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CHEMISTRY
PT & Bonding
IMPORTANT FORMULA
Δ=
⎡ ⎣
1
EA-B -
E A− A X E B − B
⎤ ⎦
1 2
EA-A,EB-B and EA-B in kcal mol-1.
χM =
χP =
I .E. + E. A. 540
(χ A ) AR
= 0.744 +
0.359 Z effective r2
r= radius of an element in Δ
Ph-0744-2422383 .Mo-93149-05055
How many Cl atoms can you ionize in the process Cl → Cl+ +e by the
energy liberated for the
Q.23 Calculate the molecular weight of HF if density of HF gas is 3.17 g/L at 300K
and 1.0 atm. Comment on the result.
Q.24 The experimental dipole moment of w
ater molecule is 1.84 D .Calculate the bond angle H-O-H in water molecule, if
dipole moment
of OH bond is 1.5 D.
Q.25 The H-O-H bond angle in the water molecule is 105°, the H-O bond distance
being 0.94Δ.
The dipole moment for the molecule is 1.85 D. Calculate the charge on the oxygen
atom.
covalent or become ionic in aqueous solution. (Ionisation energy for AlCl 3 =5137
kJ mol-1 ;
Δ hydration for Al3+ = -4665 kJ mol-1
Q.26 Estimate the lattice energy of CaCO3 if rCa+=114 pm and r CO 3 = 185 pm.
Q.27 Suppose a gaseous mixture of He, Ne, Ar and Kr is irradiated with photons
of frequency approximate to ionize Ar. What ions will be present in the mixture?
Q.28 The dipole moment of KCl is 3.336 X 10-29 coulomb meter which indicates that
it is a highly polar molecule. The inter-atomic distance between K+ and Cl- in
this molecule
is 2.6 X 10-10 m. Calculate the dipole moment of KCl molecule. if there were
opposite charge of
one fundamental unit located at each nucleus. Calculate percentage ionic character
of KCl.
Q.29 Anhydrous AlCl3 is covalent .From the data given below predict whether it
would remain
−
Δ hydration for Cl- = -381 kJ mol-1)
ANSWERS
a=7270 kJ mol-1 Q.2 1.667 X1023 Q.5 62% 11.29 1.61 Q.9 Q.14 Q.18
+1532.7 kJ mol-1
χF= 3.87
5.75 x 102
(χF )M
0.92Δ Q.20
Q.25 3.23X 10 esu cm m=78.08 Q.24 α =104 ° 20 Q.27 Initially Ar + will be present.
The EA value
of Ar +(15.76 eV) is almost
as IE1 for Ar. IE1 for Kr is 14.0 eV. so reaction , Ar+ +-1e0 →Ar, will occur ex
othermally and energy released will ionize Kr into Kr+. IE1 value for He, Ne are
larger so these atoms wi
ll not react.
Ph-0744-2422383 .Mo-93149-05055
1. 2. 3.
4. 5. 6. 7. 8. 9.
(a)
[A]
(b)
[B]
(c)
[C]
(d)
[D]
14.
The five successive ionisation energies of the element are 800, 2727,3658,25024
and
32824 kJmol-1 respectively. The number of valence electron is: (a) 3 (b) 5 (c) 4
(d) 2
The ionic radius of Cr is minimum in which of the following compounds?
(a) CrF3 (b) CrCl3 (c) Cr2O3 (d) K2CrO4
Ph-0744-2422383 .Mo-93149-05055
20. 21.
22. 23.
42. 43.
Ph-0744-2422383 .
Mo-93149-05055