Material Safety Data Sheet

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according to Regulation (EC) No. 1907/2006 (REACH) Spiritus camphoratus

Revision Date 13.09.2011

Print Date 13.09.2011

1 Identification of the substance/mixture and of the company/undertaking

Informations to product No. g219 Product name:

Spiritus camphoratus
Campherspiritus Supplier of the Product / responsible Company: Caesar & Loretz GmbH Herderstr. 31 40721 Hilden Tel.: 02103/4994-400 Fax: 02103/4994-580 e-mail: info@caelo.de Emergency telephone: Giftinformationszentrum Mainz Langenbeckstr. 1, 55131 Mainz Tel.: 06131/19240

2 Hazards identification
GHS-Labelling Elements:

Signal word: Danger H-Phrases: H225 Highly flammable liquid and vapour P-Phrases: P210 Keep away from heat/sparks/open flames/hot surfaces No smoking P211 Do not spray on an open flame or other ignition source

3 Composition / information on ingredients

Chemical characterization Description: Alkoholic mixture with more than 70% Ethanol. Hazardous components: Ethanol EINECS-No.: 200-578-6 CAS-No.: 64-17-5

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Material Safety Data Sheet

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according to Regulation (EC) No. 1907/2006 (REACH) Spiritus camphoratus

Revision Date 13.09.2011

Print Date 13.09.2011

4 First aid measures

after inhalation: Fresh air. after skin contact: Wash away with water and soap. after eye contact: Rinse out with plenty of water with the eyelid wide open. after swallowing: Drink water. Induce vomiting. Seek medical advice.

5 Fire-fighting measures
Suitable extinguishing media: All regular extinguishing media can be used. Select fire fighting measures suitable to surrounding environment. Specific hazards during fire fighting: Combustible Special protective equipment for fire-fighters: No special measures required.

6 Accidental release measures

Personal protective measures: Avoid contact with substance. Environmental protective measures: Prevent from entering into drainage, surface water, the ground water system or soil. Methods for cleaning: Absorb with liquid-binding material: Sand, silica gel, acid binder, universal binder, saw dust. Transfer into a tightly closing, labelled container. Disposal according to Chapter 13 of this MSDS

7 Handling and storage

Handling: No special requirements. Informations to fire or explosion protection: Keep away from ignition sources. Do not smoke.. Take measures to prevent electrostatic charging. Storage: Requirements for storage areas and containers: Tightly closed. Store at a dry place. At room temperature ( +15C to +25C ). Advices on common storage: Not required. Additional informations to storage conditions: Keep container tightly closed.

8 Exposure controls / personal protective equipment

Personal protective equipment: General protective and hygiene measures: Wash hands before breaks and after work. Respiratory protection: Good ventilation of working place Hand protection: Protection gloves of rubber Eye protection: Safety glasses.

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Material Safety Data Sheet

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according to Regulation (EC) No. 1907/2006 (REACH) Spiritus camphoratus

Revision Date 13.09.2011

Print Date 13.09.2011

9 Physical and chemical properties

Form: liquid Colour: colourless Odour: alkoholic Melting point / melting range: not determined Boiling point / boiling range: ca. 80C Flash point: < 21 C Density: at 20 C 0,830-0,935 g/cm Solubility in / Miscibility with Water completely miscible, partially clouding by precipitation of camphor.

10 Stability and reactivity

Thermical decomposition / conditions to avoid: No decomposition during appropriate use. Materials to avoid: Oxidants Hazardous reactions: No hazardous reactions known. Hazardous decomposition products: none

11 Toxicological information
Acute toxicity: LD50 (oral,Rat): 7060 mg/kg LD50 (inhal.,Rat): 38500 mg/m3/10h Primary irritating effect: on respiratory organs: Irritant on mucous membranes.

12 Ecological information
Information about elimination (persistence and degradability): Ist Biodegradable. Ecotoxical effects (Ethanol): Aquatic toxicity: LC50: 8140 mg/l/48h Leuciscus idus LC50: 7750 mg/l/96h Copepod Bacteria (Pseudomonas putida): Toxic concentration limit: 6500 mg/l Activated sludge : Damage above 15g/l Behaviour in sewage plants: EC50: > 1000 mg/l. Additional information: Can cause lack of oxygen in aquatic systems. CSB-Wert: 1700 mg/g BSB5-Wert: 1000 mg/g General advices: Water hazard class (german regulation) 1 (List classification): slightly hazardous for water Prevent from entering sewage water or drainage ditch undiluted or unneutralized.

13 Disposal considerations
Product: Recommendation: Disposal according to local regulations as pharmaceutical waste. Empty contaminated packaging:
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Material Safety Data Sheet

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according to Regulation (EC) No. 1907/2006 (REACH) Spiritus camphoratus

Revision Date 13.09.2011

Print Date 13.09.2011

Recommendation: Disposal according to the local regulations. Recommended cleaning agent: Water with detergent.

14 Transport informations
Land transport according to ADR: Proper shipping name: Tinctures, medical Class: 3 UN-number: 1293 Packing group: II Classification code: F1 Limited quantities (Table 3.4.6. ADR): LQ 7 Hazard classification number: 33 Special provisions (Chapter 3.3 ADR): Additional informations for sea transport IMDG: EMS-No.: F-E, S-D Properties: Fp=10C

15 Regulatory information
Labelling according to actual legislation (GHS, Globally Harmonized System of Classification and Labelling of Chemicals): The product is classified and labelled according to GHS-regulations. Hazard symbols: GHS02 Signal word: Danger H-Phrases: H225 Highly flammable liquid and vapour P-Phrases: P210 Keep away from heat/sparks/open flames/hot surfaces No smoking P211 Do not spray on an open flame or other ignition source. Labelling according to EC-regulations: The product is classified and labelled according to EC-regulations (german GefStoffV) . Signal character and hazard specification of the product: F Highly flammable R-Phrases: 11 S-Phrases: National regulations (Germany): Vbf-classification: B Water hazard class (german regulation): WGK 1 (List classification): slightly hazardous for water.

16 Other Information
The information provided in this MSDS is correct to the best of our knowledge at the date of edition. Reason for last revision: Adjustment to regulation (EC) 1907/2006 (REACH) and GHS-labelling system.

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