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+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >180C (356F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: 270C (518F) SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
STORAGE Do not store in open or unlabelled containers. Keep away from incompatible materials.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Product Name:
Page 4 of 8
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.91 Flash Point [Method]: >180C (356F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: 270C (518F) Boiling Point / Range: > 250C (482F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 6 Solubility in Water: Negligible
UEL: 7.0
Product Name:
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Viscosity: 68 cSt (68 mm/sec) at 40C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request.
Product Name:
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SECTION 12
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
Product Name:
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SECTION 14
TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, ENCS, KECI, PICCS, TSCA SECTION 16 OTHER INFORMATION AICS, IECSC, DSL,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 07: Handling and Storage - Storage Phrases was modified. Section 05: Hazardous Combustion Products was modified. Section 09: Flash Point C(F) was modified. Section 08: Environmental Control - Note was modified. Section 16: Code to MHCs was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified. %%revision_comment%%
Product Name:
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----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Oxides of carbon, Sulphur Oxides, Aldehydes, Smoke, Fume
FLAMMABILITY PROPERTIES Flash Point [Method]: >177C (351F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: Storage Do not store in open or unlabelled containers. This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation.
Product Name:
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For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: red Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.873 Flash Point [Method]: >177C (351F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 37 cSt (37 mm/sec) at 40C | 7.1 cSt (7.1 mm/sec) at 100C
Product Name:
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Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -45C (-49F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request.
Product Name:
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SECTION 12
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
Product Name:
Page 7 of 8
INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: SECTION 16 OTHER INFORMATION TSCA, AICS, EINECS
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 04: First Aid Inhalation was modified. Section 06: Notification Procedures - Header was modified. Section 07: Handling and Storage - Storage was modified. Section 11: Inhalation Lethality Test Comment was modified. Section 15: National Chemical Inventory Listing was modified. Section 16: Code to MHCs was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 08: Environmental Control - Note was added.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law,
Product Name:
Page 8 of 8
re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS TETRAPROPENYL PHENOL 121158-58-5 310-154-3
Concentration * 0.1 - 1%
Product Name:
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ZINC DITHIOPHOSPHATE
68649-42-3
272-028-3
< 2.5%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >215C (419F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
Product Name:
Page 3 of 8
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Avoid all personal contact. Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION
Product Name:
Page 4 of 8
Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: Chemical resistant gloves are recommended. Nitrile, Viton, CEN standards EN 420 and EN 374 provide general requirements and lists of glove types. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Form: clear Colour: brown Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.854
Product Name:
Page 5 of 8
Flash Point [Method]: >215C (419F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: N/D Vapour Density (Air = 1): N/D Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 102 cSt (102 mm/sec) at 40C | 14.8 cSt (14.8 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -39C (-38F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye
Product Name:
Page 6 of 8
May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Synthetic base oils: Not expected to cause significant health effects under conditions of normal use, based on laboratory studies with the same or similar materials. Not mutagenic or genotoxic. Not sensitising in test animals and humans. Branched alkylphenol and its calcium salt: Effects on liver, adrenals, and reproductive organs were seen in rats with repeated oral doses. Decreased fertility index, decreased number of live pups, and other effects were seen in reproductive studies in rats dosed orally. Time to sexual maturation and weights of the uterus and ovaries were decreased in young female rats dosed orally. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable
ECOLOGICAL DATA Component TETRAPROPENYL PHENOL Acute Aquatic Toxicity L(E)C50 >0.1 - 1 mg/L
Note: Tetrapropenyl phenol when tested in oil (1000mg/l) was not acutely toxic to aquatic organisms; based on supplier assessment. SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal.
Product Name:
Page 7 of 8
DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 06 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: ENCS, KECI, PICCS, TSCA Special Cases: AICS, IECSC, DSL,
Product Name:
Page 8 of 8
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R36; Irritating to eyes. R38; Irritating to skin. R41; Risk of serious damage to eyes. R50/53; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R62; Possible risk of impaired fertility. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 11: Ingestion Acute Lethality - Header was modified. Section 05: Hazardous Combustion Products was modified. Section 16: RCode Key was modified. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Acute Aquatic Toxicity was deleted. Section 12: Ecological Information - Acute Aquatic Toxicity was deleted.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS CALCIUM LONG CHAIN ALKYL PHENATE SULPHIDE ZINC DITHIOPHOSPHATE
68649-42-3
Product Name:
Page 2 of 8
N;R51/53 * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >215C (419F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7
Product Name:
Page 3 of 8
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION
Product Name:
Page 4 of 8
Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.88 Flash Point [Method]: >215C (419F) [ ASTM D-92]
Product Name:
Page 5 of 8
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7 Autoignition Temperature: N/D Boiling Point / Range: N/D Vapour Density (Air = 1): N/D Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C [Estimated] Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 104 cSt (104 mm/sec) at 40C | 14.3 cSt (14.3 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -27C (-17F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test
Product Name:
Page 6 of 8
CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION
Product Name:
Page 7 of 8
European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, ENCS, KECI, PICCS, TSCA SECTION 16 OTHER INFORMATION AICS, IECSC, DSL,
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R38; Irritating to skin. R41; Risk of serious damage to eyes.
Product Name:
Page 8 of 8
R51/53; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R53; May cause long-term adverse effects in the aquatic environment. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 04: First Aid Skin was modified. Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Hazard Identification: Health Hazards was modified. Section 05: Hazardous Combustion Products was modified. Composition: Component Table was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 09: Viscosity was modified. Section 08: Environmental Control - Note was modified. Section 16: RCode Key was modified. Section 16: Code to MHCs was modified. Section 09: Relative Density was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS CALCIUM SALICYLATE ZINC ALKYL DITHIOPHOSPHATE 824-35-1 212-525-4 272-028-3
Product Name:
Page 2 of 8
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: 216C (421F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
Product Name:
Page 3 of 8
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION
Product Name:
Page 4 of 8
Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: brown Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.9 Flash Point [Method]: 216C (421F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9
UEL: 7.0
Product Name:
Page 5 of 8
Autoignition Temperature: N/D Boiling Point / Range: N/D Vapour Density (Air = 1): N/D Vapour Pressure: [N/D at 20C] Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Negligible Viscosity: 87.9 cSt (87.9 mm/sec) at 40C | 14.5 cSt (14.5 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -45C (-49F) SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
Product Name:
Page 6 of 8
CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Synthetic base oils: Not expected to cause significant health effects under conditions of normal use, based on laboratory studies with the same or similar materials. Not mutagenic or genotoxic. Not sensitising in test animals and humans. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 06 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies.
Product Name:
Page 7 of 8
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: ENCS, KECI, TSCA SECTION 16 OTHER INFORMATION AICS, DSL, EINECS,
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R36; Irritating to eyes. R38; Irritating to skin. R51/53; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53; Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 08: Hand Protection was modified.
Product Name:
Page 8 of 8
Section 08: Environmental Control - Note was modified. Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 08: Environmental Control - Note was modified. Section 15: National Chemical Inventory Listing was modified. Section 16: Code to MHCs was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
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603100-60 MOBIL DTE 11M MATERIAL SAFETY DATA BULLETIN --------------------------------------------------------------------------------------------------------------------------------------------------1. PRODUCT AND COMPANY IDENTIFICATION -------------------------------------------------------------------------PRODUCT NAME: MOBIL DTE 11M 30/06/2003 SUPPLIER: EXXONMOBIL MARINE LIMITED EXXONMOBIL HOUSE MAILPOINT 29, ERMYN WAY LEATHERHEAD, KT22 8UX UNITED KINGDOM
24 Hour Health Emergency: +44 1372 222 000 Product and Technical Information: EAME +420 221 456 618 AMERICAS +1 800 662 4525 / ASIA PACIFIC +8621 5464 4588 EXT 5842
INTENDED USE: HYDRAULIC OIL -------------------------------------------------------------------------2. COMPOSITION/INFORMATION ON INGREDIENTS -------------------------------------------------------------------------CHEMICAL NAMES AND SYNONYMS: SEVERE TREAT MIN. OILS & ADDITIVES GLOBALLY REPORTABLE MSDS INGREDIENTS: None. OTHER INGREDIENTS: Substance Name Approx. Wt% -----------------------SOLVENT DEWAXED LIGHT 65-75 PARAFFINIC DISTILLATE (PETROLEUM) (CAS 64742-56-9) (EINECS 265-159-2) EU Classification ---------------------------NA
-------------------------------------------------------------------------3. HAZARDS IDENTIFICATION -------------------------------------------------------------------------Under normal conditions of use, this product is not considered
Symbol: Not applicable. Risk Phrase(s): Not applicable. POTENTIAL HEALTH EFFECTS: On prolonged, repeated skin contact, this material may defat the skin resulting in possible irritation and dermatitis. Low viscosity material-if swallowed may enter the lungs and cause lung damage. Excessive exposure may result in eye, skin or respiratory irritation. For further health effects/toxicological data, see Section 11. NOTE: This product should not be used for any other purpose without expert advice. -------------------------------------------------------------------------4. FIRST AID MEASURES -------------------------------------------------------------------------EYE CONTACT: Flush thoroughly with water. If irritation occurs, call a doctor. SKIN CONTACT: Wash contact areas with soap and water. Remove and clean oil soaked clothing daily and wash affected area. INJECTION INJURY WARNING: If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. INHALATION: Not expected to be a problem. However, if respiratory irritation, dizziness, nausea, or unconsciousness occurs due to excessive vapor or mist exposure, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or mouth-to-mouth resuscitation. INGESTION: Seek immediate medical attention. DO NOT INDUCE VOMITING. NOTE TO DOCTORS: Material if aspirated into the lungs may cause chemical pneumonitis. -------------------------------------------------------------------------5. FIRE-FIGHTING MEASURES -------------------------------------------------------------------------EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog. SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: Note: Pressurized mists may form a flammable mixture. COMBUSTION PRODUCTS: Fumes, smoke, carbon monoxide, sulfur oxides, aldehydes and other decomposition products, in the case of incomplete combustion.
Flash Point C(F): > 166(331) (IP 34 / ASTM D-93). Flammable Limits (approx.% vol.in air) LELNE, NFPA HAZARD ID: Health: 0 , Flammability: 1 ,
UEL: NE Reactivity:
-------------------------------------------------------------------------6. ACCIDENTAL RELEASE MEASURES -------------------------------------------------------------------------NOTIFICATION PROCEDURES: Report spills/releases as required to appropriate authorities. In case of accident or road spill, contact the Police and Fire Brigade and, if appropriate, the Area Water Authority. PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: LAND SPILL: Shut off source taking normal safety precautions. Take measures to minimize the effects on ground water. Recover by pumping or contain spilled material with sand or other suitable absorbent and remove mechanically into containers. If necessary, dispose of adsorbed residues as directed in Section 13. WATER SPILL: Confine the spill immediately with booms. Warn other ships in the vicinity. Notify port and other relevant authorities. Remove from the surface by skimming or with suitable absorbents. If permitted by regulatory authorities the use of suitable dispersants should be considered where recommended in local oil spill procedures. ENVIRONMENTAL PRECAUTIONS: Prevent material from entering sewers, water sources or low lying areas; advise the relevant authorities if it has, or if it contaminates soil/vegetation. PERSONAL PRECAUTIONS: See Section 8 -------------------------------------------------------------------------7. HANDLING AND STORAGE -------------------------------------------------------------------------SPECIFIC USES: HYDRAULIC OIL HANDLING: High pressure injection under the skin may occur due to the rupture of pressurized lines. Always seek medical attention. Avoid prolonged, repeated skin contact. See Section 8 for additional personal protection advice when handling this product. STORAGE: Keep containers closed when not in use. Do not store in open or unlabelled containers. Store away from strong oxidizing agents and combustible materials. Do not store near heat, sparks, flame or strong oxidants. SPECIAL PRECAUTIONS: Prevent small spills and leakages to avoid slip hazard. EMPTY CONTAINER WARNING: Empty containers retain residue (liquid and/ or vapour) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD BRAZE, SOLDER,DRILL,GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. --------------------------------------------------------------------------
8. EXPOSURE CONTROLS/PERSONAL PROTECTION -------------------------------------------------------------------------OCCUPATIONAL EXPOSURE LIMITS: When mists/aerosols can occur, the following are recommended: 5 mg/m3 (as oil mist)- ACGIH Threshold Limit Value (TLV), 10 mg/m3 (as oil mist) - ACGIH Short Term Exposure Limit (STEL) VENTILATION: If mists are generated, use adequate ventilation, local exhaust or enclosures to control below exposure limits. RESPIRATORY PROTECTION: If mists are generated, and/or when ventilation is not adequate, wear approved respirator. EYE PROTECTION: If eye contact is likely, safety glasses with side shields or chemical type goggles should be worn. SKIN PROTECTION: If prolonged or repeated skin contact is likely, oil impervious gloves MUST be worn. Good personal hygiene practices should always be followed. ENVIRONMENTAL CONTROLS: SEE SECTION 7 -------------------------------------------------------------------------9. PHYSICAL AND CHEMICAL PROPERTIES -------------------------------------------------------------------------Typical physical properties are given below. Consult Product Data Sheet for specific details. GENERAL: PHYSICAL STATE: Liquid COLOUR: Amber ODOUR: Mild ODOUR THRESHOLD-ppm: NE IMPORTANT HEALTH, SAFETY AND ENVIRONMENTAL INFORMATION: pH: NA BOILING POINT C(F): NE FLASH POINT C(F): > 166(331) (IP 34 / ASTM D-93) FLAMMABILITY (solids): NE AUTO FLAMMABILITY C(F): NA EXPLOSIVE PROPERTIES: NA OXIDIZING PROPERTIES: NA VAPOUR PRESSURE-mmHg 20 C: < 0.1 RELATIVE DENSITY, 15/4 C: 0.859 SOLUBILITY IN WATER: Negligible PARTITION COEFFICIENT: > 3.5 VISCOSITY AT 40 C, cSt: 15.0 VISCOSITY AT 100 C, cSt: 3.7 VAPOUR DENSITY: > 2.0 EVAPORATION RATE: NE OTHER INFORMATION: MELTING POINT C(F): NA POUR POINT C(F): -42(-44) FREEZING POINT C(F): NE DMSO EXTRACT, IP-346 (WT.%): <3, for mineral oil only NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING
REPRESENTATIVE -------------------------------------------------------------------------10. STABILITY AND REACTIVITY -------------------------------------------------------------------------STABILITY (THERMAL, LIGHT, ETC.): Stable. CONDITIONS TO AVOID: Extreme heat and high energy sources of ignition. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidisers. HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at ambient temperatures. HAZARDOUS POLYMERISATION: Will not occur. -------------------------------------------------------------------------11. TOXICOLOGICAL DATA ----------------------------------------------------------------------------ACUTE TOXICOLOGY--ORAL TOXICITY: Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. DERMAL TOXICITY: Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. INHALATION TOXICITY: Practically non-toxic (LC50: greater than 5 mg/l). ---Based on testing of similar products and/or the components. EYE IRRITATION: Practically non-irritating. (Draize score: greater than 6 but 15 or less). ---Based on testing of similar products and/or the components. SKIN IRRITATION: Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). ---Based on testing of similar products and/or the components. OTHER ACUTE TOXICITY DATA: Although an acute inhalation study was not performed with this product, a variety of mineral and synthetic oils, such as those in this product, have been tested. These samples had virtually no effect other than a nonspecific inflammatory response in the lung to the aerosolized mineral oil. The presence of additives in other tested formulations (in approximately the same amounts as in the present formulation) did not alter the observed effects. ---SUBCHRONIC TOXICOLOGY (SUMMARY)--No significant adverse effects were found in studies using repeated dermal applications of similar formulations to the skin of laboratory animals for 13 weeks at doses significantly higher than those expected during normal industrial exposure. The animals were evaluated extensively for effects of exposure (hematology, serum chemistry, urinalysis, organ weights, microscopic examination of tissues etc.). ---REPRODUCTIVE TOXICOLOGY (SUMMARY)--No teratogenic effects would be expected from dermal exposure, based on laboratory developmental toxicity studies of major components in this formulation and/or materials of similar composition. ---CHRONIC TOXICOLOGY (SUMMARY)--Repeated and/or prolonged exposure may cause irritation to the skin, eyes or respiratory tract. Overexposure to oil mist may result
in oil droplet deposition and/or granuloma formation. For mineral base oils: Base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic mouse skin painting studies of severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a continuing basis using various screening methods such as Modified Ames Test, IP-346, and/or other analytical methods. Synthetic base oils representative of those in this producthave been tested in the Ames assay and other tests of mutagenicity with negative results. These base oils are not expected to be carcinogenic with chronic dermal exposures. ---SENSITIZATION (SUMMARY)--Not expected to be sensitizing based on tests of this product, components, or similar products. -------------------------------------------------------------------------12. ECOLOGICAL INFORMATION -------------------------------------------------------------------------ENVIRONMENTAL FATE AND EFFECTS: In the absence of specific environmental data for this product, this assessment is based on information for representative products. ECOTOXICITY: Available ectoxicity data (LL50 >1000 mg/L) indicates that adverse effects to aquatic organisms are not expected from this product. MOBILITY: When released into the environment, adsorption to sediment and soil will be the predominant behavior. PERSISTENCE AND DEGRADABILITY: This product is expected to be inherently biodegradable. BIOACCUMULATIVE POTENTIAL: Bioaccumulation is unlikely due to the very low water solubility of this product, therefore bioavailability to aquatic organisms is minimal.
-------------------------------------------------------------------------13. DISPOSAL CONSIDERATIONS -------------------------------------------------------------------------WASTE DISPOSAL: Product is suitable for burning in an enclosed, controlled burner for fuel value. Such burning may be limited pursuant to the Resource Conservation and Recovery Act. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. EUROPEAN WASTE CODE: 13 01 10 (mineral based oils) Waste generated from the intended assigned the above waste disposal code. the intended use and/or the presence of contaminants may require an alternative non-chlorinated hydraulic use of this product is However, deviation from any potential waste disposal code to be
assigned by the end user. This waste is considered as a hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of the Directive applies. -------------------------------------------------------------------------14. TRANSPORT INFORMATION -------------------------------------------------------------------------USA DOT: NOT REGULATED BY USA DOT. RID/ADR: IMO: IATA: NOT REGULATED BY RID/ADR.
-------------------------------------------------------------------------15. REGULATORY INFORMATION -------------------------------------------------------------------------EU Labelling: Product is not dangerous as defined by the European Union Dangerous Substances/Preparations Directives. Symbol: Not applicable. Risk Phrase(s): Not applicable.
Safety Phrase(s): S24-62. Avoid contact with skin. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Contains: Base oil - unspecified. THIS PRODUCT HAS BEEN AUTHORIZED BY USDA FOR USE UNDER THE FOLLOWING CATEGORY: This product is acceptable as a lubricant where there is no possibility of food contact (complies with earlier USDA guidelines for H-2 lubricant use). Contains: Calcium Sulphonate. MAY PRODUCE AN ALLERGIC REACTION.
THE FOLLOWING PRODUCT INGREDIENTS ARE CITED ON THE LISTS BELOW: CHEMICAL NAME CAS NUMBER *** NO REPORTABLE INGREDIENTS *** --- REGULATORY ALLERGI 11=DE ALLERGY 12=DE CARC 13=DE CARC 14=DE TERAT A 15=DE LISTS SEARCHED TERAT B 16=DE TERAT C 17=AT TERAT D 18=AT CARC A1 19=AT CARC A2 20=AT LIST CITATIONS
21=CH CARC
CARC=CARCINOGEN;
SUS=SUSPECTED CARCINOGEN;
TERAT=TERATOGENIC
AT = Austria CH = Switzerland
DE = Germany DK = Denmark
NO = Norway SE = Sweden
NOTE: EXXONMOBIL PRODUCTS ARE NOT FORMULATED TO CONTAIN PCBS. Health studies have shown that many hydrocarbons pose potential human health risks which may vary from person to person. Information provided on this MSDS reflects intended use. This product should not be used for other applications. In any case, the following advice should be considered:
COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Any sections of this Material Safety Data Sheet which are printed in bold text highlights recent significant changes which have been made to the advice or information given. ********************************************************************** For Internal Use Only: MHC: 1* 1* 1* 1* 1*, MPPEC: C, TRN: 603100-60, ELIS: 400260, CMCS97: 970530 EHS Approval Date: 30JUN2003 **********************************************************************
Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. Exxon Mobil Corporation and its affiliated companies assume no responsibility for accuracy of information unless the document is the most current available from an official ExxonMobil distribution system. Exxon Mobil Corporation and its affiliated companies neither represent nor warrant that the format, content or product formulas contained in this document comply with the laws of any other country except the United States of America.
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602698-60 MOBIL DTE 13M MATERIAL SAFETY DATA BULLETIN --------------------------------------------------------------------------------------------------------------------------------------------------1. PRODUCT AND COMPANY IDENTIFICATION -------------------------------------------------------------------------PRODUCT NAME: MOBIL DTE 13M 03/08/2002 SUPPLIER: EXXONMOBIL MARINE LIMITED EXXONMOBIL HOUSE MAILPOINT 29, ERMYN WAY LEATHERHEAD, KT22 8UX UNITED KINGDOM
24 Hour Health Emergency: +44 1372 222 000 Product and Technical Information: EAME +420 221 456 618 AMERICAS +1 800 662 4525 / ASIA PACIFIC +8621 5464 4588 EXT 5842
INTENDED USE: Hydraulic oil -------------------------------------------------------------------------2. COMPOSITION/INFORMATION ON INGREDIENTS -------------------------------------------------------------------------CHEMICAL NAMES AND SYNONYMS: PET. HYDROCARBONS AND ADDITIVES GLOBALLY REPORTABLE MSDS INGREDIENTS: None. OTHER INGREDIENTS: Substance Name Approx. Wt% -----------------------SOLVENT DEWAXED LIGHT 25-35 PARAFFINIC DISTILLATE (PETROLEUM) (CAS 64742-56-9) (EINECS 265-159-2) EU Classification ---------------------------NA
-------------------------------------------------------------------------3. HAZARDS IDENTIFICATION -------------------------------------------------------------------------Under normal conditions of use, this product is not considered
POTENTIAL HEALTH EFFECTS: Under normal conditions of intended use, this product does not pose a risk to health. Excessive exposure may result in eye, skin or respiratory irritation. For further health effects/toxicological data, see Section 11. NOTE: This product should not be used for any other purpose without expert advice. -------------------------------------------------------------------------4. FIRST AID MEASURES -------------------------------------------------------------------------EYE CONTACT: Flush thoroughly with water. If irritation occurs, call a doctor. SKIN CONTACT: Wash contact areas with soap and water. Remove and clean oil soaked clothing daily and wash affected area. INJECTION INJURY WARNING: If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. INHALATION: Not expected to be a problem. However, if respiratory irritation, dizziness, nausea, or unconsciousness occurs due to excessive vapor or mist exposure, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or mouth-to-mouth resuscitation. INGESTION: Not expected to be a problem. Seek medical attention if discomfort occurs. Do not induce vomiting. -------------------------------------------------------------------------5. FIRE-FIGHTING MEASURES -------------------------------------------------------------------------EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog. SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: Note: Pressurized mists may form a flammable mixture. COMBUSTION PRODUCTS: Fumes, smoke, carbon monoxide, sulfur oxides, aldehydes and other decomposition products, in the case of incomplete combustion. Flash Point C(F): > 166(331) (IP 36 / ASTM D-92). Flammable Limits (approx.% vol.in air) LEL 0.9%, UEL: 7.0% NFPA HAZARD ID: Health: 0 , Flammability: 1 , Reactivity: 0 -------------------------------------------------------------------------6. ACCIDENTAL RELEASE MEASURES --------------------------------------------------------------------------
NOTIFICATION PROCEDURES: Report spills/releases as required to appropriate authorities. In case of accident or road spill, contact the Police and Fire Brigade and, if appropriate, the Area Water Authority. PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: LAND SPILL: Shut off source taking normal safety precautions. Take measures to minimize the effects on ground water. Recover by pumping or contain spilled material with sand or other suitable absorbent and remove mechanically into containers. If necessary, dispose of adsorbed residues as directed in Section 13. WATER SPILL: Confine the spill immediately with booms. Warn other ships in the vicinity. Notify port and other relevant authorities. Remove from the surface by skimming or with suitable absorbents. If permitted by regulatory authorities the use of suitable dispersants should be considered where recommended in local oil spill procedures. ENVIRONMENTAL PRECAUTIONS: Prevent material from entering sewers, water sources or low lying areas; advise the relevant authorities if it has, or if it contaminates soil/vegetation. PERSONAL PRECAUTIONS: See Section 8 -------------------------------------------------------------------------7. HANDLING AND STORAGE -------------------------------------------------------------------------SPECIFIC USES: Hydraulic oil HANDLING: High pressure injection under the skin may occur due to the rupture of pressurized lines. Always seek medical attention. No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. STORAGE: Keep containers closed when not in use. Do not store in open or unlabelled containers. Store away from strong oxidizing agents and combustible materials. Do not store near heat, sparks, flame or strong oxidants. SPECIAL PRECAUTIONS: Prevent small spills and leakages to avoid slip hazard. EMPTY CONTAINER WARNING: Empty containers retain residue (liquid and/ or vapour) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD BRAZE, SOLDER,DRILL,GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. -------------------------------------------------------------------------8. EXPOSURE CONTROLS/PERSONAL PROTECTION -------------------------------------------------------------------------OCCUPATIONAL EXPOSURE LIMITS: When mists/aerosols can occur, the following are recommended: 5 mg/m3
(as oil mist)- ACGIH Threshold Limit Value (TLV), 10 mg/m3 (as oil mist) - ACGIH Short Term Exposure Limit (STEL) VENTILATION: If mists are generated, use adequate ventilation, local exhaust or enclosures to control below exposure limits. RESPIRATORY PROTECTION: If mists are generated, and/or when ventilation is not adequate, wear approved respirator. EYE PROTECTION: If eye contact is likely, safety glasses with side shields or chemical type goggles should be worn. SKIN PROTECTION: Not normally required. When splashing or liquid contact can occur frequently, wear oil resistant gloves and/or other protective clothing. Good personal hygiene practices should always be followed. ENVIRONMENTAL CONTROLS: SEE SECTION 7 -------------------------------------------------------------------------9. PHYSICAL AND CHEMICAL PROPERTIES -------------------------------------------------------------------------Typical physical properties are given below. Consult Product Data Sheet for specific details. GENERAL: PHYSICAL STATE: Liquid COLOUR: Amber ODOUR: Mild ODOUR THRESHOLD-ppm: NE IMPORTANT HEALTH, SAFETY AND ENVIRONMENTAL INFORMATION: pH: NA BOILING POINT C(F): NE FLASH POINT C(F): > 166(331) (IP 36 / ASTM D-92) FLAMMABILITY (solids): NE AUTO FLAMMABILITY C(F): NA EXPLOSIVE PROPERTIES: NA OXIDIZING PROPERTIES: NA VAPOUR PRESSURE-mmHg 20 C: < 0.1 RELATIVE DENSITY, 15/4 C: 0.874 SOLUBILITY IN WATER: Negligible PARTITION COEFFICIENT: > 3.5 VISCOSITY AT 40 C, cSt: 32.0 VISCOSITY AT 100 C, cSt: 6.1 VAPOUR DENSITY: > 2.0 EVAPORATION RATE: NE OTHER INFORMATION: MELTING POINT C(F): NA POUR POINT C(F): -45(-49) FREEZING POINT C(F): NE DMSO EXTRACT, IP-346 (WT.%): <3, for mineral oil only NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE -------------------------------------------------------------------------10. STABILITY AND REACTIVITY --------------------------------------------------------------------------
STABILITY (THERMAL, LIGHT, ETC.): Stable. CONDITIONS TO AVOID: Extreme heat and high energy sources of ignition. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidisers. HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at ambient temperatures. HAZARDOUS POLYMERISATION: Will not occur. -------------------------------------------------------------------------11. TOXICOLOGICAL DATA ----------------------------------------------------------------------------ACUTE TOXICOLOGY--ORAL TOXICITY: Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. DERMAL TOXICITY: Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. INHALATION TOXICITY: Practically non-toxic (LC50: greater than 5 mg/l). ---Based on testing of similar products and/or the components. EYE IRRITATION: Practically non-irritating. (Draize score: greater than 6 but 15 or less). ---Based on testing of similar products and/or the components. SKIN IRRITATION: Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). ---Based on testing of similar products and/or the components. OTHER ACUTE TOXICITY DATA: Although an acute inhalation study was not performed with this product, a variety of mineral and synthetic oils, such as those in this product, have been tested. These samples had virtually no effect other than a nonspecific inflammatory response in the lung to the aerosolized mineral oil. The presence of additives in other tested formulations (in approximately the same amounts as in the present formulation) did not alter the observed effects. ---SUBCHRONIC TOXICOLOGY (SUMMARY)--No significant adverse effects were found in studies using repeated dermal applications of similar formulations to the skin of laboratory animals for 13 weeks at doses significantly higher than those expected during normal industrial exposure. The animals were evaluated extensively for effects of exposure (hematology, serum chemistry, urinalysis, organ weights, microscopic examination of tissues etc.). ---REPRODUCTIVE TOXICOLOGY (SUMMARY)--No teratogenic effects would be expected from dermal exposure, based on laboratory developmental toxicity studies of major components in this formulation and/or materials of similar composition. ---CHRONIC TOXICOLOGY (SUMMARY)--Repeated and/or prolonged exposure may cause irritation to the skin, eyes or respiratory tract. Overexposure to oil mist may result in oil droplet deposition and/or granuloma formation. For mineral base oils: Base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic mouse skin painting studies of severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a
continuing basis using various screening methods such as Modified Ames Test, IP-346, and/or other analytical methods. Synthetic base oils representative of those in this producthave been tested in the Ames assay and other tests of mutagenicity with negative results. These base oils are not expected to be carcinogenic with chronic dermal exposures. ---SENSITIZATION (SUMMARY)--Not expected to be sensitizing based on tests of this product, components, or similar products. -------------------------------------------------------------------------12. ECOLOGICAL INFORMATION -------------------------------------------------------------------------ENVIRONMENTAL FATE AND EFFECTS: In the absence of specific environmental data for this product, this assessment is based on information for representative products. ECOTOXICITY: Available ectoxicity data (LL50 >1000 mg/L) indicates that adverse effects to aquatic organisms are not expected from this product. MOBILITY: When released into the environment, adsorption to sediment and soil will be the predominant behavior. PERSISTENCE AND DEGRADABILITY: This product is expected to be inherently biodegradable. BIOACCUMULATIVE POTENTIAL: Bioaccumulation is unlikely due to the very low water solubility of this product, therefore bioavailability to aquatic organisms is minimal.
-------------------------------------------------------------------------13. DISPOSAL CONSIDERATIONS -------------------------------------------------------------------------WASTE DISPOSAL: Product is suitable for burning in an enclosed, controlled burner for fuel value. Such burning may be limited pursuant to the Resource Conservation and Recovery Act. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. EUROPEAN WASTE CODE: 13 01 10 (mineral based non-chlorinated hydraulic oils) Waste generated from the intended use of this product is assigned the above waste disposal code. However, deviation from the intended use and/or the presence of any potential contaminants may require an alternative waste disposal code to be assigned by the end user. This waste is considered as a hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of the Directive applies.
-------------------------------------------------------------------------14. TRANSPORT INFORMATION -------------------------------------------------------------------------USA DOT: NOT REGULATED BY USA DOT. RID/ADR: IMO: IATA: NOT REGULATED BY RID/ADR.
-------------------------------------------------------------------------15. REGULATORY INFORMATION -------------------------------------------------------------------------EU Labelling: Product is not dangerous as defined by the European Union Dangerous Substances/Preparations Directives. EU labeling not required. THIS PRODUCT HAS BEEN AUTHORIZED BY USDA FOR USE UNDER THE FOLLOWING CATEGORY: This product is acceptable as a lubricant where there is no possibility of food contact (complies with earlier USDA guidelines for H-2 lubricant use). Contains: Calcium Sulphonate. MAY PRODUCE AN ALLERGIC REACTION.
THE FOLLOWING PRODUCT INGREDIENTS ARE CITED ON THE LISTS BELOW: CHEMICAL NAME CAS NUMBER *** NO REPORTABLE INGREDIENTS *** --- REGULATORY ALLERGI 11=DE ALLERGY 12=DE CARC 13=DE CARC 14=DE TERAT A 15=DE LISTS SEARCHED TERAT B 16=DE TERAT C 17=AT TERAT D 18=AT CARC A1 19=AT CARC A2 20=AT LIST CITATIONS
21=CH CARC
CARC=CARCINOGEN;
AT = Austria CH = Switzerland
NOTE: EXXONMOBIL PRODUCTS ARE NOT FORMULATED TO CONTAIN PCBS. Health studies have shown that many hydrocarbons pose potential human health risks which may vary from person to person. Information provided on this MSDS reflects intended use. This product should not be used for other applications. In any case, the following advice
should be considered: INDUSTRIAL LABEL Under normal conditions of intended use, this product does not pose a risk to health. Excessive exposure may result in eye, skin or respiratory irritation. Always observe good hygiene measures. First Aid: Wash skin with soap and water. Flush eyes with water. If overcome by fumes or vapor, remove to fresh air. If ingested, do not induce vomiting. If symptoms persist seek medical assistance. Read and understand the MSDS before using this product.
COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Any sections of this Material Safety Data Sheet which are printed in bold text highlights recent significant changes which have been made to the advice or information given. ********************************************************************** For Internal Use Only: MHC: 1* 1* 1* 1* 1*, MPPEC: A, TRN: 602698-60, ELIS: 400364, CMCS97: 970705 EHS Approval Date:03AUG2002 **********************************************************************
Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. Exxon Mobil Corporation and its affiliated companies assume no responsibility for accuracy of information unless the document is the most current available from an official ExxonMobil distribution system. Exxon Mobil Corporation and its affiliated companies neither represent nor warrant that the format, content or product formulas contained in this document comply with the laws of any other country except the United States of America.
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+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
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immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurised mists may form a flammable mixture. Hazardous Combustion Products: Fume, Sulphur Oxides Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke,
FLAMMABILITY PROPERTIES Flash Point [Method]: >168C (334F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT
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Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
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selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.879 Flash Point [Method]: >168C (334F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible
UEL: 7.0
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Viscosity: 46 cSt (46 mm/sec) at 40C | 7.8 cSt (7.8 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -36C (-33F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on assessment of the components.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request.
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SECTION 12
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 01 10 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
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SECTION 14
TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
Contains: CALCIUM SULPHONATE May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: ENCS, TSCA SECTION 16 OTHER INFORMATION EINECS, AICS, KECI,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law,
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re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
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+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
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immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurised mists may form a flammable mixture. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >180C (356F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
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SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
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selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.884 Flash Point [Method]: >180C (356F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: N/D | < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A
UEL: 7.0
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Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 68 cSt (68 mm/sec) at 40C | 10.7 cSt (10.7 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -30C (-22F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on assessment of the components.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
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The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 01 10 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
Product Name:
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SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains: CALCIUM SULPHONATE May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: TSCA SECTION 16 OTHER INFORMATION AICS, EINECS, ENCS,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
Product Name:
Page 8 of 8
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurised mists may form a flammable mixture. Hazardous Combustion Products: Sulphur Oxides, Aldehydes Incomplete combustion products, Oxides of carbon, Smoke, Fume,
FLAMMABILITY PROPERTIES Flash Point [Method]: 212C (414F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT
Product Name:
Page 3 of 8
Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
Product Name:
Page 4 of 8
respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.888 Flash Point [Method]: 212C (414F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5
UEL: 7.0
Product Name:
Page 5 of 8
Solubility in Water: Negligible Viscosity: 100 cSt (100 mm/sec) at 40C | 13.2 cSt (13.2 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -21C (-6F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on assessment of the components.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Product Name:
Page 6 of 8
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 01 10 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
Product Name:
Page 7 of 8
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
Contains: CALCIUM SULPHONATE May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: TSCA, AICS SECTION 16 OTHER INFORMATION ENCS, EINECS,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
Product Name:
Page 8 of 8
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurised mists may form a flammable mixture. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >190C (374F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
Product Name:
Page 3 of 8
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
Product Name:
Page 4 of 8
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.895 Flash Point [Method]: >190C (374F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A
UEL: 7.0
Product Name:
Page 5 of 8
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 150 cSt (150 mm/sec) at 40C | 16.55 cSt (16.55 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -21C (-6F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on assessment of the components.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Product Name:
Page 6 of 8
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 01 10 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
Product Name:
Page 7 of 8
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains: CALCIUM SULPHONATE May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: TSCA SECTION 16 OTHER INFORMATION AICS, EINECS, ENCS,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
Product Name:
Page 8 of 8
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 9
MOBIL DTE 21
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS If swallowed, may be aspirated and cause lung damage. Frequent or prolonged contact may de-fat and dry the skin, leading to discomfort and dermatitis. May be irritating to the eyes, nose, throat, and lungs. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
Product Name:
Page 2 of 9
MOBIL DTE 21
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION Seek immediate medical attention. Do not induce vomiting. NOTE TO PHYSICIAN If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurised mists may form a flammable mixture. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >166C (331F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
Product Name:
Page 3 of 9
MOBIL DTE 21
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Avoid contact with skin. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage.
Product Name:
Page 4 of 9
MOBIL DTE 21
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: If prolonged or repeated contact is likely, chemical-resistant gloves are recommended. If contact with forearms is likely, wear gauntlet-style gloves. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.845 Flash Point [Method]: >166C (331F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 232C (450F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C
UEL: 7.0
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MOBIL DTE 21
Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): Solubility in Water: Negligible Viscosity: 10 cSt (10 mm/sec) at 40C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -24C (-11F) DMSO Extract (mineral oil only), IP-346: SECTION 10
> 3.5
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Elevated temperatures or mechanical action may form vapours, mist, or fumes which may be irritating to the eyes, nose, throat, or lungs. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
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MOBIL DTE 21
Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory tract. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 01 10 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s).
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MOBIL DTE 21
This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . . Safety Advice: S24; Avoid contact with skin. S62; If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
Contains: CALCIUM SULPHONATE May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, ENCS, KECI, PICCS, TSCA SECTION 16 OTHER INFORMATION AICS, IECSC,
Product Name:
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MOBIL DTE 21
Revision Changes: Hazard Identification: Health Hazards was modified. Section 04: First Aid Skin - Header was modified. Section 04: First Aid Ingestion - Header was modified. Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 11: Ingestion Acute Lethality - Header was modified. Section 11: Ingestion Lethality Conclusion was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 09: Vapour Pressure was modified. Hazard Identification: Health Hazards was modified. Section 11: Inhalation Lethality Test Comment was modified. Section 11: Dermal Irritation Test Comment was modified. Section 11: Eye Irritation Test Comment was modified. Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 08: Environmental Control - Note was modified. Section 15: National Chemical Inventory Listing was modified. Section 16: Code to MHCs was modified. Composition: No components was modified. Section 15: Sensitiser Statement was modified. Section 11: Other Health Effects was modified. Section 11: Inhalation Lethality Test Data was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Composition: CAS Number was deleted. Composition: Concentration - Header was deleted. Composition: Component Table was deleted. Composition: EINECS/ELINCS was deleted. Composition: Symbol/Risk Phrase Header was deleted. Section 16: RCode Key - Header was deleted. Composition: Concentration Footnote was deleted. Composition: Substance or Complex Substance Name was deleted. Section 16: RCode Key was deleted. Composition: Substances Table - Header was deleted.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
Product Name:
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MOBIL DTE 21
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 2A, 0B, 0, 0, 0, 1
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >207C (405F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
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Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
STORAGE Do not store in open or unlabelled containers. Keep away from incompatible materials.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Product Name:
Page 4 of 8
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.87 Flash Point [Method]: >207C (405F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible
UEL: 7.0
Product Name:
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Viscosity: 68 cSt (68 mm/sec) at 40C | 8.6 cSt (8.6 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -15C (5F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Product Name:
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The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 01 10 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
Product Name:
Page 7 of 8
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: ENCS, KECI, TSCA SECTION 16 OTHER INFORMATION AICS, DSL, EINECS,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 07: Handling and Storage - Storage Phrases was modified. Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 08: Environmental Control - Note was modified.
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Section 16: Code to MHCs was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 9
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
Product Name:
Page 2 of 9
SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurised mists may form a flammable mixture. Hazardous Combustion Products: Oxides of carbon, Incomplete combustion products, Smoke, Fume
FLAMMABILITY PROPERTIES Flash Point [Method]: >250C (482F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: N/D Autoignition Temperature: N/D SECTION 6
UEL: N/D
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other
Product Name:
Page 3 of 9
shipping. Remove from the surface by skimming or with suitable absorbents. specialist before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation.
Product Name:
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For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Colourless Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.968 Flash Point [Method]: >250C (482F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: N/D Vapour Density (Air = 1): N/D Vapour Pressure: [N/D at 20C] Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): >= 7 Solubility in Water: Negligible Viscosity: 95.7 cSt (95.7 mm/sec) at 40C | 10.6 cSt (10.6 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16.
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OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -30C (-22F) SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY
Product Name:
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Majority of components -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Majority of components -- Expected to be inherently biodegradable
Duration 96 hour(s)
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 01 11 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport
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SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: Special Cases: Inventory ELINCS IECSC SECTION 16 Status Restrictions Apply Restrictions Apply OTHER INFORMATION TSCA
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 13: Disposal Considerations - Disposal Recommendations was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Color was modified. Section 09: Pour Point C(F) was modified. Section 09: n-Octanol/Water Partition Coefficient was modified. Section 08: Hand Protection was modified. Section 09: Vapour Pressure was modified. Section 07: Handling and Storage - Handling was modified. Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flammable Limits - LEL was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 09: Viscosity was modified. Section 15: EU Dangerous/not Dangerous was modified. Section 15: EU Labeling - Header was modified.
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Section 15: National Chemical Inventory Listing was modified. Section 09: Relative Density was modified. Composition: No components was modified. Section 16: MSN, MAT ID was modified. Section 09: Flammable Limits - UEL was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 12: Mobility - Header was added. Section 12: Environmental tox table header was added. Section 12: Test - Column Header was added. Section 12: Organism Type - Column Header was added. Section 12: Duration - Column Header was added. Section 12: Test Results - Column Header was added. Section 08: Exposure limits/standards was added. Section 08: Exposure limits/standards - Header was added. Hazard Identification: EU - Not Hazardous Statement was added. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added. Section 12: Ecological Information - Mobility was added. Section 12: Ecological Information - Mobility was added. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Biodegradation was added. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Biodegradation was added. Section 12: Environmental tox table in section 12 was added. Section 12: Ecological data - Header was added. Hazard Identification: Environmental Hazard was deleted. Hazard Identification: Environmental Hazard - Header was deleted. Section 15: EC Classification - Header was deleted. Section 15: EC Classification was deleted. Section 15: NATURE OF SPECIAL RISK was deleted. Section 15: EC Risk Phrases - EU Header was deleted. Composition: CAS Number was deleted. Composition: Concentration - Header was deleted. Hazard Identification: EU - Hazards Statement was deleted. Composition: Component Table was deleted. Composition: Regulated as statement was deleted. Composition: EINECS/ELINCS was deleted. Composition: Symbol/Risk Phrase Header was deleted. Section 16: RCode Key - Header was deleted. Hazard Identification: Classification was deleted. Hazard Identification: Classification - Header was deleted. Section 15: EU Safety Advice - EU Header was deleted. Composition: Concentration Footnote was deleted. Composition: Substance or Complex Substance Name was deleted. Section 16: RCode Key was deleted. Section 15: EU Safety Advice was deleted. Composition: Substances Table - Header was deleted. Section 12: Ecological Information - Biodegradation was deleted. Section 12: Ecological Information - Biodegradation was deleted. Section 12: Ecological Information - Acute Aquatic Toxicity was deleted.
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----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
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+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
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immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurised mists may form a flammable mixture. Hazardous Combustion Products: Oxides of carbon, Incomplete combustion products, Smoke, Fume
FLAMMABILITY PROPERTIES Flash Point [Method]: >240C (464F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: N/D Autoignition Temperature: N/D SECTION 6
UEL: N/D
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
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Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
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respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Colourless Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.968 Flash Point [Method]: >240C (464F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: N/D Vapour Density (Air = 1): N/D Vapour Pressure: [N/D at 20C] Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/A Solubility in Water: Negligible Viscosity: 64.9 cSt (64.9 mm/sec) at 40C | 8.3 cSt (8.3 mm/sec) at 100C
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Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -36C (-33F) SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms.
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MOBILITY Majority of components -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Majority of components -- Expected to be inherently biodegradable
Duration 96 hour(s)
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 01 11 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
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INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: Special Cases: Inventory ELINCS IECSC SECTION 16 Status Restrictions Apply Restrictions Apply OTHER INFORMATION TSCA
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 13: Disposal Considerations - Disposal Recommendations was modified. Section 01: Product Code was modified. Section 13: European Waste Codes was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Color was modified. Section 09: Boiling Point C(F) was modified. Section 09: Pour Point C(F) was modified. Section 08: Hand Protection was modified. Section 09: Vapour Pressure was modified. Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flammable Limits - LEL was modified. Section 09: Flash Point C(F) was modified.
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Section 09: Viscosity was modified. Section 09: Viscosity was modified. Section 09: Relative Density was modified. Section 16: MSN, MAT ID was modified. Section 15: Special Cases Table was modified. Section 09: Flammable Limits - UEL was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 12: Mobility - Header was added. Section 12: Environmental tox table header was added. Section 12: Test - Column Header was added. Section 12: Organism Type - Column Header was added. Section 12: Duration - Column Header was added. Section 12: Test Results - Column Header was added. Section 08: Exposure limits/standards was added. Section 08: Exposure limits/standards - Header was added. Section 12: Ecological Information - Mobility was added. Section 12: Ecological Information - Mobility was added. Section 12: Ecological Information - Biodegradation was added. Section 12: Ecological Information - Biodegradation was added. Section 12: Environmental tox table in section 12 was added. Section 12: Ecological data - Header was added. Section 12: Ecological Information - Biodegradation was deleted. Section 12: Ecological Information - Biodegradation was deleted.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
PHYSICAL / CHEMICAL HAZARDS Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Material can accumulate static charges which may cause an incendiary electrical discharge. HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. Breathing of high vapour concentrations may cause dizziness, light-headedness, headache, nausea and loss of co-ordination. Continued inhalation may result in unconsciousness.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Concentration
Symbols/Risk Phrases
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* Distillates (petroleum), hydrotreated light 64742-47-8 265-149-8 20 - 30% Xn;R65, R66, Note H
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Combustible. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >70C (158F) [ ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: N/D Autoignition Temperature: N/D SECTION 6
UEL: N/D
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NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Use proper bonding and/or earthing procedures. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Static Accumulator: This material is a static accumulator.
STORAGE Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Storage containers should be earthed and bonded. Drums must be earthed and bonded and equipped with self-closing valves, pressure vacuum bungs and flame arresters.
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RCP TWA
1200 mg/m3
165 ppm
ExxonMobil
2008
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: Use explosion-proof ventilation equipment to stay below exposure limits. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping.
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ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: red Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.87 Flash Point [Method]: >70C (158F) [ ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): N/D Vapour Pressure: < 0.133 kPa (1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 52.9 cSt (52.9 mm/sec) at 40C | 8.8 cSt (8.8 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -27C (-17F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: MATERIALS TO AVOID: Heat, sparks, flame, and build up of static electricity. Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure Conclusion / Remarks TOXICOLOGICAL INFORMATION
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INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
Minimally Toxic. Based on test data for structurally similar materials. Elevated temperatures or mechanical action may form vapours, mist, or fumes which may be irritating to the eyes, nose, throat, or lungs. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Vapour/aerosol concentrations above recommended exposure levels are irritating to the eyes and respiratory tract, may cause headaches, dizziness, anaesthesia, drowsiness, unconsciousness and other central nervous system effects including death. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and wastewater solids. High molecular wt. component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Majority of components -- Expected to be inherently biodegradable Atmospheric Oxidation: More volatile component -- Expected to degrade rapidly in air
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SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
Product Name:
Page 8 of 8
. .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, ENCS, KECI, PICCS, TSCA SECTION 16 OTHER INFORMATION AICS, IECSC, DSL,
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R51/53; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65; Harmful: may cause lung damage if swallowed. R66; Repeated exposure may cause skin dryness or cracking. R67; Vapours may cause drowsiness and dizziness. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 1
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS TRIPHENYL PHOSPHATE 115-86-6 204-112-2
Concentration * 0.1 - 1%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
Product Name:
Page 2 of 8
SECTION 4
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES
Product Name:
Page 3 of 8
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING This material is not intended for use in air compressors for breathing applications. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
STORAGE Do not store in open or unlabelled containers. Keep away from incompatible materials.
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS
Product Name:
Page 4 of 8
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Pale yellow
Product Name:
Page 5 of 8
Odour: Characteristic Odour Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.849 Flash Point [Method]: >210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 316C (601F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 43.7 cSt (43.7 mm/sec) at 40C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -38C (-37F) SECTION 10 STABILITY AND REACTIVITY
UEL: 7.0
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Product Name:
Page 6 of 8
Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS Contains: Synthetic base oils: Not expected to cause significant health effects under conditions of normal use, based on laboratory studies with the same or similar materials. Not mutagenic or genotoxic. Not sensitising in test animals and humans. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids.
ECOLOGICAL DATA ECOTOXICITY TEST Aquatic - Acute Toxicity Aquatic - Acute Toxicity Aquatic - Acute Toxicity Aquatic - Chronic Toxicity
Organism Type Water Flea Rainbow Trout Green Alga Water Flea
Test Results EL0 103 mg/l: data for similar materials LL0 101 mg/l: data for similar materials ErL50 > 100 mg/l: data for similar materials NOELR 1 mg/l: data for similar materials
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.
Product Name:
Page 7 of 8
REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 06 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: KECI, TSCA Special Cases: Inventory ELINCS Status Restrictions Apply AICS, IECSC, ENCS,
Product Name:
Page 8 of 8
SECTION 16
OTHER INFORMATION
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R50/53; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
No Reportable Hazardous Substance(s) or Complex Substance(s). Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS TRIPHENYL PHOSPHATE 115-86-6 204-112-2
Concentration * 0.1 - 1%
Product Name:
Page 2 of 8
SECTION 4
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
Notification Procedures
Product Name:
Page 3 of 8
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING This material is not intended for use in air compressors for breathing applications. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
STORAGE Do not store in open or unlabelled containers. Keep away from incompatible materials.
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS
Product Name:
Page 4 of 8
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. Personal Protection Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Pale yellow
Product Name:
Page 5 of 8
Odour: Characteristic Odour Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.85 Flash Point [Method]: >210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (601F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 66.8 cSt (66.8 mm/sec) at 40C | 10.4 cSt (10.4 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -36C (-33F) SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Product Name:
Page 6 of 8
Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS Contains: Synthetic base oils: Not expected to cause significant health effects under conditions of normal use, based on laboratory studies with the same or similar materials. Not mutagenic or genotoxic. Not sensitising in test animals and humans. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids.
ECOLOGICAL DATA ECOTOXICITY TEST Aquatic - Acute Toxicity Aquatic - Acute Toxicity Aquatic - Acute Toxicity Aquatic - Chronic Toxicity
Organism Type Water Flea Green Alga Rainbow Trout Water Flea
Test Results EL0 103 mg/l: data for similar materials ErL50 > 100 mg/l: data for similar materials LL0 101 mg/l: data for similar materials NOELR 1 mg/l: data for similar materials
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.
Product Name:
Page 7 of 8
REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 06 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: KECI, PICCS, TSCA Special Cases: Inventory ELINCS Status Restrictions Apply AICS, IECSC, ENCS,
Product Name:
Page 8 of 8
SECTION 16
OTHER INFORMATION
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >204C (399F) [ ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING This material is not intended for use in air compressors for breathing applications. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
Product Name:
Page 4 of 8
respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.9 Flash Point [Method]: >204C (399F) [ ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D
UEL: 7.0
Product Name:
Page 5 of 8
Solubility in Water: Negligible Viscosity: >20 cSt (20 mm/sec) at 40C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Product Name:
Page 6 of 8
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
Product Name:
Page 7 of 8
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains: SUBSTITUTED OXA DITHIA PHOSPHATE TETRADECANOIC ACID May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: KECI, TSCA SECTION 16 OTHER INFORMATION AICS, DSL, EINECS,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
Product Name:
Page 8 of 8
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >199C (390F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING This material is not intended for use in air compressors for breathing applications. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
Product Name:
Page 4 of 8
respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Marketable Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.872 Flash Point [Method]: >199C (390F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D
UEL: 7.0
Product Name:
Page 5 of 8
Solubility in Water: Negligible Viscosity: 43.6 cSt (43.6 mm/sec) at 40C | 6.8 cSt (6.8 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -27C (-17F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Product Name:
Page 6 of 8
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
Product Name:
Page 7 of 8
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains: SUBSTITUTED OXA DITHIA PHOSPHATE TETRADECANOIC ACID May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: KECI, TSCA SECTION 16 OTHER INFORMATION AICS, DSL, EINECS,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
Product Name:
Page 8 of 8
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
Product Name:
Page 2 of 8
SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Hydrogen Sulphide, Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion products, Oxides of carbon FLAMMABILITY PROPERTIES Flash Point [Method]: >210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other
Product Name:
Page 3 of 8
shipping. Remove from the surface by skimming or with suitable absorbents. specialist before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING This material is not intended for use in air compressors for breathing applications. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation.
Product Name:
Page 4 of 8
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: yellow Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.88 Flash Point [Method]: >210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: >90 cSt (90 mm/sec) at 40C | >10 cSt (10 mm/sec) at 100C
Product Name:
Page 5 of 8
Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: < -9C (16F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request.
Product Name:
Page 6 of 8
SECTION 12
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
Product Name:
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SECTION 14
TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains: SUBSTITUTED OXA DITHIA PHOSPHATE TETRADECANOIC ACID May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: TSCA SECTION 16 OTHER INFORMATION AICS, EINECS, KECI,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 04: First Aid Skin - Header was modified. Section 04: First Aid Ingestion - Header was modified. Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 11: Ingestion Acute Lethality - Header was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 09: Vapour Pressure was modified.
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Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 09: Viscosity was modified. Section 08: Environmental Control - Note was modified. Section 15: Sensitiser Statement was modified. Section 11: Inhalation Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 01: Supplier Mailing Address was modified. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 9
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS 1,2-Benzenedicarboxylic acid, ditridecyl ester N-PHENYL-1-NAPHTHYLAMINE 119-06-2 90-30-2 204-294-3 201-983-0
Product Name:
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68411-46-1
270-128-1
1 - 5%
N;R50/53 R52/53
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Aldehydes Smoke, Fume, Oxides of carbon, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >220C (428F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D
UEL: 7.0
Product Name:
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SECTION 6
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Avoid contact with skin. This material is not intended for use in air compressors for breathing applications. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
Product Name:
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No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: Chemical resistant gloves are recommended. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
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Relative Density (at 15.6 C): 0.957 Flash Point [Method]: >220C (428F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Negligible Viscosity: 107.2 cSt (107.2 mm/sec) at 40C | 10.12 cSt (10.12 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -36C (-33F) SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye
Product Name:
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May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS Contains: Synthetic base oils: Not expected to cause significant health effects under conditions of normal use, based on laboratory studies with the same or similar materials. Not mutagenic or genotoxic. Not sensitising in test animals and humans. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. Material -- Not expected to demonstrate chronic toxicity to aquatic organisms
Duration 21 day(s)
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 06 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s).
Product Name:
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This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. The classification of this product is based all or in part on test data. EU LABELING: Not regulated according to EC Directives . .
Contains:
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: ENCS, KECI, PICCS, TSCA Special Cases: Inventory ELINCS SECTION 16 Status Restrictions Apply OTHER INFORMATION AICS, IECSC, DSL,
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R22; Harmful if swallowed.
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R43; May cause sensitisation by skin contact. R50/53; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53; Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 04: First Aid Skin was modified. Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 07: Handling and Storage - Handling was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 15: EU Dangerous/not Dangerous was modified. Section 15: EU Labeling - Header was modified. Section 08: Hand Protection was modified. Section 08: Skin and Body Protection was modified. Section 08: Environmental Control - Note was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 12: Environmental tox table header was added. Section 12: Test - Column Header was added. Section 12: Organism Type - Column Header was added. Section 12: Duration - Column Header was added. Section 12: Test Results - Column Header was added. Section 15: EU Classification (Test data) was added. Hazard Identification: EU - Not Hazardous Statement was added. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Environmental tox table in section 12 was added. Section 12: Environmental component tox table in section 12 was added. Section 12: Environmental component tox table in section 12 was added. Section 12: Environmental component tox table in section 12 was added. Section 12: Ecological data - Header was added. Hazard Identification: Environmental Hazard was deleted. Hazard Identification: Environmental Hazard - Header was deleted. Section 15: EC Classification - Header was deleted. Section 15: EC Classification was deleted. Section 15: NATURE OF SPECIAL RISK was deleted. Section 15: EC Risk Phrases - EU Header was deleted. Section 12: Mobility - Header was deleted. Section 12: Persistence and Degradability- Header was deleted. Section 12: Biodegradation - Header was deleted. Section 12: Bioaccumulation - Header was deleted. Hazard Identification: EU - Hazards Statement was deleted. Composition: Regulated as statement was deleted.
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Hazard Identification: Classification was deleted. Hazard Identification: Classification - Header was deleted. Section 15: EU Safety Advice - EU Header was deleted. Section 15: EU Safety Advice was deleted. Section 12: Ecological Information - Mobility was deleted. Section 12: Ecological Information - Mobility was deleted. Section 12: Ecological Information - Acute Aquatic Toxicity was deleted. Section 12: Ecological Information - Biodegradation was deleted. Section 12: Ecological Information - Acute Aquatic Toxicity was deleted. Section 12: Ecological Information - Biodegradation was deleted. Section 08: Exposure Limits Table was deleted. Section 12: Ecological Information - Bioaccumulation was deleted. Section 12: Ecological Information - Bioaccumulation was deleted. Section 08: Exposure Limit Values - Header was deleted. Section 08: OEL Table - Substance Name Column - Header was deleted. Section 08: OEL Table - Source Column - Header was deleted. Section 08: OEL Table - Year Column - Header was deleted. Section 08: Exposure Limit Values - Header was deleted. Section 08: OEL Table - Form Column - Header was deleted. Section 08: OEL Table - Limit Column - Header was deleted. Section 08: OEL Table - Notation Column - Header was deleted. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is dangerous according to regulatory guidelines (see (M)SDS Section 15). CLASSIFICATION: | R53 |
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage. ENVIRONMENTAL HAZARDS May cause long-term adverse effects in the aquatic environment.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 This material is regulated as a preparation. Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / COMPOSITION / INFORMATION ON INGREDIENTS
Symbols/Risk
Product Name:
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ELINCS N-PHENYL-1-NAPHTHYLAMINE Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene DITRIDECYL ADIPATE TRIMELLITATE ESTER 90-30-2 68411-46-1 16958-92-2 CONFIDENTI AL 201-983-0 270-128-1 241-029-0 253-138-0
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel.
Product Name:
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FLAMMABILITY PROPERTIES Flash Point [Method]: >220C (428F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING This material is not intended for use in air compressors for breathing applications. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
Product Name:
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DITRIDECYL ADIPATE
TWA
5 mg/m3
ExxonMobil
2008
Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13.
Product Name:
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SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.976 Flash Point [Method]: >220C (428F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 158 cSt (158 mm/sec) at 40C | 13.2 cSt (13.2 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -30C (-22F) SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures.
Product Name:
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Based on assessment of the components. INGESTION Toxicity: LD50 > 5000 mg/kg
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Component concentrations in this formulation would not be expected to cause skin sensitization, based on tests of the components or similar formulations. Contains: Phenyl-alpha-naphthylamine (PAN): Undiluted PAN is a skin sensitizer. Human testing with lubricants containing 1.0% PAN caused no reactions indicative of sensitization. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- May cause long-term adverse effects in the aquatic environment. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Components -- Expected to be readily biodegradable. Base oil component -- Expected to be persistent.
ECOLOGICAL DATA Component N-PHENYL-1-NAPHTHYLAMINE SECTION 13 Acute Aquatic Toxicity L(E)C50 >0.1 - 1 mg/L DISPOSAL CONSIDERATIONS
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Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 06 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is dangerous as defined by the EU Dangerous Substances/Preparations Directives. CLASSIFICATION: data. Dangerous for the environment. The classification of this product is based all or in part on test
Product Name:
Page 8 of 8
Safety Advice: S61; Avoid release to the environment. Refer to special instructions/safety data sheets.
Contains:
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, ENCS, KECI, PICCS, TSCA SECTION 16 OTHER INFORMATION AICS, IECSC,
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R22; Harmful if swallowed. R43; May cause sensitisation by skin contact. R50/53; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53; Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R53; May cause long-term adverse effects in the aquatic environment. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS DITRIDECYL ADIPATE 16958-92-2 241-029-0
Concentration * 20 - 30%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
Product Name:
Page 2 of 8
SECTION 4
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Aldehydes Oxides of carbon, Sulphur Oxides, Smoke, Fume, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >204C (399F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES
Product Name:
Page 3 of 8
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
Product Name:
Page 4 of 8
No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
Product Name:
Page 5 of 8
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.854 Flash Point [Method]: >204C (399F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 63.2 cSt (63.2 mm/sec) at 40C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -48C (-54F) SECTION 10 STABILITY AND REACTIVITY
UEL: 7.0
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Product Name:
Page 6 of 8
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS Contains: Synthetic base oils: Not expected to cause significant health effects under conditions of normal use, based on laboratory studies with the same or similar materials. Not mutagenic or genotoxic. Not sensitising in test animals and humans. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 01 11 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be
Product Name:
Page 7 of 8
completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains: CALCIUM SULPHONATE May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, ENCS, KECI, PICCS, TSCA SECTION 16 OTHER INFORMATION AICS, IECSC, DSL,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified.
Product Name:
Page 8 of 8
Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 08: Environmental Control - Note was modified. Section 16: Code to MHCs was modified. Section 15: Sensitiser Statement was modified. Section 08: Exposure Limits Table was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: 210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Product Name:
Page 4 of 8
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: orange Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.857 Flash Point [Method]: 210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 260C (500F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible
UEL: 7.0
Product Name:
Page 5 of 8
Viscosity: 68 cSt (68 mm/sec) at 40C | 10.9 cSt (10.9 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -54C (-65F) SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS Contains: Synthetic base oils: Not expected to cause significant health effects under conditions of normal use, based on laboratory studies with the same or similar materials. Not mutagenic or genotoxic. Not sensitising in test animals and humans. Additional information is available by request.
Product Name:
Page 6 of 8
SECTION 12
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. Material -- Not expected to demonstrate chronic toxicity to aquatic organisms MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids.
ECOLOGICAL DATA ECOTOXICITY TEST Aquatic - Acute Toxicity Aquatic - Chronic Toxicity
Test Results LL50 1003 mg/l: data for similar materials NOELR 1 mg/l: data for similar materials
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 06 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
Product Name:
Page 7 of 8
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: TSCA SECTION 16 OTHER INFORMATION DSL, EINECS, ENCS,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used
Product Name:
Page 8 of 8
for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Product Name:
Page 4 of 8
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: orange Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.866 Flash Point [Method]: >210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible
UEL: 7.0
Product Name:
Page 5 of 8
Viscosity: 220 cSt (220 mm/sec) at 40C | 25.2 cSt (25.2 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -33C (-27F) SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS Contains: Synthetic base oils: Not expected to cause significant health effects under conditions of normal use, based on laboratory studies with the same or similar materials. Not mutagenic or genotoxic. Not sensitising in test animals and humans. Additional information is available by request.
Product Name:
Page 6 of 8
SECTION 12
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. Material -- Not expected to demonstrate chronic toxicity to aquatic organisms MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids.
ECOLOGICAL DATA ECOTOXICITY Test Aquatic - Acute Toxicity Aquatic - Chronic Toxicity
Test Results LL50 1003 mg/l: data for similar materials NOELR 1 mg/l: data for similar materials
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 06 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
Product Name:
Page 7 of 8
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: TSCA Special Cases: Inventory AICS SECTION 16 Status Restrictions Apply OTHER INFORMATION DSL, EINECS, ENCS,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Notification Procedures - Header was modified. Section 12: Ecological data - Header was added. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release - Spill Management - Water was modified.
Product Name:
Page 8 of 8
Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 12: Environmental tox table header was added. Section 12: Test - Column Header was added. Section 12: Organism Type - Column Header was added. Section 12: Duration - Column Header was added. Section 12: Test Results - Column Header was added. Section 09: DMSO IP was deleted. Section 09: DMSO IP - Header was deleted. Section 08: Environmental Control - Note was modified. Section 16: Code to MHCs was modified. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Environmental tox table in section 12 was added. Section 13: Empty Container Warning was modified.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Product Name:
Page 4 of 8
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: orange Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.867 Flash Point [Method]: >210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible
UEL: 7.0
Product Name:
Page 5 of 8
Viscosity: 320 cSt (320 mm/sec) at 40C | 38.6 cSt (38.6 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -30C (-22F) SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS Contains: Synthetic base oils: Not expected to cause significant health effects under conditions of normal use, based on laboratory studies with the same or similar materials. Not mutagenic or genotoxic. Not sensitising in test animals and humans. Additional information is available by request.
Product Name:
Page 6 of 8
SECTION 12
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. Material -- Not expected to demonstrate chronic toxicity to aquatic organisms MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids.
ECOLOGICAL DATA ECOTOXICITY Test Aquatic - Acute Toxicity Aquatic - Chronic Toxicity
Test Results LL50 1003 mg/l: data for similar materials NOELR 1 mg/l: data for similar materials
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 06 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
Product Name:
Page 7 of 8
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: KECI, TSCA Special Cases: Inventory AICS SECTION 16 Status Restrictions Apply OTHER INFORMATION IECSC, DSL, EINECS,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 11: Ingestion Acute Lethality - Header was modified. Section 06: Notification Procedures - Header was modified. Section 12: Ecological data - Header was added. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 05: Hazardous Combustion Products was modified.
Product Name:
Page 8 of 8
Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 12: Environmental tox table header was added. Section 12: Test - Column Header was added. Section 12: Organism Type - Column Header was added. Section 12: Duration - Column Header was added. Section 12: Test Results - Column Header was added. Section 09: DMSO IP was deleted. Section 09: DMSO IP - Header was deleted. Section 08: Environmental Control - Note was modified. Section 15: National Chemical Inventory Listing was modified. Section 16: Code to MHCs was modified. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Environmental tox table in section 12 was added. Section 13: Empty Container Warning was modified.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 9
MOBILARMA 798
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
PHYSICAL / CHEMICAL HAZARDS Thermal burn hazard - contact with hot material may cause thermal burns. HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage. When heated, the vapour/fumes given off may cause respiratory tract irritation.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 4 INHALATION FIRST AID MEASURES
Product Name:
Page 2 of 9
MOBILARMA 798
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If burned by contact with hot material, molten material adhering to skin should be cooled as quickly as possible with water, and see a physician for removal of adhering material and treatment of burn. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water for at least 15 minutes. Get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion products, Wax Fumes, Oxides of carbon, Amine FLAMMABILITY PROPERTIES Flash Point [Method]: >210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
Product Name:
Page 3 of 9
MOBILARMA 798
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. If liquid is too viscous for pumping, shovel it up into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Avoid contact with skin. When heated, the vapour/fumes given off may cause respiratory tract irritation. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS
Product Name:
Page 4 of 9
MOBILARMA 798
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: Adequate ventilation should be provided so that exposure limits are not exceeded. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: Chemical resistant gloves are recommended. If product is hot, thermally protective, chemical resistant gloves are recommended. If contact with forearms is likely, wear gauntlet style gloves. Eye Protection: If contact with material may occur, safety glasses and face shield are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: Chemical/oil resistant clothing is recommended. If product is hot, thermally protective, chemical resistant apron and long sleeves are recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber
Product Name:
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MOBILARMA 798
Odour: Characteristic Odour Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.88 Flash Point [Method]: >210C (410F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: [N/D at 40C] | 23.2 cSt (23.2 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A DMSO Extract (mineral oil only), IP-346: SECTION 10
UEL: 7.0
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: MATERIALS TO AVOID: High energy sources of ignition. Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: No end point data. Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Not determined. Elevated temperatures or mechanical action may form vapours, mist, or fumes which may be irritating to the eyes, nose, throat, or lungs. Based on assessment of the components.
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Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Elevated temperatures or mechanical action may form vapours, mists or fumes which may be irritating to the eyes and respiratory tract. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Hydrocarbon component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Hydrocarbon component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Hydrocarbon component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.
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REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains: PROPRIETARY POLYAMINES May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, TSCA Special Cases: AICS, IECSC,
Product Name:
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MOBILARMA 798
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R34; Causes burns. R43; May cause sensitisation by skin contact. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 08: Hand Protection was modified. Section 04: First Aid Skin was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 07: Handling and Storage - Handling was modified. Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release - Spill Management - Land was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 16: RCode Key - Header was added. Section 08: Eye Protection was modified. Section 08: Skin and Body Protection was modified. Section 08: Environmental Control - Note was modified. Section 16: RCode Key was added. Section 15: National Chemical Inventory Listing was modified. Section 16: Code to MHCs was modified. Section 15: Sensitiser Statement was added. Section 15: Sensitiser Statement - Header was added. Section 15: Special Cases Table was modified. Section 15: Sensitiser Statement was added. Section 11: Chronic Tox - Component was modified. Section 08: Exposure Limits Table was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 06: Notification Procedures - Header was modified.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
Product Name:
Page 9 of 9
MOBILARMA 798
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 1
PPEC:
AH
Product Name:
Page 1 of 9
MOBILGARD 300
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
Product Name:
Page 2 of 9
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SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Smoke, Fume Oxides of carbon, Incomplete combustion products, Sulphur Oxides,
FLAMMABILITY PROPERTIES Flash Point [Method]: >205C (401F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other
Product Name:
Page 3 of 9
MOBILGARD 300
shipping. Remove from the surface by skimming or with suitable absorbents. specialist before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation.
Product Name:
Page 4 of 9
MOBILGARD 300
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: brown Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.888 Flash Point [Method]: >205C (401F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 113 cSt (113 mm/sec) at 40C | 11.8 cSt (11.8 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16.
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OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -9C (16F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Product Name:
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The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
Product Name:
Page 7 of 9
MOBILGARD 300
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains:
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: ENCS, KECI, PICCS, TSCA Special Cases: Inventory AICS SECTION 16 Status Restrictions Apply OTHER INFORMATION IECSC, DSL, EINECS,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified.
Product Name:
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MOBILGARD 300
Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 08: Environmental Control - Note was modified. Section 15: National Chemical Inventory Listing was modified. Section 16: Code to MHCs was modified. Composition: No components was modified. Section 15: Sensitiser Statement was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 12: Bioaccumulation - Header was added. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added. Section 12: Ecological Information - Bioaccumulation was added. Section 12: Ecological Information - Bioaccumulation was added. Composition: CAS Number was deleted. Composition: Concentration - Header was deleted. Composition: Component Table was deleted. Composition: EINECS/ELINCS was deleted. Composition: Symbol/Risk Phrase Header was deleted. Section 16: RCode Key - Header was deleted. Composition: Concentration Footnote was deleted. Composition: Substance or Complex Substance Name was deleted. Section 16: RCode Key was deleted. Composition: Substances Table - Header was deleted. Section 15: Sensitiser Statement was deleted. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 DGN: 2008512XGB (545102)
PPEC:
Product Name:
Page 9 of 9
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-----------------------------------------------------------------------------------------------------------------------------------------------------
Product Name:
Page 1 of 8
MOBILGARD 312
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS CALCIUM LONG CHAIN ALKARYL SULFONATE (OVERBASED) POLYMER
Concentration * 1 - 5%
Product Name:
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MOBILGARD 312
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Fume, Oxides of carbon Sulphur Oxides, Aldehydes, Incomplete combustion products, Smoke,
FLAMMABILITY PROPERTIES Flash Point [Method]: >225C (437F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
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MOBILGARD 312
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications,
Product Name:
Page 4 of 8
MOBILGARD 312
handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Form: clear Colour: brown Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.895 Flash Point [Method]: >225C (437F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9
UEL: 7.0
Product Name:
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Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 108 cSt (108 mm/sec) at 40C | 12 cSt (12 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -6C (21F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
Product Name:
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MOBILGARD 312
CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when
Product Name:
Page 7 of 8
MOBILGARD 312
generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains: CALCIUM SULPHONATE May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: SECTION 16 OTHER INFORMATION EINECS, TSCA
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R53; May cause long-term adverse effects in the aquatic environment. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Notification Procedures - Header was modified.
Product Name:
Page 8 of 8
MOBILGARD 312
Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 08: Environmental Control - Note was modified. Section 15: Sensitiser Statement was modified. Section 01: Company Contact Methods Sorted by Priority was modified. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
MOBILGARD M330
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS CALCIUM PHENATE CARBOXYLATE CONFIDEN TIAL
Concentration * 1 - 5%
Product Name:
Page 2 of 8
MOBILGARD M330
5 - 10% CONFIDENTI AL
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: 230C (446F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D
UEL: 7.0
Product Name:
Page 3 of 8
MOBILGARD M330
SECTION 6
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation.
Product Name:
Page 4 of 8
MOBILGARD M330
PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: brown Odour: Characteristic Odour Threshold: N/D
Product Name:
Page 5 of 8
MOBILGARD M330
Relative Density (at 15 C): 0.9 Flash Point [Method]: 230C (446F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 98 cSt (98 mm/sec) at 40C | 11.6 cSt (11.6 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -6C (21F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Product Name:
Page 6 of 8
MOBILGARD M330
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Component concentrations in this formulation would not be expected to cause skin sensitization, based on tests of the components or similar formulations. Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION
Product Name:
Page 7 of 8
MOBILGARD M330
European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains: CALCIUM SALICYLATE/PHENATE COMPLEX, ALKYL HYDROXYBENZOATE May produce an allergic reaction. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: Special Cases: Inventory ELINCS Status Restrictions Apply IECSC, ENCS, TSCA
Product Name:
Page 8 of 8
MOBILGARD M330
SECTION 16
OTHER INFORMATION
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R38; Irritating to skin. R43; May cause sensitisation by skin contact. R53; May cause long-term adverse effects in the aquatic environment. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 07: Handling and Storage - Storage was modified. Section 05: Hazardous Combustion Products was modified. Section 15: Sensitiser Statement was modified.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
MOBILGARD M430
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS CALCIUM PHENATE CARBOXYLATE CONFIDEN TIAL
Concentration * 1 - 5%
Product Name:
Page 2 of 8
MOBILGARD M430
5 - 10% CONFIDENTI AL
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: 230C (446F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D
UEL: 7.0
Product Name:
Page 3 of 8
MOBILGARD M430
SECTION 6
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation.
Product Name:
Page 4 of 8
MOBILGARD M430
PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: brown Odour: Characteristic Odour Threshold: N/D
Product Name:
Page 5 of 8
MOBILGARD M430
Relative Density (at 15 C): 0.9 Flash Point [Method]: 230C (446F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 128 cSt (128 mm/sec) at 40C | 14 cSt (14 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -6C (21F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Product Name:
Page 6 of 8
MOBILGARD M430
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Component concentrations in this formulation would not be expected to cause skin sensitization, based on tests of the components or similar formulations. Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION
Product Name:
Page 7 of 8
MOBILGARD M430
European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains: CALCIUM SALICYLATE/PHENATE COMPLEX, ALKYL HYDROXYBENZOATE May produce an allergic reaction. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: Special Cases: Inventory ELINCS Status Restrictions Apply IECSC, ENCS, TSCA
Product Name:
Page 8 of 8
MOBILGARD M430
SECTION 16
OTHER INFORMATION
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R38; Irritating to skin. R43; May cause sensitisation by skin contact. R53; May cause long-term adverse effects in the aquatic environment. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 07: Handling and Storage - Storage was modified. Section 05: Hazardous Combustion Products was modified. Section 15: National Chemical Inventory Listing was modified. Section 15: Sensitiser Statement was modified.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
MOBILGARD M440
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS CALCIUM PHENATE CARBOXYLATE CONFIDEN TIAL
Concentration * 1 - 5%
Product Name:
Page 2 of 8
MOBILGARD M440
5 - 10% CONFIDENTI AL
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >230C (446F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D
UEL: 7.0
Product Name:
Page 3 of 8
MOBILGARD M440
SECTION 6
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation.
Product Name:
Page 4 of 8
MOBILGARD M440
PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: brown Odour: Characteristic Odour Threshold: N/D
Product Name:
Page 5 of 8
MOBILGARD M440
Relative Density (at 15 C): 0.907 Flash Point [Method]: >230C (446F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 126 cSt (126 mm/sec) at 40C | 14 cSt (14 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -6C (21F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Product Name:
Page 6 of 8
MOBILGARD M440
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Component concentrations in this formulation would not be expected to cause skin sensitization, based on tests of the components or similar formulations. Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION
Product Name:
Page 7 of 8
MOBILGARD M440
European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains: CALCIUM SALICYLATE/PHENATE COMPLEX, ALKYL HYDROXYBENZOATE May produce an allergic reaction. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: Special Cases: Inventory AICS Status Restrictions Apply IECSC, ENCS, TSCA
Product Name:
Page 8 of 8
MOBILGARD M440
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R38; Irritating to skin. R43; May cause sensitisation by skin contact. R53; May cause long-term adverse effects in the aquatic environment. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 07: Handling and Storage - Storage was modified. Section 05: Hazardous Combustion Products was modified. Section 15: National Chemical Inventory Listing was modified. Section 15: Sensitiser Statement was modified. Section 15: Special Cases Table was modified.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 9
MOBILGARD 570
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS BRANCHED ALKYLPHENOL AND CALCIUM BRANCHED ALKYLPHENOL (74499-35-7 & 132752-19-3)
Product Name:
Page 2 of 9
MOBILGARD 570
CALCIUM LONG CHAIN ALKARYL SULFONATE (OVERBASED) CALCIUM LONG CHAIN ALKYL PHENATE SULPHIDE
POLYMER 291-829-9
1 - 5% 5 - 10%
R53 R53
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: combustion products Smoke, Fume, Oxides of carbon, Sulphur Oxides, Aldehydes, Incomplete
FLAMMABILITY PROPERTIES Flash Point [Method]: >225C (437F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9
UEL: 7.0
Product Name:
Page 3 of 9
MOBILGARD 570
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
Product Name:
Page 4 of 9
MOBILGARD 570
No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: brown Odour: Characteristic Odour Threshold: N/D
Product Name:
Page 5 of 9
MOBILGARD 570
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.936 Flash Point [Method]: >225C (437F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 229 cSt (229 mm/sec) at 40C | 20.5 cSt (20.5 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -3C (27F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Product Name:
Page 6 of 9
MOBILGARD 570
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Sensitisation: No adverse effects were observed. The study was conducted on structurally similar material. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Branched alkylphenol and its calcium salt: Effects on liver, adrenals, and reproductive organs were seen in rats with repeated oral doses. Decreased fertility index, decreased number of live pups, and other effects were seen in reproductive studies in rats dosed orally. Time to sexual maturation and weights of the uterus and ovaries were decreased in young female rats dosed orally. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
ECOLOGICAL DATA Component BRANCHED BRANCHED 132752-19-3) Acute Aquatic Toxicity AND CALCIUM L(E)C50 >0.1 - 1 mg/L (74499-35-7 &
ALKYLPHENOL ALKYLPHENOL
Note: Tetrapropenyl phenol when tested in oil (1000mg/l) was not acutely toxic to aquatic organisms; based on supplier assessment.
Product Name:
Page 7 of 9
MOBILGARD 570
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Product Name:
Page 8 of 9
MOBILGARD 570
Complies with the following national/regional chemical inventory requirements: SECTION 16 OTHER INFORMATION
EINECS, TSCA
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R38; Irritating to skin. R50/53; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R53; May cause long-term adverse effects in the aquatic environment. R62; Possible risk of impaired fertility. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 08: Environmental Control - Note was modified. Section 11: Other Health Effects was modified. Section 11: Chronic Tox - Component was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 12: Section 12 Footnote was added. Section 12: Environmental component tox table in section 12 was added. Section 12: Environmental component tox table in section 12 was added. Section 12: Environmental component tox table in section 12 was added. Section 12: Ecological data - Header was added. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 9 of 9
MOBILGARD 570
Product Name:
Page 1 of 8
MOBILGARD L540
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS CALCIUM LONG CHAIN ALKARYL SULFONATE (OVERBASED) CALCIUM LONG CHAIN ALKYL POLYMER 291-829-9
Concentration * 1 - 5% 5 - 10%
Product Name:
Page 2 of 8
MOBILGARD L540
PHENATE SULPHIDE * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: 225C (437F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/A SECTION 6
UEL: 7.0
Product Name:
Page 3 of 8
MOBILGARD L540
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION
Product Name:
Page 4 of 8
MOBILGARD L540
Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: brown Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.92 Flash Point [Method]: 225C (437F) [ ASTM D-92]
Product Name:
Page 5 of 8
MOBILGARD L540
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/A Boiling Point / Range: > 288C (550F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 227 cSt (227 mm/sec) at 40C | 20.5 cSt (20.5 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -3C (27F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test
Product Name:
Page 6 of 8
MOBILGARD L540
CHRONIC/OTHER EFFECTS For the product itself: Sensitisation: No adverse effects were observed. The study was conducted on structurally similar material. Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05
Product Name:
Page 7 of 8
MOBILGARD L540
NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: KECI, TSCA Special Cases: Inventory PICCS SECTION 16 Status Premarketing Notification File OTHER INFORMATION IECSC, EINECS,
Product Name:
Page 8 of 8
MOBILGARD L540
KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R53; May cause long-term adverse effects in the aquatic environment. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 08: Environmental Control - Note was modified. Section 01: Company Contact Methods Sorted by Priority was modified. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS CALCIUM LONG CHAIN ALKYL PHENATE SULPHIDE ZINC DITHIOPHOSPHATE
68649-42-3
Product Name:
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N;R51/53 * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >215C (419F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7
Product Name:
Page 3 of 8
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION
Product Name:
Page 4 of 8
Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.88 Flash Point [Method]: >215C (419F) [ ASTM D-92]
Product Name:
Page 5 of 8
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7 Autoignition Temperature: N/D Boiling Point / Range: N/D Vapour Density (Air = 1): N/D Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C [Estimated] Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 104 cSt (104 mm/sec) at 40C | 14.3 cSt (14.3 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -27C (-17F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test
Product Name:
Page 6 of 8
CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION
Product Name:
Page 7 of 8
European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, ENCS, KECI, PICCS, TSCA SECTION 16 OTHER INFORMATION AICS, IECSC, DSL,
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R38; Irritating to skin. R41; Risk of serious damage to eyes.
Product Name:
Page 8 of 8
R51/53; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R53; May cause long-term adverse effects in the aquatic environment. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 04: First Aid Skin was modified. Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Hazard Identification: Health Hazards was modified. Section 05: Hazardous Combustion Products was modified. Composition: Component Table was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 09: Viscosity was modified. Section 08: Environmental Control - Note was modified. Section 16: RCode Key was modified. Section 16: Code to MHCs was modified. Section 09: Relative Density was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: combustion products Aldehydes, Oxides of carbon, Smoke, Fume, Sulphur Oxides, Incomplete
FLAMMABILITY PROPERTIES Flash Point [Method]: >200C (392F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Product Name:
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No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: brown Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.884 Flash Point [Method]: >200C (392F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Negligible Viscosity: 100 cSt (100 mm/sec) at 40C | 11.2 cSt (11.2 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16.
Product Name:
Page 5 of 8
OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -12C (10F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory tract. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Product Name:
Page 6 of 8
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
Product Name:
Page 7 of 8
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
Contains: Alkyl Amine May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: Special Cases: Inventory NDSL SECTION 16 Status Restrictions Apply OTHER INFORMATION AICS, EINECS, TSCA
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 05: Hazardous Combustion Products was modified. Section 15: National Chemical Inventory Listing was modified. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added.
Product Name:
Page 8 of 8
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Sulphur Oxides Smoke, Fume, Oxides of carbon, Incomplete combustion products,
FLAMMABILITY PROPERTIES Flash Point [Method]: >200C (392F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Product Name:
Page 4 of 8
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.888 Flash Point [Method]: >200C (392F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 150 cSt (150 mm/sec) at 40C | 14.7 cSt (14.7 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16.
Product Name:
Page 5 of 8
OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -9C (16F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory tract. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Product Name:
Page 6 of 8
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
Product Name:
Page 7 of 8
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
Contains: Alkyl Amine May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: AICS, EINECS, KECI Special Cases: Inventory NDSL SECTION 16 Status Restrictions Apply OTHER INFORMATION IECSC, TSCA, PICCS,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 15: National Chemical Inventory Listing was modified. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added.
Product Name:
Page 8 of 8
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Sulphur Oxides Smoke, Fume, Oxides of carbon, Incomplete combustion products,
FLAMMABILITY PROPERTIES Flash Point [Method]: >200C (392F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Product Name:
Page 4 of 8
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.894 Flash Point [Method]: >200C (392F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 220 cSt (220 mm/sec) at 40C | 19 cSt (19 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16.
Product Name:
Page 5 of 8
OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -9C (16F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory tract. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Product Name:
Page 6 of 8
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
Product Name:
Page 7 of 8
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
Contains: Alkyl Amine May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: TSCA, EINECS Special Cases: Inventory NDSL SECTION 16 Status Restrictions Apply OTHER INFORMATION AICS, PICCS, KECI,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 15: National Chemical Inventory Listing was modified. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added.
Product Name:
Page 8 of 8
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Sulphur Oxides Smoke, Fume, Oxides of carbon, Incomplete combustion products,
FLAMMABILITY PROPERTIES Flash Point [Method]: >200C (392F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Product Name:
Page 4 of 8
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.9 Flash Point [Method]: >200C (392F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 320 cSt (320 mm/sec) at 40C | 24.1 cSt (24.1 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16.
Product Name:
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OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -9C (16F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory tract. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Product Name:
Page 6 of 8
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
Product Name:
Page 7 of 8
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
Contains: Alkyl Amine May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: KECI, EINECS, IECSC Special Cases: Inventory NDSL SECTION 16 Status Restrictions Apply OTHER INFORMATION TSCA, AICS, PICCS,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 15: National Chemical Inventory Listing was modified. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added.
Product Name:
Page 8 of 8
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Sulphur Oxides Smoke, Fume, Oxides of carbon, Incomplete combustion products,
FLAMMABILITY PROPERTIES Flash Point [Method]: >200C (392F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Product Name:
Page 4 of 8
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.904 Flash Point [Method]: >200C (392F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 460 cSt (460 mm/sec) at 40C | 30.6 cSt (30.6 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16.
Product Name:
Page 5 of 8
OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -9C (16F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory tract. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Product Name:
Page 6 of 8
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
Product Name:
Page 7 of 8
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
Contains: Alkyl Amine May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: PICCS, TSCA Special Cases: Inventory NDSL SECTION 16 Status Restrictions Apply OTHER INFORMATION AICS, EINECS, KECI,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
Product Name:
Page 8 of 8
available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
MOBILGEAR 600 XP 68
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
MOBILGEAR 600 XP 68
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: carbon, Sulphur Oxides Aldehydes, Incomplete combustion products, Smoke, Fume, Oxides of
FLAMMABILITY PROPERTIES Flash Point [Method]: >185C (365F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
MOBILGEAR 600 XP 68
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Product Name:
Page 4 of 8
MOBILGEAR 600 XP 68
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.88 Flash Point [Method]: >185C (365F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Negligible Viscosity: 68 cSt (68 mm/sec) at 40C | 8.8 cSt (8.8 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16.
Product Name:
Page 5 of 8
MOBILGEAR 600 XP 68
OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -15C (5F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory tract. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Product Name:
Page 6 of 8
MOBILGEAR 600 XP 68
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
Product Name:
Page 7 of 8
MOBILGEAR 600 XP 68
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
Contains: Alkyl Amine May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: IECSC, AICS, PICCS, TSCA Special Cases: Inventory NDSL SECTION 16 Status Restrictions Apply OTHER INFORMATION EINECS, KECI,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 15: National Chemical Inventory Listing was modified.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
Product Name:
Page 8 of 8
MOBILGEAR 600 XP 68
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Sulphur Oxides Smoke, Fume, Oxides of carbon, Incomplete combustion products,
FLAMMABILITY PROPERTIES Flash Point [Method]: >200C (392F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Product Name:
Page 4 of 8
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.914 Flash Point [Method]: >200C (392F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 680 cSt (680 mm/sec) at 40C | 36.4 cSt (36.4 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16.
Product Name:
Page 5 of 8
OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -3C (27F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory tract. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Product Name:
Page 6 of 8
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
Product Name:
Page 7 of 8
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
Contains: Alkyl Amine May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: TSCA, EINECS, KECI Special Cases: Inventory NDSL SECTION 16 Status Restrictions Apply OTHER INFORMATION AICS, PICCS, IECSC,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 15: National Chemical Inventory Listing was modified.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
Product Name:
Page 8 of 8
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
MOBILGEAR 626
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name:
Page 2 of 8
MOBILGEAR 626
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >185C (365F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Product Name:
Page 3 of 8
MOBILGEAR 626
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
STORAGE Do not store in open or unlabelled containers. Keep away from incompatible materials.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Product Name:
Page 4 of 8
MOBILGEAR 626
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.86 Flash Point [Method]: >185C (365F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Negligible
UEL: 7.0
Product Name:
Page 5 of 8
MOBILGEAR 626
Viscosity: 68 cSt (68 mm/sec) at 40C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -15C (5F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory tract. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test
Product Name:
Page 6 of 8
MOBILGEAR 626
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
Product Name:
Page 7 of 8
MOBILGEAR 626
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains: Alkyl Amine May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: KECI, PICCS, TSCA SECTION 16 OTHER INFORMATION AICS, DSL, EINECS,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
Product Name:
Page 8 of 8
MOBILGEAR 626
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
--------------------------------------------------------------------------
610865-60 MOBILGEAR 629 MATERIAL SAFETY DATA BULLETIN --------------------------------------------------------------------------------------------------------------------------------------------------1. PRODUCT AND COMPANY IDENTIFICATION -------------------------------------------------------------------------PRODUCT NAME: MOBILGEAR 629 22/08/2001 SUPPLIER: EXXONMOBIL MARINE LIMITED EXXONMOBIL HOUSE MAILPOINT 29, ERMYN WAY LEATHERHEAD, KT22 8UX UNITED KINGDOM
24 Hour Health Emergency: +44 1372 222 000 Product and Technical Information: EAME +420 221 456 618 AMERICAS +1 800 662 4525 / ASIA PACIFIC +8621 5464 4588 EXT 5842
INTENDED USE: Industrial gear oil -------------------------------------------------------------------------2. COMPOSITION/INFORMATION ON INGREDIENTS -------------------------------------------------------------------------CHEMICAL NAMES AND SYNONYMS: PET. HYDROCARBONS AND ADDITIVES GLOBALLY REPORTABLE MSDS INGREDIENTS: None.
-------------------------------------------------------------------------3. HAZARDS IDENTIFICATION -------------------------------------------------------------------------Under normal conditions of use, this product is not considered hazardous according to EU regulatory guidelines (see Section 15).
POTENTIAL HEALTH EFFECTS: Under normal conditions of intended use, this product does not pose a risk to health. Excessive exposure may result in eye, skin or respiratory irritation. For further health effects/toxicological data, see Section 11.
NOTE: This product should not be used for any other purpose without expert advice. -------------------------------------------------------------------------4. FIRST AID MEASURES -------------------------------------------------------------------------EYE CONTACT: Flush thoroughly with water. If irritation occurs, call a doctor. SKIN CONTACT: Wash contact areas with soap and water. Remove and clean oil soaked clothing daily and wash affected area. (See Section 16 - Injection Injury) INHALATION: Not expected to be a problem. However, if respiratory irritation, dizziness, nausea, or unconsciousness occurs due to excessive vapor or mist exposure, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or mouth-to-mouth resuscitation. INGESTION: Not expected to be a problem. Seek medical attention if discomfort occurs. Do not induce vomiting. -------------------------------------------------------------------------5. FIRE-FIGHTING MEASURES -------------------------------------------------------------------------EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog. SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: None. COMBUSTION PRODUCTS: Fumes, smoke, carbon monoxide, sulfur oxides, aldehydes and other decomposition products, in the case of incomplete combustion. Flash Point C(F): > 204(399) (IP 34 / ASTM D-93). Flammable Limits (approx.% vol.in air) LEL 0.9%, UEL: 7.0% NFPA HAZARD ID: Health: 0 , Flammability: 1 , Reactivity: 0 -------------------------------------------------------------------------6. ACCIDENTAL RELEASE MEASURES -------------------------------------------------------------------------NOTIFICATION PROCEDURES: Report spills/releases as required to appropriate authorities. In case of accident or road spill, contact the Police and Fire Brigade and, if appropriate, the Area Water Authority. PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: LAND SPILL: Shut off source taking normal safety precautions. Take measures to minimize the effects on ground water. Recover by pumping or contain spilled material with sand or other suitable absorbent and remove mechanically into containers. If necessary, dispose of adsorbed residues as directed in Section 13. WATER SPILL: Confine the spill immediately with booms. Warn other ships in the vicinity. Notify port and other relevant authorities. Remove from the surface by skimming or with suitable absorbents. If permitted by regulatory authorities the use of suitable dispersants should be considered where
recommended in local oil spill procedures. ENVIRONMENTAL PRECAUTIONS: Prevent material from entering sewers, water sources or low lying areas; advise the relevant authorities if it has, or if it contaminates soil/vegetation. PERSONAL PRECAUTIONS: See Section 8 -------------------------------------------------------------------------7. HANDLING AND STORAGE -------------------------------------------------------------------------SPECIFIC USES: Industrial gear oil HANDLING: No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. STORAGE: Keep containers closed when not in use. Do not store in open or unlabelled containers. Store away from strong oxidizing agents and combustible materials. Do not store near heat, sparks, flame or strong oxidants. SPECIAL PRECAUTIONS: Prevent small spills and leakages to avoid slip hazard. EMPTY CONTAINER WARNING: Empty containers retain residue (liquid and/ or vapour) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD BRAZE, SOLDER,DRILL,GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. -------------------------------------------------------------------------8. EXPOSURE CONTROLS/PERSONAL PROTECTION -------------------------------------------------------------------------OCCUPATIONAL EXPOSURE LIMITS: When mists/aerosols can occur, the following are recommended: 5 mg/m3 (as oil mist)- ACGIH Threshold Limit Value (TLV), 10 mg/m3 (as oil mist) - ACGIH Short Term Exposure Limit (STEL) VENTILATION: If mists are generated, use adequate ventilation, local exhaust or enclosures to control below exposure limits. RESPIRATORY PROTECTION: If mists are generated, and/or when ventilation is not adequate, wear approved respirator. EYE PROTECTION: If eye contact is likely, safety glasses with side shields or chemical type goggles should be worn. SKIN PROTECTION: Not normally required. When splashing or liquid contact can occur frequently, wear oil resistant gloves and/or other protective clothing. Good personal hygiene practices should always be followed. ENVIRONMENTAL CONTROLS: SEE SECTION 7 -------------------------------------------------------------------------9. PHYSICAL AND CHEMICAL PROPERTIES --------------------------------------------------------------------------
Typical physical properties are given below. Sheet for specific details. GENERAL: PHYSICAL STATE: Liquid COLOUR: Dark Amber ODOUR: Mild ODOUR THRESHOLD-ppm: NE
IMPORTANT HEALTH, SAFETY AND ENVIRONMENTAL INFORMATION: pH: NA BOILING POINT C(F): > 316(600) FLASH POINT C(F): > 204(399) (IP 34 / ASTM D-93) FLAMMABILITY (solids): NE AUTO FLAMMABILITY C(F): NA EXPLOSIVE PROPERTIES: NA OXIDIZING PROPERTIES: NA VAPOUR PRESSURE-mmHg 20 C: < 0.1 RELATIVE DENSITY, 15/4 C: 0.86-1 SOLUBILITY IN WATER: Negligible PARTITION COEFFICIENT: > 3.5 VISCOSITY AT 40 C, cSt: 150.0 VISCOSITY AT 100 C, cSt: 15.8 VAPOUR DENSITY: > 2.0 EVAPORATION RATE: NE OTHER INFORMATION: MELTING POINT C(F): NA POUR POINT C(F): -27(-17) FREEZING POINT C(F): NE DMSO EXTRACT, IP-346 (WT.%): <3, for mineral oil only NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE -------------------------------------------------------------------------10. STABILITY AND REACTIVITY -------------------------------------------------------------------------STABILITY (THERMAL, LIGHT, ETC.): Stable. CONDITIONS TO AVOID: Extreme heat and high energy sources of ignition. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidisers. HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at ambient temperatures. HAZARDOUS POLYMERISATION: Will not occur. -------------------------------------------------------------------------11. TOXICOLOGICAL DATA ----------------------------------------------------------------------------ACUTE TOXICOLOGY--ORAL TOXICITY: Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. DERMAL TOXICITY: Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. INHALATION TOXICITY: Practically non-toxic (LC50: greater than 5
mg/l). ---Based on testing of similar products and/or the components. EYE IRRITATION: Practically non-irritating. (Draize score: greater than 6 but 15 or less). ---Based on testing of similar products and/or the components. SKIN IRRITATION: Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). ---Based on testing of similar products and/or the components. OTHER ACUTE TOXICITY DATA: Although an acute inhalation study was not performed with this product, a variety of mineral and synthetic oils, such as those in this product, have been tested. These samples had virtually no effect other than a nonspecific inflammatory response in the lung to the aerosolized mineral oil. The presence of additives in other tested formulations (in approximately the same amounts as in the present formulation) did not alter the observed effects. ---SUBCHRONIC TOXICOLOGY (SUMMARY)--No significant adverse effects were found in studies using repeated dermal applications of similar formulations to the skin of laboratory animals for 13 weeks at doses significantly higher than those expected during normal industrial exposure. The animals were evaluated extensively for effects of exposure (hematology, serum chemistry, urinalysis, organ weights, microscopic examination of tissues etc.). ---REPRODUCTIVE TOXICOLOGY (SUMMARY)--No teratogenic effects would be expected from dermal exposure, based on laboratory developmental toxicity studies of major components in this formulation and/or materials of similar composition. ---CHRONIC TOXICOLOGY (SUMMARY)--Repeated and/or prolonged exposure may cause irritation to the skin, eyes or respiratory tract. Overexposure to oil mist may result in oil droplet deposition and/or granuloma formation. For mineral base oils: Base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic mouse skin painting studies of severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a continuing basis using various screening methods such as Modified Ames Test, IP-346, and/or other analytical methods. Synthetic base oils representative of those in this producthave been tested in the Ames assay and other tests of mutagenicity with negative results. These base oils are not expected to be carcinogenic with chronic dermal exposures. ---SENSITIZATION (SUMMARY)--Not expected to be sensitizing based on tests of this product, components, or similar products. -------------------------------------------------------------------------12. ECOLOGICAL INFORMATION -------------------------------------------------------------------------ENVIRONMENTAL FATE AND EFFECTS: In the absence of specific environmental data for this product, this
assessment is based on information for representative products. ECOTOXICITY: Available ectoxicity data (LL50 >1000 mg/L) indicates that adverse effects to aquatic organisms are not expected from this product. MOBILITY: When released into the environment, adsorption to sediment and soil will be the predominant behavior. PERSISTENCE AND DEGRADABILITY: This product is expected to be inherently biodegradable. BIOACCUMULATIVE POTENTIAL: Bioaccumulation is unlikely due to the very low water solubility of this product, therefore bioavailability to aquatic organisms is minimal.
-------------------------------------------------------------------------13. DISPOSAL CONSIDERATIONS -------------------------------------------------------------------------WASTE DISPOSAL: Product is suitable for burning in an enclosed, controlled burner for fuel value. Such burning may be limited pursuant to the Resource Conservation and Recovery Act. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. EUROPEAN WASTE CODE: 13 02 05 (mineral-based non-chlorinated engine, gear and lubricating oils) Waste generated from the intended use of this product is assigned the above waste disposal code. However, deviation from the intended use and/or the presence of any potential contaminants may require an alternative waste disposal code to be assigned by the end user. This waste is considered as a hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of the Directive applies. -------------------------------------------------------------------------14. TRANSPORT INFORMATION -------------------------------------------------------------------------USA DOT: NOT REGULATED BY USA DOT. RID/ADR: IMO: IATA: NOT REGULATED BY RID/ADR.
-------------------------------------------------------------------------15. REGULATORY INFORMATION -------------------------------------------------------------------------EU Labelling: Product is not dangerous as defined by the European
Union Dangerous Substances/Preparations Directives. EU labeling not required. THE FOLLOWING PRODUCT INGREDIENTS ARE CITED ON THE LISTS BELOW: CHEMICAL NAME CAS NUMBER *** NO REPORTABLE INGREDIENTS *** --- REGULATORY ALLERGI 11=DE ALLERGY 12=DE CARC 13=DE CARC 14=DE TERAT A 15=DE LISTS SEARCHED TERAT B 16=DE TERAT C 17=AT TERAT D 18=AT CARC A1 19=AT CARC A2 20=AT LIST CITATIONS
21=CH CARC
CARC=CARCINOGEN;
AT = Austria CH = Switzerland
NOTE: EXXONMOBIL PRODUCTS ARE NOT FORMULATED TO CONTAIN PCBS. Health studies have shown that many hydrocarbons pose potential human health risks which may vary from person to person. Information provided on this MSDS reflects intended use. This product should not be used for other applications. In any case, the following advice should be considered: INJECTION INJURY WARNING: If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. INDUSTRIAL LABEL Under normal conditions of intended use, this product does not pose a risk to health. Excessive exposure may result in eye, skin or respiratory irritation. Always observe good hygiene measures. First Aid: Wash skin with soap and water. Flush eyes with water. If overcome by fumes or vapor, remove to fresh air. If ingested, do not induce vomiting. If symptoms persist seek medical assistance. Read and understand the MSDS before using this product.
COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Any sections of this Material Safety Data Sheet which are printed in bold text highlights recent significant changes which have been made
to the advice or information given. ********************************************************************** For Internal Use Only: MHC: 1* 1* 1* 1* 1*, MPPEC: A, TRN: 610865-60, ELIS: 400311, CMCS97: 970874 EHS Approval Date: 22AUG2001 **********************************************************************
Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. Exxon Mobil Corporation and its affiliated companies assume no responsibility for accuracy of information unless the document is the most current available from an official ExxonMobil distribution system. Exxon Mobil Corporation and its affiliated companies neither represent nor warrant that the format, content or product formulas contained in this document comply with the laws of any other country except the United States of America.
--------------------------------------------------------------------------
610873-60 MOBILGEAR 630 MATERIAL SAFETY DATA BULLETIN --------------------------------------------------------------------------------------------------------------------------------------------------1. PRODUCT AND COMPANY IDENTIFICATION -------------------------------------------------------------------------PRODUCT NAME: MOBILGEAR 630 22/08/2001 SUPPLIER: EXXONMOBIL MARINE LIMITED EXXONMOBIL HOUSE MAILPOINT 29, ERMYN WAY LEATHERHEAD, KT22 8UX UNITED KINGDOM
24 Hour Health Emergency: +44 1372 222 000 Product and Technical Information: EAME +420 221 456 618 AMERICAS +1 800 662 4525 / ASIA PACIFIC +8621 5464 4588 EXT 5842
INTENDED USE: Industrial gear oil -------------------------------------------------------------------------2. COMPOSITION/INFORMATION ON INGREDIENTS -------------------------------------------------------------------------CHEMICAL NAMES AND SYNONYMS: PET. HYDROCARBONS AND ADDITIVES GLOBALLY REPORTABLE MSDS INGREDIENTS: None.
-------------------------------------------------------------------------3. HAZARDS IDENTIFICATION -------------------------------------------------------------------------Under normal conditions of use, this product is not considered hazardous according to EU regulatory guidelines (see Section 15).
POTENTIAL HEALTH EFFECTS: Under normal conditions of intended use, this product does not pose a risk to health. Excessive exposure may result in eye, skin or respiratory irritation. For further health effects/toxicological data, see Section 11.
NOTE: This product should not be used for any other purpose without expert advice. -------------------------------------------------------------------------4. FIRST AID MEASURES -------------------------------------------------------------------------EYE CONTACT: Flush thoroughly with water. If irritation occurs, call a doctor. SKIN CONTACT: Wash contact areas with soap and water. Remove and clean oil soaked clothing daily and wash affected area. (See Section 16 - Injection Injury) INHALATION: Not expected to be a problem. However, if respiratory irritation, dizziness, nausea, or unconsciousness occurs due to excessive vapor or mist exposure, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or mouth-to-mouth resuscitation. INGESTION: Not expected to be a problem. Seek medical attention if discomfort occurs. Do not induce vomiting. -------------------------------------------------------------------------5. FIRE-FIGHTING MEASURES -------------------------------------------------------------------------EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog. SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: None. COMBUSTION PRODUCTS: Fumes, smoke, carbon monoxide, sulfur oxides, aldehydes and other decomposition products, in the case of incomplete combustion. Flash Point C(F): > 204(399) (IP 34 / ASTM D-93). Flammable Limits (approx.% vol.in air) LEL 0.9%, UEL: 7.0% NFPA HAZARD ID: Health: 0 , Flammability: 1 , Reactivity: 0 -------------------------------------------------------------------------6. ACCIDENTAL RELEASE MEASURES -------------------------------------------------------------------------NOTIFICATION PROCEDURES: Report spills/releases as required to appropriate authorities. In case of accident or road spill, contact the Police and Fire Brigade and, if appropriate, the Area Water Authority. PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: LAND SPILL: Shut off source taking normal safety precautions. Take measures to minimize the effects on ground water. Recover by pumping or contain spilled material with sand or other suitable absorbent and remove mechanically into containers. If necessary, dispose of adsorbed residues as directed in Section 13. WATER SPILL: Confine the spill immediately with booms. Warn other ships in the vicinity. Notify port and other relevant authorities. Remove from the surface by skimming or with suitable absorbents. If permitted by regulatory authorities the use of suitable dispersants should be considered where
recommended in local oil spill procedures. ENVIRONMENTAL PRECAUTIONS: Prevent material from entering sewers, water sources or low lying areas; advise the relevant authorities if it has, or if it contaminates soil/vegetation. PERSONAL PRECAUTIONS: See Section 8 -------------------------------------------------------------------------7. HANDLING AND STORAGE -------------------------------------------------------------------------SPECIFIC USES: Industrial gear oil HANDLING: No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. STORAGE: Keep containers closed when not in use. Do not store in open or unlabelled containers. Store away from strong oxidizing agents and combustible materials. Do not store near heat, sparks, flame or strong oxidants. SPECIAL PRECAUTIONS: Prevent small spills and leakages to avoid slip hazard. EMPTY CONTAINER WARNING: Empty containers retain residue (liquid and/ or vapour) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD BRAZE, SOLDER,DRILL,GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. -------------------------------------------------------------------------8. EXPOSURE CONTROLS/PERSONAL PROTECTION -------------------------------------------------------------------------OCCUPATIONAL EXPOSURE LIMITS: When mists/aerosols can occur, the following are recommended: 5 mg/m3 (as oil mist)- ACGIH Threshold Limit Value (TLV), 10 mg/m3 (as oil mist) - ACGIH Short Term Exposure Limit (STEL) VENTILATION: If mists are generated, use adequate ventilation, local exhaust or enclosures to control below exposure limits. RESPIRATORY PROTECTION: If mists are generated, and/or when ventilation is not adequate, wear approved respirator. EYE PROTECTION: If eye contact is likely, safety glasses with side shields or chemical type goggles should be worn. SKIN PROTECTION: Not normally required. When splashing or liquid contact can occur frequently, wear oil resistant gloves and/or other protective clothing. Good personal hygiene practices should always be followed. ENVIRONMENTAL CONTROLS: SEE SECTION 7 -------------------------------------------------------------------------9. PHYSICAL AND CHEMICAL PROPERTIES --------------------------------------------------------------------------
Typical physical properties are given below. Sheet for specific details. GENERAL: PHYSICAL STATE: Liquid COLOUR: Dark Amber ODOUR: Mild ODOUR THRESHOLD-ppm: NE
IMPORTANT HEALTH, SAFETY AND ENVIRONMENTAL INFORMATION: pH: NA BOILING POINT C(F): > 316(600) FLASH POINT C(F): > 204(399) (IP 34 / ASTM D-93) FLAMMABILITY (solids): NE AUTO FLAMMABILITY C(F): NA EXPLOSIVE PROPERTIES: NA OXIDIZING PROPERTIES: NA VAPOUR PRESSURE-mmHg 20 C: < 0.1 RELATIVE DENSITY, 15/4 C: 0.86-1 SOLUBILITY IN WATER: Negligible PARTITION COEFFICIENT: > 3.5 VISCOSITY AT 40 C, cSt: 220.0 VISCOSITY AT 100 C, cSt: 19.5 VAPOUR DENSITY: > 2.0 EVAPORATION RATE: NE OTHER INFORMATION: MELTING POINT C(F): NA POUR POINT C(F): -24(-11) FREEZING POINT C(F): NE DMSO EXTRACT, IP-346 (WT.%): <3, for mineral oil only NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE -------------------------------------------------------------------------10. STABILITY AND REACTIVITY -------------------------------------------------------------------------STABILITY (THERMAL, LIGHT, ETC.): Stable. CONDITIONS TO AVOID: Extreme heat and high energy sources of ignition. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidisers. HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at ambient temperatures. HAZARDOUS POLYMERISATION: Will not occur. -------------------------------------------------------------------------11. TOXICOLOGICAL DATA ----------------------------------------------------------------------------ACUTE TOXICOLOGY--ORAL TOXICITY: Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. DERMAL TOXICITY: Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. INHALATION TOXICITY: Practically non-toxic (LC50: greater than 5
mg/l). ---Based on testing of similar products and/or the components. EYE IRRITATION: Practically non-irritating. (Draize score: greater than 6 but 15 or less). ---Based on testing of similar products and/or the components. SKIN IRRITATION: Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). ---Based on testing of similar products and/or the components. OTHER ACUTE TOXICITY DATA: Although an acute inhalation study was not performed with this product, a variety of mineral and synthetic oils, such as those in this product, have been tested. These samples had virtually no effect other than a nonspecific inflammatory response in the lung to the aerosolized mineral oil. The presence of additives in other tested formulations (in approximately the same amounts as in the present formulation) did not alter the observed effects. ---SUBCHRONIC TOXICOLOGY (SUMMARY)--No significant adverse effects were found in studies using repeated dermal applications of similar formulations to the skin of laboratory animals for 13 weeks at doses significantly higher than those expected during normal industrial exposure. The animals were evaluated extensively for effects of exposure (hematology, serum chemistry, urinalysis, organ weights, microscopic examination of tissues etc.). ---REPRODUCTIVE TOXICOLOGY (SUMMARY)--No teratogenic effects would be expected from dermal exposure, based on laboratory developmental toxicity studies of major components in this formulation and/or materials of similar composition. ---CHRONIC TOXICOLOGY (SUMMARY)--Repeated and/or prolonged exposure may cause irritation to the skin, eyes or respiratory tract. Overexposure to oil mist may result in oil droplet deposition and/or granuloma formation. For mineral base oils: Base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic mouse skin painting studies of severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a continuing basis using various screening methods such as Modified Ames Test, IP-346, and/or other analytical methods. Synthetic base oils representative of those in this producthave been tested in the Ames assay and other tests of mutagenicity with negative results. These base oils are not expected to be carcinogenic with chronic dermal exposures. ---SENSITIZATION (SUMMARY)--Not expected to be sensitizing based on tests of this product, components, or similar products. -------------------------------------------------------------------------12. ECOLOGICAL INFORMATION -------------------------------------------------------------------------ENVIRONMENTAL FATE AND EFFECTS: In the absence of specific environmental data for this product, this
assessment is based on information for representative products. ECOTOXICITY: Available ectoxicity data (LL50 >1000 mg/L) indicates that adverse effects to aquatic organisms are not expected from this product. MOBILITY: When released into the environment, adsorption to sediment and soil will be the predominant behavior. PERSISTENCE AND DEGRADABILITY: This product is expected to be inherently biodegradable. BIOACCUMULATIVE POTENTIAL: Bioaccumulation is unlikely due to the very low water solubility of this product, therefore bioavailability to aquatic organisms is minimal.
-------------------------------------------------------------------------13. DISPOSAL CONSIDERATIONS -------------------------------------------------------------------------WASTE DISPOSAL: Product is suitable for burning in an enclosed, controlled burner for fuel value. Such burning may be limited pursuant to the Resource Conservation and Recovery Act. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. EUROPEAN WASTE CODE: 13 02 05 (mineral-based non-chlorinated engine, gear and lubricating oils) Waste generated from the intended use of this product is assigned the above waste disposal code. However, deviation from the intended use and/or the presence of any potential contaminants may require an alternative waste disposal code to be assigned by the end user. This waste is considered as a hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of the Directive applies. -------------------------------------------------------------------------14. TRANSPORT INFORMATION -------------------------------------------------------------------------USA DOT: NOT REGULATED BY USA DOT. RID/ADR: IMO: IATA: NOT REGULATED BY RID/ADR.
-------------------------------------------------------------------------15. REGULATORY INFORMATION -------------------------------------------------------------------------EU Labelling: Product is not dangerous as defined by the European
Union Dangerous Substances/Preparations Directives. EU labeling not required. THE FOLLOWING PRODUCT INGREDIENTS ARE CITED ON THE LISTS BELOW: CHEMICAL NAME CAS NUMBER *** NO REPORTABLE INGREDIENTS *** --- REGULATORY ALLERGI 11=DE ALLERGY 12=DE CARC 13=DE CARC 14=DE TERAT A 15=DE LISTS SEARCHED TERAT B 16=DE TERAT C 17=AT TERAT D 18=AT CARC A1 19=AT CARC A2 20=AT LIST CITATIONS
21=CH CARC
CARC=CARCINOGEN;
AT = Austria CH = Switzerland
NOTE: EXXONMOBIL PRODUCTS ARE NOT FORMULATED TO CONTAIN PCBS. Health studies have shown that many hydrocarbons pose potential human health risks which may vary from person to person. Information provided on this MSDS reflects intended use. This product should not be used for other applications. In any case, the following advice should be considered: INJECTION INJURY WARNING: If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. INDUSTRIAL LABEL Under normal conditions of intended use, this product does not pose a risk to health. Excessive exposure may result in eye, skin or respiratory irritation. Always observe good hygiene measures. First Aid: Wash skin with soap and water. Flush eyes with water. If overcome by fumes or vapor, remove to fresh air. If ingested, do not induce vomiting. If symptoms persist seek medical assistance. Read and understand the MSDS before using this product.
COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Any sections of this Material Safety Data Sheet which are printed in bold text highlights recent significant changes which have been made
to the advice or information given. ********************************************************************** For Internal Use Only: MHC: 1* 1* 1* 1* 1*, MPPEC: A, TRN: 610873-60, ELIS: 400352, CMCS97: 970984 EHS Approval Date: 22AUG2001 **********************************************************************
Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. Exxon Mobil Corporation and its affiliated companies assume no responsibility for accuracy of information unless the document is the most current available from an official ExxonMobil distribution system. Exxon Mobil Corporation and its affiliated companies neither represent nor warrant that the format, content or product formulas contained in this document comply with the laws of any other country except the United States of America.
Product Name:
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+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS ZINC DIALKYL DITHIOPHOSPHATE 68457-79-4 270-608-0
Product Name:
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* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Under normal conditions of intended use, this material is not expected to be an inhalation hazard. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: combustion products Aldehydes, Oxides of carbon, Sulphur Oxides, Smoke, Fume, Incomplete
FLAMMABILITY PROPERTIES Flash Point [Method]: >204C (400F) [ EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES
Product Name:
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NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Allow spilled material to solidify and shovel it up into a suitable container for recycle or disposal. Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. shipping. Skim from surface Warn other
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.
SECTION 8
Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage.
Product Name:
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Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Solid Form: semi-fluid Colour: dark blue Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.88 Flash Point [Method]: >204C (400F) [ EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F)
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Vapour Density (Air = 1): N/D Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 220 cSt (220 mm/sec) at 40C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/D DMSO Extract (mineral oil only), IP-346:
< 3 %wt
Note: Most physical properties above are for the oil component in the material. SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: No end point data. Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on assessment of the components.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components.
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CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 12 01 12 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies.
Product Name:
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Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: SECTION 16 OTHER INFORMATION EINECS
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R38; Irritating to skin. R41; Risk of serious damage to eyes. R51/53; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified.
Product Name:
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Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 08: Environmental Control - Note was modified. Section 16: Code to MHCs was modified. Section 11: Inhalation Lethality Test Data was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 9
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# EINECS / ELINCS Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene LITHIUM SALT OF ALIPHATIC ACID 68411-46-1 Confidential 270-128-1
Concentration * 1 - 5% 1 - 5%
Product Name:
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10254-57-6 68457-79-4
233-593-1 270-608-0
1 - 5% < 2.5%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Under normal conditions of intended use, this material is not expected to be an inhalation hazard. SKIN CONTACT Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >204C (400F) [ EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES
Product Name:
Page 3 of 9
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. shipping. Skim from surface Warn other
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Avoid contact with skin. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.
SECTION 8
Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use
Product Name:
Page 4 of 9
with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: Chemical resistant gloves are recommended. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Solid Form: semi-fluid Colour: red Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 1 Flash Point [Method]: >204C (400F) [ EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F)
Product Name:
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Vapour Density (Air = 1): N/D Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 460 cSt (460 mm/sec) at 40C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/D Note: Most physical properties above are for the oil component in the material. SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: No end point data. Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on assessment of the components.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components.
CHRONIC/OTHER EFFECTS
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Contains: Synthetic base oils: Not expected to cause significant health effects under conditions of normal use, based on laboratory studies with the same or similar materials. Not mutagenic or genotoxic. Not sensitising in test animals and humans. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids.
ECOLOGICAL DATA ECOTOXICITY Test Aquatic - Acute Toxicity Aquatic - Acute Toxicity Aquatic - Acute Toxicity Aquatic - Chronic Toxicity
Organism Type Water Flea Green Alga Rainbow Trout Water Flea
Test Results EL0 1000 mg/l EL50 >1000 mg/l LL0 1000 mg/l NOELR 1 mg/l
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 12 01 12 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and
Product Name:
Page 7 of 9
subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
Contains: BENZOTRIAZOLE DERIVATIVE May produce an allergic reaction. This material contains one or more sensitizers <1.0% by weight which are not identified in the Composition Section. REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: TSCA Special Cases: Inventory AICS KECI NDSL SECTION 16 Status Restrictions Apply Restrictions Apply Restrictions Apply OTHER INFORMATION IECSC, EINECS,
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only):
Product Name:
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R22; Harmful if swallowed. R38; Irritating to skin. R41; Risk of serious damage to eyes. R43; May cause sensitisation by skin contact. R51/53; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53; Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R53; May cause long-term adverse effects in the aquatic environment. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 04: First Aid Skin was modified. Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 11: Inhalation Lethality Conclusion was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 07: Handling and Storage - Handling was modified. Section 11: Inhalation Lethality Test Comment was modified. Section 05: Hazardous Combustion Products was modified. Composition: Component Table was modified. Section 06: Accidental Release - Spill Management - Land was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Skin and Body Protection was modified. Section 08: Environmental Control - Note was modified. Section 11: Skin Irritation Conclusion was modified. Section 11: Inhalation Lethality Test Comment was modified. Section 16: RCode Key was modified. Section 15: National Chemical Inventory Listing was modified. Section 16: Code to MHCs was modified. Section 15: Special Cases Table was modified. Section 15: Sensitiser Statement was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 12: Environmental tox table in section 12 was added. Section 12: Ecological data - Header was added. Section 12: Ecological data - Header was deleted. Section 12: Environmental tox table in section 12 was deleted.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
Product Name:
Page 9 of 9
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 9
MOBILTAC 375 NC
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is dangerous according to regulatory guidelines (see (M)SDS Section 15). CLASSIFICATION: | R52/53 |
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage. When heated, the vapour/fumes given off may cause respiratory tract irritation. ENVIRONMENTAL HAZARDS Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 This material is regulated as a preparation. Reportable Hazardous Substance(s) or Complex Substance(s) COMPOSITION / INFORMATION ON INGREDIENTS
Product Name:
Page 2 of 9
MOBILTAC 375 NC
Name
CAS#
ASPHALT (PETROLEUM) Hexanoic acid, 2-ethyl-, zinc salt HYDROTREATED LIGHT DISTILLATE
Symbols/Risk Phrases None Xi;R36/38 R10, Xn;R65, R66, R67, N;R51/53, Note 4, Note H Xi;R36 Xn;R65, R66, N;R51/53
12001-85-3 64741-44-2
234-409-2 265-044-7
1 - 5% 5 - 10%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION Seek immediate medical attention. Do not induce vomiting.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
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MOBILTAC 375 NC
protect personnel. Unusual Fire Hazards: May generate irritating and harmful gases/vapours/fumes when burning. Hazardous Combustion Products: Hydrogen Sulphide, Smoke, Fume, Sulphur Oxides, Incomplete combustion products, Oxides of carbon, Nitrogen Oxides FLAMMABILITY PROPERTIES Flash Point [Method]: 121C (250F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: N/D Autoignition Temperature: N/D SECTION 6
UEL: N/D
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. shipping. Skim from surface Warn other
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Avoid elevated temperatures for prolonged periods of time. Avoid contact with skin. Avoid vapour from heated materials to prevent exposure to potentially toxic/irritating fumes. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
STORAGE Store in a cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames and high temperatures. Do not store in open or unlabelled containers. > -1C (30F) Storage Temperature:
SECTION 8
Product Name:
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MOBILTAC 375 NC
EXPOSURE LIMIT VALUES Exposure limits/standards (Note: Exposure limits are not additive)
Substance Name ASPHALT (PETROLEUM) ASPHALT (PETROLEUM) ASPHALT (PETROLEUM) [benzene solubles] HYDROTREATED LIGHT DISTILLATE [total hydrocarbon vapour] STRAIGHT-RUN MIDDLE DISTILLATES STRAIGHT-RUN MIDDLE DISTILLATES Form Fume. Fume. Inhalable fraction. TWA Non-Aer osol Stable Aerosol. Vapour. 200 mg/m3 5 mg/m3 200 mg/m3 Skin ACGIH 2008 Limit/Standard STEL 10 mg/m3 TWA 5 mg/m3 TWA 0.5 mg/m3 Note Source UK EH40 UK EH40 ACGIH Year 2007 2007 2008
TWA TWA
ExxonMobil ExxonMobil
2008 2008
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
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MOBILTAC 375 NC
Chemical resistant gloves are recommended. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Solid Form: semi-fluid Colour: black Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.95 - 0.98 Flash Point [Method]: 121C (250F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: 174C (345F) - 260C (500F) Vapour Density (Air = 1): N/D Vapour Pressure: [N/D at 20C] Evaporation Rate (N-Butyl Acetate = 1): < 1 [n-Butyl Acetate] pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: [N/D at 40C] Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A SECTION 10 STABILITY AND REACTIVITY
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MOBILTAC 375 NC
CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: No End Point Data Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Not determined. Elevated temperatures or mechanical action may form vapours, mist, or fumes which may be irritating to the eyes, nose, throat, or lungs. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Mildly irritating to skin with prolonged exposure. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory tract.
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Expected to be harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. MOBILITY More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and wastewater solids. High molecular wt. component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids.
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MOBILTAC 375 NC
PERSISTENCE AND DEGRADABILITY Biodegradation: Low molecular wt. component -- Expected to be inherently biodegradable High molecular wt. component -- Expected to be persistent. Atmospheric Oxidation: More volatile component -- Expected to degrade rapidly in air BIOACCUMULATION POTENTIAL Majority of components -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Suitable routes of disposal are supervised incineration, preferentially with energy recovery, or appropriate recycling methods in accordance with applicable regulations and material characteristics at the time of disposal. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 02 05 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport
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MOBILTAC 375 NC
SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is dangerous as defined by the EU Dangerous Substances/Preparations Directives. CLASSIFICATION: Dangerous for the environment.
R52/53; Harmful to aquatic organisms, may cause long-term adverse effects in the
Safety Advice: S61; Avoid release to the environment. Refer to special instructions/safety data sheets.
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, ENCS, KECI, PICCS, TSCA SECTION 16 OTHER INFORMATION AICS, IECSC, DSL,
N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R10; Flammable. R36; Irritating to eyes. R38; Irritating to skin. R51/53; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53; Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65; Harmful: may cause lung damage if swallowed. R66; Repeated exposure may cause skin dryness or cracking. R67; Vapours may cause drowsiness and dizziness. THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 04: First Aid Skin was modified. Section 06: Notification Procedures - Header was modified. Section 11: Skin Irritation Conclusion was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified.
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MOBILTAC 375 NC
Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 07: Handling and Storage - Handling was modified. Section 05: Hazardous Combustion Products was modified. Composition: Component Table was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Skin and Body Protection was modified. Section 08: Environmental Control - Note was modified. Section 16: RCode Key was modified. Section 15: National Chemical Inventory Listing was modified. Section 16: Code to MHCs was modified. Section 08: Exposure Limits Table was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 11: Other Health Effects Header was added. Section 11: Other Health Effects was added. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Ecotoxicity was deleted. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 2, 1
PPEC:
Product Name:
Page 1 of 8
MOBILTHERM 603
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
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MOBILTHERM 603
mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >194C (381F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 Autoignition Temperature: N/D SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants.
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MOBILTHERM 603
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator.
STORAGE Do not store in open or unlabelled containers. Keep away from incompatible materials.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
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MOBILTHERM 603
Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Liquid Colour: Pale yellow Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.835 Flash Point [Method]: >194C (381F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 20.2 cSt (20.2 mm/sec) at 40C | 4.1 cSt (4.1 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point:
N/D
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MOBILTHERM 603
Melting Point: N/A Pour Point: -3C (27F) DMSO Extract (mineral oil only), IP-346: SECTION 10
< 3 %wt
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar materials. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
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MOBILTHERM 603
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Material -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Material -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Material -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 13 03 07 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
Product Name:
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MOBILTHERM 603
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives . .
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, ENCS, KECI, PICCS, TSCA SECTION 16 OTHER INFORMATION AICS, IECSC, DSL,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Notification Procedures - Header was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Color was modified. Section 09: Boiling Point C(F) was modified. Section 09: Pour Point C(F) was modified. Section 08: Hand Protection was modified. Section 08: Environmental Control - Note was modified. Section 07: Handling and Storage - Storage Phrases was modified. Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 09: Viscosity was modified. Section 08: Environmental Control - Note was modified. Section 15: National Chemical Inventory Listing was modified. Section 16: Code to MHCs was modified.
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Section 09: Relative Density was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Dermal Lethality Test Data was modified. Section 01: Company Contact Methods Sorted by Priority was modified. %%revision_comment%% ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
MOBILUX EP 1
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 SDS-NORDEN@EXXONMOBILCOM
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Under normal conditions of intended use, this material is not expected to be an inhalation hazard.
Product Name:
Page 2 of 8
MOBILUX EP 1
SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: combustion products Oxides of carbon, Aldehydes, Smoke, Fume, Sulphur Oxides, Incomplete
FLAMMABILITY PROPERTIES Flash Point [Method]: >204C (400F) [ EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. shipping. Skim from surface Warn other
Product Name:
Page 3 of 8
MOBILUX EP 1
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.
SECTION 8
Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove
Product Name:
Page 4 of 8
MOBILUX EP 1
manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Solid Form: semi-fluid Colour: brown Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.9 Flash Point [Method]: >204C (400F) [ EST. FOR OIL, ASTM D-92 (COC)] UEL: N/D Flammable Limits (Approximate volume % in air): LEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): N/D Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 150 cSt (150 mm/sec) at 40C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/D DMSO Extract (mineral oil only), IP-346:
< 3 %wt
Product Name:
Page 5 of 8
MOBILUX EP 1
Note: Most physical properties above are for the oil component in the material. SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on assessment of the components.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY
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Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
ECOLOGICAL DATA ECOTOXICITY Test Aquatic - Acute Toxicity Aquatic - Chronic Toxicity
Test Results EL0 100 mg/l: data for similar materials NOELR 1 mg/l: data for similar materials
Note: Not toxic to aquatic organisms at maximum water solubility. SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 12 01 12 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
Product Name:
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MOBILUX EP 1
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, PICCS, TSCA Special Cases: Inventory ENCS KECI SECTION 16 Status Restrictions Apply Restrictions Apply OTHER INFORMATION AICS, IECSC,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified.
Product Name:
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Section 11: Skin Irritation Conclusion was modified. Section 11: Inhalation Lethality Test Comment was modified. Section 15: National Chemical Inventory Listing was modified. Section 09: Relative Density was modified. Section 09: Melting Point C(F) was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 12: Environmental tox table header was added. Section 12: Test - Column Header was added. Section 12: Organism Type - Column Header was added. Section 12: Duration - Column Header was added. Section 12: Test Results - Column Header was added. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added. Section 12: Environmental tox table in section 12 was added. Section 12: Section 12 Footnote was added. Section 12: Ecological data - Header was added.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
MOBILUX EP 0
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Under normal conditions of intended use, this material is not expected to be an inhalation hazard. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the
Product Name:
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MOBILUX EP 0
body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: carbon, Sulphur Oxides Aldehydes, Smoke, Fume, Incomplete combustion products, Oxides of
FLAMMABILITY PROPERTIES Flash Point [Method]: >204C (400F) [ EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. shipping. Skim from surface Warn other
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
Product Name:
Page 3 of 8
MOBILUX EP 0
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.
SECTION 8
Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
Product Name:
Page 4 of 8
MOBILUX EP 0
No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Solid Form: semi-fluid Colour: brown Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.9 Flash Point [Method]: >204C (400F) [ EST. FOR OIL, ASTM D-92 (COC)] UEL: N/D Flammable Limits (Approximate volume % in air): LEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): N/D Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 150 cSt (150 mm/sec) at 40C | >16 cSt (16 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/D DMSO Extract (mineral oil only), IP-346:
< 3 %wt
Note: Most physical properties above are for the oil component in the material.
Product Name:
Page 5 of 8
MOBILUX EP 0
SECTION 10
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on assessment of the components.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms.
Product Name:
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MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
ECOLOGICAL DATA ECOTOXICITY Test Aquatic - Acute Toxicity Aquatic - Chronic Toxicity
Test Results EL0 100 mg/l: data for similar materials NOELR 1 mg/l: data for similar materials
Note: Not toxic to aquatic organisms at maximum water solubility. SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 12 01 12 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
Product Name:
Page 7 of 8
MOBILUX EP 0
SECTION 14
TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, PICCS, TSCA Special Cases: Inventory ENCS KECI SECTION 16 Status Restrictions Apply Restrictions Apply OTHER INFORMATION AICS, IECSC,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 01: Product Description was modified. Section 06: Accidental Release - Spill Management - Land was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified.
Product Name:
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Section 09: Viscosity was modified. Section 15: National Chemical Inventory Listing was modified. Section 09: Relative Density was modified. Section 09: Melting Point C(F) was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added. Section 12: Environmental tox table in section 12 was added. Section 12: Section 12 Footnote was added. Section 12: Ecological data - Header was added. Section 16: RCode Key - Header was deleted. Section 12: Ecological data - Header was deleted. Section 12: Environmental tox table in section 12 was deleted. Section 16: RCode Key was deleted.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
MOBILUX EP 2
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 SDS-NORDEN@EXXONMOBILCOM
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Under normal conditions of intended use, this material is not expected to be an inhalation hazard.
Product Name:
Page 2 of 8
MOBILUX EP 2
SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Sulphur Oxides Smoke, Fume, Incomplete combustion products, Oxides of carbon,
FLAMMABILITY PROPERTIES Flash Point [Method]: >204C (400F) [ EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. shipping. Skim from surface Warn other
Product Name:
Page 3 of 8
MOBILUX EP 2
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.
SECTION 8
Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove
Product Name:
Page 4 of 8
MOBILUX EP 2
manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Solid Form: semi-fluid Colour: brown Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.9 Flash Point [Method]: >204C (400F) [ EST. FOR OIL, ASTM D-92 (COC)] UEL: N/D Flammable Limits (Approximate volume % in air): LEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): N/D Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 150 cSt (150 mm/sec) at 40C | 11.8 cSt (11.8 mm/sec) at 100C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/D DMSO Extract (mineral oil only), IP-346:
< 3 %wt
Product Name:
Page 5 of 8
MOBILUX EP 2
Note: Most physical properties above are for the oil component in the material. SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on assessment of the components.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY
Product Name:
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Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
ECOLOGICAL DATA ECOTOXICITY Test Aquatic - Acute Toxicity Aquatic - Acute Toxicity
Test Results EL0 100 mg/l: data for similar materials NOELR 1 mg/l
Note: Not toxic to aquatic organisms at maximum water solubility. SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 12 01 12 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
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MOBILUX EP 2
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, PICCS, TSCA Special Cases: Inventory ENCS KECI SECTION 16 Status Restrictions Apply Restrictions Apply OTHER INFORMATION AICS, IECSC,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Color was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 01: Product Description was modified. Section 06: Accidental Release - Spill Management - Land was modified.
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Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 11: Skin Irritation Conclusion was modified. Section 11: Inhalation Lethality Test Comment was modified. Section 15: National Chemical Inventory Listing was modified. Section 09: Relative Density was modified. Section 09: Melting Point C(F) was modified. Section 11: Chronic Tox - Component was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 12: Environmental tox table header was added. Section 12: Test - Column Header was added. Section 12: Organism Type - Column Header was added. Section 12: Duration - Column Header was added. Section 12: Test Results - Column Header was added. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added. Section 12: Environmental tox table in section 12 was added. Section 12: Section 12 Footnote was added. Section 12: Ecological data - Header was added.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC:
Product Name:
Page 1 of 8
MOBILUX EP 3
+44 1372 222 000 EAME +420 221 456 618 / Americas +1 800 662 4525 / Asia Pacific +8621 5464 4588 EXT 5842 sds-norden@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH HAZARDS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
INHALATION Under normal conditions of intended use, this material is not expected to be an inhalation hazard.
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SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: products, Oxides of carbon Aldehydes, Sulphur Oxides, Smoke, Fume, Incomplete combustion
FLAMMABILITY PROPERTIES Flash Point [Method]: >204C (400F) [ EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. shipping. Skim from surface Warn other
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MOBILUX EP 3
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.
SECTION 8
Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s): France L'Institut National de Recherche et de Scurit (INRS) Germany Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE) ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove
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MOBILUX EP 3
manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Consult the Supplier in Section 1 for additional
Typical physical and chemical properties are given below. data. GENERAL INFORMATION Physical State: Solid Form: semi-fluid Colour: brown Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.9 Flash Point [Method]: >204C (400F) [ EST. FOR OIL, ASTM D-92 (COC)] UEL: N/D Flammable Limits (Approximate volume % in air): LEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): N/D Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20C Evaporation Rate (N-Butyl Acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 150 cSt (150 mm/sec) at 40C Oxidising properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/D DMSO Extract (mineral oil only), IP-346:
< 3 %wt
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MOBILUX EP 3
Note: Most physical properties above are for the oil component in the material. SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Acute Toxicity Route of Exposure
INHALATION Toxicity: LC50 > 5000 mg/m3 Irritation: No end point data.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar materials. Negligible irritation to skin at ambient temperatures. Based on assessment of the components.
Eye Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components.
CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY
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Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
ECOLOGICAL DATA ECOTOXICITY Test Aquatic - Acute Toxicity Aquatic - Chronic Toxicity
Test Results EL0 100 mg/l: data for similar materials NOELR 1 mg/l: data for similar materials
Note: Not toxic to aquatic organisms at maximum water solubility. SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION European Waste Code: 12 01 12 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
Product Name:
Page 7 of 8
MOBILUX EP 3
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID) : Not Regulated for Land Transport INLAND WATERWAYS (ADNR) : Not Regulated for Inland Waterways Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION
Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Complies with the following national/regional chemical inventory requirements: EINECS, PICCS, TSCA Special Cases: Inventory ENCS KECI SECTION 16 Status Restrictions Apply Restrictions Apply OTHER INFORMATION AICS, IECSC,
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 08: Hand Protection was modified. Section 06: Accidental Release - Spill Management - Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified.
Product Name:
Page 8 of 8
MOBILUX EP 3
Section 11: Skin Irritation Conclusion was modified. Section 11: Inhalation Lethality Test Comment was modified. Section 15: National Chemical Inventory Listing was modified. Section 09: Relative Density was modified. Section 09: Melting Point C(F) was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 12: Environmental tox table header was added. Section 12: Test - Column Header was added. Section 12: Organism Type - Column Header was added. Section 12: Duration - Column Header was added. Section 12: Test Results - Column Header was added. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added. Section 12: Environmental tox table in section 12 was added. Section 12: Section 12 Footnote was added. Section 12: Ecological data - Header was added.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only MHC: 0, 0, 0, 0, 0, 0
PPEC: