Soparaion and Enrchmoni ol Baro Earih Elomoni- n Pho-phorio n

Xnhua Zhjn Cuzhou

!
Zhan, |o
1!
Shun Chuanmn
2
Yan, Cuolon,
1
Xo Io
1
1. 1ineo/ Indus/y Co//ege Cui:/ou |nicesi/y Cuiyong 550003 C/ino 2. Ceoscience Co//ege C/engdu |ni-
cesi/y C/engdu 610000 C/ino
Abstrat 1ho pho-phorio oro--dopo-i- rch n raro oarih olomoni- BEE n Zhjn Xnhua Cuzhuo occur- n iho oarly
Camhran Ho-hucun and ai iho hoiiom pari ol on,zhu- -ia,o iho uppor layor ol pho-phorio- holon,n, io Yan,z
-iraium -ocion. 1ho lvn, croaiuro -crap- wa- provod ox-ioni n dolomic-pho-phorio- hy oxpormoni- 1ho BEE could
ho oxiraciod io provdo iho worihy daia lor iho lurihor u-n,. Adopin, iho H^U
3
io oxiraci BEE ihrou,h iho on oxchan,o
moihod iho BEE rocovory raio could ho roachod 85. 44% havn, corian roloronco valuo.
Key words raro oarih olomoni- pho-phorio- -oparaion and onrchmoni
CLC number U614. 33 Doument ode A Artile ID 1002 0721 2006 0413 02
1ho pho-phorio oro--dopo-i- rch n BEE n iho
Zh|n XnHua CuZhuo occur- n iho oarly Camhran
Ho-hucun -ia,o and ai iho hoiiom pari ol on,zhu-
-ia,o. 1ho po-ion ol ih- ,oolo,cal -iruciuro 1ho
uppor layor ol iho pho-phorio - ai ond ol iho -ouih-
wo-i ol iho mddlo apophy-- ol CuZhou holon,n, io
Yan,z -iraium -ocion.
1ho carhonnaio-pho-phorio- coniann, BEE aro
,ray-h hlack or ,ray or ,ray-h yollow. 1ho pho-phor-
io- can ho dvdod nio iwo pho-phaio-hoarn, rock
iypo- carhonaio-pho-phorio iypo rch ol iho lvn,
croaiuro -crap- and -lcoou--pho-phorio a--orimoni
iypo. 1ho lormor - moro popular.
1ho ioxiuro ol pho-phorio- could ho cla--lod n-
io ihroo iypo- collodal collophano-mcrio ioxiuro
,ranular ioxiuro and cry-ial al,al ioxiuro. 1ho hocla--
ic ioxiuro - iho mo-i mporiani and common ioxiuro ol
all. 1ho ordnary mnoral- accompanod lvn,- aro do-
lomi calcio quariz clay mnoral -phalorio ana-
ia-o and pyrio-
1
. 1ho ro-uli- ol iho X-analy-- -how
ihai iho pho-phaio holon,- io an-omorph -oro- ol car-
hanaio-lluorapaiio
2
pho-phaio- n iho lorm ol iho
crypio-cry-iallno non-cry-iallno and collophano aro
-uh-iiuiod hy lvn,-cla-ic -odmoni cla-ic-crypio-
cry-iallno and non-cry-iallno.
1 Expormonial
A- ho-do- rock pho-phaio powdor iho moro
valuahlo n rock pho-phaio coniann, BEE ha- a h,h
-iora,o capaciy and could ho achovod a comprohon-
-vo uilzaion. Snco i- conioni - ioo low wo havo io
choo-o iho lollown, io-i -chomo io -iudy iho -oparaion
and onrchmoni ol iho BEE ro,ardn, io iho proco-- ol
chomcal produci- ol pho-phaio n ndu-iry ol Cuzhou
a- major projoci pro,ro--n, modol oxpormoni- ol pro-
ducn, io ohian produci- n proco-- ihon don, iho
oxiracion oxpormoni ol BEE. In ih- way wo iry io a-
chovo iho opimum -chomo lor rocovorn, BEE.
1. 1 Samplo-
1ho -amplo- u-od n ih- papor woro cho-on lrom
dolomic pho-phorio whch had corian onrchmoni
n BEE. 0. 01% ~0. 1%.
1. 2 Analy-- ro-uli- ol mnoral olomoni
1ho chomcal analy-- ro-uli- ol rou,h oro aro
-hown n 1ahlo 1.
In ordor io ho ropro-oniaivo -amplo- P
0
~ P
6
woro cho-on n iho -amo way. 1ho rou,h oro holon,-
io dolomic pho-phorio coniann, iho lvn, croaiuro
-crap- whch ha- a -iora,o capaciy ol 92% n all
pho-phorio.
1. 3 Expormonial condion-
1ho oxpormoni adopiod H^U
3
io oxiraci iho lq -
JOURNA OF RARE EARTHS
Va/. 24 Spec. Issae Dec. 2006 p. 413

! Reeived date 2006 07 10 revised date 2006 09 10
Foundation item Projoci -upporiod hy iho ^aional ^aiural Sconco Ioundaion ol Chna 40372047 50164001
Biography Zhan, |o 1955 Halo Ha-ior Prolo--or
! Corresponding author E-mal zhj59106C163. com

1ahlo 1 Anly-i- daia % ol con-iani olomoni- in
pho-phoriio coniainin, BEE
!
Samplo- P
0
P
1
P
2
P
3
P
5
P
6
SiU
2
53. 42 4. 11 2. 77 10. 24 5. 60 5. 43
CaU 1. 64 48. 19 45. 82 31. 76 38. 93 38. 26
H,U 1. 18 2. 68 5. 34 14. 40 10. 16 11. 99
P
2
U
5
0. 33 29. 93 25. 16 3. 18 10. 58 10. 22
Io
2
U
3
8. 41 1. 52 1. 12 1. 50 0. 91 1. 12
Al
2
U
3
4. 55 1. 29 0. 88 0. 68 1. 24 0. 72
CU
2
0. 49 7. 73 15. 52 36. 74 30. 60 31. 00
K
2
U 2. 88 0. 36 0. 17 0. 23 0. 66 0. 26
^a
2
U 0. 12 0. 16 0. 13 0. 06 0. 06 0. 18
BEE
2
U
3
0. 13 0. 13 0. 12 0. 016 0. 066 0. 05
! P
0
oxidizod pho-phoriio P
1
~ P
6
pho-phoriio- coniainin, livin,
croaiuro -crap- and BEE
uid and ii carriod on undor iho normal iomporaiuro.
1ho -amplo- aro olion lamollar -iruciuro hui iho -am-
plo- coniainin, livin, croaiuro -crap- and BEE woro
normally powdor.
1. 4 Exporimonial proco--
Alior iakin, iho powdor ol pho-phoriio H^U
3
wa- addod and iho roaciion la-iod lor 4 h ihon 2000
ml waior wa- inlu-od inio ihom and liliraiod. Alior iho
ro-iduo had hoon waiorod addod ahoui 400 ml K^U
3
dopondin, on iho conioni ol lluorin inio ii and
churnod ii up and laid a-ido lor 4 h ihon liliraiod. 1o
oliminaio PU
4
3
zirconium niohium and ianialum
proviou- -oluiion could ho ionic oxchan,od ai 0. 5 ~
0. 8 ml min
1
. Alior ihai oluiod iho -oluiion u-in,
100 ml waior ihon ai iho -amo -pood u-in, 200 ml
wa-hin, liquid ol Y| io oliminaio Io Al Hn Ca
H, and I hy ion oxchan,o proco--. I-od wa-hin, liq-
uid io oluio iho BEE collociion and ihon addod
-iron,or ^H
4
UH inio ii io mako iho BEE dopo-ii. Al-
ior hoin, liliraiod wiih lilior papor romovod iho dopo-
-iiion and iho lilior papor inio con-iani woi,hi crucihlo
ihon hurnod ai 850 ' io con-iani woi,hi. 1ho ro-uli-
aro ihai BEE ha- hoon roclaimod 1. 3671 , in all
BEE in ,round pho-phoriio i- 1. 60 , and ii- rocovory
raio i- 85. 44% 1ahlo 2. 1hi- i- al-o iho hi,ho-i
rocovory raio in all oxporimoni-.
1ahlo 2 Exiraciion raio ol BEE u-in, H^U
3
a- oxiraci
Samplo-
!
a h c d
Voi,hi ol -amplo- , 10 10 10 10
Voi,hi ol BEE in -amplo- m, 16 16 16 16
H^U
3
ml 20 ml H^U
3
+20 ml H
2
U 15 ml H^U
3
+20 ml H
2
U 20 ml H^U
3
+10 ml H
2
U 10 ml H^U
3
+10 ml H
2
U
Porconi ol BEE in -odimoni % 1. 367 0. 659 0. 371 0. 114
Voi,hi ol BEE in -odimoni m, 13. 67 6. 59 3. 71 1. 14
Bocovory raio % 85. 44 41. 19 23. 19 7. 12
! Exiraci condiiion- normal iomporaiuro pH =2. 5. ryin, iomporaiuro -amplo- a and h ai 850 ' c and d ai 105 '
2 Conclu-ion-
1. olo-pho-phoriio- coniainin, livin, croaiuro
-crap- havo hoon provod hy ahovo oxporimoni- and iho
BE olomoni- could ho oxiraciod lor iho lurihor u-in,.
2. Adopiin, iho H^U
3
io oxiraci iho liquid mai-
cho- hy iho ion oxchan,o moihod iho rocovory raio ol
iho BEE can ho roachod 85. 44% havin, coriain rol-
oronco valuo.
3. 1ho valuo in rocovory and u-o ol iho BEE aro
docidod hy iho proco-- ol rocovory and muliia-poci do-
concy do,roo ol rou,h oro.
!"#"$"%&"
1

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2

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6

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7

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8

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9

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10

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4 1 4

JOURNA OF RARE EARTHS Va/. 24 Spec. Issae Dec. 2006