Vidyamandir Classes

VMC/Thermodynamics 1 HWT/Chemistry
DATE : TIME : 30 Minutes MARKS : [ ___ /10] TEST CODE : THERMO [1]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. An ideal gas expands in volume from
3 3
1 10 m

to
2 3
1 10 m

at 300 K against a constant pressure of

5 2
1 10 Nm

. The work
done is:
(A) 900 J (B) 900 kJ (C) 270 kJ (D) 900 kJ
2. Which one of the following is an exothermic reaction?
(A)
2 2
N (g) O (g) 180.8 kJ 2NO(g) + + (B)
2 2 3
N (g) 3H (g) 90 kJ 2NH (g) +
(C)
2 2
C(g) H O(g) CO(g) H (g) 131.1 kJ + + (D)
2
C(graphite) 2S(s) CS ( ) 91.9 kJ l +
3. Which of the following taking place in the blast furnace is endothermic?
(A)
3 2
CaCO CaO CO + (B)
2
2C O 2CO +
(C)
2 2
C O CO + (D)
2 3 2
Fe O 3CO 2Fe 3CO + +
4. Which one of the following is not a state function?
(A) Enthalpy (B) Entropy (C) Work (D) Free energy
5. The work done during the expansion of a gas from a volume of 4 dm
3
to 6 dm
3
against a constant external pressure of 3 atm is :
(A) 6 J (B) 608 J (C) 304 J + (D) 304 J
6. Which is an extensive property?
(A) Temperature (B) Chemical potential (C) Gibbs free energy (D) Molar volume
7. In an adiabatic process :
(A) p . V 0 A = (B) q = + W (C) E q A = (D) q = 0
8. Which of the following is a path function?
(A) Internal energy (B) Enthalpy (C) Work (D) Entropy
9. For the following two reactions,
I.
4 2 2 2
CH (g) 2O (g) CO (g) 2H O
H 890.4kJ
+ +
A =
II.
2
2HgO(s) 2Hg( ) O (g) 181.6 kJ l +
Which one of the following statements is correct?
(A) Both of them are exothermic (B) Both of them are endothermic
(C) I is exothermic and II is endothermic (D) I is endothermic and II is exothermic
10. A process is taking place at constant temperature and pressure. Then :
(A) H E A = A (B) H T S A = A (C) H 0 A = (D) S 0 A =
Vidyamandir Classes
VMC/Thermodynamics 2 HWT/Chemistry
DATE : TIME : 30 Minutes MARKS : [ ___ /10] TEST CODE : THERMO [2]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Which is correct for an endothermic reaction?
(A) H A is positive (B) H A is negative (C) E A is negative (D) H 0 A =
2. In an isothermal process :
(A) q 0 and E 0 = A = (B) q 0 and E 0 = A = (C) q 0 and E 0 = A = (D) q 0 and E 0 = A =
3. When one mole of monoatomic ideal gas at TK undergoes adiabatic change under a constant external pressure of 1 atm change
volume from 1 L to 2L. The final temperature in Kelvin would be :
(A)
2/ 3
T
2
(B)
2
T
3 0.0821
+

(C) T (D)
2
T
3 0.0821

4. Which of the following is an endothermic reaction?

(A)
2 2 3
N (g) 3H (g) 92kJ 2NH (g) + (B)
2 2
N (g) O (g) 180.8kJ 2NO(g) + +
(C)
2 2
H (g) Cl (g) 2HCl(g) 184.6 kJ + + (D)
2 4
C(graphite) 2H (g) CH (g) 74.8 kJ + +
5. To calculate the amount of work done in joules during reversible isothermal expansion of an ideal gas, the volume must be
expressed in :
(A) m
3
only (B) dm
3
only (C) cm
3
only (D) Any of these
6. A gas can expand from 100 mL to 250 mL under a constant pressure of 2 atm. The work done by gas is :
(A) 30.38 J (B) 25 J (C) 5 kJ (D) 16 J
7. What is E A for system that does 500 cal of work on surrounding and 300 cal of heat is absorbed by the system?
(A) 200 cal (B) 300 cal (C) 200 cal + (D) 300 cal +
8.
2 2
C(s) O (g) CO (g); H 94kcal + A =
2 2
2CO(g) O 2CO (g); H 135.2 kcal + A =
The heat of formation of CO (g) is :
(A) 26.4 kcal (B) 41.2 kcal (C) 26.4 kcal (D) 229.2 kcal
9. Internal energy is sum of :
(A) Kinetic energy of potential energy (B) All type of energy of the system
(C) Energy of internal system (D) None of the above
10. If
2 2
C(s) O (g) CO (g); H r + A = and
2 2
1
CO(g) O CO (g); H s
2
+ A = then the heat of formation of CO is:
(A) r + s (B) r s (C) s r (D) rs
Vidyamandir Classes
VMC/Thermodynamics 3 HWT/Chemistry
DATE : TIME : 30 Minutes MARKS : [ ___ /10] TEST CODE : THERMO [3]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. A gas expands isothermally against a constant external
pressure of 1 atm from a volume of 10 dm
3
to a volume
of 20 dm
3
. It absorbs 800 J of thermal energy from its
surroundings. The U A is :
(A) 312 J (B) + 123 J
(C) 213 J (D) + 231 J
2. Hesss law is based on :
(A) Law of conservation of mass
(B) Law of conservation of energy
(C) First law of thermodynamics
(D) None of the above
3. A hypothetical reaction A 2B , proceeds through
following sequence of steps
I. A C; H q A = II.
C D; H v A =
III.
1
D B; H x
2
A =
Then the heat of reaction is :
(A) q v 2x + (B) q v 2x +
(C) q + v + 2x (D) q 2v 2x +
4. The first law of thermodynamics is expressed as :
(A) q W E = A (B) E q W A =
(C) q E W = A (D) W q E = + A
5. The sublimation energy of I
2
(s) is 57.3 kJ/mol and the
enthalpy of fusion is 15.5 kJ/mol. The enthalpy of
vaporization of I
2
is :
(A) 41.8 kJ/mol (B) 41.8 kJ / mol
(C) 72.8 kJ/mol (D) 72.8 kJ / mol
6. The value of E A for combustion of 16 g of CH
4
is
885389 J at 298 K. The H A combustion for CH
4
in
1
J mol

at this temperature will be :

(Given that,
1 1
R 8.314JK mol

= )
(A) 55337 (B) 880430
(C) 885389 (D) 890348
7. Hesss law states that :
(A) The standard enthalpy of an overall reaction is
the sum of the enthalpy changes in individual
reactions.
(B) Enthalpy of formation of a compound is same
an the enthalpy of decomposition of the
compound into constituent elements, but with
opposite sign.
(C) At constant temperature the pressure of a gas is
inversely proportional to its volume.
(D) The mass of a gas dissolved per litre of a
solvent is proportional to the pressure of the
gas in equilibrium with the solution.
8. If gas, at constant temperature and pressure expands then
it.
(A) Entropy increases and then decreases
(B) Internal energy increases
(C) Internal energy remains the same
(D) Internal energy decreases
9. The value of enthalpy change ( H) A for the reaction
2 5 2 2 2
C H OH( ) 3O (g) 2CO (g) 3H O( ), l l + +
1
at 27 C is 1366.5kJ mol

. The value of internal

energy change for the above reaction at this temperature
will be :
(A) 1371.5 kJ (B) 1369.0 kJ
(C) 1364.0 kJ (D) 1361.5 kJ
10. Consider the reaction,
2 2 2 5 r
4NO (g) O (g) 2N O (g), H 111kJ + A = .
If N
2
O
5
(s) is formed instead of N
2
O
5
(g) in the above
reaction, the
r
H A value will be :
(Given, H A of sublimation for
1
2 5
N O is 54 kJ mol

)
(A) 165 kJ (B) + 54 kJ
(C) + 219 kJ (D) 219 kJ
Vidyamandir Classes
VMC/Thermodynamics 4 HWT/Chemistry
DATE : TIME : 30 Minutes MARKS : [ ___ /10] TEST CODE : THERMO [4]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The amount of the heat released when 20 mL 0.5 M NaOH is mixed with 100 mL 0.1 M HCl is x kJ. ? The heat of neutralization is:
(A) 100x kJ / mol (B) 50x kJ / mol (C) + 100x kJ/mol (D) + 50x kJ/mol
2. The species which by definition has zero standard molar enthalpy of formation at 298 K is :
(A) Br
2
(g) (B) Cl
2
(g) (C) H
2
O (g) (D) CH
4
(g)
3. The standard enthalpy of formation of NH
3
is
1
46.0kJ mol

. If the enthalpy of formation of H

2
from its atoms is
1
436 kJ mol

and that of N
2
is
1
712kJ mol

, the average bond enthalpy of N H bond in NH

3
is :
(A)
1
964 kJ mol

(B)
1
352 kJ mol

+ (C)
1
1056kJ mol

+ (D)
1
1102 kJ mol

4. In which of the following reactions, the enthalpy is the least?

(A)
3 3 2
CH COOH NaOH CH COONa H O + + (B)
4 4 2
HCl NH OH NH Cl H O + +
(C)
2
HCl NaOH NaCl H O + + (D)
4 4 2
HCN NH OH NH CN H O + +
5. For the reaction A B; H 24kJ / mol and B C; H 18 kJ / mol A = + A = , the decreasing order of enthalpy of A, B, C follows
the order:
(A) A, B, C (B) B, C, A (C) C, B, A (D) C, A, B
6.
2 2 2 2 2
5
C H O 2CO H O ; H 310 kcal
2
+ + A =
2 2
C O CO ; H 94 kcal + A =
2 2 2
1
H O H O; H 68 kcal
2
+ A =
On the basis of the above equations,
f
H A (enthalpy of formation) of C
2
H
2
will be :
(A) 148 kcal (B) + 54 kcal (C) 54 kcal (D) + 80 kcal
7. The enthalpy of formation of NH
3
is
1
46kJ mol

. The enthalpy change for the reaction

3 2 2
2NH (g) N (g) 3H (g) + is :
(A) + 184 kJ (B) + 23 kJ (C) + 92 kJ (D) + 46 kJ
8. Calculate H A in kJ for the following reaction
2 2
C(g) O (g) CO (g) +
Given that,
2 2
H O(g) C(g) CO(g) H (g); H 131kJ + + A =+
2 2
1
CO(g) O (g) CO (g); H 282kJ
2
+ A =
2 2 2
1
H (g) O (g) H O(g); H 242kJ
2
+ A =
(A) 393 (B) + 393 (C) + 655 (D) 655
Vidyamandir Classes
VMC/Thermodynamics 5 HWT/Chemistry
9. The heat of formations for CO
2
(g), H
2
O (l) and CH
4
(g) are
1 1 1
400 kJ mol , 280 kJ mol and 70 kJ mol

respectively.
The heat of combustion of CH
4
in
1
kJ mol

is :
(A) 890 (B) 160 (C) 890 (D) 90
10. Using the following thermochemical equations
I.
1
2 3
3
S(rhombic) O (g) SO (g) ; H 2x kJ mol
2

+ A =
II.
1
2 2 3
1
SO (g) O (g) SO (g) ; H y kJ mol
2

+ A =
Find out the heat of formation of SO
2
(g) in
1
kJ mol

.
(A) (2x + y) (B) (x + y) (C) 2x y (D) , ) y 2x
Vidyamandir Classes
VMC/Thermodynamics 6 HWT/Chemistry
DATE : TIME : 30 Minutes MARKS : [ ___ /10] TEST CODE : THERMO [5]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Which of the following reaction defines
f
H A

?
(A)
2 2
C(diamond) O (g) CO (g) + (B)
2 2
1 1
H (g) F (g) HF(g)
2 2
+
(C)
2 2 3
N (g) 3H (g) 2NH (g) + (D)
2 2
1
CO(g) O (g) CO (g)
2
+
2. Consider the reaction,
2 2 3
N 3H 2NH + carried out at constant temperature and pressure. If H and U A A are the enthalpy
and internal energy changes for the reaction, which of the following expressions is true?
(A) H U A >A (B) H U A <A (C) H U A =A (D) H 0 A =
3. The relation between H and U A A is :
(A) H U RT A = A + (B) H U nRT A = A A (C) H U nRT A = A + A (D) U H nRT A = A + A
4. The bond energy is the energy required to :
(A) Dissociate one mole of the substance (B) Dissociate bond in 1 kg of the substance
(C) Break one mole of similar bonds (D) Break bonds in one mole of substance
5. For an ideal gas, the heat of reaction at constant pressure and constant volume are related as :
(A) H E pV + = (B) E H p V = + A (C)
p v
q q nRT = + A (D) None of these
6. A monoatomic ideal gas undergoes a process in which the ratio of p to v at any instant is constant and equals to 1. What is the
molar heat capacity of the gas?
(A)
4R
2
(B)
3R
2
(C)
5R
2
(D) 0
7. For the reaction, A(g) 2B(g) 2C(g) 3D(g) + + the change of enthalpy at 27 C

is 19 kcal. The value of E A is :

(A) 21.2 kcal (B) 17.8 kcal (C) 18.4 kcal (D) 20.6 kcal
8. In an isochoric process, H A for a system is equal to
(A) p . V A (B) pV (C) E p . V + A (D) E A
9. The enthalpy of reaction,
2 2 2 1
1
H (g) O (g) H O(g) is H
2
+ A and that of
2 2 2 2
1
H (g) O (g) H O( ) is H
2
l + A .
Then :
(A)
1 2
H H A < A (B)
1 2
H H 0 A + A = (C)
1 2
H H A > A (D)
1 2
H H A = A
10. Identify the reaction for which H E A = A
(A)
2 2
S(rhombic) O (g) SO (g) + (B)
2 2
N (g) O (g) 2NO(g) +
(C)
2 2
H (g) Cl (g) 2HCl (g) + (D)
2 2
1
CO(g) O (g) CO (g)
2
+
Vidyamandir Classes
VMC/Thermodynamics 7 HWT/Chemistry
DATE : TIME : 30 Minutes MARKS : [ ___ /10] TEST CODE : THERMO [6]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Which of the following indicates the heat of reaction equal to heat of formation?
(A)
2 2
C(graphite) O (1 atm) CO (1 atm) + (B)
2 2
C(diamond) O (1 atm) CO (2 atm) +
(C)
2 2
C(graphite) O (1 atm) CO (2 atm) + (D)
2 2
C(diamond) O (1 atm) CO (1 atm) +
2. The H H bond energy is
1
430 kJ mol and Cl Cl

bond energy is
1
240 kJ mol , H for HCl is 90 kJ

A . The H Cl bond
energy is about :
(A)
1
180 kJ mol

(B)
1
360 kJ mol

(C)
1
213 kJ mol

(D)
1
425 kJ mol

3. The amount of energy released when 20 mL of 0.5 M NaOH are mixed with 100 mL of 0.1 M HCl is x kJ. The heat of
neutralization is
1
(in kJ mol )

.
(A) 100 x (B) 50 x (C) + 100 x (D) + 50 x
4. The heat of neutralization of HCl by NaOH is 55.9 kJ / mol , the energy of dissociation of HCN is :
(A) 43.8 kJ (B) 43.8kJ (C) 68 kJ (D) 68 kJ
5. If the bond dissociation energies of XY, X
2
and Y
2
(all diatomic molecules) are in the ratio of 1 : 1 : 0.5 and
f
H A for the formation
of XY is
1
200 kJ mol

. The bond dissociation energy of X

2
will be :
(A)
1
400 kJ mol

(B)
1
300 kJ mol

(C)
1
20 kJ mol

(D) None of these

6. For the gaseous reaction involving the complete combustion of iso-butane :
(A) H E A = A (B) H E A > A (C) H E A < A (D) None of these
7. The cooling in refrigerator is due to :
(A) Reaction of the refrigerator gas (B) Expansion of ice
(C) The expansion of the gas in the refrigerator (D) The work of the compressor
8. What would be the heat released when an aqueous solution containing 0.5 mole of HNO
3
is mixed with 0.3 mole of OH

(enthalpy
of neutralization is 57.1 kJ ) ?
(A) 28.5 kJ (B) 17.1 kJ (C) 45.7 kJ (D) 1.7 kJ (E) 2.85 kJ
9. If
2 2
S O SO ; H 298.2kJ + A =
2 2 3
1
SO O SO ; H 98.7 kJ
2
+ A =
3 2 2 4
SO H O H SO ; H 130.2 kJ + A =
2 2 2
1
H O H O ; H 287.3 kJ
2
+ A =
Then the enthalpy of formation of H
2
SO
4
at 298 K will be :
(A) 814.4 kJ (B) + 320.5 kJ (C) 650.3 kJ (D) 933.7 kJ
10. The heat of neutralization of any strong acid and a strong base is nearly equal to :
(A) 75.3kJ (B) + 57.3 kJ (C) 57.3 kJ (D) + 75.3 kJ
Vidyamandir Classes
VMC/Thermodynamics 8 HWT/Chemistry
DATE : TIME : 30 Minutes MARKS : [ ___ /10] TEST CODE : THERMO [7]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Heat required to raise the temperature of 1 mole of a substance by 1

is called :
(A) Specific heat (B) Molar heat capacity (C) Water equivalent (D) Specific gravity
2. Enthalpy of formation of HF and HCl are 161 kJ and 92 kJ respectively. Which of the following statements is incorrect?
(A) HCl is more stable than HF
(B) HF and HCl are exothermic compounds
(C) The affinity of fluorine to hydrogen is greater than the affinity of chlorine to hydrogen
(D) HF is more stable than HCl
3. The enthalpies of formation of Al
2
O
3
and Cr
2
O
3
are 1596 kJ and 1134 kJ respectively. H A for the reaction,
2 3 2 3
2Al Cr O 2Cr Al O + + is :
(A) 2730 kJ (B) 462 kJ (C) 1365 kJ (D) + 2730 kJ
4. Which of the following equations correctly represents the standard heat of formation
f
( H ) A

of methane?
(A)
4
C(diamond) 4H(g) CH (g) + (B)
2 4
C(diamond) 2H (g) CH (g) +
(C)
2 4
C(graphite) 2H (g) CH (g) + (D)
4
C(graphite) 4H (g) CH (g) +
5. Average C H bond energy is
1
416 kJ mol

. Which of the following is correct?

(A)
4
CH (g) 416 kJ C(g) 4H(g) + + (B)
4
CH (g) C(g) 4H(g) 416 kJ + +
(C)
4
CH (g) 1664 kJ C(g) 4H(g) + + (D)
4
CH (g) C(g) 4H(g) 1664 kJ + +
6. For he reaction, A(s) 3B(g) 4C(g) D( ) H and U l + + A A are related as :
(A) H U A = A (B) H U 3RT A = A + (C) H U RT A = A + (D) H U 3RT A = A
7. For the gaseous reaction,
2 4 2
N O 2NO
(A) H E A < A (B) H E A = A (C) H 0 A = (D) H E A > A
8. For the reaction,
5 3 2
PCl (g) PCl (g) Cl (g) +
(A) H E A = A (B) H E A > A (C) H E A < A (D) None of these
9. The enthalpy change ( H) A for the process
2 4
N H (g) 2N(g) 4H(g) + is
1
1724 kJ mol

. If the bond energy of N H bond

in ammonia is
1
391 kJ mol

, what is the bond energy for N N bond in N

2
H
4
?
(A)
1
391 kJ mol

(B)
1
160 kJ mol

(C)
1
1173 kJ mol

(D)
1
320 kJ mol

10. Which of the reaction defines

f
H A

?
(A)
2 2
C(diamond) O (g) CO (g) + (B)
2 2
1 1
H (g) F (g) HF(g)
2 2
+
(C)
2 2 3
N (s) 3H (g) 2NH (g) + (D)
2 2
1
CO(g) O (g) CO (g)
2
+
Vidyamandir Classes
VMC/Thermodynamics 9 HWT/Chemistry
DATE : TIME : 30 Minutes MARKS : [ ___ /10] TEST CODE : THERMO [8]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Troutons rule gives the relation between :
(A) T
b
and T
c
(B) T
b
and critical pressure
(C) Enthalpy of vaporization and boiling point (D) Normal boiling point and boiling point
2. For the reaction,
2 2 2
2H (g) O (g) 2H O(g); H 573.2 kJ + A =
The heat of decomposition of water per mole is :
(A) 286.6 kJ (B) 573.2 kJ (C) 28.66 kJ (D) zero
3. The bond energy of O H bond is 109 kcal/mol.
When amole of water is formed, then :
(A) 109 kcal is released (B) 218 kcal is absorbed (C) 109 kcal is absorbed (D) 218 kcal is released
4. A plot of ln k against 1/T (abscissa) is expected to be a straight line with intercept on coordinate axis equal to :
(A)
S
2.303 R
A

(B)
S
R
A

(C)
S
R
A

(D) R S A

5. For a particular reversible reaction at temperature T, H and S A A were found to be both +ve. If T
e
is the temperature at
equilibrium, the reaction would be spontaneous when :
(A) T
e
> T (B) T > T
e
(C) T
e
is 5 times T (D) T = T
e
6. Which of the following reaction define ?
f
G A

(A)
2 2
C(diamond) O (g) CO (g) + (B)
2 2
1 1
H (g) F (g) HF(g)
2 2
+
(C)
4 2 7 2 3 4
H P O H O 2H PO + (D)
2 2 3
1
SO (g) O (g) SO (g)
2
+
7. For a chemical reaction, G A will always be negative if :
(A) H and T S A A both are positive (B) H and T S A A both are negative
(C) H negative and T S positive A A (D) H positive and T S negative A A
8. Standard entropy of X
2
, Y
2
and XY
3
are 60, 40 and
1 1
50 JK mol

, respectively. For the reaction,
2 2 3
1 3
X Y XY , H 30kJ
2 2
+ A = , to be at equilibrium, the temperature will be :
(A) 1250 K (B) 500 K (C) 750 K (D) 1000 K
9. For which reaction change of entropy will be positive?
(A)
2 2
H (g) I (g) 2HI(g) +

(B)
3 4
HCl(g) NH (g) NH Cl(s) +

(C)
4 3 2 2
NH NO (s) N O(g) 2H O(g) +

(D)
2 2
MgO(s) H (g) Mg(s) H O( ) l + +

10. Which is the correct expression, that relates changes of entropy with the change of pressure for an ideal gas at constant temperature
in the following?
(A)
2
1
p
S nRT ln
p
A = (B) , )
2 1
S T p p A = (C)
1
2
p
S nRT ln
p
A = (D)
1
2
p
S 2.303 nRT ln
p
=
Vidyamandir Classes
VMC/Thermodynamics 10 HWT/Chemistry
DATE : TIME : 30 Minutes MARKS : [ ___ /10] TEST CODE : THERMO [9]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Considering the reaction,
2 2
C(s) O (g) CO (g) 393.5 kJ + + the signs of
H, S and G A A A respectively are :
(A) +, , (B) , +, +
(C) , , (D) , +,
2. The correct relationship between free energy change in a
reaction and the corresponding equilibrium constant K
c
is :
(A)
c
G RT ln K A = (B)
c
G RTln K A =
(C)
c
G RT ln K A =

(D)
c
G RTln K A =

3. The direct conversion of A of B is difficult, hence it is

carried out by the following shown path
C D
B A
+ |

Given;
(A C)
S 50 eu

A =
(C D)
S 30 eu

A =
(B D)
S 20 eu

A =
Where eu is entropy unit, then
(A B)
S

A is :
(A) + 100 eu (B) + 60 eu
(C) 100 eu (D) 60 eu
4. For a chemical reaction, the free energy change ( G) A is
negative. The reaction is :
(A) A spontaneous reaction
(B) An equilibrium reaction
(C) A non-spontaneous reaction
(D) Characterized by r
f
= r
b
(where, r
f
and r
b
are
rates of forward ad backward reaction respectively)
5. For the reaction at 298 K
A(g) B(g) C(g) D(g) + +

1
H 29.8 kcal, S 0.100 kcal K

A = A =

What is the value of G A

?
(A) 1 (B) 0
(C) 2 (D) 4
6. What is the relation between E and K

?
(A)
0.0591
E log K
n
=

(B)
n
E log K
0.0591
=
(C)
2.303R
E log K
nF
=

(D)
2.303RT
E log K
n
=
7. Unit of entropy is :
(A)
1 1
JK mol

(B)
1
J mol

(C)
1 1 1
J K mol

(D)
1
JK mol

8. A schematic plot of ln K
eq
versus inverse of temperature
for a reaction is shown below :
The reaction must be :
(A) Highly spontaneous at ordinary temperature
(B) One with negligible enthalpy change
(C) Endothermic (D) Exothermic
9. If an endothermic reaction is non-spontaneous at
freezing point of water becomes feasible at its boiling
point then :
(A) H is ve, S is ve A A +
(B) H and S both are ve A A +
(C) H and S both are ve A A
(D) H is ve, S is ve A + A
10. For a system in equilibrium, G 0 A = under conditions of
constant :
(A) Temperature and pressure
(B) Temperature and volume
(C) Pressure and volume
(D) Energy and volume
Vidyamandir Classes
VMC/Thermodynamics 11 HWT/Chemistry
DATE : TIME : 30 Minutes MARKS : [ ___ /10] TEST CODE : THERMO [10]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Molar heat change is
1 1
16J mol K

, the boiling points of the liquid is :
(A) 375 C

(B) 375 K (C) 273 K (D) 102 C

2. The entropy change for the reaction

2 2
H (g) Cl (g) 2HCl (g) + will be : [Given that,
1 1
S (HCl) 187 JK mol

=

1 1
2
S (H ) 131JK mol

=

and
1 1
2
S (Cl ) 223 JK mol

=

]
(A)
1 1
20 JK mol

(B)
1 1
20 JK mol

(C)
1 1
167 JK mol

(D)
1 1
167 JK mol

3. The free energy for a reaction having

1 1
H 31400 cal, S 32 cal K mol at 1000 C

A = A =

is :
(A) 9336 cal (B) 7386 cal (C) 1936 cal (D) 9336 cal +
4. Spontaneous adsorption of a gas on solid surface is an exothermic process because :
(A) H A increases for system (B) S A increases for gas
(C) S A decreases for gas (D) G A increases for gas
5.
1 1
vap vap
H 30 kJ / mol and S 75 J mol K

A = A = . Find temperature of vapour, at 1 atm.
(A) 400 K (B) 350 K (C) 298 K (D) 250 K
6. The enthalpy change for the transition of liquid water to steam is
1
40.8 kJ mol at 373 K

. What is the entropy of vaporization of

water?
(A) 209.4 (B) 109.4 (C) 250.0 (D) 209.4
7. For spontaneity of a cell, which is correct?
(A) G 0, E 0 A = A = (B) G ve, E 0 A = A = (C) G ve, E ve A = + A = + (D) G ve, E ve A = A = +
8. Which of the following statements is true?
(A) G A is always less than H A (B) G A is always more than H A
(C) G A is always proportional to H A (D) G A may be lesser, greater or equal to H A
9. In a reversible process,
system surrouding
S S A + A is :
(A) > 0 (B) < 0 (C) 0 > (D) = 0
10. For a process to be spontaneous, the most favourable condition is :
(A) H 0, S 0 A > A > (B) H 0, S 0 A < A > (C) H 0, S 0 A < A < (D) H 0, S 0 A > A <