FILE NO.

IIT 248/24(14-11-2008)
CODE SURYA

NARAYANA
I I T A C A D E M

JR IIT SPARK (50032)

TWO YEAR CLASS ROOM PROGRAM [69-Bits model test] E X .DT: 15- 11-2008 Tim e: 3 h ou r &'e" e re"( )he i* )ru+)io* +"re,u''-. .ou "re "''o))e( 5 mi*u)e INSTRUCTIONS
A.
General: 1. This booklet is your Question Paper containing 69 questions. The booklet has 16 pages. 2. The question paper CODE is printe on the right han top corner o! this booklet. ". #lank papers$ clipboar s$ log tables$ sli e rules$ calculators$ cellular phones$ pagers$ an electronic ga gets in any !or% are not allo&e to be carrie insi e the e'a%ination hall. (. The ans&er sheet$ a %achine)rea able Ob*ecti+e ,esponse -heet .O,-/$ is pro+i e separately. 0. DO 1OT T23PE, 45T6 7 38T592TE T6E O,- O, T6E #OO:9ET. Filling the ORS 6. On the lo&er part o! the O,-$ &rite in ink$ your na%e in bo' 91$ your ,egistration 1o. in bo' 92 an 1a%e o! the Centre in bo' 9". Do not write these an where else. ;. 4rite your ,egistration 1o. in ink$ in the bo' 9( pro+i e in the lo&er part o! the O,- an arken the appropriate bubble UNDER each igit o! your ,egistration 1o. &ith a goo quality 6# pencil. <. The O,- has a CODE printe on its lo&er an upper parts. 9. 3ake sure the CODE on the O,- is the sa%e as that on this booklet an put your signature in ink in bo' 90 on the O,- a!!ir%ing that you ha+e +eri!ie this. 1=. 5> T6E CODE- DO 1OT 32TC6$ 2-: >O, 2 C621?E O> T6E #OO:9ET. !"estion #a#er $or%at: 11. The question paper consists o! & #arts '(art I: Mathe%ati)s* (art II: (h si)s* (art III: Che%istr +. Each part has ( sections. 12. Se)tion I consists o! Questions 1 to 9.These are single correct ans&er type. >or each correct ans&er " %arks &ill be a&ar e an each incorrect choice 1 %ark &ill be e ucte

!"#im um m "r$ : 24% /e+i,i+"''- ,or )hi /ur/o e.

1(. Se)tion III contains 2 paragraphs. P an P . #ase upon each paragraph$ " %ultiple choice questions ha+e to be ans&ere . Each question has ( choices .a/$ .b/$ .c/$ an . / $ out o! &hich O19@ O1E is correct. >or each correct ans&er ( %arks &ill be a&ar e an each incorrect choice 1 %ark &ill be e ucte . Se)tion I, contains " questions. Each Question contains state%ents gi+en in t&o colu%ns &hich ha+e to be %atche . -tate%ents .2$#$C$D/ in Colu%n)5 ha+e to be %atche &ith state%ents .p$q$r$s/ in Colu%n)55. The ans&ers to these questions ha+e to be appropriately bubble as illustrate in the !ollo&ing e'a%ple. 5! the correct %atches are 2)p$ 2)s$ #)q$ #)r$ C)p$ C)q an D)s$ then the correctly bubble %atri' shoul be as !ollo&sA >or each correct ans&er 6 %arks &ill be a&ar e . There is no negati+e %arking !or these questions. There coul be a single ans&er or %ultiple ans&er. Mar-ing S)he%e: >or each questions in Se)tion I$ you &ill be awar.e. & %ar-s i! you ha+e arkene only the bubble correspon ing to the correct ans&er an Bero %ark i! no bubble is arkene . 5n all other cases$ %in"s one '/0+ %ar- &ill be a&ar e . >or each question in Se)tion II$ you &ill be awar.e. 1 %ar-s i! you ha+e arkene all the bubble.s/ correspon ing to the correct ans&er an Bero %ark !or all other cases. 5! %ay be note that there is no negati2e %ar-ing $or wrong answer. >or each question in Se)tion III$ you &ill be awar.e. & %ar-s i! you arken only the bubble correspon ing to the correct ans&er an Bero %ark i! no bubble is arkene . 5n all other cases$ %in"s one '/0+ %ar- &ill be a&ar e . >or each question in Se)tion I,$ you &ill be awar.e. 1 %ar-s i! you arken only the bubble correspon ing to the correct ans&er an 3ero %ar- i! no bubble is arkene . 5n all other cases$ %in"s one '/0+ %ar- will 4e awar.e..
1()16 1;)19

10.

B.

D. 16.

1;.

1<.

C.

19.

Na%e o$ the St".ent

Roll N"%4er

I ha2e rea. all the instr")tions an. shall a4i.e 4 the% CC..CCCCCCCCCCCCCCCCCCCCC Signat"re o$ the Can.i.ate
1". Se)tion II contains ( questions nu%bere 1= to 1". Each question contains -T2TE3E1T)1 .2ssertion/ an -T2TE3E1T)2 .,eason/. Each question has ( choices .a/$ .b/$ .c/$ an . / $ out o! &hich O19@ O1E is correct. >or each correct ans&er " %arks &ill be a&ar e an each incorrect choice 1 %ark &ill be e ucte . 1(.

I ha2e 2eri$ie. all the in$or%ation $ille. in 4 the Can.i.ate CCCCCCCCCCCCCCCCCCCCC.. Signat"re o$ the In2igilator

MATHEMAT CS

(ART / I
SECTION / I Straight O45e)ti2e T #e
This section contains 6 %ultiple choice questions. Each question has ( choices .2/$ .#/$ .C/ an .D/$ out o! &hich ON6Y ONE is correct.

1. The centre o! the ellipse (' 2 + 9y 2 + 16' 1<y 11 = = is A .a/ .)2$)1/ .b/ .)2$ 1/ .c/ .2$ )1/ . / .2$ 1/ 2. 5! C is the centre o! the ellipse 9'2D16y2E1(( an - is one !ocus$ then the ratio o! C-to the se%i %a*or a'is is A .a/ ; A16 .b/ ; A ( .c/ 0 A ; . / 16 A ; ". The equation o! the ellipse &ith %a*or a'is along ')a'is an %inor a'is along y)a'is an passing through the points .($"/ an .6$2/ is A ' 2 y2 ' 2 y2 ' 2 y2 ' 2 y2 .a/ .b/ .c/ . / + =1 + =1 + =1 + =1 0= 1" 02 1" 1" 02 02 1; (. 5! the seg%ent *oining the !oci o! an ellipse subten s angle o! 9== at an e'tre%ity o! the %inor a'is$ then the eccentricity is A .a/ 0. .a/
1 6 . 1"$=/ are 2<< 1"

.b/ .b/

1 " . 0$=/ . 1"" 1"

.c/ .c/

1 2 2<< 169

. / . /

1 2 ""< 12

+ertices o! an ellipse &ith !oci

'2 y2 + = 1 represents r 1 " r .b/ 1 < r < 2

Then the length o! the latus rectu% isA

6. The equation .a/

1< r < "

stan ar ellipse then A .c/

2<r<"

. /rE6

SECTION / II M"lti#le Corre)t Answer T #e

This section contains ( %ultiple correct ans&er.s/ type questions. Each question has ( choices .2/$ .#/$ .C/ an .D/$ out o! &hich ONE OR MORE is7are correct.

;. 2n ellipse has !oci ."$ =/ an passes through the point .($1/. Then ' 2 y2 ' 2 y2 .a/ Equations o! the ellipse is .b/ equation o! the ellipse + =1 + =1 1< 9 "6 1< ( 2 .c/ eccentricity o! the ellipse is . / eccentricity o! the ellipse is 0 0 2 2 ' y <. >or the ellipse + = 1$ &hich one o! the !ollo&ing are correctF 20 16 ( " .a/ eccentricity is .b/ eccentricity is 0 0 16 "2 .c/ latusrectu% is . / latusrectu% is 20 0 2 2 ' y 9. >or the ellipse 2 + 2 = 1 &hich o! the !ollo&ing are correctF a b b2 b 2 a .a/ The point o! intersection o! tangents ra&n at the points ae$ an ae$ is $ = . a a e .b/ The !oot o! the perpen icular ra&n !ro% !ocus onto a tangent lies on ' 2 + y 2 = a 2

a == e . / 5! >1 $ >2 are the t&o !oci an # is one en o! the %inor a'is such that #>1>2 is equilateral then the 1 eccentricity o! the ellipse is 2 .c/ equation o! the irectri' correspon s to the !ocus .ae$=/ is ' 1=. >or the ellipse ' 2 y2 + = 1 .a G b/$ the length o! the latus rectu% is 1= an the istance bet&een the a 2 b2 !oci is equal to the length o! the %inor a'is. Then 1 .a/ eccentricity is .b/ se%i %a*or a'is is 1= 2 .c/ !oci are ( 0$ = ) . / +ertices are ( 1=$ = ) SECTION / III Reasoning T #e

This section contains ( reasoning type questions. Each question has ( choices .2/$ .#/$ .C/ an .D/$ out o! &hich ON6Y ONE is correct. CODE
'A+ 'B+ 'C+ 'D+ STATEMENT/0 is Tr"e* STATEMENT/7 is Tr"e8 STATEMENT/7 is a )orre)t e9#lanation $or STATEMENT/0 STATEMENT/0 is Tr"e* STATEMENT/7 is Tr"e8 STATEMENT/7 is NOT a )orre)t e9#lanation $or STATEMENT/0 STATEMENT/0 is Tr"e* STATEMENT/7 is False STATEMENT/0 is False* STATEMENT/7 is Tr"e

11. State%ent : I : The angle bet&een the tangents ra&n !ro% the point .2$"/ to the ellipse 9' 2 + 16y 2 = 1(( is 9== State%ent : II : 9ocus o! the point o! intersection o! perpen icular tangents to the ellipse the circle ' 2 + y 2 = a 2 + b 2 12. State%ent : I :P is a point on the ellipse
' 2 y2 + =1 a 2 b2 ' 2 y2 + =1 a 2 b2

is

&hose eccentricity is e an !oci >1an >2 . 5! The e 1 = 1+ e

angle PF1 F2 = 1 and angle PF2 F1 = 2 $ then tan 1 tan 2 2 2

State%ent : II : 5n
2#C$ tan 2 .s b/.s c/ = 2 s.s a/

&here s is the se%iperi%eter o! 2#C

"' 2 + (y 2 + 6' <y 0 = = 1 " b 2 = a 2 .1 e 2 / >1 = ."$=/ an >2 = . "$=/$ Then

1". State%ent : I : The eccentricity o! the ellipse

is

State%ent : II : The eccentricity e o! the ellipse .aGb/ is gi+en by 1(. State%ent : I :5! P.'$y/ is a point on the ellipse 16' 2 + 20y 2 = (== an P>1 + P>2 is 1= State%ent : II : 5n an ellipse$ the su% o! the istances o! a point on the ellipise !ro% the !oci is al&ays constant SECTION / I, 6in-e. Co%#rehension T #e
This section contains " paragraphs. #ase upon each paragraph$ " %ultiple choice questions ha+e to be ans&ere . Each question has ( choices .2/$ .#/$ .C/ an .D/$ out o! &hich ON6Y ONE is correct.

(aragra#h $or !"estions Nos. 0; to 0< &01102E I &"r"3r"/h ,or 4ue )io* No .15 )o 15

> is one o! the !oci o! the ellipse

' 2 y2 + =1 a 2 b2

&ith HOI as centre.

2#

an

CD

are %a*or an %inor a'es

respecti+ely. 5! O> E 6 an the ia%eter o! the incircle o! is 2$ Then ans&er the questions 10$ 16$ 1;/ 10. .a/
0 1" a= $b= 2 2

.b/

a=

1" $ b=0 2 2

.c/

0 1" a= $ b= ( (

. /

a=

1" 0 $ b= ( (

16. eccentricity o! the ellipse is A .a/

12 1"

.b/

2 "

.c/

0 1"

. /

11 12

1;. . 2#/ .CD/ is equal to A .a/ (0

.b/ 00

.c/ 60 &01102E II

. / ;0

&"r"3r"/h ,or 4ue )io* No .18 )o 20 2 ro 2# o! 2= units length &ith its en s H2I on ')a'is an # on the y)a'is is sli ing bet&een the a'es. P is a %arke point on 2# such that 2P E < 2ns&er the questions 1<$ 19$ 2= 1<. The locus o! P is A .a/ .a/
' 2 y2 + =1 1(( 6( ( 9

.b/ .b/

' 2 y2 + =1 6( 1(( 9 (

.c/ .c/

' 2 y2 + =1 20 96 2 "

. / . / . /

'2 y2 + =1 169 1(( 0 " ' 2 + y 2 = (1

19. The eccentricity o! the conic is A 2=. The locus o! the point o! inter section o! perpen icular tangents is A .a/ ' 2 + y 2 = 2== .b/ ' 2 + y 2 = 2=< .c/ ' 2 + y 2 = "1" &01102E III &"r"3r"/h ,or 4ue )io* No .21 )o 23 ' 2 y2 + = 1 is the stan ar ellipse . ie a G b/. 2ns&er the Questions a 2 b2 a 21. I$ the tangent at ( %eets the .ire)tion 9 = in Q an - is .a e$ =/$ then 2ngle P-Q is A e = = .a/ 6= .b/ "= .c/ 9== . / (0= 22. I$ (! is a $o)al )hor.* an. 1 $ 2 are their eccentric angles$ Then + + .a/ cos 1 2 = e cos 1 2 .b/ e cos 1 2 = cos 1 2 2 2 2 2 + + .c/ a cos 1 2 = cos 1 2 . / cos 1 2 = a cos 1 2 2 2 2 2 2". 5! P an Q are en s o! a !ocal chor &ith eccentric angles 1 an 2 respecti+ely$ then 1 e e +1 .a/ tan 1 tan 2 = .b/ cot 1 cot 2 = 2 2 1+ e 2 2 e 1 e +1 e 1 .c/ tan 1 tan 2 = . / cot 1 cot 2 = 2 2 e 1 2 2 e +1

PHYS CS

(ART / II
SECTION / I Straight O45e)ti2e T #e
This section contains 6 %ultiple choice questions. Each question has ( choices .2/$ .#/$ .C/ an .D/$ out o! &hich ON6Y ONE is correct.

2(. 4hich o! the !ollo&ing state%ents is correct !or ther%o%eter. .a/ Co)e!!icient o! cubical e'pansion o! liqui %ust be greater than that o! bulb %aterial .b/ #ulb o! the ther%o%eter is %a e o! a poorly con ucting %aterial .c/ -ole purpose o! %aking &alls o! the bulb thin is to pro+i e %a'i%u% possible space !or liqui . . / 1one o! these. 20. 2 %etal ball i%%erse in alcohol &eighs &1 at == C an & 2 at 0==C. The coe!!icient o! cubical e'pansion o! the %etal is less than that o! alcohol. 5! the ensity o! the %etal is large co%pare to that o! alcohol$ then .a/ &1 G &2 .b/ &1 E &2 .c/ &1 J &2 . / can not be eter%ine 26. T&o ro s one o! alu%inu% an the other %a e o! steel$ ha+ing initial lengths l1 an l2 are

connecte together to !or% a single ro o! length l1 D l2. 5! the length o! each ro increases by the sa%e a%ounts on increasing the te%perature by l= C$ the ratio coe!!icients o! linear e'pansions is gi+en by.
.a/ 1 7 2 .b/ 2 7 1 .c/ l1 in ter%s o! l1 + l2

2 1 . / .1 + 2 / .1 + 2 /

2;. T&o %etal &ires each o! length l an ha+ing the sa%e area o! cross sections are *oine en to

en an !i'e bet&een t&o rigi supports. The istance through &hich the *oint &oul %o+e i! the syste% is coole by te%p HtI .The t&o %etals ha+e coe!!icients o! linear e'pansions 1 $ 2 an young %o ules y1 $ y2/
.a/ lt

( y 2 2 y11 )

y1 + y 2 lt ( y 21 y11 ) .c/ y1 y 2

lt ( y1 2 y 2 1 ) y1 + y 2 lt ( y1 2 y11 ) . / y 2 y1 .b/

2<. T&o bo ies o! i!!erent %aterials but o! equal %ass are heate at uni!or% rate un er i entical con itions !ro% == C . One bo y %elts at 6== C a!ter heating !or 2 %inutes &hile the other %elts at (== C a!ter heating !or ( %inutes. The ratio o! their speci!ic heats is A .a/ 1 A 0 .b/ 1 A " .c/ 1 A ( . /1 A 2 = 29. -tea% at 1== C is passe into 1.1kg o! &ater containe in a calori%eter o! &ater equi+alent =.=2kg at 10= C till the te%perature o! the calori%eter an its contents rises to <== C . The %ass o! the stea% con ense in kg is . latent heat o! +aporiBation o! &ater K 0(= cal 7 g $ speci!ic heat o! &ater 1 cal7g/ .a/ =.1" .b/ =.=60 .c/ =.26 . / =.1"0

SECTION / II M"lti#le Corre)t Answer T #e

This section contains ( %ultiple correct ans&er.s/ type questions. Each question has ( choices .2/$ .#/$ .C/ an .D/$ out o! &hich ONE OR MORE is7are correct.

"=. 2 %etal ro is shape into a ring &ith a s%all gap. 5! this is heate . .a/ The length o! the ro &ill increase .b/ The gap &ill ecrease .c/ The gap &ill increase . / The ia%eter o! the ring &ill increase in the sa%e ratio as the length o! the ro "1. 4hich o! the !ollo&ing state%ents are not true .a/ 6eat is a %acroscopic quantity .b/ 6eat is intrinsic property o! bo y .c/ 6eat is store in a bo y as internal energy . / 6eat is path in epen ent "2. 2 +essel is partly !ille &ith a liqui . Coe!!icient o! cubical e'pansion o! %aterial o! the +essel an liqui are + an l respecti+ely. 5! the syste% is heate then +olu%e "no))"#ie. by the liqui &ill necessarily .a/ increase i! + > l .b/ ecrease i! + < l .c/ re%ains un change i! + = l . / 5ncrease i! + = l "". -o%e &ater at == C place in a large insulate enclosure. The &ater +apour !or%e is pu%pe out continuously. 5! the latent heat o! +apourisation is se+en ti%es the latent heat o! !usion th .a/ ; < o! initial %ass o! &ater !reeBes .b/ 5! 1=kg o! &ater is place in the enclosure$ %ass o! +apor !or%e is 1.20kg. .c/ %ass o! +apor !or%e is in epen ent o! latent heat. . / Data is insu!!icient to arri+e at conclusion SECTION / III Reasoning T #e

( )

This section contains ( reasoning type questions. Each question has ( choices .2/$ .#/$ .C/ an .D/$ out o! &hich ON6Y ONE is correct. CODE
'A+ 'B+ 'C+ 'D+ STATEMENT/0 is Tr"e* STATEMENT/7 is Tr"e8 STATEMENT/7 is a )orre)t e9#lanation $or STATEMENT/0 STATEMENT/0 is Tr"e* STATEMENT/7 is Tr"e8 STATEMENT/7 is NOT a )orre)t e9#lanation $or STATEMENT/0 STATEMENT/0 is Tr"e* STATEMENT/7 is False STATEMENT/0 is False* STATEMENT/7 is Tr"e

"(. 2ssertion .2/A)T&o i entical rectangular strips$ one o! copper an the other o! steel are ri+ete together to !or% a bi%etallic strip. copper > steel the strip ben s &ith steel on con+e' si e upon cooling. ,eason.,/A) Change in length o! copper is greater &ith change in te%perature "0. 2ssertion .2/ A >oo gets cooke !aster in a pressure cooker ,eason .,/ A 4ater boils at a te%perature higher than 1=== at higher pressure . "6. 2ssertion .2/ A 2 bo y .o! coe!!icient o! cubical e'pansion ( b ) / !loating an a !lui o! cubical

e'pansion coe!!icient ( ! ) &oul sink in the !lui at so%e higher te%perature HtI i! ! > 4 ,eason .,/ A #uoyant !orce ecreases &ith increase in te%perature i! ! > 4 ";. 2ssertion.2/ ACalorie is e!ine as the a%ount o! 6eat require to raise te%perature o! 1g o! &ater by 1= C at all te%peratures ,eason .,/ A 6eat require to raise te%perature o! 1g o! &ater by 1= C epen s on the te%perature o! &ater. SECTION / I,

6in-e. Co%#rehension T #e
This section contains " paragraphs. #ase upon each paragraph$ " %ultiple choice questions ha+e to be ans&ere . Each question has ( choices .2/$ .#/$ .C/ an .D/$ out o! &hich ON6Y ONE is correct.

&01102E I &"r"3r"/h ,or 4ue )io* No .38 )o 40 >our ro s 2$ #$ C$ D o! the sa%e length an %aterial but o! i!!erent ra ii r$ r 2$ r " an 2r respecti+ely are hel in parallel bet&een t&o rigi &alls. The te%perature o! all ro s is increase through the sa%e range. 5! the ro s o not ben $ then ans&er the !ollo&ing questions. "<. The stresses in the ro s 2$ #$ C an D are in the ratio A .a/ 1 A 1 A 1 A 1 .b/ 1 A 2 A " A ( .c/ ( A " A 2 A 1 . /(A"A2A1 "9. The !orce on the ro s e'erte by the &all are in the ratio A .a/ 1 A 1 A 1 A 1 .b/ 1 A 2 A " A ( .c/ ( A " A 2 A 1 . /(A"A2A1 (=. The energy store in the ro s ue to elasticity are in the ratio A .a/ 1 A 1 A 1 A 1 .b/ 1 A 2 A " A ( .c/ ( A " A 2 A 1 . /(A"A2A1 &01102E II &"r"3r"/h ,or 4ue )io* No .41 )o 43 2 substance is in the soli !or% at == C . The a%ount o! heat a e to this substance an its te%perature is plotte in the !ollo&ing graph.

5! the relati+e speci!ic heat capacity o! the soli substance is =.0 (1. 4hat is the %ass o! the substance F .a/ =.=1kg .b/ =.=2kg .c/ =.="kg . / =.=(kg (2. The speci!ic latent heat o! the %elting process is A .a/ 1====cal7kg .b/ 2====cal7kg .c/ "==== cal7kg . / (==== cal7kg (". The speci!ic heat o! the substance in the liqui -tate is .a/ 0== cal kg 1k 1 .b/ 6== cal kg 1k 1 .c/ ;== cal kg 1k 1 . / <== cal kg 1k 1 &01102E III &"r"3r"/h ,or 4ue )io* No .44 )o 4% 2n iron ro o! length 1% is %easure using a %eter scale %a e up o! copper at == C . The coe!!icient 6 = 6 o! linear e'pansion !or iron an copper is A i = 12 1= 7 C an c = 1; 1= 7 C ((. The length o! the iron ro %easure by copper scale at "== C is .a/ =.999<0 % .b/ 1.===10% .c/ =.99<0% . / 1one o! these (0. 2ctual increase in length o! ro at "== C is .a/ =."6%% .b/ "6 1=( % .c/ "6 1=0 % . / 1one o (6. L error in the %easure%ent o! the length o! the ro A at "= C .a/ =.10L .b/ =.1L .c/ =.0L . / 1one

CHEM STRY

(ART / III
SECTION / I Straight O45e)ti2e T #e
This section contains 6 %ultiple choice questions. Each question has ( choices .2/$ .#/$ .C/ an .D/$ out o! &hich ON6Y ONE is correct.

(;.

2rrange the !ollo&ing %olecules in the increasing or er o! aci ic nature. 1/ CH "COOH a/ 1 > 2 > " 2/ HCOOH b/ 2 > 1 > " "/ C6 H 0COOH c/ 2 > " > 1 b/ O2 N CH 2 COOH / ( CH " ) " Si CH 2COOH
/ CH "O

/ " >1 > 2

(<.

4hich o! the !ollo&ing is a &eak aci F a/ R2 N + CH 2 COOH c/ ( CH " ) " C CH 2COOH

(9.

Decreasing or er o! basicity !or the !ollo&ing

a/ NH 2

b/ H b/ b > d > c > a

c/ HC C c/ a > c > d > b

a/ a > b > c > d 0=.

/ c>b>a>d

5ncreasing or er o! stability in the !ollo&ing resonance structures a/ HO CH + NH 2 b/ HO CH = NH 2 a/ a > b > c b/ b > c > a c/ HO = CH NH 2 c/ a > c > b / b>a >c

01.

4hich is %ore basic in the !ollo&ingF a/ a/ a b/ b/ b c/ a = b

1 / Cannot be pre icte .

02.

4hich o! the !ollo&ing state%ent is7are correctF

1O2

a/

O6

CCl"

O6

Cl O6

:a or er E 5 G 555 G 55

5
O6 1O2 O6

55
O6

555

O1

b/

1O2

2ci ic nature 5 G 55 G 555

1O2

1O2 5

O21

1O2 55

1O2

555

1O2

162

c/

G
1

basic nature

< OH < F #asic nature / NH 2

SECTION / II M"lti#le Corre)t Answer T #e

This section contains ( %ultiple correct ans&er.s/ type questions. Each question has ( choices .2/$ .#/$ .C/ an .D/$ out o! &hich ONE OR MORE is7are correct.

0".

4hich one o! the !ollo&ing state%ent is7are correctF a/ 2ccor ing to 6yper con*ugation bon length C D < C H b/ D5 in ucti+e e!!ect o! D > H
162 162 .O/

c/

.5/ 61 1 . .55/ 5 5 /

.555/

:b or erA 5 G 55 G 555

/
1 1 6

basicity or er E y G ' GB .y/

.N/

0(.

4hich is the !ollo&ing state%ent is7are correct accor ing to stability a/

<
G

b/

D
c/
Cl

G
Cl
>

O CH " C CH 2 > CH " C = CH 2

O
( H 2 N C NH 2
1 6
1
a)

00.

P
162

NH (

b)

55

555

5M

4hich is7are correct state%ents a/ 5 is %ore basic than 55 c/ 55 is %ore basic than 5$ 555 P 5M 06. 4hich is7are less aci ic than #enBoic aci F a/ CH "COOH b/ 2ll are aro%atic bases / 5n 5M hy rogenIs are aci ic at QaR$ basic at QbR

b/

COOH c/

COOH / H 2O

CH "

SECTION / III Reasoning T #e

NO2

This section contains ( reasoning type questions. Each question has ( choices .2/$ .#/$ .C/ an .D/$ out o! &hich ON6Y ONE is correct.
Co.e
'A+ STATEMENT/0 is Tr"e* STATEMENT/7 is Tr"e8 STATEMENT/7 is a )orre)t e9#lanation $or STATEMENT/0 'B+ STATEMENT/0 is Tr"e* STATEMENT/7 is Tr"e8 STATEMENT/7 is NOT a )orre)t e9#lanation $or STATEMENT/0 'C+ STATEMENT/0 is Tr"e* STATEMENT/7 is False. 'D+ STATEMENT/0 is False* STATEMENT/7 is Tr"e.

0;.

-tate%ent K 5A 2llyl ra ical oes not contain one carbon K carbon single bon an one carbon K carbon ouble bon . -tate%ent K 55A #ecause o! ,esonance$ it contains t&o i entical bon s.

0<.

-tate%ent K 5A
C6"

%ore stable than

-tate%ent K 55A 5n %ethyl benBene hyper con*ugation cannot take place.

O6 COO Et

09.

-tate%ent K 5A Dipole %o%ent

O6

are not equal to Bero

COO Et

-tate%ent K 55A -ubstituents in both ha+e non)linear %o%ents. 6=. -tate%ent K 5A -quaric aci is a strong aci . -tate%ent K 55 A e elocalisation is greater in the syste% hence it can onate O6) group !aster.

SECTION / I, 6in-e. Co%#rehension T #e

This section contains " paragraphs. #ase upon each paragraph$ " %ultiple choice questions ha+e to be ans&ere . Each question has ( choices .2/$ .#/$ .C/ an .D/$ out o! &hich ON6Y ONE is correct.

&01102E I &"r"3r"/h ,or 4ue )io* No .%1 )o %3 #asic nature o! 1)co%poun s epen upon a/ ,esonance e!!ects c/ -teric e!!ects 61. 4hich o! the !ollo&ing &ill ha+e high K b F a/ b/ b/ 6ybri isation / -ol+ent e!!ects

c/

62. .

4hich o! the !ollo&ing &ill ha+e high K b F O ll a/ ll O 16 b/ O ll 16 c/ 16 = / ll = 16

6".

4hich o! the !ollo&ing &ill ha+e high basic natureF 162 162 162 a/ C6" b/ C6" C6" &01102E II c/ /

162

&"r"3r"/h ,or 4ue )io* No .%4 )o %% Electronic e!!ects are %ost i%portant. 5n or er to e'plain stability$ ,eacti+ity$ #on length$ ipole %o%ent etc.$ #ase upon the e!!ects e'plain the !ollo&ingA 6(. 5n &hich o! the !ollo&ing resonance$ in ucti+e an hyper con*ugati+e e!!ects can take place O6 C>" O6 O6 C6" 1O2 a/ b/ c/ / 162 1O2 c'" 1O2 1,2 1O2

60.

4hich o! the !ollo&ing set ha sa%e con*ugate base a/

( Cyano Aniline P ( Nitro Aniline

b/ Pyri ine P pyrrol /

c/ HN = C = O P N C OH 66.

162 16 The !raction o! the charge that e'ist in ortho)nitro phenol$is =.20 P bon length in 22=

R C

162 P

R C

162

( HO C C NO2 ) Calculate the

a/ 1.0D

ipole %o%ent o!!ere by 1O2 group. 5! ipole %o%ent o! O6

group is 1D .2ssu%e presence o! intra 6)bon angle ecrease to 06= (cos 06 = = =.6 ) . b/ 2.(D c/ "D / ".0D

&01102E III &"r"3r"/h ,or 4ue )io* No .%5 )o %6 The e!!ect o! the sol+ent on aci ity sol+ation o! any species ecreases the entropy o! the sol+ent because the sol+ent %olecules beco%e %uch %ore or ere as they surroun %olecules o! the solute.
E'A -ol+ation o! CH "CO2 is stronger the sol+ent$ the sol+ent %olecules beco%e %ore or erly

aroun it. S = !or the ioniBation o! CH "COOH $there!ore$ is negati+e. This %eans that the
TS = ter% in G = = H = TS = %akes an aci )&eakening positi+e contribution to G = $ 5n

!act the TS = ter% contributes %ore to G = than H = . 6ence epen ing upon abo+e !acts
G = !or ioniBation o! CH "COOH is positi+e.

6;.

4hich o! the !ollo&ing state%ent is 7 are in polar protic sol+ent a/ The charge trans!er by anion to&ar s sol+ent is basicity b/ The charge that re%ainIs a!ter sol+ation is calle nucleophilicity c/ #asicity is kinetic property / 1ucleophilicity is kinetic property
8nsature organic Co%poun O .organic carbocation /D > ( #ase ) -ol+ent

6<.

>or &hich o! the reaction ? = is %ore negati+e &ith respect to pro uct.
H O a/ X g + F
2

Acetic acid b/ X g + F CS / Xg + F
2

NH c/ X g + F
"

69.

Consi er the reaction

C6"

C6" 6

CH " C O H + H O + H O + H H "C C O+ H + H 2O
C6" 6 C6"

A
A B H = f kJ A = 2(.2; B = 20.(( S = J .K 1 2(6.( 202."

4hat is the co%position o! the equilibriu% %i'ture at 20= C . a/ L A = 2".6 b/ L B = 2".6 c/ L A = 0= / L B = (6

&0&E7 1ETTE7
Mr. G.S.N. M"rth Mr. Mano5 B"%ar Mr. Brishna Bishore

: 81&-79 (0: :0!&;1)

@A1@07<011 @1@0;C@@1; @@07&1&CCC

MAT?S (?YSICS C?EMISTRY