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Answeranytourquestions.i,p
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a) Polysaccharides playan importantroleastiructuralandstoragecompoundsin plants.
By givingone examplefor eachof thesecompounds, explainhowtheirmolecular
structuresare relatedto theirfunctions.
[8 marks]
(b) (i) Withthe aid ot a diagrarn,showhow a triglycerideis formedthroughthe
esterificationprocess.
[3 marks]
(ii). Describethe structureof lecithinand its importancein cell membranestructure.
[4 marks]
are two groupsof autotrophicorganisms.
and photoautotroph
6. Chemoautotroph
Methane 16 -182
Ammonia 17 -33
Water 18 100
Explainwhy thesethreehydrideshaveverydifferentboilingpoints.
[4 marks]
CONFIDENTIAL-
2NO(g)+ Oz(g)-,2NOz(9)
of NOz
the concentration
Therateof reactioncan be foundby measuring
at differenttimes.
Definethe term rate of reaction.
Sketcha graphto showhowthe concentration of NO2changeswithtime.
Indicatehowthe initialrateof reactioncouldbe obtainedfromyourgraph.
[4 marks]
of sulphurtrioxidefromsulphurdioxide,nitrogen
(ii)In the manufacture
monoxide can be usedin a two-stageprocessto increasethe rateof
production.
1 CHsCHzCOOH 4.9
2. CHoCHCICOzH 2.8
3 CHgCCIzCOOH i.+
4 CHzCICHzCOOH 4 . 1
acid(acid1).
the pH of a 0.010motdm{solutionof propanoic
(iii)Calculate
[6 marks]
+ u{ +4-
l,.lA
't
,
l/ -
t+fJLA'J
\.q - fr rn-l
LN ffJ
kqtno] =t+*t[u]
roH+ =[rrl
q k.Hr 'rgodl
CONFIDENTIAL-
(ii) Statewhatyouwouldobservewhenchlorinewaterreactswitha
solutionof potassiumiodide.Writean equationfor the reaction.
Statethe roleof chlorinein the reaction.
[3 marks]
betweenseparate
(iii)Givea reagentwhichcouldbe usedto'distinguish
sotutionsof potassiumbromideandpotassium iodide.Statewhatwouldbe
observedwhenthis reagentis addedto eachof the separatesolutionsof
potassiumbromideand potassium iodide.Writean equationfor one of the
reactions.
behavein differentwayswhen
andsilicontetrachloride
(b) Carbontetrachloride
addedto water.Statehoweachchloridebehavesandexplainthe differen@.
[5 marks]
gS=
3f
\.i )r'-)gb
CONFIDENTIAL*
hydroxidehasa numericalvalueof
(c) Thesolubilityproduct,K"o,of magnesium
2.0x 10-11.
in a
of Mg(OH)z
(ii)Usethe valueof K"ogivento calculatethe concentration
saturatedsolution.
0
I
1\ *-
q5
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CONFIDENTIAL* 30
of the reactionwhen1-chloropropane
g. (a) (i) Writethe mechanism is refluxedwith
aqueoussodiumhydroxide. Nameof the typeof reactioninvolved [3 marks]
to
(iii) Writeequationsto showhowyouwouldchange 1-chloropropane
2-chloropropane [5 marks]
H H
I
I I
H2N-C{OOH H2N-C{OOH
ll
cHg cH2oH
alanine serine
formedin b(i).
(ii) Nameone of thedipeptides
,*ttd ,""u
"it
CONFIDENTIAL* 2
1, Findtheangle
between
vectors
aandOitlel=s, lpl=Sandla-4=Z QD*"t
[4 ma*sl
5.
a) Provethat ,
i) BA = BC. rksl
ai) ZBAC= ZADC. rksl
b) lf AC = AD, provethattriangleACD and triangleBCA are similar\riangle{.
\ ftnlarksl
954t2
*Thisquestion
paperis CONFIDENTIAL
untiltheexamination
is over. CONFIDENTTAL*
CONFIDENTIAL*
(a) Findliry1f(x)andjgrt"l.
Hence,determine at x = 1.
whetherf is continuous [3 marks]
95411
*Thisquestion
papbris CONFIDENTIAL
untiltheexamination
is over.
CONFIDENTIAL*
GONFIDENTIAL*
A y=- J.-j---._.
y=6_xx;T
;theequation
Acurvehastheequation
(a) Writetheequations
of theasymptotes
of thiscurye. [2 marks]
(b) Findtheturningpointsanddetermine
its nature. [5 marks]
(c) Sketchthecurve. [3 marks]
9 S h o w th a tth e e q u am2x+y-
ti on Bm =0is atangenttothe
cuvexy =16for
fl valuesof m, m * 0.
A perpendicularlinefromthe originmeetsthis tangent at R. Findthe coordinates
of R in termsof m .
Showthat the equationof the locusof R as m variesis (x' + y,Y -- 64xy.
[10 marks]
(k 1 -1 )
a =12-3 1 l,
[z 1 2J
(1 2 3l
e= 12 3 4 .' ,
['' 5 6)
(o -17
6 = l- 6 6 - 3 8
[51 34
:l
ol
Showthat k = 1 if the determinantof A is- 17.
D" rksl
*Thisquestion
paperis coNFIDENTIAL
untiltheexamination
is over.
CONFIDENTIAL*
2. By usingfirst principles,
showthat the valueof the firstderivativeof
xelRatx=a is3a2.
a"-n(bn-an\
5. Thesumoffirstntermsofaserier
t it
* i, b + a .
Findthe nn term of the series. arksl
I
Xence,
showthattheseriesis a geometric
series. r@'r'r
\(
cryn \)
lr-
C- C- C-
L -Ll
I
/' \
*v
q C,L
(' i t r \ '>
. w '. \ {t J
L' t,\L.
vr
\U
('
\-
c; u'
f/-
CONFIDENTIAL"
dp3
6. a) Findthe solutionof the differentialequation 12,forwhichp = 0 wh e n
E*tP=
f= 0. H)",'no
Sketcha graphto showthe relationshipbetweenp and f if f >0.
0"*o
b) The accelerationof a moving particleis given by g - gt(f , where g and k are
positiveconstantsand v is the speedof the particle.
q}l Write down a differential equation relating v and time f. Hence, express y
explicltlyin terms of f if the particlemovesfrom rest. 17 marksl
7. The random variable X has a Poisson distribution with mean 1,. Giveh that
ZP( X= 1) = P ( X =2).
'7 2] r anoP(Xnn= *.
P(xlY).=
a) Determine
thevalueof m.
0 \t
5( )
l-
O"*o
b) TabulateP(X= x).
v
r ( .. 'Lq @a*q
c) FindE(sX- 3)
L
$Lrt '
95412
*Thisquestionpaperis CONFIDENTIAL
untiltheexaminationis over. CONFIDENTIAr
CONFIDENTIAL*
10. randomvariableXhas probability
Thecontinuous densityfunction,f(x)as shown
in the diagrambelow.
0*o
a) Findf(x).
functionof X andsketchits graph. @r.arf<sl
distribution
b) Findthe cumulative
a) Findthe probability
thata randomlychosenstandardbottlecontainslessttrFrrJ
0.750/dresof mineralwater. \[/matf<s]
b) Findthe probability
thata boxof 10 randomly
chosenstandardbottlescontpinqpt
leastthreebottleswhosecontentsareeachlessthan0.750lrfres. [3 parks]
c) Findthe probability
thatthereis moremineralwater
in fourrandomlycnosffiarO
bottlesthanin threerandomly chosenlargebottles. \l/a*sl
2 1 -3 0 2
3 1 -4 0 5
4 1-5 0 11
51 -60 23
61 -70 47
71-80 20
8 1-9 0 I
91 - 100 3
ii) percentage
@*"r
of studentswhosemarksarewithinthe rangeof onegtantgrd
from
deviation mean. ( 13mp*sl
silt2 \/
*Thisquestion
paperis CONFIDENTIAL
untiltheexamination
is over. CONFIDENTIAL*