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This publication is published as an aid to cooling tower purchasers and designers. CT! makes no warranty of fitness for particular purpose or merchantability. The reproduction of any part of this or any other CT! code or standard is a violation of federal Law.
This publication is published as an aid to cooling tower purchasers and designers. CT! makes no warranty of fitness for particular purpose or merchantability. The reproduction of any part of this or any other CT! code or standard is a violation of federal Law.
This publication is published as an aid to cooling tower purchasers and designers. CT! makes no warranty of fitness for particular purpose or merchantability. The reproduction of any part of this or any other CT! code or standard is a violation of federal Law.
July 2008 WTG-155(08) FOREWORD This Cooling Technology Institute (CTI) publication is published as an aid to cooling tower purchasers and designers. It may be used by anyone desiring to do so, and efforts have been made by CT! to assure the accuracy and reliability of the data contained herein. However, CT! makes no warranty of fitness for particular purpose or merchantability nor any other warranty expressed, implied or statutory. In no event shall CT! be liable or responsible for Incidental, Consequential or Commercial losses or damage of any kind resulting from this publication's use; or violation of any federal, state, or municipal regulation with which this publication may conflict or for the infringement of any patent resulting from the use of this publication. All CT! codes and standards are copyrighted with all rights reserved to CT!. The reproduction of any part of this or any other CT! code or standard is a violation of Federal Law. One must recognize and appreciate commitment by a number of volunteer members who donate their time to develop and update CT! codes and standards. The monies spent for code development, administrative staff support and publication are essential and constitute a substantial drain on CTJ. The purchase price of these documents helps to offset these costs. Reproduction and distribution by others, in addition to being unethical, undermines this system and constitutes a further financial drain on CT!. When copies are needed, you are requested to call or write the Cooling Technology Institute, P .0. Box 73383, Houston, Texas 77273, (281) 583-4087. Please request that your associates buy the required codes and standards rather than copy them. Your cooperation in this matter is greatly appreciated. Nothing contained herein is to be construed as granting any right for the manufacture, sale or use in connection with any method, apparatus, or product covered by letters patent, nor as insuring anyone against liability for infringement of letters patent. This guideline document summarizes the best current state of knowledge regarding the specific subject. This document represents a consensus of those individual members who have reviewed this document, its scope and provisions. It is intended to aid all users or potential users of cooling towers. Approved by the eT! Executive Board. This document has been reviewed and approved as part ofCTl's Five Year Review Cycle. This document is again subject to review in 2013. Copyright 2008 Approved by the CT! Executive Board by Cooling Technology Institute Printed in U .S.A. 2 WTG-155(08) Table of Content Section/Title 1. 2. 3. Introduction Mission Statement What is Internal Plant Cooling Water Reuse? Why Reuse? The Steps to an Internal Plant Water Reuse Project Internal Plant Cooling Water Reuse Audit Process Page 5 5 5 5 5 7 4. Physical Processes, Chemical Processes, and Water Component Measurement 8 Physical and Chemical Processes 9 5. Membrane Filtration Other Processes and Procedures Analytical Instrumentation for Monitoring Reuse Water Quality Turbidity and Suspended Solids Impact of Reuse Waters on Cooling System Materials of Construction, Water Chemistry and Chemical Control Cooling System Materials Under Consideration Cooling System Heat Exchangers Considerations for Cooling Tower Fill Cooling System Chemistry and Control 6. Summary Appendices A Water Chemistry Evaluation with Software Tools B References From Cooling Technology Institute Publications Figures and Tables Fig. 1 Internal Plant Cooling Water Reuse Design Process Flow Tab. I Tab. 2 Example Ion Pairs Used to Estimate Free Ion Concentrations 3 11 12 13 14 15 15 15 15 15 15 16 16 19 6 17 18 4 Internal Plant Cooling Water Reuse SECTION 1. INTRODUCTION Mission Statement The purpose of this document is to provide general guidelines to plant owners and operators for water conservation through internal plant cooling water reuse. What is Internal Plant Cooling Water Reuse? Internal plant water reuse is the use of any previously used water stream existing within the plant facilities, with or without water treatment, in water consuming units, such as evaporative cooling systems, boilers, and/or process operations. When such a water source is used as makeup water for the cooling system, it is Cooling Water Reuse. The main objective of water reuse is to reduce fresh water intake and wastewater discharge. Why Reuse? Industry has historically given water reuse projects low priority for a number of reasons. Most important of these is that new plants have typically been sited near abundant and inexpensive sources of fresh water. Also, the logistics of retrofitting plant piping to take advantage of reuse opportunities are often complex and expensive. 5 In the past few years several changes have taken place that make water reuse more attractive: Increased regulatory activity around treatment of waste water before discharge Curtailed good quality water supply to industry to meet higher priority drinking water needs Unusual weather patterns which have reduced water supplies drastically in some areas for several years Rapid escalation of costs for developing new water supplies and expanding existing supplies Deterioration or contamination of existing water supplies in heavily industrialized areas Industry can no longer assume that good quality water will always be available in unlimited quantities. It is likely that industry will invest more capital and spend more operating dollars for water in the future. As this happens the economic justification for water reuse will increase. SECTION 2. THE STEPS TO AN INTERNAL PLANT WATER REUSE PROJECT A flowsheet depicting a typical water reuse project process is shown in Figure I: Internal Plant Cooling Water Reuse Design Process Flow \ W rite an Initial goal statement Evaluate the Reuse Project I ... Prepare a plant water balance I ~ Identify and survey all water streams. Including water generators Identify water users and characterize their water requirements Identify the availability and quantity of use for each selection L. I ~ ~ Identify water quantity and qUBI.'.'.Y and reuse potential Begin to choose the water reuse plan by developing reuse scenarios. [: etermine the potential reuse cases Evaluate the change in waslewater Review goals Review treatment and distribution costs [-ReView eionomlCS /' Can goals be met within the budget? Ves No Refine all projections and go forward Determine the effectIveness and the costs/savings ~ Continue 1------' Stop ) Figure 1 6 1 Document the 1 L decision J Like any process modification made within an operating plant, every water reuse plan must be tecbnologically feasible and economically justified. A combined engineering and economic evaluation of each proposal should proceed as follows: Develop the concept showing how the reuse can be achieved o Estimate the investment required and the costs involved with the proposed plan Compare the proposal against alternative course of action (or inaction) Choose the best alternative based on a common measure of profitability, such as net return on investment or net present value When in doubt on how to proceed with a project, refer to your corporate project implementation guidelines General Reuse Project Guidelines Before proposals can be made to save water, one must know in as much detail as possible, where and how water is currently being used on the site. If the site has critical water issues that may impact future continuity of operation, it is essential to conduct a site water balance. This entails determining all site water uses down to the 5-10 gpm range. Most water reuse projects will not require this level of detail, but the more data that is available the more likely that the reuse project will be successful. Along with the quantity of the water being used on the site, one must also know the quality (degree of contamination) of all the water streams. Streams that are highly contaminated can be eliminated from further consideration. Some of the common sources of water for reuse in a typical industrial plant are: Once-through cooling water (water that is pumped from its source through one set of heat exchangers before being discharged). Wastewater from water treatment equipment (filter backwash, softener rinse, reverse osmosis unit reject, etc.) Biological wastewater treatment plant effluent o Process condensates o Captured stonnwater A few examples of reuse opportunities are: Replacing once through water use with a closed loop chilled water system or an open recirculating cooling tower system 7 Using reject from a reverse osmosis unit (where the makeup has been pre-softened) to supplement boiler feedwater Using biotreater effluent as makeup to a cooling tower system There are, of course, many more options to consider. Through careful analysis of the water balance, combined with a feel for process needs and limitations, a logical network of interconnecting water use and reuse systems can be developed. No matter what kind or how much water reuse is proposed, it is almost certain that additional treatment of the water will be required at some point in the system. This could take place at the wastewater discharge from a specific user, in the recycle water loop, or, at final waste treatment. Making sure the proper treatment options are selected (see Section 4) is the most important step in providing a working water reuse system. Some of the more important items to consider when reviewing treatment options are: Can concentrated wastes be isolated and treated at the source? Will the effluent be compatible to existing final waste treatment processes and be able to meet existing discharge permit limits? Can dependable, accepted waste treatment unit operations be used, or, will more sophisticated or less proven technology be called for? Will additional chemical treatment be necessary to reduce corrosion, scaling, or fouling tendencies in the recycle system? How will the solid wastes generated in the recycle/waste treatment process be handled? Disposed of? Recovered? A water/wastewater treatment consultant (along with your current water treatment chemical supplier) can assist in selecting the best treatment programs and in developing proposed process flowsheets. At this point of the study, enough data should be in hand to proceed with the evaluation of the proposed water reuse alternatives according to your corporate project guidelines. 3. INTERNAL PLANT COOLING WATER REUSE AUDIT PROCESS It is important to maintain a water reuse program through careful monitoring and control. Although operating areas must continue to be responsible for their own water consumption and wastewater discharge, a specific person or plant group should be given site monitoring and control authority. Deviations in normal water use patterns should be investigated as soon as they appear. New water use requirements should be analyzed thoroughly using the same criteria set forth in the original conservation program. SECTION 4. PHYSICAL PROCESSES, CHEMICAL PROCESSES, AND WATER COMPONENT MEASUREMENT When used water requires treatment before reuse, physical and chemical treatment processes can prepare the water for reuse. The following table lists the processes used and the types of contaminants each process treats. After the table each process is discussed and explained. Discussions of types of analytical instrumentation for monitoring the reused water quality follow the discussions of the processes. Physical Water Component or Contaminant Removed Or Debris Suspended Dissolved Macro- Oxidiz- Chemical Process Solids Solids molecules able . Material Mechanical screening X Filtration: sand, X multimedia and other Centrifugal separation X Clarification: X conventional, Lamella, and tube settler Lime softening X Calcium, Magnesium, Phosphate, some silica, others Granulated activated X Some carbon Secondary Manganese Greensand X Iron and Secondary Manganese and H,S Binn X Iron and Secondary Manganese Ion exchange X X Secondary Microfiltration X X Secondary Ultrafiltration X Nanofiltration Some X Reverse osmosis X X Oxidation X Biological treatments: X Some Some activated sludge, Secondary trickling filters, others Degasification/ Air HCO,' with pH Stripping adjustment API, Oil/water or , physical separation 8 Organics . Some X Others Some Some Some Some Some X Some X Physical and Chemical Processes Nfecha1lical Screening Mechanical Screening is a physical process that removes debris, such as rocks and other large objects before they can clog process equipment or any other water service in the plant. Gravity Sand Filters The most basic of sand filters, gravity filters utilize existing head pressure and distributes the flow evenly through a porous media bed consisting usually of anthracite for bulk solids removal of larger particles and silica sand for polishing. The inlet total suspended solids (TSS) loading and required emuent quality dictate the flow rate per square foot of surface area. The service is typically 3-5 gallons per minute (gpm) per square foot of media surface area with 20- micron efficiency for raw water treatment. Backwash water is collected in a storage compartment above the media bed. Backwash cycles are initiated by head loss. Flow is reversed, eliminating the need for a pressurized backwash supply. There are several design variations, but the basic concept remains similar. Conti1l1l0llS Cleaning Sand Filters This is a type of gravity filter that differs from conventional gravity filters mentioned above. These filters capture contaminants continuously from the sand media. Both the upflow and downflow versions operate with the same basic principle. The contaminated sand media is air lifted tilrough a dedicated sparger pipe creating a scrubbing action. The pipe discharges into a wash box where final separation occurs, Waste goes over an internal weir to drain and the cleaned sand is returned to the media. Pressure Sand Filters Selected silica sand filters are tile most economical effective method of efficiently removing sediment from water. Garnet or gravel, graded for the intended use of the filter supports the sand. There is very little particulate penetration of the media bed since there is usually one layer of sand media. Thus it is more of a surface filter rather than a deptil filter and is more susceptible to solids loading and thus can backwash frequently. Typical flow rates are 5-8 gpm per square foot of media surface area with 20 micron nominal efficiency. 9 Backwash cycles are initiated either manually or by an automated pressure differential sensor with a back up timer. Backwash flow rates range from 150-200% of service flow rates for 10-15 minutes. Pressure Multimedia Sand Filters Multimedia filters usually contain two or more types of media structured with coarse media, such as anthracite, at the top to trap larger particles, with successively smaller media graded lower to capture smaller particles. Multi-graded gravel and garnet support the bed. The result is a highly efficient depth filter because particulate removal takes place throughout the entire bed depth. Efficiency is moderate for 10 micron sized particles and good for 20 micron sized particles at flow rates from 8-12 gallons per minute per square foot of surface area. Variations depend on the quality of influent and the desired effluent quality Backwash is initiated either manually or by an automatic differential pressure sensor with a back up timer. Backwash flow rates need to be 100-150% of service flow rate for 15-20 minutes. High Efficiency Sand Filters These filters utilize a variety of flow mechanisms to create centrifugal and turbulent forces to allow for the utilization of fine sand, 0.2mm), for filtration. These flow mechanisms provide separation of particulate in the water above the fine sand bed and produce a scrubbing effect on the sand surface. The result is that the fine sand surface limits the flow of particulate 0.5 micron and larger and then the turbulence above the bed removes the particles from the sand surface. The particles removed from the filter bed by the turbulence are stored on the filter tank surfaces and low turbulence areas by centrifugal force or natural migration from high to low turbulence. Service flow rates are in the range of 15-20 gpm per square foot of filtration surface area. Since there is minimal deptil penetration of particulate, backwash flow rates are usually 50% of the filter service throughput and the backwash time ranges from 5 to 8 minutes. Backwash initiation results from exceeding the capacity of cell wall and low turbulence storage areas. When these storage capacities are exceeded the turbulent water above the bed becomes saturated with particulate that limits the ability of the turbulence to maintain tile cleanliness of the sand surface. As a result, the pressure differential increases rapidly signaling the need for backwash. Since backwasb frequency is related to particle loading in the water above the filter bed, high TSS levels in waters to be filtered can limit the capabilities of this type of filtration. Centrifugal Separation Centrifugal Separation uses a centrifuge that spins the water at a high speed. Thls causes separation of the solids and the water portion. The solids are recovered and removed and the clean water is used for plant purposes or further processing. Clarification Clarification, sometimes called sedimentation, is the removal by gravity of settleable solids in water. The solids include sand, grit, silt, chemical precipitants, pollutants, floc, and other settable solids. Commonly, synthetic pOlyelectrolytes are added to aid in the settling process. Lamella Clarifiers Lamella sedimentation separates suspended solids from water by directing flow between a TSS removal there is the additional partial reduction of calcium, magnesium, ferrous iron, alkalinity, total dissolved solids and carbon dioxide. Some moderate reduction in silica may also be obtained. The addition of lime reduces these constituents. The metal ions are removed by precipitation mainly as hydroxides and carbonates. Hot process softening occurs at temperatures at or above 212"F (IOO"C) in conjunction with filtration and ion exchange. Its main advantage over cold process softening is that it can significantly further reduce silica (particularly with dolomitic lime or magnesium bydroxide use) and also metal ion concentration in solution due to the decreased solubility of precipitated metal salts. For this reason, it is usually used as a boiler feed water preparation process. Granulated Activated Carbon Granulated activated carbon (GAC) is made from natural substances such as coconut shells, coal, wood, p e ~ etc. activated by selective oxidation with steam at elevated temperatures. The media has a high absorbency capacity for removing chlorine, organics, tannins, color and objectionable taste and odors from drinking water. There are approximately 150 different 10 series of inclined plates (lamellae) spaced about 2 inches apart at a 55 incline that is equivalent to their horizontal projection. The projected effective settling area (PESA) is equal to the sum of the projected area of each plate. The coagulated stream enters the plate chamber longitudinally near the bottom section of the plates and flows upward between them. As the stream flows upward, solids agglomerate, collect and settle downward to a collection hopper without impeding the continuous incoming flow of raw water. A portion of the collected sludge can be pumped to the attached chemical mixing chamber for solids seeding when turbidity levels are low. The effluent guarantee is usually 10 NTU, with 5 NTU typical performance. There are no moving parts and the compact design enables an installation footprint of approximately 1/10"' the area of a conventional round clarifier Lime Softening Lime softening can include both cold process softening and hot process softening. Cold process softening occurs at ambient temperatures and is often considered to be one step beyond clarification because in addition to types available. The choice depends on tlle application. Although the media will capture sediment, it is not intended for this use and should be preceded by a sediment filter if turbidity is a problem. However, periodic backwashing is recommended to keep the media clean and to protect its absorbency. Factors such as designed purpose, temperature, pH, and cblorine content, dictate the media type, depth and surface area requirements. The media's life expectancy is determined by the absorbency capacity of the contaminant. GAC can only be regenerated off site. Manganese Greensolld Greensand media, a naturally occurring, mined product, is manganese dioxide coated for excellent removal of dissolved iron and manganese as well as hydrogen sulfide. As the contaminated water passes through the media bed, the iron and manganese are oxidized into a filterable precipitate and retained by the media. Periodic backwashing and rinsing is required for media cleaning. Regeneration is required to restore the oxidizing ability of the media. Regeneration is achieved by using potassium permanganate either on a batch basis or continuously to avoid downtime. Birm Binn is a manufactured media. It is a very effective and economical media used in the removal of dissolved iron and manganese from raw water. However, in order to be effective there must be a dissolved oxygen (D.O.) content equal to or greater than 15% of the iron and manganese content. As a general rule of thumh the pH must be 6.8 or higher for iron removal and between 8.0 and 9.0 for manganese removal. Binn acts as an insoluble catalyst to enbance the reaction between the D.O. and iron compounds. The media is not consumed in the removal process; therefore, there is no need for external chemical regeneration. Periodic backwashing is required similar to sand filters. [011 Exchange Ion Exchange is the process of exchanging the more desirable ions for the less desirable ones. Ion exchange media is composed of solid and insoluble high molecular weight polyelectrolytes, which exchange the mobile ions for other ions of equal charge from the surrounding water environment. The ion exchange process is a batch process with reversible reactions. Currently, the most widely used modem ion exchangers are synthetic organic materials called ion exchange resins. The ion exchange resins are defmed as cation exchangers or anionic exchangers. A cationic exchanger is usually in the hydrogen (H') or sodium (Na"') fonn in which the H+ or ti,e Na + is exchanged for the undesirable cations such as Ca 2 + or Mg2+. Anionic exchangers exchange OH" and HCO; for the undesirable anions such as SO'" and cr. When a cation exchanger in the Na + form only is employed, it is called "water softening". A mixed bed exchanger uses both types of resins in one vessel. If the resins are in the Wand the OH fonn, pure water is produced. When the resins have been totally exchanged with the undesirable ions, they are "regenerated" to restore the original activity of the resin. The solution used in this process is called a "regenerant". The ion exchange resins are then rinsed of the regenerant solution and put back into service. Another part of the operating cycle of ion exchange resins is called the backwash. In this process, water flow is reversed in order to expand and clean the bed before the regeneration process. I I Membrane Filtration Microjillralioll The type of membrane filtration that a facility chooses depends on the size of the contaminants that are to be removed. It is a function of the pore size rating of the membrane as to whether micro filtration, ultrafiltration, nanofiltration or hyperfiltration (reverse osmosis) is chosen. Microfiltration, which comes in two common forms, full-flow filtration and cross-flow filtration, will usually remove colloidal particles, but not dissolved solids. Full-flow filtration means that you have one flow in and one flow out, with all the flow passing through the filter medium. An example of this type of filtration is a cartridge filter where the feed water enters the filter, passes through the filtering material and exits. The particles that are too large to pass through the pores of the filtering material are trapped either on the surface or in the filtering material. These entrapped particles can be removed by backwashing or by replacing the cartridge filter. The other fonn of filtration is cross-flow filtration. Here you have one flow in (feed water) and two flows out (permeate or filtrate and concentrate). In cross-flow filtration the feed water enters the filter and passes across the surface of the membrane. Pressure forces a portion of the feed water through the membrane, which exits the filter as permeate. The remainder of the feed water and contaminates exit the filter as concentrate. Microfiltration wiII generally reject particles including colloids down to O. I to 1.0 microns in size, but will not reject any dissolved particles. Though it is usually not a factor, micro filtration will also reject substances with a molecular weight above 200,000. UltrafiltrationUltrafiltration is another fonn of membrane filtration that generally uses cross- flow filtration to separate different liquids or contaminants. Ultrafiltration will generally reject particles including colloids down to 0.0 I to O. I microns. It essentially rejects all suspended particles and some dissolved compounds (mainly organic). The efficiency for removal of these materials is dependent on the molecular weight cutoff rating of the membrane. The molecular weight cutoff is a rating given to ultrafiltration filters to indicate the minimum molecular weight that the membrane wiII reject. Therefore, a filter with a high molecular weight cutoff wiII reject all suspended particles but wiII not reject any dissolved substances. A filter with a low molecular weight cutoff, for example 1,000, will still reject all suspended particles but will begin to reject dissolved molecules such as large organic compounds. Membranes are commonly installed in pressure vessels and require periodic cleaning, Backwashable UF membranes are now being used. The backwashable membranes are constructed of hollow fibers or spiral wound cellulose acetate materials. They can be installed in-line in pressurized vessels or submerged in an atmospheric container with a vacuum pump creating flow. Nallofiitratioll Nanofiltration is the third classification of membrane filtration that separates liquids, suspended particles and dissolved solids. Nanofiltration will not filter particles or molecules as small as reverse osmosis does, but it requires only about half the pressure and energy to perform the separation. Nanofiltration is a cross-flow filtration that rejects all suspended particles and dissolved solids down to around 0.001 microns (1 nanometer) in size. This includes things such as sugars, bacteria, proteins and dyes. It also does a good job of rejecting uncharged compounds with molecular weights generally greater than 250. Nanofiltration will generally reject douhle and triple charged ions, such as scale forming calcium and magnesium, hence the reason they are sometimes referred to as softening membranes. Reverse Osmosis or Hyperjiitralioll Reverse Osmosis is the ultimate membrane filtration technique used when essentially all suspended particles and most dissolved solids need to be removed from a water source. This system will reject uncharged compounds with molecular weights greater than 100 to 150 and generally rejects 95 to 99 per cent of all dissolved solids. Reverse osmosis is a cross- flow filtration process that uses a high-pressure pump to force water through a semi-permeahle memhrane. The water forced through the membrane is called the product or permeate While the water flowing across the membrane surface and exiting the element is called the reject or concentrate. The reject water contains the concentrated dissolved solids while the permeate has a much lower level of dissolved solids. 12 The semi-permeable membranes used in RO systems are either cellulose acetate (CA) or thin film composites (TFC). Cellulose acetate membranes are more expensive than thin film composite membranes, but because they are chlorine tolerant, they are less likely to experience microbiological problems. However, the thin film composite membranes are more commonly used due to lower pressure requirements, higher rejection rates and wider pH operating ranges. Reverse osmosis membranes require good feed water, usually including pre-filtration to minimize fouling problems. Microbiological growth, s l ~ colloids and other suspended particles and metals can foul the membrane elements. They can also be subject to scaling due to the concentration of dissolved solids in the feed water. Other Processes and Procedures OxidizersOxidizing agents are used to control microbiological growth in cooling waters. Such agents can also be utilized to oxidize certain contaminants in used water for ultimate reuse in cooling systems. The contaminants can include soluble iron, ammonia, phenols, and other organics, etc. The choice of an oxidizing agent depends upon the particular contaminants present in the reuse water. Chlorine and alteroative chlorine donors, such as sodium hypochlorite (bleach), are relatively inexpensive and an effective means of oxidizing many contaminants. Soluble iron, for example, is readily oxidized to iron oxides through this process. Ammonia can also be oxidized to nitrogen with this chemistry. One of the potential disadvantages of chlorine chemistry is the formation of environmentally harmful chlorinated organics, such as trihalornethanes. Additionally, the effectiveness as a microbiocide changes with pH, requiring more chlorine to perform the same microbial control as pH rises. Bromine or bromide and chlorine are sometimes used to extend oxidation control into elevated pH ranges. Chlorine dioxide is a relatively selective oxidant and can be effectively used for microbial control as well as the destruction of phenols and other special applications. Chlorine dioxide is applied through the use of an on-site generator, which mixes the dissolved gas in the fluid stream Chlorine dioxide's effectiveness as a microbiocide is pH independent. Chlorine dioxide does not react readily with most organic compounds, and not at all with ammonia. Ozone is another oxidant that is non-persistent and has higher demands because of its higher reactivity. The application of ultraviolet (UV) light can also be used in certain waters to control microbiological popnlations. Biological/rea/mell// Trickle Fil/ra/ioll alld Anaerobic Digestion There are various biological systems that are used by industrial plants to treat water. Conventional activated sludge systems use microorganisms to digest the sludge and produce a usable supernatant. Other variations of the process involve the removal of the ammonia and liberation of nitrogen - nitrification and denitrification. These processes involve zones of varying degree of aeration called aerobic, anaerobic or anoxic zones to preferentially select certain microorganisms to achieve the appropriate nutrient removal. Trickling filters are another treatment approach that has been in use for nearly 100 years. A trickling filter is an attached growth, biological process that uses an inert media to attract microorganisms, which fonn a film on the media surface. The microorganism population in a trickling filter consists of aerobic, anaerobic, and facultative bacteria, fungi, algae, and protozoans. Fungi are important in industrial wastewater treatment when the pH is low. Degasijica/ioll/Air S/rippillg The presence of CO, in water presents possible effects due to its chemical nature. Carbon dioxide can be removed by degasification or air stripping. This process is governed by Henry's law, which states that the amount of gas dissolved in water is directly proportional to the partial pressure of that gas in the vapor space above the water/gas interface. Also governing this process is Dalton's law which states that the total pressure of a mixture of gases is made up of the individual pressures of the gases in the liquid and is directly proportional to their molar ratios in the vapor space. Mechanical devices called strippers or degasifiers are design to remove Carbon dioxide by taking advantage of the characteristics stated above. Often the water pH is lowered to convert dissolved HCO; or CO;' to gaseous CO, to remove it by stripping and thus reduce alkalinity; this is common in demineralization and boiler feedwater preparation. 13 Oil alld Wo/er Separatioll Oil can become a contaminant in plant water systems, and the reuse of this water in cooling systems necessitates the separation and removal of the oil. Common gravity separators are widely used, such as the American Petroleum Institute (API) separator. This functions by allowing the less dense oil to naturally float to the top of the mixed fluid, where it is then removed by skimming or pumping off. The API separator is not applicable for emulsified oil. In such a case, the emulsion must first be Chemically/physically broken, or other methods of oil/water separation are required. Other methods to separate emulsified oil and water include air flotation, which bubbles air through tile fluid and can break the emulsion; air flotation with the addition of treatment chemicals; and chemical coagulation and sedimentation. Analytical Instrumentation for Monitoring Reuse Water Quality The list below contains the most common water constituents or contaminants that are of concern for water being used for reuse purposes. This section discusses the online teclmiques for real- time monitoring and potential control of these constituents. These constituents plus possible biological constituents can also be analyzed in the laboratory using methods from the Standard Methods for the Examination of Water and Wastewater (published by the American Public Health Association, the American Water Works Association and the Water Environment Federation) and other similar procedures. Water Constituents or Contaminants Tested Onlille or ill the Laborat01J' Sensor based analysis: pH, ORP,conductivity, suspended solids Organics: total organic carbon (TO C), biological oxygen demand (BOD), chemical oxygen demand (COD), Oil and Grease Titrametric Techniques (hardness), Alkalinity and Ion Specific (field): Ammonia, Phosphate, Sulfide, Electrode Calcium Chloride, Colorimetric metilOds: Alkalinity, Sulfate, Sulfide, Chloride - can be online, but commonly a laboratory procedure Iron - laboratory method a Other site or application specific contaminants. Others are specific based on the chemistry of the specific system in question. pH Measurement Gild Control When considering reuse water, pH measurement and control are vital. Process and reuse water must meet specific pH ranges. The ranges are commonly between pH values of7.0 to 9.0 but may be in other ranges based on system specific requirements. ORP (Oxidation Reduction Potentia) The variability of reuse water may require the use of ORP either as an incoming water monitor or to monitor and control the recirculating water. Alkalinity Alkalinity is a measure of the capacity of water to neutralize acids. High alkalinity waters are more prone to precipitate sparily soluble salts. Conductivityl Total Dissolved Solids Electrolytic conductivity is the measure of the ability of a solution to conduct an electric current. Electrolytic conductivity is defined as the inverse or reciprocal of electrical resistance (siemans) and is typically expressed as microsiemans per centimeter. Conductivity is an indication of the quantity of ions contained in a solution and therefore there is a relationship between conductivity and total dissolved solids (TDS). Turbidity and Suspended Solids The American Public Health Association (APHA) defines turbidity as an "expression of the optical property that causes light to be scattered and absorbed rather than transmitted in straight lines through the sample." Turbidity can be interpreted as a measure of the relative clarity of water. Turbidity is not a direct measure of suspended particles in water but, instead, a measure of the scattering effect such particles have on light. Suspended solids are particles that include silt, clay, algae and other microorganisms, organic matter and other minnte particles. Suspended solids contribute to the turbidity of the water. Organic Contaminants The presence of any organic chemical in the reuse stream makes the water unusable for any reuse purpose without further treatment. Acceptable organic concentrations should be controlled to near zero. Laboratory tests for organics include oil and grease test, plus tests for Biochemical Oxygen Demand (BOD), Chemical 14 Oxygen Demand (COD), and Total Organic Carbon (TOC). Chemical Oxygen Demand (COD) Chemical oxygen demand is "a measure of the oxygen equivalent of the organic matter content of a sample that is susceptible to oxidation by a strong chemical oxidant."* Oxygen demand is determined by measuring the amount of oxidant consumed using titrimetric or photometric methods. *Standard Methods for the Examination of Water alld Wastewater, 15th Edition Biochemical Oxygen DelliOlld (BOD) Biochemical Oxygen Demand (BOD) is the amount of oxygen, expressed in mg/L or parts per million (ppm), that bacteria consume when they oxidize organic matter. It is critical that the BOD concentrations be known to determine the potential value of the water for reuse or to determine if further treatment is necessary. Total OrganiC Carbon (TOC) The TOe analysis will measure all natural biodegradable organic carbon and all synthetic organic carbon. This analysis can be automated and can be continuous, offering advantages for process control versus BOD and COD analyses. It is critical that the TOe concentration be known to determine the potential value of the water for reuse or to determine if further treatment is necessary. Other tests: Titrametric alld 1011 Specific Electrodes Techlliques for Ammonia, Calcium (Hardlless), Phosphate, Suifide, Chloride Other tests are routinely performed to measure the quality of water for reuse in cooling towers including some listed below: Phosphate: measurement of the concentration of phosphates is based on a series of calorimetric reactions Sulfide: measured by titration to an oxidation reduction potential (ORP) endpoint using a silver electrode. Ammonia: measured by using an ammonia ion specific electrode or a calorimetric procedure. Calcium (hardness): calcium is measured by laboratory titration technique Chloride: chloride is measured by using an ion selective electrode for chloride. SECTION 5. IMPACT OF REUSE WATERS ON COOLING SYSTEM MATERIALS OF CONSTRUCTION, WATER CHEMISTRY AND CHEMICAL CONTROL The water chemistry in the cooling system usually changes as a result of water reuse, even with additional treatment outside the cooling system. It is important to predict the changes in the water chemistry and understand the consequences of the chemistry changes and accept or mitigate and/or control the impact of these changes. Water chemistry changes impact the cooling system in many ways: the materials of construction, the heat exchangers, the tower fill and structure all must be considered. The water treatment program must be evaluated to insure it will fit the new water chemistry. Often water reuse results in higher amounts of impurities such as salts or metals or organics in the system. These can stress the system: the capability of the treatment chemistry, chemical control equipment and the testing methods must be evaluated. Cooling System The cooling system includes all the wetted surfaces such as cooling towers, heat exchangers, pumps and piping. Each has specific material of construction considerations as they relate to the reuse water. Materials Under Consideration The wetted surfaces may include wood, concrete, stainless steel alloys, ferrous alloys, copper alloys, nickel alloys, aluminum alloys, titanium, carbon, plastics and galvanized steel. Additionally, gaskets and fasteners of various materials may come in contact with the reuse water. Individual systems may include additional materials not covered in this list. The system survey should identify all materials wetted by the rellse water, including any storage vessels, pumps and piping. Cooling System Heat Exchangers The consideration of use of relIse water may be affected by heat exchanger design and operating conditions. These may include various heat fluxes, residence times, velocities, tube surface roughness, and bulk water and heat exchanger metal surface temperatures. Particular attention should he paid to shell side water heat exchanger cooling water flow profiles. Some of the cooling systems will have non-standard heat exchangers that may require individual evaluation to 15 determine the effect of reuse water upon their operation. Considerations for Cooling Tower Fill Fill selection is normally determined by make-up water quality, types of circulating water contamination (process leaks, airborne matter) and quality of biological control. The goal is to select the highest thermal performance fill that provides long term consistent performance. Therefore, when considering reuse of a cooling water stream, the type of fill must he considered. The changes in water chemistry as discussed in the water chemistry section below must he evaluated and controlled to protect the fill from fonling conditions . .various forms of fill are susceptible in varying degrees to fouling hy suspended solids, precipitation of dissolved solids, and by microbiological fouling. This must by considered in the project evaluation and the fill must be protected or the systems capability to produce cooled water may he reduced. The types of fill used in a cooling tower fall into broad categories: splash fill and film fills. In general, if the tower has splash fill, it can accept very poor quality make-up water. Splash fills have a lower thermal performance, but will not normally he effected by changes in water quality. This statement is true of both cross-flow and counter-flow splash filled cooling towers. There are some variations in splash fill that should be noted. Hollow extruded lath, small diameter perforated splash har or splash fill with an area that can accumulate minerals and debris, may be vulnerable to problems with make-up water containing higher levels of contamination. These splash fills must be reviewed to ensure the higher mineral concentrations and suspended solids do not appreciably interfere with the fill's performance or significantly add to the fill weight, which could lead to structural problems. If the tower has film fill, more attention to water quality is required. Film fills wiII vary greatly in their fouling potential.. For more specifics relating to your application, it is recommended that you contact the cooling tower or fill manufacturer. Cooling System Chemistry and Control Changes in the cooling water chemistry due to use of reuse waters can impact the treatment chemistry and control. Water chemistry is a key factor and the method of operation of the systems is important. The operating personnel's available time and attention for the cooling system water treatment program becomes a factor, as does the treatment of the reused water stream. An evaluation must be made to ensure that there will be no loss of system efficiency or equipment integrity due to corrosion or fouling of any part of the system caused by increases in the water minerals, suspended solids, other contamination, or microbiological growth. Automation of reuse water treatment steps should be considered and often is required. In order to protect the integrity of the cooling system, modern practice calls for a water treatment management program including automated control of cycles of concentration, good microbiological control (usually automated), and a good water treatment program (control of corrosion, scale, suspended solids and biological growth). If pH is controlled by addition of an acid or base, this addition must be automatically controlled. Summary Reuse waters are a viable resource for recirculating cooling water systems. However, reuse waters may have high concentrations of contaminants that require further treatment and additional monitoring. This document provides an overview of pertinent issues surrounding the reuse of cooling water. AppendixA. Water Chemistry Evaluation with Software Tools Water Chemistry Evaluation Reuse water provides a challenge that traditional indices and rules of thumb for predicting scale and corrosion can not always meet. Methods such as the Langelier Saturation Index, Ryznar Stability Index, and Practical (Puckorius) Index are limited to predicting calcium carbonate in low TDS waters. Rules of thumb for predicting calcium sulfate, silica and magnesium silicate scales are even more restricted to ballpark estimates of scale potential. Most of these indices and guidelines for their use were developed to meet the prediction requirements of early alkaline treatments and chromates. Their application to the current high pH operating ranges and higher TDS systems can lead to serious errors. Areas of concern include: unexpected scales activity coefficient estimation common ion effects evaluating at a single condition. Computer programs provide the calculation power to overcome the deficiencies of traditional index calculations. Wen designed programs incorporate all of the scales expected. They account for activity coefficients and common ion effects encountered in high TDS waters. And they allow evaluation over the total operating range expected: from the lowest concentration ratio to the highest, from the lowest temperature 16 to the highest, and from the lowest pH to the highest anticipated. Indices Calculated Software calculates the Degree of Saturation which is also called Saturation Level, Saturation Index, and Saturation Ratio. This index is derived from the definition of the solubility product. For calcium sulfate, this would be defined as: {Ca}{SO,} Ksp The index is the ratio of the observed ion activity product {Ca} {S04} to the solubility product: S.l. ({Ca}{SO,})/Ksp The index is less than 1.0 if a water is undersaturated with the scale being evaluated; 1.0 if at equilibrium; and greater than 1.0 if supersaturated. {Ca}{SO,l < Ksp Undersaturated - scale not expected, may dissolve {Ca}{SO,l Ksp At equilibrium - scale not expected {Ca}{SO,l > Ksp Supersaturated - scale may form Saturation indices can be calculated for all common, and many not so common, cooling water scales. Table 1 summarizes typical scales included in generally available software. Table 1 Calcium carbonate Calcite CaC0 3 Aragonite CaC0 3 Calcium suI fate Gypsum CaS04.2H,O Anhydrite CaS04 Silica Amorphous Silica SiO, Magnesium Silicate MgSi0 3 Calcium phosphate Hydroxylapatite Cas(P04lJ(OH) Tricalcium Phosphate CaJ(P04)2 Magnesium hydroxide Brucite Mg(OH), Calcium fluoride Fluorite CaF, Iron phosphate Strengite Fe(PO J ), Iron carbonate Siderite FeC0 3 Iron hydroxide Amorphous Ferric Hydroxide Fe(OH)3 Barium suI fate Barite Barium carbonate Witherite Strontium sulfate Celestite Strontium carhonate Strontianite Ion Pairing The Saturation Index discussed can be calculated based upon total analytical values for the reactants. Ions in water, however, do not tend to exist totally as free ions. Calcium, for example, may be paired with sulfate, bicarbonate, carbonate, phosphate and other species. Bound ions are not readily available for scale formation. Computer programs calculate saturation levels based upon the free concentrations of ions in a water rather than the total analytical value which includes those which are bound. Indices developed in the past, such as the Langelier Saturation Index (LSI) for calcium carbonate scale, are based upon total analytical values rather than free species primarily due to the intense calculation requirements for detennining the distribution of species in a water. Speciation of a water is time prohibitive without the use of a computer for the number crunching required. 11le process is iterative and involves: 1. Checking the water for electroneutrality via a cation-anion balance, and balancing with an appropriate ion (e.g. sodium or potassium for cation deficient waters, sulfate, chloride, or nitrate for anion deficient waters). 17 BaS04 BaC0 3 SrS04 STC0 3 2. Estimating ionic strength, calculating and correcting activity coefficients and dissociation constants for temperature, correcting alkalinity for non-carbonate alkalinity. 3. Iteratively calculating the distribution of species in the water from dissociation constants (a partial listing is outlined in Table 1 ). 4. Checking the water for balance and adjusting ion concentrations to agree with analytical values. 5. Repeating the process until corrections are insignificant. 6. Calculating saturation levels based upon tlle free concentrations of ions estimated using the ion association model (ion pairing). The use of ion pairing to estimate tlle free concentrations of reactants overcomes several of tlle major shortcomings of traditional indices. Indices such as the LSI correct activity coefficients for ionic strength based upon the total dissolved solids. They do not account for l1common ionl! effects. Common ion effects increase the apparent solubility of a compound by reducing the concentration of reactants available. A common example is sulfate reducing the available calcium in a water and increasing the apparent solubility of calcium carbonate. The use of indices which do not account for ion pairing can be misleading when comparing waters where the TDS is composed of ions which pair with the reactants versus ions which have less interaction with them. It is common for water chemistry evaluation software to perform calculation of over one hundred (lOO) ion pairs in estimating free ion concentrations. Table 2 outlines typical ion pairs included in computer evaluations. Table 2: Example Ion Pairs Used To Estimate Free Ion Concentrations CALCIUM [Calcium] = [Ca+ lI ] + [CaSO,] + [CaHCO,+'] + [CaCO,] + [Ca(OHt'] + [CaHPO,] + [CaPO.'] + [CaH 2 PO/'] MAGNESIUM [Magnesium] = [Mg+lI] + [MgSO,] + [MgHCO,+'] + [MgCO,] + [Mg(OHt'] + [MgHPO,] + [MgPO.']+[MgH,PO/']+[MgF+'] BARIUM [Barium] = [Ba+ lI ] + [BaSO,] + [BaHCO,+'] + [BaCO,] + [Ba(OHt'] STRONTIUM [Strontium] = [Sr+lI] + [SrSO,] + [SrHCO,+'] + [SrCO,] + [Sr(OHj"] SODIUM [Sodium] = [Na+'] + [NaSO.'] + [Na2S0,] + [NaHCO,] + [NaCO;'] + [Na,CO,] + [NaCI]+[NaHPO.'] POTASSIUM [Potassium] = [K+']+[KSO.'] + [KHPO.'] + [KCI] IRON [Iron] = [Fe+ lI ] + [Fe+ lII ] + [Fe(OHj"] + [Fe(OHt'] + [Fe(OH),"] + [FeHP04+1] + [FeHPO,] + [FeCI+ II ] + [FeCI,'] + [FeC!,] + [FeSO,] + [FeSO/'] + [FeH 2 PO/'] + + [Fe(OH),] + [Fe(OH)4'] + [Fe(OHh] + [FeH 2 PO/'] ALUMINUM [Aluminum] = [Atlll] + [AI(OHj'II] + [AI(OHh+'] + [AI(OH)4'] + [AIF+ II ] + [AIF,"] + [AIF,] + [AlF.'] + [AISO/'] + [AI(SO,h"] Operating Range Profiles A major shortcoming of many water treatroent evaluations is that they are conducted under one set of operating conditions. Unfortunately, cooling systems fail to cooperate, as even with good automation almost all cooling systems have variation, even if only to natural water supply and air temperature and humidity variations from weather changes. Evaluations should be performed over the entire range expected for 18 critical parameters such as pH, temperature, and concentration ratio. Software Based Water Chemistry Evaluation Summary A well designed computer program can evaluate the impact of water reuse on scale potential in a cooling system. The program should account for all of the scales anticipated in a cooling system using reuse water. It should be designed to handle calculations for high total dissolved solids water. An ion association model should be incorporated into the system to account for the reduced availability of scale forming species in high TDS systems. And finally, a water chemistry evaluation should be conducted over the entire operating range expected for critical parameters such as concentration ratio, pH and temperature. Appendix B References From Cooling Technology Institute Publications Water Reuse iPaper# Title Author lP.l3.09 I jwater Reuse Within a Refinery CTP-93-09) .K.S. Eble & 1. Feathers, Betz iIndustrial ,Date 1993 :Abstract: Before optimized within a -all water 'utility water streams must be identified and their contaminants must be characterized. The !streams can then be mixed and matched to minimize total refinery water use, water discharge, ;and water treatment. The cooling system is typically the largest consumer of water within a 'refinery, and consequently, it is the most likely place to reuse water. This paper identifies many process water streams found in a refinery, characterizes their contaminants, and compares those :characteristics with the level of contaminants which can be successfully treated in the cooling 'system. TP.l4.0B 11 ,Reuse of Industrial Waste Stream as Cooling ___ -' Tower Makeup lEverett C. Phillips & Richard 1 :Strittrnatter, Nalco Chemical Co., 1994 Abstract: Decreasing water supplies, increasing government regulations, and community 'awareness compel industry to consider water reuse. With their high water demand and :relatively low water quality requirements, open recirculating cooling water systems are often :consider ideal candidates for reusing industrial waste streams. However, contaminants in the 'waste streams frequently present new and significant challenges in corrosion control, scale control, and microbiological control. Overcoming these difficulties requires investigation of the jvarious pretreatment options and internal treatment programs. The optimum combination can iresult in significant water and dollars savings while still providing excellent protection of the 'cooling water system. Recent practical applications of reuse of industrial waste streams as Icooling tower make-up will be presented. TP.l4-09 I [Innovative Thinking in Water . IMikel E. Goldblatt, Betz Ind'l 1994 IAbstract: Two non-traditional examples of water reuse are presented, illustrating the value of iinnovative thinking in addressing specific water conservation challenges. Case I illustrates the :se of a large cooling system as a repository for demineralizer waste. NorrnalIy this is not done, :'due to this stream's high salinity. However, the overriding objective of minimizing wastewater, land tile establishment of protective measures alIowed for successful reuse of this stream at iminimal risk. Case 2 illustrates the benefits of cascading cooling water from a system Icontaining barometric condensers as makeup to another cooling system, thus maximizing reuse of medium quality cooling water. .. -- --,-'--'----- ---- ---- I -- " TP.l5.05 IIWater Conservation via New Cooling Water ]Nicholas 1. Alfano, Calgon Corp., ___ . _::::J ITec1u:ology .. _ _ _ _ _ . _ pennis 1. Sherren, Power Corp. 1995 19 --'--- .. 'Abstract: A substantial portion of the annual cooling water treatment costs at Enron Power Corporation in Texas City, Texas include the acquisition of makeup water and the disposal of blowdown. This paper describes how the application of a newly developed high cycle cooling ;water treatment program directly resulted in a substantial savings in water use and overall :cooling water treatment costs while maintaining scale and corrosion controL The cooling water treatment program is designed to control CaC03 scaling at Langelier Saturation Index values 'approaching +3.5. lP95-11 I ',',Re-Use of Reclaimed Municipal Waste Water as Narasirnha M. Rao, Nalco Chemical ___ --'- Cooling Water Make-Up - Challenges and ,Company 1995 'Solutions Abstract: High levels of total dissolved solids, ammonia, phosphate and organic impurities characterize municipal wastewaters. This paper presents results of an in depth laboratory and 'on-site study investigating the use of tertiary treated municipal effluent as cooling water make- iup. The corrosion, fouling and microbiological challenges unique to this water are analyzed and :solutions presented. An analysis of the various components of the cost for treating this water is 'presented. lP95-15 I Water Tower for , .Refinery/Petrochenncal Plants - Southern Activities and Time Table R. Puckorius, & IAssociates, Inc., Kris Helm, West iBasin Municipal Water Dist., Chris 1995 iSpurrell, Chevron U.S.A. ,Abstract: The use of Title 22 Reclaimed Sewage Plant Effluent as Cooling Tower Make-up in ,Place of Fresh water is an important milestone. Its use, in place of fresh water, requires critical ,considerations for successful and economical applications. The details of how reuse should be considered, how it has been evaluated, and the required treatment considerations are provided in this presentation. TP01-01 I Water Reuse in refineries, Chemical Plants, and :Paul R. puckorlus, Gary A. Loretitsch, ;2001 ___ --'-I ,Utilities: Experiences Throughout the USA and 'Torry Tvedt, Puckorius & Associates, j :Texas - Guidelines and Case Histories IInc. Abstract: Water reuse has been successful and cost effective in cooling water and boiler water [systems when properly planned and matched with system operation and materials of construction. Specific guidelines are provided for cooling and boiler water systems and ,treatment requirements. Case histories throughout the USA and Texas illustrated specific :experiences and results in system protection. TP02-17 I '"Cooling Components the c-----' Impact of Reuse Waters. IPaul R. Puckorius, Puckorius & !Associates, Inc. '2002 ' i Abstract: The increase in reuse waters replacing fresh water supplies in cooling tower systems 'requires an understanding of potential impacts on cooling tower and heat exchange equipment. This paper identifies those reuse water ingredients that impact on scale, fouling, corrosion, and biological concerns. It identifies those components that are impacted, depending upon their :materials of construction and location in the cooling system. Guidelines are provided as to what : :are potential problems and corrective measures. Several case histories are provided. ' TP03-031 iWater Reuse Experiences With Cooling Tower iPaul Puckorius, Puckorius &2003 in San Antonio, Texas iAssociates, Inc. and Ken DieW, San i IAntonio Water System 'Abstract: Water reuse studies in pilot plant cooling-tower system were conducted that showed :major benefits over use of aquifer fresh water supplies. Actual case histories are reviewed which identify the fresh water and chemical savings, as well as other items to consider with lreclaimed water in cooing tower water systems. Comparison of fresh and reclaimed water use ;in San Antonio provides some guidelines for other potential users to consider. . . - - - --. ... .._. - - 20 1Rl4-01 11 Tower Water ___ ---' ,Program . - f -- - ." ;Paul R. Puckorius and David A. ipuckorius - Puckorius and Associates, Inc. 'Jim Reed - Denver Water 2004 i Abstract: The Denver Water Board has initiated a cooling tower water audit program. The 'purpose of this program is to identify if and to what extent water conservation is possible 'through optimizing cooling tower system operation. This paper provides the results of these audits to date. It includes the water savings that have been identified along with specific data on water quality that could be maintained. Over 700 cooling towers could be involved to help reduce Denver's drought condition. There will also be a brief review of the Denver Water Board 1 s time schedule for water rate increases and their overall program for water conservation. ' '2005 1Rl5-13 ! :Evaluation into th: use of Mine Drainage to pr. A Harriram and D.G. ___ --' !Supplement Coohllg Water Nieuwenhuis, Sasol Technology __ _ Abstract: The Sasol petrochemical complex located in Secunda, South Africa operates the ,world's largest coal to synthesis gas conversion process. Expansion projects have resulted in an 'increase in cooling water requirements which is difficult in this water short catchment. Conversely, drainage water continuously accumulating in old coal mine workings is a growing liability. In an effort to balance the supply and demand within the complex, investigations were initiated into the use ofmin drainage water. The mine drainage contains amongst others, 'elevated concentrations of Calcium (- 250 mg/I), Magnesium (- 150 mg/I), and Sulphate (- 2,955 mg/I) as well as trace quantities ofiron and manganese. The addition of up to 12% of such mine drainage water to a cooling medium could tender the blend highly conducive to ,fouling, scaling and corrosion. Pilot scale cooling towers were operated over a twelve month :period and the results including the limitations observed will be discussed. [Dr. Chris L. Wiatr, Buckman 'Laboratories, Inc. 1Rl5-16! of Resistant Bacteria in Recirculating ,-__ -l,Water Systems 2005 Abstract: Bacteria are everywhere in recirculating cooling water systems. Controlling bacterial !populations in the bulk water and on cooling system surfaces is necessary to maintain and 'operate the cooling system properly. Control of micro organisms in the field requires successful :application of biocide agents. However, bacterial resistance to biocides is inevitable and irreversible, a natural consequence of bacterial adaptation to exposure to anti microbials. This 'paper presents mechanisms of bacterial resistance to anti microbials, strategies for overcoming 'resistant cell populations, and a supportive case history using biocides successfully against !resistance bacteria. I [Monitoring Cooling Water for Potential Reuse [Phil Kiser, Hach Company i2005 21 Abstract: With decreasing water supplies in most industrialized areas of the United States, cooling water discharges are beiog studied for potential reuse applications. Serious concerns ,exist among potential reuse water recipients due to the perceived content of this water. Health :concems and aesthetic concerns impact any reuse decision. One key way of alleviating these concerns and making quick decisions concerning the quality of the water is usiog real time 'analytical instrumentation. Advances in online testiog and online instrumentation allowing . quick decisions about the quality ofthese waters. This paper will discuss the analysis of these 'waters and instrumentation that allows careful monitoring to be achieved. 22 ) 23 COOLING TECHNOLOGY INSTITUTE PO Box 73383 Houston, TX 77273 281.583.4087 Fax: 281.537.1721 24