Chapter 4 and 5

Test 1 Workshop 1 Test 2 Workshop 2 Test 3 Workshop 3 Test 4 Workshop 4 Middle Exam

T Chemistry Test #1 Electron Configuration and Periodic Properties September 23, 2013 Name_________________________ 10 ___ 30pts. Student Score Do not scratch, or erase. Check your spelling. Use pen only. Answer the following questions. Be clear neat. One point each
1. Match the outermost electron configuration with the corresponding property. You may use them Several times or none. Higher electronegativity ______ Higher reactivity ______ Lower atomic radius ______ Lower ionization electrons ______ Eight valence electrons ______ It forms ions 4______

2. The properties of the element 120 would be: (write high or low where necessary) Ionization energy _____ atomic radius ______ reactivity ______ electronegativity _______ electron Affinity ______ type of ion __________ metallic character _________ # valence electrons _______ 3. Three isoelectronic ions are: _____________________________________ 4. Predict the formula that better represents the compound when indium combines with iodine by using The following information: GaP, , _________________________ 5. The successive ionization energies (in kJ/mol) for an unknown element are: IE1: 1314 IE2: 3388 IE:5300 IE4: 7469 IE5: 10990 To which group number in the periodic table the unknown element most likely belong? ______________ 6. The noble gas configuration of is ________________________ 7. Write the equation for the electron affinity of Cl. The electron affinity is -36107 kJ/mol, ____________________________________ 8. Arrange them in decreasing order of their size: , , Ar, , __________________________ 9. Would you expect the electron affinities for the three isotopes of hydrogen, hydrogen, deuterium and Tritium to be the same of different? _________________________

10. Along with the increased distance of the outer electron from the nucleus, the __________________ of the Inner electrons causes ionization energy to decrease going down a column of the periodic table . 11. The atomic radius of F, Cl, and I are 64,89 and 138 pm respectively. From this information (and not your Book) estimate a reasonable atomic radius of Br from thelist: S3, 198,26,162,114 ____________ 12. Rank each of the following in order of INCREASING electronegativity : V,Y,O ____________ 13. Rank each of the following in order of DECREASING ionization energy: Cl,Cu,Au _________________ 14. Rank each of the following in order of DECREASING atomic radius : Os, Ni, Fe ________________ 15. Rank each of the following in order of INCREASING metallic character: Mn, Nb, Ir, Hf ________________ 16. Which property is illustrated in the graph across a period? _____________________________

17. I am one of the elements. I have the highest ionization energy in my group. I increase in size when I Become an ion and it is higher than the element at my left. The elemente at my left has a smaller Electron affinity but the element at my right has a more positive electron affinity and I do not why. I Have no d electron and I am necessary for the existence of living matter. Who am I? _______ (symbol) Support your answer. (2 points)

Second Quarter: Chemistry Workshop #1 10 grades Electron Configuration and Periodic Properties Date ________________ Name ________________

Answer the following questions. Be clear and neat 1. I am one of the elements. I have a high electron affinity (highly negative value), and my atomic number is X. The element with atomic number X-1 has lowest ionization energy and a lower electron affinity (less negative value).The element with atomic number X+1 has higher ionization energy and basically no electron affinity (positive value). I am toxic and reactive in my elemental state, but I am very commonly found in my nontoxic ionic state. Within my group, I have the second highest ionization energy. Who am I? Support your answer.

2. Rank the following elements by increasing atomic radius: carbon, aluminum, oxygen, potassium.

3. Which species of each pair has the largest radius? K+ or Cl P3 or N3

4. Order the following groups from largest to smallest radii a) Ar, Cl, K+, S2b) Na, Mg, Ar, P 5. For each of the following pairs, which of the two species is smaller? a) K+ or Li+ b) P3- or N3-

6. Pick a noble gas, write its shorthand e- configuration and determine its number of electrons. Then find the halogens, alkali metal and alkaline earth metal with the same number of electrons. Write these as their most stable ion. They will constitute an isoelectronic series Noble Gas Species symbol Electron configuration Z # of electrons Order them by increasing atomic or ionic radius. Alkali metal Alkaline earth metal Halogen

7.1. Which is the largest atom in Group IV? 7.2. Which is the smallest atom in Group VII? 7.3. Which is the smallest atom in period 5? 8. Which species of each pair has the higher Ionization energy? A. Mg or Mg2+ B. O or O2C. K+ or Cl9. Which of the following has the largest IE2? A. B. C. D. K Ca Sc Fe

10. Shown below are the Ionization energies for three elements in the third period. Label each box with the correct element IE1 496 737 578 IE2 4560 1451 1816 IE3 6912 7733 2744 IE4 9543 10,540 11,577

11. Choose the orbital in which an electron would experience the highest Z, effective nuclear charge (least shielded), an highest IE1 A. B. C. D. E. Na (3s) Mg (3s) Al (3p) P (3p) S (3p)

12. Match the following electron configuration with the appropriate Ionization energies (IE1) A. 1s22s2 2p63s24s23d10 4p65s1 hjk1356 kj/mol B. 1s2 2s2 2p6 3s2 3p6 4s2mkl595 kj/mol C. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 mkl409 kj/mol 13. Why do you think sodium has more negative electron affinity value than magnesium?

14. Nitrogen has a positive value for electron affinity, yet oxygen has a negative value. Explain this using an orbital diagram

15. Rank the following by increasing electronegativity: N, P, O

16. Choose from the following atoms to answer the next 4 questions (A) Fluorine (B) Oxygen (C) Lithium (D) Sodium (E) Potassium

Which element is the least electronegative? Which element has the lowest ionization energy? Which element has the smallest ion? Which atom has the smallest atomic radius? 17. The following is a list of the charge found on the ions of a series of elements: Y+ W2* Z2+ V3+ X+

State which elements are most likely to be metals 18. Given the valence electron configuration of elements a, b, c and d : A. 4s1 B. 5s1 C. 5s2 D.5sp3

Which elements have the lowest first ionization energy? _______________________ 19. Which of these elements would have the lowest first ionization energy? Has one valence electron and forms X+? Element A Element B Element C Element D

20. The chemical formulas for the oxides of potassium, calcium, gallium and germanium are, respectively, K2O, C2O, Ga2O2 and GeO2. Refer to the periodic table and predict the chemical formula for each of the following compounds: Explain
(a) Rubidium oxide (b) Strontium oxide (c) Indium oxide (d) Lead oxide

21. Predict which of the following metals has chemical properties most similar to Zinc : Fe, Cu or Cd. 22.Write the noble gas electron configuration for each of the following (a)Cd2+ (b) P3-

Ionic Bonds and Ionic Compound / Metallic Bonding

Short Answers (2 points each one) A. Cristal lattice of metals is formed by

B. Metals are good conductors of heat. Why?

C. Write the fallowing substances in increasing order of the properties indicated: a) Cristal lattice of CaO, Sr3P2, MgO b)Melting Point of LiCl, Li2S, LiBr

D. Use the information below to answer. (3 points) property Melting Point Boiling Point Water Solubility Conductivity in the solid state Conductivity in the liquid state Distorsion of the solid A 801C 1456C yes no yes brittle b -117C 78C yes no no c -39C 357C no yes yes yes

Sustance a has atoms joined by the type of bond called ________________________ Sustance b has atoms joined by the type of bond called ________________________ Sustance c has atoms joined by the type of bond called ________________________ E. Determine the type of bond, if there is any, according to the type of atoms (4 points) Type of Atoms Type of Bond Na Na S Cl Br Ca Fe Zn

F. Use Lewis diagrams to show the formation of the compound formed with carbonate (CO3-2) and lithium. (3 points)

G. Use Lewis structure to show the formation of the compound formed with silicon and sulfide.(2pts)

H. Write the property of metals that is shown: (2 points)

_____________________________________________

____________________________________________________

Ionic Bonding and Ionic Bonds/ Metallic Bonding 1. Use Lewis diagrams to represent the formation of compounds that is formed from the elements selenium and sulfur and(b) write the symbol of the ions that form the compound illustrated in figure (b. Write formulas for each one. (c)

2. Write which compound is ionic and which is covalent or metallic: a) Compound X has a melting point of 1011 degrees Celcius and dissolves in water. ____________________ b) Compound W is gaseous, does not conduct electricity and dissolves in water. ____________________ c) d) NH4Cl_______________________

e) __________________________ ______________________________

f) Tungsten_________________ g) It can be shaped into useful tools________________________ h) CN-______________________ 3. Which has the highest crystal lattice energy: AIN or K3N. Explain

4. Put the following substances in decreasing order of their boiling points: explain. LiBr,N2,HCl,HBr,HF,RbBr._______________________________________ 5. Use the noble gas electron configurations of atoms and ions to explain why when cobalt combines chemically whit oxygen it can form two types of ionic compounds, however when cadmium combines chemically whit oxygen, one type of compound is formed. What are the ratios of the ions in each of the three compounds ?

6. Write what metallic property is illustrated:_______________________________

7. Three metals have the following melting points in kelvin: 1112,1814 and 336. Write the melting points in the corresponding place in the below:

State what happens to the strength of the metallic bond for these metals . Explain as fully as you can the effect you have described.

Geometra Molecular

Formula

Dibujo de geometra molecular

su Nombre forma

de

la Angulo (s)

Polaridad de la molcula

SO3

H3O+

SeCl5I

H2O2

2. Dibuja la formula estructural de Lewis con su forma de la especie en la cual el tomo de nitrgeno esta unido a dos tomos de azufre y el ngulo es aproximadamente 180. Estructura de Lewis nombre de la forma

3. Predice cual tiene la propiedad ms baja. Por qu? La solubilidad en agua del HF y el CS2 ____________________________ Por qu el CO2 es un gas y no un lquido bajo condiciones normales de temperatura y presin?

4. Predice todos los ngulos posibles en las molculas.

________________________ 5. Prediga la hibridizacin de los tomos numerados

________________________

6. Cules son las fuerzas intermoleculares que determinan las propiedades de cada compuesto?

____________________________________ ____________________________________ ___________________________________

_________________________________ _________________________________ _________________________________

Instituto Panamericano Tercer trimestre: Taller de Qumica #4 Geometra Molecular

1. Completa la tabla:
Frmula Dibujo de su geometra molecular Nombre de la forma ngulo Polaridad de los enlaces Polaridad de la molcula

SbH5

NbBr5

H3C2O2-

ONCl

C2H2

Cl2CO

N2O4 2. Dibuja la estructura de Lewis y luego la forma de la especie en la cual el tomo de nitrgeno est unido a dos tomos de azufre y el ngulo es aproximadamente 120. Diagrama de Lewis forma geometra molecular nombre de la

3. Prediga que propiedad es la ms baja en cada par. Por qu? a) El punto de fusin del agua o del cloruro de hidrgeno (HCl) _________________________________

b) El punto de fusin del CH4 o CHCl3 ___________________________________

4. Prediga todos los ngulos posibles en la molcula. H R C N H C H O O H

5.Prediga la hibridizacin de los tomos numerados: CH CHCH CH=CHCH CH

C1_____ C2_____ C3_____

6. Cules de las siguientes fuerzas intermoleculares est incorrectamente asignada como la fuerza intermolecular principal del compuesto?

a) CH4 , London b)NH3 , enlaces de hidrgeno c) H2S, dipolo-dipolo d) H3P, puentes de hidrgeno e) AsH3 ,dipolo-dipolo

7. Los aminocidos son los materiales bsicos de las protenas. Dos molculas del aminocido ms simple a continuacin. Dibuje los enlaces de hidrgeno entre ellos.

H N H

H C H C H H C H S H C H H C

H N

H C H C H H C H S H C H H C

OH

OH