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chapter 9
9.2 Rubber
9.3 Plastic 9.4 Polymer 9.5 Gypsum 9.6 Glass 9.7 Fiber Reinforced Polymer
ASPHALT
Also known as bitumen Dark brown to black Highly viscous Hydrocarbon produced from petroleum distillation residue. At least 80% carbon, which explains its deep black color. The Paving Grades of bitumen are 30/40, 60/70 and 80/100. Sulphur is another ingredient. Primarily used as a sealant for rooftops and a durable surface for roads, airport runways, playgrounds and parking lots.
ASPHALT
Asphalt can be separated from the other components in crude oil By the process of fractional distillation, usually under vacuum conditions.
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TYPES OF ASPHALT
The major types of asphalt used in construction are ;
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a.
b.
Rolled asphalt
Mastic asphalt.
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A. ROLLED ASPHALT
Made of aggregate, or solid materials such as sand, gravel, or recycled concrete, with an asphalt binder. Used to make roads and other surfaces, such as parking lots, by being applied in layers and compacted.
Different types of rolled asphalt are distinguished according to the process used to bind the aggregate with the asphalt.
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A. ROLLED ASPHALT
Warm mix asphalt concrete (WAM or WMA) Reduces the temperature required for manufacture by adding asphalt emulsions, waxes, or zeolites. Benefits both the environment and the workers, as it results in less fossil fuel consumption and reduced emission of fumes.
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ROLLED ASPHALT
Cold mix asphalt concrete,
Emulsified in soapy water before mixing it with the aggregate, eliminating the need for high temperatures altogether. The asphalt produced is not nearly as durable as HMAC or WAM Typically used for low traffic areas or to patch damaged HMAC.
http://www.dykespaving.com/wp-content/themes/classic/images/coldmix.jpg
A. ROLLED ASPHALT
Cut-back asphalt concrete Illegal in the United states since the 1970s, but many other countries around the world still use it. The least environmentally friendly option, resulting in significantly more air pollution than the other forms. Made by dissolving the asphalt binder in kerosene before mixing it with the aggregate, reducing viscosity while the concrete is layered and compacted.
B. MASTIC ASPHALT
Also called sheet asphalt. Lower bitumen content than the rolled asphalt. Used for some roads and footpaths. Used also in roofing and flooring .
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B. MASTIC ASPHALT
Stone mastic asphalt (SMA), is another variety.
Becoming increasingly popular as an alternative to rolled asphalt. Benefits include -Anti-skid property -The absence of air pockets But if laid improperly -May cause slippery road conditions.
Rheology
ALTERNATIVE ASPHALT
renewable resources of Asphalt - molasses and rice, corn and potato starches. Made from waste material - fractional distillation of used motor oils.
Nonpetroleum based bitumen binders can be made light-colored - absorb less heat from solar radiation, and less hot than darker surfaces, reducing their contribution to the urban heat island effect.
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use of a pycnometer can be expressed as the ratio of the weight of a given volume of the material at 250C or at 15.60C to that of an equal volume of water at the same temperature 2. Sampling Bituminous (ASTM D140)
cover the method used to sample bituminous material at points of manufacture, storage or delivery is to determine the true nature and condition of the material
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Materials (ASTM D5) measure the hardness and softness of the material test are taken at least 3 determination on the surface of the sample at points not less than 10 mm from the side of the container and not less than 10 mm apart. However, the test is empirical and many engineers would like to replace it with ASTM D2171 (Viscosity of Asphalts by Vacuum Capillary Viscometer)
6. Float Test (ASTM D139) is a consistency test used for material that are too soft to undergo the standard penetration test and too hard for use with viscosity test
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9.2 Rubber
9.3 Plastic 9.4 Polymer 9.5 Gypsum 9.6 Glass 9.7 Fiber Reinforced Polymer
RUBBER
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RUBBER
This is a substance in which the arrangement of the polymer molecules allows considerable reversible extension to take place at normal temperatures. Elastomer exists as long chain molecules which are irregularly coiled, bent and generally entangled when in the unstressed state. RUBBER Used as such as a lining material for the construction of plants. Classifieds of rubber :
1. Natural Rubber 2. Soft rubber. 3. Hard Rubber 4. Synthetic Rubber.
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CLASSIFIEDS OF RUBBER :
CLASSIFIEDS OF RUBBER :
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RUBBER PROPERTIES
Elastomer is used in Civil Engineering for some good reason such as:
Long lasting Good in impact absorption Good bonding with metal Good resistance to ageing Good tearing properties Good physical properties Good resistance to oil and chemicals Suitable for hot and cool temperature.
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ii. Neoprene
iii. High Damping Rubber (HDRB) iv. Styrene-butadiene Rubber (SBR) v. Acrylonitrile-butadiene Rubber (NBR) or Nitrile Rubber vi. Ethylene-propylene Diene Monomer (EPDM), as for liquid EPDM,it can be used for roof coating
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PROPERTIES OF ELASTOMER
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Rubber Dampens Rubber Seals Rubber Protects Corrosion Effects Rubber Gives Thermal Insulation Rubber Gives Passive Fire Protection Rubber is Ablative Rubber Wears Rubber Bonds with Metal Rubber is Impermeable
ii.
iii.
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v.
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vii.
viii.
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9.2 Rubber
9.3 Plastic 9.4 Polymer 9.5 Gypsum 9.6 Glass 9.7 Fiber Reinforced Polymer
PLASTIC
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PLASTIC
A plastic is a polymeric (usually organic) of high molecular weight which can be shaped by flow. Plastic characteristics
lightness in weight (generally half as light as aluminum) high dielectric strength (electric insulation) low heat conductivity (heat insulation) special properties toward lights (colorability) extremely resistant toward chemical
metal insert may be molded into the plastic (since plastics are inert toward such materials)
many high-quality products can be developed by using a lathe, sawing, punching and drilling.
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PLASTIC IN CONSTRUCTION
Light weight, easy and cheap for transformation
Available in variety of shape and easily fabricated Used for storing number of materials In machines, plastic material is preferred wherever moving parts are present indicating that it offers less resistant Plastic are synthetic resins containing long chains of atoms linked to form giant or macromolecules (polymer)
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advantages
Low thermal and electrical resistance Excellent resistance to weak mineral acids Unaffected by inorganic salts. Resistant to small changes to pH
disadvantages
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** The strength of plastics materials is generally much lower than that of other constructional material. Nevertheless, plastics are light material with relative density between 0.9 and 2.0. pls refer to Table 9.2
TYPE OF PLASTIC
Vinyl Thermoplastic:
an organic plastic, either natural or synthetic, which remain permanently soft at elevated temperatures. Upon cooling, they again become hard. These materials can be shaped and reshaped any number of times by repeated heating and cooling. Some of the most familiar natural thermoplastics include asphalts, bitumen, pitches and resin.
an organic plastic that were originally soft or soften at once upon heating, then harden permanently. Thermosetting plastic are hardened by chemical changes due to heat, catalyst or to both. Thermosetting plastics remain hardened without cooling and do not soften appreciably when reheated. The most common thermosetting plastic is polyester.
are those that harden by the addition of a suitable chemical to the composition just before molding or by subsequent chemical treatment following fabrication.
VINYL THERMOPLASTIC:
Polythene(PE) : HD - Acid-resisting lining. Babies baths, kitchen and other household ware. Piping, toys, fabric filaments. Sheet, wrapping material, polythene bags, electric insulation ink cartridge. LD - Sheets, wrapping material, polythene bags, squeeze bottles, electrical insulation, ink cartridge.
THERMOSETTING PLASTICS
Silicones Water-proof coating fabrics. Anti foaming agents. Hydraulic fluids. Electrical equipment such as switch parts, induction heating equipment, insulation for motors and generator coils. Epoxides Sold as resins and syrups. Used as adhesive for gluing metal, lowpressure laminations, surface coating, casting and repairing casting.
Polyamide Bearings, compressor valves, piston rings, diamond abrasive wheel binders
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9.2 Rubber
9.3 Plastic 9.4 Polymer 9.5 Gypsum 9.6 Glass 9.7 Fiber Reinforced Polymer
POLYMER
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POLYMER
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Polymer engineering is generally an engineering field that designs, analyses, and/or modifies polymer materials. Polymer engineering covers aspects of petrochemical industry, polymerization, structure and characterization of polymers, properties of polymers, compounding and processing of polymers and description of major polymers, structure property relations and applications
POLYMER
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protein
carbohydrates
: muscles
: cellulose
natural rubber
: latex
Polymer Classifications Thermoset: cross-linked polymer that cannot be melted (tires, rubber bands) Thermoplastic: Meltable plastic Elastomers: Polymers that stretch and then return to their original form: often thermoset polymers Thermoplastic elastomers: Elastic polymers that can be melted (soles of tennis shoes) Polymer Families Polyolefins: made from olefin (alkene) monomers Polyesters, Amides, Urethanes, etc.: monomers linked by ester, amide, urethane or other functional groups Natural Polymers: Polysaccharides, DNA, proteins
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POLYMER WHY ??
Strong Inert to chemical attacks
9.2 Rubber
9.3 Plastic 9.4 Polymer 9.5 Gypsum 9.6 Glass 9.7 Fiber Reinforced Polymer
GYPSUM
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GYPSUM
In nature : Gypsum Rock Pure gypsum rock : CaSO4.2H2O calcium sulfate Impurities : MgO, Al2O3, Fe2O3, SiO2, CaCO3, MgCO3...
Manufacture :
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Excavating Crushing (~25 mm diameter) Grinding Heating (calcining) Cooling and Pulverizing Marketing in Bags
CALCINATION
Gypsum rock wahen heated to 100-190C looses of its water.
CaSO4.2H2O CaSO4.H2O + 3/2 H2O Plaster of Paris
BOARDS APPLICATION
Regular white board, from 1/4" to 3/4" thickness
Greenboard, the drywall that contains an oil-based additive in the green colored paper covering that provides moisture resistance. It is commonly used in washrooms and other areas expected to experience elevated levels of humidity.
Blueboard, blue face paper forms a strong bond with a skim coat or a built-up plaster finish providing both water and mould resistance.
Cement board, which is more water-resistant than greenboard, for use in showers or sauna rooms, and as a base for ceramic tile
Soundboard is made from wood fibers to increase the sound rating (STC)
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BOARDS APPLICATION
Soundproof board is a laminated board made with gypsum, other materials, and damping polymers to significantly increase the STC Enviroboard, a board made from recycled agricultural materials Lead-lined gypsum board, used around radiological equipment Foil-backed gypsum board to control moisture in a building or room Controlled density (CD), also called ceiling board, which is available only in 1/2" thickness and is significantly stiffer than regular white board
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PLASTERS APPLICATION
Plaster of Paris
Plaster of paris is made from carefully selected white rock
Mixed with water to form a plaster Sets in 15 to 20 minutes Used to do small patch jobs, making molds
Keenes Cement
If gypsum is subjected to temperatures of 400 c it is completely dehydrated
PLASTERS APPLICATION
Casting Plaster
Made from specially selected rock and ground much finer then regular plaster of paris Has a slower setting and cooler working Makes it ideal for ornamental molded plaster work
PLASTERS APPLICATION
Cement bond plaster
Intended for application to concrete surfaces Requires the addition only of water
Finish plaster
Mixed with hydrated lime putty and water Used a finish coat Prepared finish plaster
Requires only water Contains no lime So the surface can be decorated as soon as it dries Has a off white color
PLASTERS APPLICATION
Texture Plaster
Similar to manufacture prepared finish plaster
A texture is added most likely sand.
Texture spray
Is a dry gypsum based material designed to cover minor imperfections and provide a uniform, durable white surface.
Acoustical Plaster
Calcined gypsum is mixed with lightweight mineral aggregate to make a type of finish plaster that has a high rate of sound absorption
Joint Filler
Is used to make the paste for filling nail holes and covering joints in gypsum wallboard
9.2 Rubber
9.3 Plastic 9.4 Polymer 9.5 Gypsum 9.6 Glass 9.7 Fiber Reinforced Polymer
GLASS
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INTRODUCTION TO GLASS :
It is a mixture of number of mettalic silicate, one of which is usually that of an alkali metal. Most important fact about glass is it is amorphous, transparent or translucent. The glass has been used as an engineering material since ancient times. But because of the rapid progress made in the glass industry in recent times, the glass has come out as the most versatile engineering material of the modern times. With the help of techniques developed in the glass industry, the glass of any type and quality can be produced to suit the requirements of different industries
FACT FILE :
The fibre glass reinforced with plastics can be used in the construction of furniture, lampshades, bathroom fittings, navy boats, aeroplanes, cars, trucks, etc. The glass is the only transparent material strong enough to go upto the bottom of ocean. It is therefore used in the construction of noses of deep-diving vehicles. The glass linings are applied on equipments likely to be affected by the chemical corrosion such as valves, pumps, pipes, etc. In the construction of modern homes, the walls and ceilings of hollow glass blocks can be made which controls the glare and heat considerably while admitting the light.
CHARACTERSTICS OF GLASS :
It absorbs, reflects or transmits light. It has no sharp melting point. It is an excellent electrical insulator at high temperatures due to the fact that glass can be considered as an ionic liquid. It is extremely brittle. It is not usually affected by air or water.
Silicon-free glass
BULLET PROOF GLASS FIBRE GLASS FLOAT GLASS FOAM GLASS GLASS BLOCKS HEAT EXCLUDING GLASS OBSCURED GLASS
SAFETY GLASS PERFORATED GLASS SHIELDING GLASS SOLUBLE GLASS STRUCTURAL GLASS ULTRA VOILET RAY GLASS WIRED GLASS
9.2 Rubber
9.3 Plastic 9.4 Polymer 9.5 Gypsum 9.6 Glass 9.7 Fiber Reinforced Polymer
WHAT IS FRP?
FRP stands for Fiber Reinforced Plastic
Resin Types
+ Epoxy + Polyester
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The use of ligno cellulosic materials in the form of fibres or particles results not only in a considerable increase in biodegradability of a composite but also changes its properties, including flame retardancy characteristic.
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They display acoustic insulation and absorb vibrations and large quantities of energy when subjected to destruction.
Natural vegetable fibers can be applied to the reinforcement of the natural polymers such as starch, lignin, hemicellulose and India-rubber and the material obtained in this way is 100% biodegradable. Reaction to fire of composites based on lignocellulosic fibers is much more beneficial comparing to polymers significant reduction of heat release rate
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APPLICATIONS OF FRP
FRPs can be used in concrete in three basic forms:
Internal reinforcement for reinforced concrete structures Reinforcement bars for Concrete
External reinforcement for strengthening or repairing existing deficient structures; FRP sheets can be used to increase flexural strength in weakened or underdesigned members FRP structural elements (e.g. beams, girder, and column) in concreteFRP composite structures. Prestressing Tendons for Concrete Members
Braiding
+ Creates surface deformations which enhance the FRP to concrete bond
Hybrid Rods
ADVANTAGES OF FRP
Will Not Corrode In Field Conditions Lightweight Strong in Tension Methods of Construction Same as Steel Reinforcement
DISADVANTAGES OF FRP
Low Moduli of Elasticity
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CONCLUSION
FRP Reinforcement is an Engineered Material that Shows Great Promise In the Future of Civil Engineering