Chemistry for Changing Times,

Thirteenth Edition

Lecture Outlines

Chapter 5
Chemical Accounting

John Singer, Jackson Community College

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Chemical Sentences: Equations

Chemical equations represent the sentences in the language of chemistry. They communicate a chemical change using symbols and formulas to represent the elements and compounds involved in a chemical reaction.

2013 Pearson Education, Inc.

Chapter 5

Chemical Sentences: Equations

Reactants are the species present before the reaction. Products are the species present after the reaction. Reactants Products The arrow () means yield(s) or react(s) to produce.

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Chapter 5

Chemical Sentences: Equations

The following are used to denote the state of a species in an equation: (s) (l) (g) (aq) = = = = solid liquid gas aqueous solution

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Chapter 5

Chemical Sentences: Equations

Coefficients are numbers used to balance a chemical equation. Never change the subscripts.

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Volume Relationships in Chemical Equations

Law of Combined Volumes: When all measurements are made at the same temperature and pressure, the volumes of gaseous reactants and products are in a small whole-number ratios.

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Chapter 5

Volume Relationships in Chemical Equations

Avogadros hypothesis: When measured at the same temperature and pressure, volumes of all gases contain the same number of molecules.

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Chapter 5

Avogadros Number
Avogadros number is defined as the number of atoms in a 12-g sample of carbon-12 and is

6.02 x

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Chapter 5

The Mole
A mole (mol) is defined as the amount of a substance that contains 6.02 x 1023 particles.

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Chapter 5

The Mole

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The Mole
Formula mass is the average mass of a formula unit relative to that of a carbon-12 atom. It is simply the sum of the atomic masses for all atoms in a formula. If the formula represents a molecule, often the term molecular mass is used.

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The Mole

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The Mole
Molar volume of a gas: One mole of any gas occupies a volume of 22.4 L at standard temperature and pressure (STP). STP is defined as 1 atmosphere (atm) of pressure and a temperature of 0 oC.

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Mole and Mass Relationships in Chemical Equations

Stoichiometry involves the quantitative relationship between reactants and products in a balanced chemical equation. The coefficients of a balanced chemical equation represent moles.

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Mole and Mass Relationships in Chemical Equations

2 H2 + O2 2 H2O This equation can be read as follows: 2 mol of H2 reacts with one mol O2 to yield 2 mol of H2O.

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Mole and Mass Relationships in Chemical Equations

Steps in a Stoichiometric Calculation: 1.Write and balance the chemical equation for the reaction. 2.Determine molar masses of substances involved in the calculation. 3.Use the coefficients of the balanced equation to convert the moles of the given substance to the moles of the desired substance. 4.Use the molar mass to convert the moles of the desired substance to grams of the desired substance.
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Mole and Mass Relationships in Chemical Equations

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Solutions
The amount of solute in a given amount of solvent is defined as solution concentration. A dilute solution contains relatively small amounts of solute in a given amount of solvent. A concentrated solution contains relatively large amounts of solute in a given amount of solvent.

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Solutions
Molarity (M) is defined as the moles of solute per liter of solution.

mol M= liter

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Solutions
Percent Concentration

volume of solute x 100 Percent by volume = volume of solution

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Solutions

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Solutions
Percent Concentration

mass of solute Percent by mass = x 100 mass of solution

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Solution Concentration

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