osite ends of the diameter of the ring The wheel now rotates with an angular velocity a! D & D ' "m! b! D & D ' m! c! D ' "m! & D d! D & D ' "m! A uniform solid s#here is resting on a hori.ontal surface. An im#ulse 5 is a##lied at a height at above the centre and its begin to roll without sli##ing! Then h&E is e9ual to a! 1&" b!"&4 c! "&8 d! 1&4 The angular momentum of a flywheel having a moment of interia of ,.2 kg m" decreases from (., to ,., >g&m"&s in a #eiod " seconds. The average tor9ue acting on the flywheel duing this #eriod is a! 1, /= m b! ".4 / =m c! 4/=m d! 1.4 / m A Farticle of mass 4 gm is moving with a uniform s#eed of (" cm&s in the x y #lane along the line y * x ' 2. The magnitude of its angular momentum about the origin in gm"-cm" & sec is -

a! .ero b! (, c! (, " d! +, Q.", Two man A and : are carrying a uniform bar of length G on their shoulders. Teh bar is hel d hori.ontally such that A gets a&2 load. 5f A is at one end of the bar, the distance of : from that ens is a! G&( b! G&" c! "G&( d! (G&2 Q."1 A meter stick is held vertically with one end on the floor and is then allowed to fall. The s#eed of the other and when its hits the floor assuming that end at floor does not sli# a! (." m&sec b! 4.2 m&sec c! 8.+ m&sec d! 1." m&sec Q."" 5f earth rotates x times faster than its #resent s#eed about axis in order that bodies lying on its e9uator just off into s#ace, then x is nearly given by a! x*1 b! x*" c! x * 18 d! x * "01 Q."( Two uniform circular disc A and : e9ual masses and thickness are made of materials of densities dA and d: res#ectively. 5f their moment of inertia about then axis #assing through the centre and normal to the circular face are 5A and 5: res#ectively then 5A&5: * a! d:&dA b! dA&d: c! d":&d"A d! d"A&d": Q."2 A Farticle #erforms uniform cicular motion with an angular momentum @GA. 5f the fre9uency of #articles motion is doubled and its kinetic energy is halved the angular momentum be comes a! "G b! 2G c! G&" d! G&" Q."4 A solid cylinder of radius are free to rotate about the axis which are hori.ontal. A string is wound around it and a mass @mA is attached to its free end. when m falls through a distance h, its s#eed at that instant is a! Fro#ortional to E b! Fro#ortional to 1&E " c! Fro#ortional to 1&E d! 5nde#ended to E Q."+ A false balance has e9ual arms. An object weights x when #laced in one #an and y when #laced in the other #an. The true weight of the object is e9ual to a! xy!1&" b! x ' y & " c! x" ' y" & " d! x" ' y"!1&" & " . Q."8 5n a figure a * +cm and b * ", cm. 5f the moment of interia of the system is (",, kg-m", its angular acceleration would be a! 1,-1 rad&s" b! 1,-" rad&s" c! 1,-( rad&s" d! 1,-2 rad&s" A disc of mass D and radius r rolls on a hori.ontal surface and then rolls u# an inclined lane as shown in figure. 5f the velocity of the disc is $, find the height h to which the disc will rise on the incline a!h * (v" & 2g b!h * 2v" & (g c! h * v" & (g d!h * "v" & (g A smooth rod of two smooth fixed su##orts A and :. )rom a #oint ; on it a ball of mass 1 kg is sus#ended by an inextensible string of length 1m. -hen the string makes on angle (,, with vertical, the ball is released from its rest #osition. /ow when the string makes a maximum angle with the vertical on the other side, then the dis#lacement of the rod would be - a! , b! ,." m c! ,."4 m d! ,.4 m

Q."0

Q."1

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Q.(, Q.(1

The H-com#onent of angular momentum is given by a! %H * x#I - y#J b! %H * y#I - x#J c! %H * .#I - y#J

d! %H * .#I - x#J

An infinite number of indentical #oint masses each e9ual to 1 kg are #laced at #oints x * 1, x*", x*2, x*0, The total gravitational #otential at #oint x * , is a! -K b! -"K c! -2K d! /one Q.(" A body is sus#ended from s s#ring balance ke#t in a satellites. The reading of the balance is -1 when the satellite goes in a orbit of radius E and is -" when it goes to an orbit radius "E. Then a! -1 * -" b! -1 L -" c! -1 M -" d! -1 * -" Q.(( Two #articles of mass m and " m are at rest at infinite se#aration. 5f #articles are left, they move towards each other due mutual interaction. Then their relative velocity of a##roach when the se#aration between them reduced to 1m is a! "KD!1&" b! 2KD! c! +KD!1&" d! 0KD!1&" Q.(2 5magine a #lanet revolving aroundf a star in circular orbit of radius E with a #eriod revo lution T. 5f the gravitational force of attaraction between #lanet and star is #ro#ortional to E -4&" , then T" is #ro#ortional to a! E 4&2 b! E 4&" c! E 8&2 d! E 8&" Q.(4 A #article of mass ,.+8 kg is at a distance of ,."(m from one end of a uniform rod of length (., m and mass 4., kg. The magnitude of graviational force due to rod on the #article is a! 4.2 x 1,-1 / b! 1." x 1,-1, / c! (., x 1,-1, / d! 4.2 x 1,-11 / Q.(+ Two metallic balls of mass D are sus#ended by two strings of length G. The distance between u##er ends is l. The angle at which the string will be inclined with vertical due to alteration is a! tan-1 KD & gl" b! tan-1 KD & gl" c! tan-1 KD & gl d! tan-1 KD & gl Q.(8 The largest and the shortest distance of the earth from the sun r1 and r" its form the sun when it is at the #er#endicular to the major axis of the orbit drawn from the sun. a! r1 ' r" &2 b! r1 r" &r1 ' r" c! "r1 r" &r1 ' r" d! r1 ' r" & ( Q.(0 A s#herical hollow is made in a lead s#here of radius E such that its surface touches the outside surface of the lead s#here and #asses through its centre. The mass of the s#here before hollowing was D, with what force according to the law of universal gravitational will the hollowed s#here attract a small s#here of mass m, which lies at a distance d form the centre of the lead s#here on the straight line connecting the centres of the s#heres and of the hollow. a! "KDm&d"61-1 & 0 1-E&"d!"7 b! "KDm&d"61-1 & 2 1-E&"d!"7 c! KDm&d"61-1 & 0 1-E&"d!"7 d! /one of these Q.(1 These concentric sheels of uniform density heve masses D1 and D" and their are res#ec tively A #article of mass m is #laced at a distance d form the centre, such that E"MdME1. The net force on the #article is a! KD1m & d" b! K D1' D"! m c! K D1' D"! m & d-E1! E" - d! d! /one of these Three Farticles each of mass m are situated at the vertices of an e9uilateral triangle of side a. Nnly mutual gravitational forces are acting between the #articles. /ow these #ar ticles move in a circle in such away that their mutual se#aration a remains unchanged. The s#eed of the #articles will be a! "Km&(a!1&" b! "Km & a!1&" c! Km&"a!1&" d! Km & a!1&" A test tube with some lead shots in it has a total mass D gm. 5t floats u#right in a li9uid of density d gm&#er cm(. The cross sentional area of the tube is A cm". 5t is #ressed sightly

Q.2,

Q.21

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Q.2"

Q.2(

downwards from #osition of stable e9ili brium and released , then it executes a 3OD with a #eriod of a! T * " m &Agd!1&" b! T * " m &"Agd!1&" c! T * " m &Agd!1&" d! T * " DA &Agd!1&" A ball of mass m is fixed at the middle of a hori.ontally streched string of lengthl. The tension in the string T, is assumed to be constant and TMMmg. Then the #eriod of oscilla tions in a vertical #lane, Ferformed by a! " ml & T!1&" b! " ml & "T !1&"1 c! ml & T!1&" d! " m & lT!1&" A uniform s#ring whose unstressed length is l has a force constant >. The s#ring is cut in two #ieces of unstressed lengths l1 * nl" being an interger. -hat are the corres#onding force constant >1 and >" in terms of n and > P a! > n'1&n!, > n'1! b! >n& n'1!, > n c! >n, > n'1! d! l n'1!, > n! A sim#le #endlum set u# to swing in front of a second #endulum of a clock is seen to gain so that the two swing in #hase at intervals of "1 seconds. The time of vibration of the sim#le #endulum is a! 1.4 3econds b! 1.0( 3econds c! 1.18 3econds d! ?ither1.0( 3econds or 1.18 seconds Two linear sim#le harmonic motions of e9ual am#litude and fre9uencies and " are im#ressed on a #article along the axes of x and y res#ectively. 5f the inital #hase differ ence between them is &", find the resultant #ath followed by #articles. a! y" * x" 61-x" & A"7 b! y" * "x" 61-x" & A"7 c! y" * x" 61'x" & A"7 d! y" * 2x" 61-x" & A"7 A body of mass D and charge 9 is sus#ended from a s#ring when sightly dis#laced, it oscillates with #eriod T. 5f a uniform electric fields acts vertically downwards then the new time #eriod will be a! TA L T b! TA M T c! TA * T d! /othing can be said A body of mass D is situadted in a #oetntial field B x! * BN 1 - cos x!, where BN and Q are constants. The time #eriod of small oscillations will be a! " D& "B,!1&" b! " BN & D"!1&" c! " DBN"! d! " BN"&D!1&" 5n the adjoining figure the velocity i! and acceleration ii! of a #article executing 3OD are shown. The time #eriod of the #article is a! 1"4& Q b! & Q 1"4 c! ".4 d! 1 & 1."4 A uniform rod of length l1 #ivoted at N is de#icted in the following figure. The moment of interia of the rod about the axis #er#endicular to the rod and #assing through #oint N is 5, A mass m sus#ended from one end of the s#ring is connected with one end or rod as the shown figure. The s#ring constant of the s#ring is >. Eod in balanced #osition is hori.on tal. 5f rod is set in to small oscillations, then its fre9uency a! 1&" 25 ' ml" & kl"!1&" b! 1&" kl" & 25 ' ml"!1&" c! 1&"Q Q 25 ' ml & kl"!1&" d! 1&" kl" & 5 ' ml" !1&" 5n arrangement given in figure, if the block o#f mass m is dis#laced, the fre9uency is given by < a! n * R >1- >" & m!1&" b! n * 1&" >1' >" & m!1&" c! n * 1&" m & >1' >" !1&" d! n * 1&" m & >1- >" !1&" A uniform ro#e of length l lies on a table . 5f the coefficient of friction is , then the maximum length l1 of the #art of this ro#e which can overhang from the edge of the table without sliding down is a! l & '1 b! l & -1 c! l & '1 d! '1& l

Q.22

Q.24

Q.2+

Q.28

Q.20 Q.21

Q.4,

Q.41

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Fulling force making an angle Qto the hori.ontal is a##lied on a block of weight #laced on a hori.ontal table. 5f the angle of friction is , the magnitude of force re9uired to move the body is e9ual to a! - sin & ;os S Q- !T b! - cos & cos S Q- c! - tan & sin SQ - !T d! - sin & tan Q- !T Q.4( Two blocks A and : each of mass m are connected by a massless s#ring of natural length G and s#ring constant >. The blocks are initally resting on a smooth hori.ontal floor with the s#ring at its natural length, as shown figure. A third indentical block ;, also of mass m, moves on the floor with a s#eed v along the line joining A and :, and collides with A. Then a! The kinetic energy of the A-: system, at maximumcom#ression of the s#ring, is mv" & 2 b! The maximum com#ression of the string is vQ m & "k!1&" c! both A U : d! /either A nor : Q.42 A car running at "4km&h can be brought to rest by a##lying brakes in a distance of ,.4 m. if a car is running at at 84km&h , how far will it go before it coming to rest , if the braking force remaining the sameP a! 1 m b! " m c! (m d! 2.4 m Q.44 A car accelerates from rest to a s#eed of 1, m&s. Get energy s#ent be ?. if we accelerate the car from 1, m&s , the energy s#ent will bea! ? b! " ? c! ( ? d! 2? Q.4+ A vehicle is moving on a hori.ontal road at a constant s#eed of 1, m&s. The engine needs to s#end 4 kj energy #er second. what is the force of the #er vehicle. a! 4, k / b! 4 k / c! ,.4 k / d! ,.,4 k / Q.48 A s#ring is held com#ressed. its stored eergy is ".2 joule. its ends are in contact with masses of 1 gm and 20 gm #laced on a smooth hori.ontal surface. when the s#ring is released , the mass of 20 gm will ac9uire a velocity ofa! ".2,&121 m&s b! "2 x 21 & 20 m&s c! 1, & 8 m&s d! 1,2&8 m&s Q.40. A moving mass of 0 kg collides elastically with a stationary mass of " kg. if >.? will of the moving mass , the kinetic energy left with it after the collision will bea! ,.0, ? b! ,.+2 ? c! ,.(+ ? d! ,.,0 ? Q.41 A ball collides elastically with another ball of the same mass. The collision is obli9ue and intially one of the ball was at rest. After the collision , the two balls move with same s#eed. what will be the angle between the velocity of the balls after the collision P a! (,, b! 24, c! +,, d! 1,, Q.+, A ball im#ings directly on a similar ball at rest. The first ball is brought to rest by the im#act. if half the kinetic energy is lost by im#act, what is the value of the coefficient of restitutionP a!1 & "" b!1 & ( c! 1 & " d! ( & " Q.+1 Two e9ual billiard balls are in contact on a table. A third e9ual ball strikes them sym metrically and remains at rest after im#act. The coefficient of restitution is a! "&( b! 1 & ( c! 1 & + d! ( & " Q.+" A mass of ,.1 kg attached to a string 1 m long is rotated in such a way that it just de scribes a vertical circle of radius 1 m. which statement& statements, is &are correcta the tension has the lowest value of 1.1+ units. b! there are at least two #oints in the #ath where the angular momentum is ,.42"" unit c! both A and : d! neither A nor : Q.+( A motor drives a body along a straight line with a constant force. The #ower F develo #ed by the motor much very with time asa! b! Q.4"

c!

d!

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Q.+2

The ratio of the radii of the #lanets F1 and F" is k1. The ratio of the acceleration due to the gravity on then is >".The ratio of the esca#e velocities from them will bea! k1 k" b! k1 k" !1&" c! k1& k"!1&" d! k"& k1!1&" A satellite is orbiting around the earth with a #eriod T. if the earth suddently shrinks to half its radius without change in mass, the #eriod of revolutoon of the satellite will bea! T&" b! T&" c! T d! T A stellite is revolving around the earth in a circular orbit 2 times the radius of the #arking orbit. what will be the time #eriod of the satellite P a! " days b! 2 days c! 1"+ days d! /one of the above A #lanet is revolving around the sun in elli#tical orbit. its closest orbits from the sun is r and the farthest distance is E. if the orbital velocity of the #lanet of the #lanet closest to the sun be v,then when is the velocity at the farthest #ointP a! vr&E b! vE&r c! v r & E!1&" d! v E&r!1&" Two satellites 31 and 3" revolve round the #lanet in co#lanar circular orbit in the same sense and their #eriods of revolution are one hour and eight hours.The radius of orbit of 31 is 1, km. what will be the angular s#eed of 3"as observed from 31 when they are closest to each other a! & Q ( radian & hr b! "&( radian & hr c! radian & hr d! " radian & hr The orbital #eriod of a statellite in a circular orbit of radius r about s#herical #lanet of mass D and mean density # for a low altitude orbit will bea! 6(& Q K#71&" b! 6( K#71&" c! 6Q& K#71&" d! 6" K#71&" A loo# and disc have the same mass and roll without sli##ing with the same linear velocity v. if the total kinetic energy of the loo# is 0 , the kinetic energy of the disc must be a! +j b! 0j c! 1,j d! 1" % A right hori.ontal smooth rod A: of mass ,.84 kg and length 2, cm can rotate freely about a fixed vertical axis through its mid #oint N. Two rings of mass 1 kg initially at rest at a dis tance of 1, cm from N on either side of the rod. the rod is sent in rotation with an angular velocity of (, radins #er sec. when the rings reach the ends of the rod, then angular veloc ity in rad& sec isa! 1, b! 14 c! ", d! "4 A wheel and an axle, having a total moment of inertia ,.,," kg m" , is caused to rotate about a hori.ontal axis by means of an 0,, g mass attached to a called assumed massless! that is wound around the axle. The radius of the axle is " cm. starting from rest , how far must the mass fall in order to give the wheel a s#eed of ( rev.&sP a! "."4 cm b! (."4 cm c! 2.4 cm d! 4."4 cm -hen 1,, j of work is done u#on a flywheel its a angular s#eed increases from +, rev&min to 10, rev.&min. The moment of inertia of the flywheel is a! ,."1 kg-m" b! ,.+( kg-m"s c! ,.02 kg-m" d! 1.,4 kg-m" 5f a sim#le harmonic oscillator has got dis#lacement of ,.," m and accleration e9ual to "., m&s" at any time , then angular fre9uency of the oscillator is e9ual to a! 1, rad&sec. b! ,.1 rad&sec. c! 1,, rad&sec. d! 1rad&sec.s A sim#le harmonic oscillator has an am#litude a and time #eriod T. The time re9uired by it to travel from x * a to x * a&" is. a! T&+ b! T&2 c! T&( d! T&"

Q.+4 Q.++ Q.+8

Q.+0

Q.+1 Q.8, Q.81

Q.8"

Q.8(

Q.82

Q.84

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CHEMISTRY
Q.76 "# the intial concentration of a reactant A is 9uadru#les and the rate of the reaction is doubled, the order of reaction w.r.t. A is A! first :! one-half ;! .ero V! second Q.77 The rate constant of a reaction is 1."x1$% mol-"G"s-1.The order of reaction is a! , b! 1 c! " V! ( Q.80 The rate constant of a reaction has the units as that of rate of reaction. The reaction order is a! , b! 1 c!" V! ( Q81 5n the first order reaction, 84W of the reaction disa##eared in ".(,( h. ;alculate rate constant of the reaction A! ,.+,", h-1 c! ,.,+,", h-1 b! +.,", h-1 d! ,.(,1, h-1 Q0, 5f initial concentration is doubled, the half-life #eriod of reaction is also doubled. The order of reaction is A! .ero :! third ;! second V! first Q01 5dentify the state function among the following A! 9 :! 9 - w ;! 9&w V! 9 ' w Q0" -hich one of the following conditions corres#onds to a transformation that cannot take #lace at all P A! O,-ve and3o've :! O,-ve and So -ve ;! Oo've and 3o-ve V! O,'ve and3o've Q0( 5n an endothermic reaction, the energy of the #roducts (A) is less than that of the reactants :! is greater than that of the reactants ;! is same as that of the reactants V! is .ero Q02 OessXs law of heat summation includes A! initial reactants only :! initial reactants and final #roducts ;! final #roducts V! intermediates only Q04 )or the reaction ; s! ' Y" g! Z ;N" g![ l. -rxn * - (1( k% Oow many grams of ; s! must be burned to release "84 k% of heatP A! "".( g ;! 1".,1 :! ,.8, 1 V! 0.2, 1 Q0+ Oow much heat is absorbed from the surrounding, when 14g of N" react according to the e9uationP ,' N" N( O,r\n * 1,( k% A! 2.+ x 1,-( k% :! 20 k% ;! 1+ k% V! (" >j Q.08 The N.3. of oxygen in Ft)+ is a! .ero b! ' R c!' 1 d! -1&" Q 00 The oxidation number of Je in JeN)" is A! , :! " X ;! 2. d! ( Q 01 The oxidation number of #hos#horus in ATF adenosine tri#hos#hate! is A! 2 :! ( ;! 4 V! ". Q1, The oxidation number of oxygen in #otassium su#eroxide >N" is A! < " :! - 1 ;! -1&" V! -1&2. Q.11ln the reaction] 2)e ' (N" 2)e(' ' +N"- -hich of the following statement is correctP A! A redox reaction :! )e is reducing agent ;! )e(' is an oxidi.ing agent V! )e is reduced to )e(' Q1" The reaction] O"3 ' O"," 3 ' "O"N manifests A! acidic nature of O"N" :! alkaline nature of O"N" ;! Nxidi.ing action of O"N" V! Eeducing action of O"N" Q1( The unit of electrochemical e9uivalent is A! g :! g A-1 ;! g ;-1 V! ; g-1 &94 -hich one of the following molecules can not serve as a monomer for an addition #olymerP 'A( C"C) * ;O" :! O";* ;O;/ V! ;O(;NO)'C( ) C ** C)%;+O4 Q 14 -hat ty#e of #olymer is re#resented by the following segmentP + %COC) C) %CO%OC) C) O% A! #olyamide :! #olyester ;! #olyolefin V! #olyethylene

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.Q 1+ -hich one of the following is a #oly-hydrocarbon P A!starch :! natural rubber ;! casein V! terylene Q18 -hich of the following, glycol is an im#ortant constituentP A! Vacron :! acrilan ;! teflon V! viscose rayon Q10 -hich of the following statement is incorrectP A! Folyth-ethylene contain double bonds :! the monomer used to make teflon is ;")2 ;! condensation #olymers are known as co#olymers V! a denatured #rotein could have the same #rimary structure as the active #rotein Q 11 ?lectron affinity for a noble gas is a##roximately.e9ual to A! that of halogens :! .ero ;! that of oxygen family V! that of nitrogen family

Q 1,, 3i.e of ionic s#ecies follows the order ] A! 5L 5'L 5 :! 5- L 5 L 5' ;! 5'L5L5V! 5'L5-L5

&1$1 )ind the e.m.f. of the following cell at "4Y;. A5&A5'( ,.1 D!&Al'( ,."D!&Al A! ,.,8 volts :! 0.0059 volts ;! ,. ,,1 volts V! ,.1 volts

Q1," -hen 3N" gas is #assed through an acidified solution of >";r"N8 A! The solution becomes blue :! The solution becomes colourless

;! 3," is reduced V! Kreen ;r" 3,2!( is formed. Q.103 The first order rate constant for the decom#osition of /Fs is +.1J1,-2sec-5.-hat is the half life #eriod for this decom#ositionP 'A( 1118.8 sec ;! 1300sec :! 14$$sec V! 1500sec. Q1,2 A first order reaction takes +1.( minutes for 4,W com#letion. Oow much time will be needed for 0,.W com#letionP 'A( 1+,.1 min ;! (,.,min :! ",., min V! 2,., min & 1$5 Nn adding ammonium hydroxide solution to a9ueous A5" 3,2!( A! A #reci#itate is formed which does not dissolve in .excess of ammonium hydroxide. . d! /one :! A #reci#itate is formed which dissolves in excess of ammonia solution ;! /o #reci#itate is formed Q1,+ Dost ionic chloride is A! Fb;5" :! ;;52 ;! Fb;l2 V! 3i;52 Q1,8?va#oration of water is] A! An exothermic change :!An endothermic change ;! A #rocess where no heat change occur V! A #rocess accom#anied by chemical reaction. &1$85n which of the following neutrali.ation reaction, the heat of neutrali.ation will be highestP A! /O2NO and O"3N2 :! O;5 and /aNO ;! ;O(;NNO and >NO V! ;O(;NNO and /O2NO &1$9The rate constant of forward and backward reactions for certain hy#othetical reaction are 1.1x1, -" and 1.4 x1,-( res#ectively. The e9uilibrium constant for the reaction is ] A! 8.(( ;! 8(..( :! .,.8(( V!8(( &+11$ -hich of the following ex#ression is correct for first order reactions ;o refers to initial concentration of reactant! A! t1, ;o ;! t1, ;,-" :! t1&" ;o-5 V! t1&" ;oo Q111 11W of a first order reaction was com#leted in (" minute. -hen will 11.1W of the reaction com#lete A! 4, min :! 2+ min ;! 21 min V! 20 mi Q11" )or a hy#othetical reaction[ A- G, the rate ex#ression is]

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Eate * -d;A&dt a! negative sign re#resents that rate is negative :! negative sign #ertains to the decrease in the concentrations of reactants. ;! negative sign indicates the attractive forces between reactant. V! none of the above is correct. &113 Among the following reactions, the fastest one is] A! burning of ;oal :! rusting of iron in moist air ;! conversion of monoclinic sul#hur to rhombic sul#hur V! Freci#itation of silver chloride by mixing silver nitrate and sodium chloride solutions Q114Foint out the incorrect statement A! Eate law is an ex#erimental fact where as law of mass action is a theoretical #ro#osal. :! Eate law is always different from the ex#ression of law of mass action.! ;! Eate law is more informative than law of mass action for the develo#ment of mechanism V! Nrder of reaction is e9ual to the sum of #owers of concentrations terms in the rate law. &115 A hy#othetical reaction A" ' :" "A: follows the mechanism as given below] A" L A ' A fast! A ' :" A: ' : 3low! A ' : A: fast! The order of over all reaction is] A! " :! 1 ;!11&" V! , Q11+ )or hy#othetical chemical reaction A 5, it is found that the reaction is third order in A. -hat ha##ens to the rate of reaction when the concentration of A is doubled A! rate increases by a fraction of ". :! rate decreases by a factor of ( ;! rate increases by a factor of 0. V! rate remains unaffected. &117 -hich of the following rate laws has the over all order of the reaction e9ual to ,.4 A! r * k6x71&" [y]1/2 [z]1/2 :! r * k6J7(&"6y7-16.7, ;! r * [x] 6y7, 6z]-1 V! r * k6x7 6y7 [z] &118 A chemical reaction involves two reacting s#ecies. The rate of reaction is directly #ro#ortional to the conc. of one of them and inversely #ro#ortional to the concentration of the other. The order of reaction is A! 1 :!" ;! .ero ,! un#redictable Q111 The standard free energy change G$! is related to e9uilibrium constant >! as ] A! G$ * % +3$3 ET ?n > :! G$ * ,3$3 ET log > ;! G$ * ET log > V! G$ * % +3$3 ET log > &1 $ 5n #resence of dil O"3N2 the e9uivalent weight of >DnN2 is] A! 1&4 of itsX molecular weight :! 1&+ of its molecular weight ;! 1&1, of its molecular weight V! 1&" of its molecular weight Q1"1 -ith the hel# of following data, find out the change in heat content for the reaction] C )4 'g( ' O" g! K"Oe g! ;"O+ :ond :ond energy >%! ;-O 21( ;-; (20 ;*; +1, O-O 2(+ 'A( -1"0 >% ;! ' "4+>% :! '1"0 >% V! -"4+ >% Q1"" Vuring electrolysis of O"N, the molar ratio of O" andN"formed 5s ] (a) " ] 1 :! 1 ] " ;!1](

V!1]1

Q1"( To #roduce 1+,g of oxygen, the number of moles of water re9uired to be electrolysed is ] A! ".4 0! 4 ;!1, V!",

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Q1"2.Oow many coulomb of electricity are consumed when1,, mA current is #assed thorugh a solution of Ag/N( for (, minute during an electrolysis ex#eriment] A! 1,0 :! 10,,,, ;! 10, V! (,,, Q1"41.0 g of metal were de#osited by a current of ( V am#ere for 4, minute. The e9uivalent wt. of metal is A! ",.4 0! "4.0 ;! 11.( V! (,.8 Q1"+ )ind out the concentration of Hn'" ion in the right half of the cell ] Hn ^ Hn'" ,.,1 D!^Hn' D *P!! ^Hn if its e.m.f. at $-C * $+$ $! volts. A! ,.,01" D :! ,.,211"D ;! ,.,10 D V! ,.,,8 D Q1"8 ,."1+2 gram of co##er was de#osited on #assage of a current of ,.4A for (, minutes throught a solution of co##er sul#hate. ;alculate the atomic weight of co##er 1 )araday * 1+,4,, coulombs!. A! 0,."2 gram '.( 9$+14 gram ;! !3+5! gram '/( !9+14 gram Q1"0 The density of co##er is 8.94 g/ml. )ind out the number of coulombs needed to #late an area 1Ncmx1Ncm to a thickness o# 1$% c0. using ;u3N2 solution as electrolyte 6;u * +(.4[ one faraday * 1+,4,, coulombs7 'A( 11.2(2 ;!"8,18" :! (4,+80 V! 2,,18" &1 9 The weight ratio of A5 and Ag de#osited using the same 9uantity of current is ] X A! 1 ] 1,0 :! " ] 1" ;! 1,0 ] 1 V! ( ] 0
Q 129 ;is-1 ,2-#olybutadiene is ex#ected to be ] a! Thermo setting #lastic b! Thermo#lastic c! Eesin d! ?lastic rubber! Q130 :una-3 is a #olymer of ] a! :utadiene and styrene b! f(utadiene ;! 3tyrene d! :utadiene and chloro#rene &131 Oigh density #olyethylene OVF?! can be #re#ared )rom ethylene by ] A! Hiegler-/atta #rocess b! Oeating with #eroxides ;! ;ondensing in sealed tubes d! condensing with styrenes

Q 1(" A radioactive element has a half-life of one day. After three days, the amount of the element left will be A! 1&" of the original amount :! 1&2 of the original amount ;! 1&0 of the original amount V! 1&1+ of the original amount Q.1(( 5f 0., gm of a radioactive isoto#e has a half-lifeof1, h, the half-life of "." 1 of the-same substance is A!".4h 0!4h ;!1,h V!2,h

&134 841o 1$ 8 1b $! 2 4 )e
If the gro3p n30ber of 8 1b is 14, then gro3p n30ber o# 84 Po is 'A( 1 '.(1! 'C(4 '/( ! 38 &135 A#ter the e0ission of an a%particle #ro0 the ato0 9 4 , the n30ber of ne3trons in the ato0 5ill be 'A( 138 '.( 14$ 'C( 144 '/( 15 &13! "# 3rani30 '0ass n30bers 38 and ato0ic n30ber9 ( e0its an a%particle has 0ass n30ber and ato0ic n30ber ( 3! and 9 'C( 38 and 9$ '.( 34 and 9$ '/( 3! and 9$ &137 6hich one of the #ollo5ing 0olec3les can not ser7e as a 0ono0er #or an addition poly0er8 'A( C"C) * ;O" :! O";* ;O;/ V! ;O(;N%O)'C( ) C ** C)%;+O4 Q138 The half life #eriod of a radio-active nuclide is ( hours. 5n 1 hours its activity will be reduced by A!1&1 :! 8&0 ;! 1&"8 V!1&X+ Q139 The binding energy of an element is +2Dev. 5f :?& nucleon is +.2, the number of nucleons are] A!1, :!;2 ;!1+ V!+ Q.12, 3uccessive emission of al#ha-#article and two beta-#article by an atom of an element results in the formation of A! 5sodia#her :! 5somor#h ;! 5soto#e V! 5sotherm. &141 Facking fraction is related to] A! Dass defect :! Atomic number ;! /uclear s#in V! /one &14 6hat is the true for the reaction] 1C"5 'g( 1C"3'g( ' ;l" g! A! H * ? :! O M ? ;! O L ? V! /one ofthese &+143 )ollowing adiabatic conditions, work done on the system is e9uivalent to 4,,ca_. -hat are the values of 9, -, and ?P A! 9 * -4,,, ? * ,, - * '4,, :! 9 * ,, ? * '4,, - * -4,, ;! 9 * a - * ' 4,, ? * -4,, V! 9 * , - * ? * 4,,

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&+144 The gaseous endothermic reaction] 1, 1 2 & 9 at "8Y; takes #lace s#ontaneously, because A! O L ,[ 3 L , 0! ZO M ,] Z3 M , ;! ZO L ,[ Z3 M , X ,! ZO M , [ Z3 L a $+145 5ce and water are at e9uilibriulT% at "8(> because] A! O M T3 :! O * T3 ;! OL T 3 V! K is #ositive Q.12+ )or the va#ourisation of water] O"N(L) L*M O"N g! 61 atm. #ressure7 Kiven ,3] 1 $ :;%1 and ) ** 245+$;: <7al3ate the tem#erature at which li9uid water and water va#ours are in e9uilibrium at 1 atm. #ressure. A! "8( > :! (8,> ;! (8( > V! (84 > &+147+ +5 > cal heat is released in the combustion of " gm methane. The heat of combustion of methane will be] A! 1, > ;al :! ", > cal ;! (, > ;al V! 2, > ;al &+149 Turn :ullAs blue is] A! )e( 6)e ;/!+7" :! >2)e;/+ ;! >()e ;/!+ V! a! "e(# )$ &+15$ >DnN2 in acid medium is always reduced to] A! Dn2' 0! Dn"' ;!Dn+' V! Dn

------------------------------------------------------------------------------------------------------------------------------PCC Opposite Gopichand Arya Mahila college 11 College road , Abohar, Cell 9417135881