Vidyamandir Classes

VMC/Ionic Equilibrium 18 HWT/Chemistry

DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : ION-EQ [1]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. A weak monobasic acid is 1% ionized in 0.1 M solution at 25 C

. The percentage of ionization in its 0.025 M solution is :

(A) 1 (B) 2 (C) 3 (D) 4
2. Three reaction involving
2 4
H PO

are given below :

I.
3 4 2 3 2 4
H PO H O H O H PO
+
+ + II.
2
2 4 2 4 3
H PO H O HPO H O
+
+ +
III.
2
2 4 3 4
H PO OH H PO O

+ +
In which of the above does
2 4
H PO

act as an acid ?
(A) II only (B) I and II (C) III only (D) I only
3. At a certain temperature, the dissociation constant of formic acid and acetic acid are
4 5
1.8 10 and 1.8 10

respectively.
The concentration of acetic acid solution in which the hydrogen ion has the same concentration as in 0.001 M formic acid solution
is equal to :
(A) 0.01 M (B) 0.001 M (C) 0.1 M (D) 0.0001 M (E) 0.1010 M
4. For a concentrated solution of a weak electrolyte A
x
B
y
of concentration C, the degree of dissociation ' ' o is given as :
(A) , )
eq
K / C x y o = + (B) , )
eq
K / C x y o =
(C)
, )
, ) 1/ x y
x y 1 x y
eq
K / C x y
+
+
o = (D)
, ) eq
K / Cxy o = (E)
, )
xy
eq
K / C o =
5. The first and second dissociation constant of an acid
5 10
2
H A are 1.0 10 and 5.0 10

respectively. The overall dissociation
constant of the acid will be :
(A)
5
5.0 10

(B)
15
5.0 10 (C)
15
5.0 10

(D)
5
0.2 10
6. The ionisation of acetic acid in H
2
SO
4
, compared to in water, is :
(A) weak, low (B) strong, more (C) medium, the same (D) no ionisation, 100 %
7. CH
3
COOH is weaker acid than H
2
SO
4
. It is due to :
(A) more ionisation (B) less ionisation (C) covalent bond (D) electrovalent bond
8. Which of the following base is weakest ?
(A)
6
4 b
NH OH; K 1.6 10

= (B)
10
6 5 2 b
C H NH ; K 3.8 10

=
(C)
4
2 5 2 b
C H NH ; K 5.6 10

= (D)
10
9 7 b
C H N; K 6.3 10

=
9. An acid HA ionizes as, HA H A
+
+

The pH of 1.0 M solution is 5. Its dissociation constant would be :

(A)
10
1 10

(B) 5 (C)
8
5 10

(D)
5
1 10

10. pH value of which one of the following is not equal to one ?

(A) 0.1 M HNO
3
(B) 0.05 M H
2
SO
4
(C) 0.1 M CH
3
COOH (D) 50 cm
3
of 0.4 M HCl + 50 cm
3
of 0.2 M NaOH
Vidyamandir Classes
VMC/Ionic Equilibrium 19 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : ION-EQ [2]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The pH of
10
10 M NaOH

solution is nearest to :
(A) 4 (B) 10 (C) 4 (D) 7
2. The pH of a neutral water sample is 6.5. Then the temperature of water :
(A) is 25 C (B) is more than 25 C
(C) is less than 25 C (D) can be more or less than 25 C
3. The solubility of a sparingly soluble salt AB
2
in water is
5
1.0 10 M

. Its solubility product will be :

(A)
10 3
1.0 10 M

(B)
15 3
4 10 M

(C)
10 3
4 10 M

(D)
15 3
1 10 M

4. The pH value of 0.001 M aqueous solution of NaCl is :

(A) 7 (B) 4 (C) 11 (D) unpredictable
5. A solution contains 10 mL 0.1 N NaOH and 10 mL 0.05 N H
2
SO
4
, pH of this solution is :
(A) less than 7 (B) 7 (C) zero (D) greater than 7
6. The pH values of 0.1 M solution of HCl, CH
3
COOH, NH
4
Cl and CH
3
COONa will have the order :
(A) HCl < CH
3
COOH < NH
4
Cl < CH
3
COONa (B) CH
3
COONa < NH
4
Cl < CH
3
COOH < HCl
(C) NH
4
Cl < CH
3
COONa < CH
3
COOH < HCl (D) All will have same of pH value
7. When 200 mL of aqueous solution of HCl (pH = 2) is mixed with 300 mL of an aqueous solution of NaOH (pH = 12), the pH of
the resulting mixture is :
(A) 10 (B) 2.7 (C) 4.0 (D) 11.3
8.
3
M M M
30 cc of HCl, 20 cc of HNO and 40 cc of NaOH
3 2 4
solutions are mixed and the volume was made up 1 dm
3
. The pH of
the resulting solution is :
(A) 8 (B) 2 (C) 1 (D) 3
9.
6
10 M NaOH

is diluted 100 times. The pH of the diluted base is :

(A) between 7 and 8 (B) between 5 and 6 (C) between 6 and 7 (D) between 10 and 11
10. 100 mL of 0.015 M HCl solution is mixed with 100 mL of 0.005 M HCl. What is the pH of the resultant solution ?
(A) 2.5 (B) 1.5 (C) 2 (D) 1
Vidyamandir Classes
VMC/Ionic Equilibrium 20 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : ION-EQ [3]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. 50 mL of H
2
O is added to
3
50 mL of 1 10 M

barium hydroxide solution. What is the pH of the resulting solution?

(A) 3.0 (B) 3.3 (C) 11.0 (D) 11.7
2. Which of the following solutions will have pH = 9 at 298 K?
(A)
9
1 10 M HCl solution

(B)
5
1 10 M NaOH solution

(C)
9
1 10 M KOH solution

(D) Both (A) and (B)

3. The pH of
8
10 M HCl

solution is :
(A) 8 (B) more than 8 (C) between 6 and 7 (D) slightly more than 7
4. The approximately pH of 0.005 molar sulphuric acid.
(A) 0.005 (B) 2 (C) 1 (D) 0.01
5. Calculate pOH of 0.001 M NH
4
OH, when it is 1% dissociated in the solution :
(A) 5 (B) 2.96 (C) 9.04 (D) 11.4
6. HA is a weak acid. The pH of 0.1 M HA solution is 2. What is the degree of dissociation , ) o of HA?
(A) 0.5 (B) 0.2 (C) 0.1 (D) 0.301
7. An aqueous solutions of 1 M NaCl and 1 M HCl is :
(A) not a buffer but pH < 7 (B) not a buffer but pH > 7
(C) a buffer with pH < 7 (D) a buffer with pH > 7
8. pK
a
or a weak acid is defined as :
(A)
a
logK (B)
a
1
log K
(C)
a
1
log
K
(D)
a
1
log
K

9. Which statement is false? (Assume complete dissociation in each case)

(A) If 2.0 L of a solution of H
2
SO
4
contains 0.1 mole, then pH of the solutions is 1
(B) The concentration of OH in 0.005 M HNO
3
is
12
2.0 10 mol / L

(C) The pH of 0.01 M KOH is 12

(D) In a 0.001 M solution of NaOH the concentration of
3
H is 10 mol / L
+
10. In 1L saturated solution of AgCl [K
sp
(AgCl) = 1.6 10
10
], 0.1 mole of CuCl [K
sp
(CuCl) = 1.0 10
6
] is added. The resultant
concentration of Ag in the solution is 1.6 10
x
. The value of x is :
(A) 3 (B) 5 (C) 7 (D) 9
Vidyamandir Classes
VMC/Ionic Equilibrium 21 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : ION-EQ [4]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The K
sp
for Cr (OH)
3
is 1.6 10
30
. the molar solubility
of this compound in water is :
(A)
30 2
1.6 10

(B)
30 4
1.6 10

(C)
30 4
1.6 10 / 27

(D) 1.6 10
30
/ 27
2. The solubility product (K
sp
) of the following compound
are given at 25 C
Compound K
sp
I. AgCl (i) 1.1 10
10
II. AgI (ii) 1.0 10
16
III. PbCrO
4
(iii) 4.0 10
14
IV. Ag
2
CO
3
(iv) 8.0 10
12
The most soluble and least soluble compound are :
(A) AgCl & PbCrO
4
(B) AgI & Ag
2
CO
3
(C) Ag
2
Cl & Ag
2
CO
3
(D) Ag
2
CO
3
& AgI
(E) Ag
2
Co
3
& PbCrO
4
3. H
2
S is passed into one dm
3
of a solution containing 0.1
mole Zn
3
and 0.01 mole Cu
2
till the sulphide ion
concentration reaches 8.1 10
10
moles. Which one of
the following statements is true ? [K
sp
or ZnS and CuS
are 3 10
22
and 8 10
36
respectively]
(A) Only ZnS precipitaes
(B) Both CuS and ZnS precipitates
(C) Only CuS precipitates
(D) No precipitation occurs
4. The solubility of Ca
3
(PO
4
)
2
is water is y moles/litre.
Its solubility product is :
(A) 6y
4
(B) 36 y
4
(C) 64 y
5
(D) 108 y
5
5. At 25 C , the solubility product of Mg(OH)
2
is
precipitating in the form of Mg(OH)
2
from a solution of
0.001 M Mg
2
ions ?
(A) 9 (B) 10 (C) 11 (D) 8
6. 1 dm
3
solution containing
5
10

moles each of Cl ions

and
2
4
CrO ions is treated with
4
10

moles of silver
nitrate. Which one of the following observation is
made?
12
sp 2 4
[K Ag CrO 4 10 ]

= ;
10]
sp
[K AgCl 1 10

=
(A) Precipitation does not occur
(B) Silver chromate gets precipitated first
(C) Silver chloride gets precipitated first
(D) Both silver chromate and silver chloride start,
precipitating simultaneously
7. The molar solubility
1
(in mol L )

of a sparingly soluble
salt MX
4
is s. The corresponding solubility product is
K
sp
s is given in terms of K
sp
by the relation.
(A) s = (K
sp
/128)
1/4
(B) s = (128 K
sp
)
1/4
(C) s = (256 k
sp
)
1/5
(D) s = (K
sp
/256)
1/5
8. The solubility product of Hg
2
I
2
is equal to :
(A)
2
2
Hg I
+
1 1
( (
] ]
(B)
2
Hg I
+
1 1
( (
] ]
(C)
2
2
2
Hg I
+
1 1
( (
] ]
(D)
2
2
Hg I
+
1 1
( (
] ]
9. Solid Ba(NO
3
)
2
is gradually dissolved in a
4
2 3
1.0 10 M Na CO

solution. At what concentration

of Ba
2+
will a precipitate begin to form ? (K
sp
for
BaCO
3
=
9
5.1 10

)
(A)
5
4.1 10 M

(B)
5
5.1 10 M

(C)
8
8.1 10 M

(D)
7
8.1 10 M

10. The solubility product of iron (III) hydroxide is

19
1.6 10

. If X is the solubility of iron (III)

hydroxide, which one of the following expression can
be used to calculate X ?
(A) K
sp
= X
4
(B) K
sp
= 9X
4
(C) K
sp
= 27 X
3
(D) K
sp
= 27 X
4
Vidyamandir Classes
VMC/Ionic Equilibrium 22 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : ION-EQ [5]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. If
17
sp 2
K of Ag S is 10

, the solubility of Ag
2
S in 0.1
M solution of Na
2
S will be :
(A)
8
10

(B)
9
5 10

(C)
15
10

(D)
16
10

2. Solubility product constant [K

sp
] of salts of types MX,
MX
2
and M
3
X at temperature T are
8
4.0 10

,
3.2 10
14
and 2.7 10
15
respectively. Solubilities
(mol, dm
3
) of the salts at temperature T are in the
order.
(A) MX > MX
2
> M
3
X
(B) M
3
X > MX
2
> MX
(C) MX
2
> M
3
X > MX
(D) MX > M
3
X > MX
2
3. Addition of sodium acetate to 0.1 M acetic acid will
cause :
(A) increases in pH (B) decrease in pH
(C) no change in pH
(D) change in pH that cannot be predicted
4. Solubility product of Mg (OH)
2
at ordinary temperature
is
11
1.96 10

. pH of a saturated solution of Mg(OH)

2
will be :
(A) 10.53 (B) 8.47
(C) 6.94 (D) 3.47
5. Solubility product of a salt AB is 1 10
8
m
2
in a
solution in which the concentration A
+
ions is
3
10 M

.
The salt will precipitate when the concentration of
B

ions is kept.
(A) between 10
8
to 10
7
M
(B) between 10
7
M to 10
8
M
(C) >10
5
M (D) <10
8
M
6. An aqueous solution contains Ni
2+
, CO
2+
and Pb
2+
ions
at equal concentrations. The solubility product of NiS,
PbS and CoS in water at 25 C are respectively.
Indicate which of these ions will be precipitated first
and last when sulphide concentration is progressively
increased from zero ?
(A) NiS and PbS (B) NiS and CoS
(C) CoS and NiS (D) PbS and NiS
7. In a saturated solution of the sparingly soluble strong
electrolyte AgIO
3
(molecular mass = 283) the
equilibrium which sets in is
3 3
AgIO (s) Ag (aq) IO (aq)
+
+

If the solubility product constant K

sp
of AgIO
3
at a
given temperature is
8
1.0 10

, what is the mass of

AgIO
3
contained in 100 mL of its saturated solution?
(A)
2
28.3 10 g

(B)
3
2.83 10 g

(C)
7
1.0 10 g

(D)
4
1.0 10 g

8. At 30 C the solubility of
12
2 3 sp
Ag CO (K 8 10 )

=
would be greatest in 1 L of :
(A) 0.05 M Na
2
CO
3
(B) 0.05 M AgNO
3
(C) pure water (D) 0.05 M NH
3
9. The value of the ionic product of water depends
(A) on volume of water
(B) on temperature
(C) changes adding acid or alkali
(D) always remain constant
10. Some chemists at ISRO wished to prepare a saturated
solution of a silver compound and they wanted it to
have the highest concentration of silver ion possible.
Which of the following compounds, would they use?
, )
10
sp
K AgCl 1.8 10

= ;
, )
13
sp
K AgBr 5.0 10

= ;
, )
12
sp 2 4
K Ag CrO 2.4 10

=
(A) AgCl (B) AgBr
(C) Ag
2
CrO
4
(D) None of these
Vidyamandir Classes
VMC/Ionic Equilibrium 23 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : ION-EQ [6]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The solubility of Pb(OH)
2
in water is
6
6.7 10 M

. Its solubility in a buffer solution of pH = 8 would be

6
26 10

.
(A)
2
1.2 10

(B)
3
1.6 10

(C)
2
1.6 10

(D)
3
1.2 10

2. On adding 0.1 M solution each of [Ag

+
], [Ba
2+
], [Ca
2+
] in a Na
2
SO
4
solution, species first precipitated is :
11 5 5
sp 4 sp 4 sp 2 4
K BaSO 10 , K CaSO 10 , K Ag SO 10

1
= = =
]
(A) Ag
2
SO
4
(B) BaSO
4
(C) CaSO
4
(D) All of these
3. A precipitate of AgCl is formed when equal volumes of the following are mixed
10
sp
K for AgCl 10

1
=
(
]
(A)
4 7
3
10 M AgNO and10 M HCl

(B)
5 6
3
10 M AgNO and10 M HCl

(C)
4 4
3
10 M AgNO and10 M HCl

(D)
6 6
3
10 M AgNO and10 M HCl

4. A solution which is
3
10 M

each in Mn
2+
, Fe
2+
, Zn
2+
and Hg
2+
is treated with
16
10 M

sulphide ion. If K
sp
of Mns, FeS, ZnS and
HgS are
15 23 20 54
10 , 10 , 10 and 10

respectively, which one will precipitate first ?
(A) FeS (B) MgS (C) HgS (D) Zns
5. In the following reaction, AgCl KI KCl AgI + +

As KI is added, the equilibrium is shifted towards right giving more AgI precipitate, because :
(A) both AgCl and AgI are sparingly soluble (B) the K
sp
of AgI is lower than K
sp
of AgCl
(C) the K
sp
of AgI is higher than K
sp
of AgCl (D) both AgCl and AgI have same solubility product
6. A buffer solution contains 0.1 mole of sodium acetate dissolved in 1000 cm
3
of 0.1 M acetic acid. To the above buffer solution,
0.1 mole of sodium acetate is further added and dissolved. The pH of the resulting buffer is :
(A) pK
a
(B) pK
a
+ 2 (C)
a
pK log 2 (D)
a
pK log2 +
7. The pH of an aqueous solution of CH
3
COONa of concentration C(M) is given by :
(A)
a
1 1
7 pK log C
2 2
(B)
w b
1 1 1
pK pK log C
2 2 2
+ +
(C)
w b
1 1 1
pK pK log C
2 2 2
+ (D)
w a
1 1 1
pK pK log C
2 2 2
+ +
8. Which buffer solution comprising of the following has its pH value greater than 7?
(A) CH
3
COOH + CH
3
COONa (B) HCOOH + HCOOK
(C) CH
3
COONH
4
(D) NH
4
OH + NH
4
Cl
9. The buffering action of an acidic buffer is maximum when its pH is equal to :
(A) 5 (B) 7 (C) 1 (D) pK
a
10. A strong acid is titrated with weak base. At equivalence point, pH will be :
(A) < 7 (B) > 7 (C) = 0 (D) Cannot predict
Vidyamandir Classes
VMC/Ionic Equilibrium 24 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
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\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : ION-EQ [7]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1.
2
2.5 mL of M
5
weak monoacidic base
, )
12
b
K 1 10 at 25 C

=

is titrated with
2
M HCl
15
in water at 25 C

. The concentration
of H
+
at equivalence point is :
, )
14
w
K 1 10 at 25 C

=

(A)
13
3.7 10 M

(B)
7
3.2 10 M

(C)
2
3.2 10 M

(D)
2
2.7 10 M

2. The pK
a
of a weak acid, HA, is 4.80. The pK
b
of a weak base, BOH is 4.78. The pH of an aqueous solution of the corresponding
salt, BA, will be :
(A) 9.58 (B) 4.79 (C) 7.01 (D) 9.22
3. A buffer solution is prepared by mixing 0.1 M ammonia and 1.0 M ammonium chloride. At 298 K, the pK
b
of NH
4
OH is 5.0. The
pH of buffer is :
(A) 10.0 (B) 9.0 (C) 6.0 (D) 8.0
4. The solubility of mercurous chloride in water will be given as :
(A) K
sp
(Hg
2
Cl
2
) (B)
sp 2 2
K (Hg Cl ) / 4 (C)
1/ 3
sp 2 2
[K (Hg Cl ) / 4] (D) [K
sp
(Hg
2
Cl
2
)]
1/3
5. Which one of the following salts will produce an alkaline solution while dissolving in water ?
(A) NH
4
Cl (B) Na
2
CO
3
(C) NaNO
3
(D) Na
2
SO
4
6. The aqueous solutions of HCOONa, C
6
H
5
NH
3
Cl and KCN are respectively.
(A) acidic, acidic, basic (B) acidic, basic, neutral
(C) basic, neutral, neutral (D) basic, acidic, basic
7. The pK
a
of a weak acid (Ha) is 4.5. The pOH of an aqueous buffered solution of HA in which 50% of the acid ionised is :
(A) 4.5 (B) 2.5 (C) 9.5 (D) 7.0
8. Which one of the following salts give an acidic solution in water ?
(A) CH
3
COONa (B) NH
4
Cl (C) NaCl (D) CH
3
COONH
4
9. A certain buffer solution contains equal concentration of X and HX

. The K
b
for
10
X is 10

. The pH of the buffer is :
(A) 4 (B) 7 (C) 10 (D) 14
10. Degree of hydrolysis (h) of a salt of weak acid and a strong base is given by :
(A)
h
h K = (B)
h
C
h
K
= (C)
h
K
h
C
= (D) None of these
Vidyamandir Classes
VMC/Ionic Equilibrium 25 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : ION-EQ [8]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The hydrolysis of sodium carbonate involves the
reaction between :
(A) sodium ion & water (B) Na and OH
+
(C)
2
3
CO and water

(D)
2
3
CO and H
+
2. The rapid change of OH

near the stoichiometric point

of an acid base titration is the basis of indicator
detection. pH of the solution is related to the ratio of the
concentrations of the conjugate acid (HIn) and base
(In

) forms of the indicator given by the expression.

(A)
In
[In ]
log pK pH
[HIn]

=
(B)
In
[HIn]
log pK pH
[In ]

=
(C)
In
[HIn]
log pH pK
[In ]

=
(D)
In
[In ]
log pH pK
[HIn]

=
3. In a mixture of acetic acid and sodium acetate the ratio
of concentration of the salt to the acid is increased ten
times. Then, the pH of the solution :
(A) increases by one (B) decreases by one
(C) decreases ten fold (D) increased ten fold
4. A solution of FeCl
3
in water acts as acidic solution due
to :
(A) hydrolysis of Fe
3+
(B) acidic impurities
(C) dissociation (D) ionisation
5. Relation between hydrolysis constant and dissociation
constant are given. Which is the correct formula for
MgCl
2
?
(A)
w
h
a
K
K
K
= (B)
w
h
b
K
K
K
=
(C)
w
h
a b
K
K
K K
=

(D)
h
w
b
K
K
K
=
6. Consider the following solutions of equal
concentrations:
A = NH
4
Cl ; B = CH
3
COONa ;
C = NH
4
OH ; D = CH
3
COOH
A buffer solution can be obtained by mixture by mixing
equal volume of :
(A) C and D (B) A and B
(C) A and C (D) C and D
7. 0.1 mole of
4
3 2 b
CH NH (K 5 10 )

= is mixed with
0.08 mole of HCl and diluted to 1L. What will be the H
+
concentration in the solution ?
(A)
2
8 10 M

(B)
11
8 10 M

(C)
11
1.6 10 M

(D)
5
8 10 M

8. Statement 1: The pH of a buffer solution containing

equal moles of acetic acid and sodium acetate is
4.8 (pK
a
of acetic acid is 4.8)
Statement 2: The ionic product of water at 25C is
10
14
mol
2
L
2
.
(A) Statement-1 is True, Statement-2 is True and
Statement-2 is a correct explanation for
Statement-1
(B) Statement-1 is True, Statement-2 is True and
Statement-2 is NOT a correct explanation for
Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
9. HX is a weak acid
5
a
(K 10 )

= . It forms a salt NaX

0.1 M on reacting with caustic soda. The degree of
hydrolysis of NaX is :
(A) 0.01 % (B) 0.0001%
(C) 0.1 % (D) 0.5 %
10. The degree of hydrolysis in hydrolytic equilibrium
2
A H O HA OH

+ +

at salt concentration of
0.001 M is
5
a
(K 1 10 )

=
(A)
3
1 10

(B)
4
1 10

(C)
4
5 10

(D)
6
1 10

Vidyamandir Classes
VMC/Ionic Equilibrium 26 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : ION-EQ [9]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The pK
b
value of NH
3
is 5. Calculate the pH of the buffer solution, 1 L of which contains 0.01 M NH
4
Cl and 0.10 M NH
4
OH
(A) 4 (B) 6 (C) 8 (D) 10
2. Study the following table.
Buffer Solution I II III IV
Volume (in mL) of 1 M
weak acid
4.0 4.0 40.0 0.1
Volume (in mL) of 0.1 M
sodium salt of weak acid
4.0 40.0 4.0 10.0
Which of the two sets of buffer solution have least pH ?
(A) I and II (B) I and III (C) II and III (D) II and IV
3. The pH of 0.1 M solution of the following salts increases in the order.
(A) NaCl < NH
4
Cl < NaCN < HCl (B) HCl < NH
4
Cl < NaCl < NaCN
(C) NaCN < NH
4
Cl < NaCl < HCl (D) HCl < NaCl < NaCN < NH
4
Cl
4. A mixture of sodium oxide and calcium oxide are dissolved in water and saturated with excess carbon dioxide gas. The resulting
solution is.. . It contains :
(A) basic; NaOH and Ca(OH)
2
(B) neutral; Na
2
CO
3
and CaCO
3
(C) basic; Na
2
CO
3
and CaCO
3
(D) acidic; NaOH and CaCO
3
5. An amphoteric buffer solution in which conc. of H
+
and HX is same. The value of K
a
of HX is
8
10

, then pH of buffer solution is :

(A) 3 (B) 8 (C) 10 (D) 14
6. An electrolyte.
(A) gives complex ions in solution (B) dissolves in water to give ions
(C) is ionised in the solid state (D) generates ions on passing electric current
7. Which one is strongest electrolyte in the following ?
(A) NaCl (B) CH
3
COOH (C) NH
4
OH (D) C
6
H
12
O
6
8. Which will not affect the degree of ionisation?
(A) Temperature (B) Concentration (C) Type of solvent (D) Current
9. The degree of dissociation of 0.1 M HCN solution is 0.01% its ionisation constant would be :
(A)
3
10

(B)
5
10

(C)
7
10

(D)
9
10

10. Degree of dissociation of 0.1 N CH

3
COOH is (dissociation constant =
5
1 10

)
(A)
5
10

(B)
4
10

(C)
3
10

(D)
2
10

Vidyamandir Classes
VMC/Ionic Equilibrium 27 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : ION-EQ [10]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Which of the following will suppress the ionisation of acetic acid is aqueous solution?
(A) NaCl (B) HCl (C) KCl (D) Unpredictable
2. In which of the following, dissociation of NH
4
OH will be minimum?
(A) NaOH (B) H
2
O (C) NH
4
Cl (D) NaCl
3. The conjugate base of
2
NH

is :
(A) NH
3
(B)
2
NH

(C)
4
NH
+
(D)
3
N

4. In the reaction
2 3
HCl H O H O Cl
+
+ +

(A) H
2
O is the conjugate base of HCl acid (B) Cl

is the conjugate base of HCl acid

(C)
1
Cl

is the conjugate acid of H

2
O base (D) H
3
O
+
is the conjugate base of HCl
5. The conjugate acid of NH
3
is :
(A) NH
3
(B)
4
NH
+
(C) N
2
H
4
(D) NH
2
OH
6. The conjugate base of
2 4
H PO

is :
(A) H
3
PO
4
(B) P
2
O
5
(C)
3
4
PO

(D)
2
4
HPO

7. Conjugate base of
4
HSO

is :
(A)
2
4
SO

(B) H
2
SO
4
(C)
2 4
H SO
+
(D) None of these
8. pH scale was introduced by :
(A) Arrhenius (B) Sorensen (C) Lewis (D) Lowry
9. What is the pH value of
7
N
KOH
10
solutions?
(A) 7 (B) between 7 and 8 (C) 8 (D) between 6 and 7
10. The pH of a
9
10 M

solution of HCl in water is :

(A) 8 (B) 8 (C) between 7 and 8 (D) between 6 and 7