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'
4)
12
3 10 T
8. The pressure exerted by an electromagnetic wave of intensity I ( watt m
-2
) on a non reflecting surface is(c
is the velocity of the light)
1) Ic 2) Ic
2
3)
I
c
4)
2
I
c
9. Energy from the sun is received on earth at the rate of 2 cal cm
-2
min
-1
. If average wavelength of solar light
be taken at 5500A
0
, then how many photons are received on the earth in cm
-2
min
-1
( h =
34
6.6 10 Js, 1 cal = 4.2J
)
1)
13
1.5 10
2)
13
2.9 10
3)
19
2.3 10
4)
19
1.75 10
10. The threshold frequency for a metallic surface corresponds to an energy of 6.2 eV and the stopping
potential for a radiation incident on the surface is 5V. The incident radiation lies in
1) ultraviolet region 2) infrared region 3) visible region 4) X-ray region
11. The magnetic moment () of a revolving electron around the nucleus varies with principal quantum number
n as
1) n 2)
1
n
3)
2
n
4) 2
1
n
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12. A radioactive nucleus of mass M emits a photon of frequency o and the nucleus recoils .The recoil energy
will be
1)
2 2
2
h
2Mc
o
2) zero 3)
ho
4) Mc
2
-
ho
13. In a semiconducting material the mobilities of electrons and holes are
e
and
h
respectively. Which of
the following is true ?
1)
e h
> 2)
e h
< 3)
e h
= 4)
e h
0; 0 < >
14. An amplifier has a voltage gain A
v
= 1000 . The voltage gain in dB is
1) 30 dB 2) 60 dB 3) 3 dB 4) 20 dB
15. Two concentric coils each of radius equal to 2 cm are placed at right angles to each other. 3A and 4A are
the currents flowing in each coil respectively. The magnetic induction in Wbm
-2
at the centre of the coil will
be (
7 1 1
0
4 10 wbA m
= )
1)
5
12 10
2)10
-5
3)
5
5 10
4)
5
7 10
16. In the adjacent figure is shown a closed path P. A long straight conductor carrying a current I passes
through O and perpendicular to the plane of the paper. Then which of the following holds good ?
1)
P
B.d 0 =
}
2)
0
P
B.d I =
}
3)
0
P
B.d I >
}
4) None of these
17. A magnet is suspended in such a way that it oscillates in the horizontal plane. It makes 20 oscillations per
minute at a plane where dip angle 30
0
and 15 oscillations per minute at a place where dip angle is 60
0
. The
ratio of earths magnetic field at two places is
1)
3 3 : 8
2)
16: 9 3
3) 4 : 9 4)
2 2 : 3
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18. A long magnet is cut into two equal parts, such that the length of each half is same as that of original
magnet.If the period of original magnet is T, the period of new magnet is
1) T 2) T/2 3) T/4 4) 2T
19. Figure shows a mixture of blue, green and red coloured rays incident normally on a right angled prism .The
critical angles of the material of the prism for red, green and blue are 46
0
, 44
0
and 43
0
respectively. The
arrangement will separate
1) red colour from blue and green 2) blue colour from red and green
3) green colour from red and blue 4) All the three colours
20. A ray falls on a prism AB(AB = BC) and travels as shown in figure. The least value of refractive index of
material of the prism , should be
1) 1.5 2)
2
3) 1.33 4)
3
21. If youngs double slit experiment , is performed in water
1) the fringe width will decrease 2) the fringe width will increase
3) the fringe width will remain unchanged 4) there will be no change
22. The critical angle of a certain medium is
1
3
sin
5
|
|
'
. The polarizing angle of the medium is
1)
1
4
sin
5
|
|
'
2)
1
5
ta n
3
|
|
'
3)
1
3
ta n
4
|
|
'
4)
1
4
ta n
3
|
|
'
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23. The quantities A and B are related by the relation m = A/B, where m is the linear density and A is the force.
The dimensions of B are of
1) pressure 2) work 3) latent heat 4) energy
24. A thiefs car is moving with a speed of 10 m/s. A police van chasing this car with a speed of 5m/s fires a
bullet at the thiefs car with muzzle velocity 72km/hr.Find the speed with which the bullet will hit the car.
1) 10 m/s 2) 20 m/s 3) 15 m/s 4) 30 m/s
2 5 . F r o m t h e t o p o f a t o w e r i f t w o s t o n e s , w h o s e m a s s e s a r e i n t h e r a t i o 1 : 2 a r e t h r o w n o n e s t r a i g h t u p w i t h
i n i t i a l s p e e d u a n d t h e s e c o n d s t r a i g h t d o w n w i t h t h e s a m e s p e e d u . T h e n n e g l e c t i n g t h e a i r r e s i s t a n c e ,
1 ) T h e h e a v i e r o n e h i t s t h e g r o u n d w i t h a h i g h e r s p e e d
2 ) T h e l i g h t e r o n e h i t s t h e g r o u n d w i t h a h i g h e r s p e e d
3 ) B o t h t h e s t o n e s w i l l h a v e t h e s a m e s p e e d w h e n t h e y h i t s t h e g r o u n d
4 ) T h e s p e e d c a n n o t b e d e t e r m i n e d w i t h t h e g i v e n d a t a
2 6 . A p a r t i c l e i s p r o j e c t e d w i t h v e l o c i t y u s o t h a t i t s h o r i z o n t a l r a n g e i s t h r i c e t h e g r e a t e s t h e i g h t a t t a i n e d . W h a t
i s i t s h o r i z o n t a l r a n g e
1 )
2
1 u
25 g
2)
2
1 u
24 g
3)
2
25 u
24 g
4)
2
24 u
25 g
27. A bus is going due north at a speed of 30 km/h. It makes a 90
o
left turn without changing the speed. The
change in the velocity of the bus is
1) 30 km/h towards west 2) 30 km/h towards south west
3) 42.4 km/h towards north - west 4) 42.4 km/h towards south - west
28. A particle moves in a circle of radius 25 cm at two revolutions per second. The acceleration of the
particle in m/s
2
is :
1) 2)
8
3)
2
4
4)
2
2
29. A horizontal force of 10N is necessary to just hold a block stationary against a wall. The coefficient of
friction between the block and the wall is 0.2. The weight of the block is
1) 2N 2) 20N 3) 50N 4) 100N
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30. An impulse is supplied to a moving object with the force at an angle of 20
o
with respect to velocity vector.
The angle between the impulse vector and the change in momentum vector is
1) 0
o
2) 60
o
3) 160
o
4) 240
o
31. A water pump driven by petrol rises water at a rate of 0.5 m
3
/min from a depth of 30 m. If the pump is 70%
efficient, the power developed by the engine is
1) 1750 W 2) 2450 W 3) 7000 W 4) 3500 W
32. The potential energy of a system increases if work is done
1) upon the system by a non-conservative force
2) by the system against a conservative force
3) by the system against a non-conservative force
4) upon the system by a conservative force
33. Three identical spheres, each of mass M are placed at the corners of a right angled triangle with mutually
perpendicular sides equal to 2m. Taking their point of intersection as the origin, the position vector of
centre of mass is
1) ,
1
i j
3
2) ,
2
i j
3
3) ,
2
i j
3
+
4) ,
1
i j
3
+
34. The moment of inertia of a thin uniform rod of mass M and length L about an axis passing through its
m i d p o i n t a n d p e r p e n d i c u l a r t o i t s l e n g t h i s I
0
. Its moment of inertia about an axis passing through one of its
ends and perpendicular to its length is
1)
2
0
ML
I
2
+ 2)
2
0
ML
I
4
+ 3)
2
0
I 2ML + 4)
2
0
I ML +
35. A simple pendulum has a time period T
1
when on the earths surface, and T
2
when taken to a height R
above the earths surface, where R is the radius of the earth. The value of
2
1
T
T
is
1) 1 2)
2
3) 4 4) 2
36. A particle of mass M is situated at the centre of a spherical shell of same mass and radius a . The gravitational
potential at a point situated at
a
2
distance from the centre , will be
1)
3GM
a
2)
2GM
a
3)
GM
a
4)
4GM
a
2)
2
3 3
ClO , CO
3)
2
3 3
CO , SO
4)
2
3 3
NO , CO
48. Predict in which of the following entropy decreases?
1) A liquid crystallises into solid 2) Temp. of crystalline solid is raised from 1K to 115
K
3)
3(s ) 2 3(s ) 2( g) 2 ( g)
2NaHCO Na CO CO H O + + 4)
, 2(g) g
H 2H
49. A cell in which the following reaction occurs
,
3 2
(aq) (aq) 2(s) aq
2Fe 2I 2Fe I
+ +
+ +
has
0
cell
E 0.236 V = at
298 K. The standard Gibbs energy change for the cell reaction in kJ is
1) 90.11 2) 45.55 3) 22.25 4) 11.25
50. Match suitably
Column - I (Conc. of HCl) Column-II (pH)
A) 10
6
M p) 7.0
B) 10
7
M q) 6.98
C) 10
8
M r) 6.0
D) 10
9
s) 6.70
1) Ap, Bq, Cr, D , Ds 2) Ar, Bs, Cq, Dp
3) Ar, Bs, Cp, Dq 4) As, Br, Cp, Dq
SPACE FOR ROUGHWORK
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51. Freundlich isotherm explains the behaviour of adsorption in an approximate manner. The factor
1
n
can
have value
1) 1 in case of physical adsorption 2) 1 in case of chemisorption
3) Between 0 and 1 in all cases 4) Between 2 and 4 in all cases
52. The number of geometrical isomers for octahedral ,
3 4
2
Co NH Cl
(
, square planar
j
2 2
AuCl Br
and
, ,
2
2 3
5
Co NO NH
+
(
are
1) 2, 2, 2 2) 2, 2, no isomerism 3) 3, 2, 2 4) 2, 3, no isomerism
53. Which haloalkane cant be prepared by free radical halogenation of alkanes?
1) CH
3
Cl and CH
3
F 2) CHCl
3
and CH
3
I 3) CCl
4
and CHBr
3
4) CH
3
F and CH
3
I
54. Which is an incorrect statement about ionisation enthalpy?
1) It increases across a period
2) The higher the screening effect, the higher is its value
3) In a given shell, s > p > d > f
4) Ionisation enthalpy ,
1
1
H A
of helium is highest in the periodic table
55. During hydration of alkali metal cations
1) G, H, S A A A are ve 2) G, H A A are ve;
S A
is positive
3) G, H, S A A A are +ve 4) G, S A A are ve;
H A
is +ve
56. XeF
2
reacts with PF
5
to give
1) XeF
4
2)
j j
6
XeF PF
+
3)
j j
3 4
XeF PF
+
4)
j j
2 2
4 4
XeF PF
+
57. An ideal gas is initially at temp. T and volume V. Its volume increases by
V A
due to increase in temp. of
T A
, pressure remaining constant. The quantity
V
V. T
A
=
A
1) 2) 3) 4)
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58. If proton, electron and o -particle have equal kinetic energy, their de-Broglie wavelengths would be in the
order
1)
e p o
i = i < i
2)
p e o
i < i < i
3)
p e o
i > i > i
4)
p e o
i > i > i
59. Which of the following statement is incorrect?
1) A secondary alcohol on oxidation gives a ketone
2) Ethanol reacts with conc. H
2
SO
4
at 180 C to yield ethylene
3) Methanol reacts with iodine and sodiumhydroxide to give yellow ppt of iodoform
4) Hydrogen gas is liberated when sodium is added to alcohol
60. Phenol undergoes electrophilic substitution more readily in presence of alkali than the phenol itself because
1) Of the formation of a more stable carbocation as an intermediate
2) Of the formation of a more stable carbanion as an intermediate
3) Of the formation of a more stable neutral intermediate
4) In presence of alkali, a stronger electrophile is produced
61. In the Stephens reaction an
1) Alkyl cyanide is reduced with LiAlH
4
2) Alkyl cyanide is reduced with SnCl
2
and HCl
3) Alkyl cyanide is reduced with sodium and alcohol
4) Alkanoylchloride is reduced in presence of Pd/BaSO
4
62. When an aldehyde is heated with alkali, part of its was converted into alcohol and part of it into an acid.
The aldehyde is an
1) Aliphatic aldehyde other than formaldehyde
2) Aliphatic aldehyde or salicylaldehyde
3) Aromatic aldehyde other than salicyl aldehyde
4) Aromatic aldehyde or formaldehyde
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63. Match suitably
Column-I Column-II
A)
4
2
Red P
2 2 Br
RCH CH COOH
p) Esterification
B)
R CH
2
C OR + NaOEt
O
q) Hydrolysis
C)
RCOOH R OH ' +
r) HVZ reaction
D) RCOOCH
3
+ NaOH s) Claisen condensation
1) Ar; Bs; Cp; Dq 2) Ar; Bs; Cq; Dp
3 Ar; Bq; Cp; Ds 4) Ar; Bq; Cs; Dp
64. D glu cos e o and D glu cos e | differ from each other due to difference in one of the carbons with
respect to is
1) Size of hemiacetal ring 2) No. of OH groups
3) Configuration 4) Conformation
65. Aminoacids are
1) Basic as a typical amine and acidic as a carboxylic acid
2) Less basic than a typical amine and less acid than a COOH
3) More basic than a typical amine and more acidic than aCOOH
4) Basicity and acidity cant be predicted
66. When borax is heated on the loop of a platinum wire, its swells up due to loss of water of crystallisation.
When it is further heated it melts into a liquid which solidifies to a transparent glassy mass. The glassy mass
consists of
1) NaBO
2
+ B
2
O
3
2) NaBO
2
3) Na
2
BO
2
4) BN
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67. Which is incorrectly matched?
1) Neoprene :
CH
2
C CH CH
2
Cl
n
2) Nylon 66 :
NH(CH
2
)
6
NH CO (CH
2
)
4 C O
O
n
3) Terylene : OCH
2
CH
2
O C
O
C
O
n
4) PMMA :
CH
2
C
CH
3
COOCH
3
n
68. Which is incorrect about saccharin?
1) It is
SO
2
C
O
NH [Orthosulphobenzimide]
2) 550 times sweeter than sugar
3) Artificial sweetening agent 4) It is a methyl ester of dipeptide
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69.
1 2 3
, , and
4
atm. are the osmotic pressure of 5% (mass/volume) solutions of urea, fructose sucrose
and KCl respectively at certain temp. The correct order of their magnitude is
1)
1 4 2 3
> > > 2)
1 4 2 3
< < < 3)
4 1 2 3
> > > 4)
4 1 3 2
> > >
70. Which one of the following is not a surfactant?
1)
CH
3
(CH
2
)
15
N
+
CH
3
Br
CH
3
CH
3
2)
3 2 14 2 2
CH (CH ) CH NH
3)
3 2 16 2 2
CH (CH ) CH OSO Na
+
4) OHC (CH
2
)
14
CH
2
COO
Na
+
71. Which of the following statement is not true?
1) In the process of precipitation of silver from sodiumdicyanoargentate (I), the zinc act as reducing agent
as well as complexing agent
2) In the process of roasting, the copper pyrites is converted into a mixture of Cu
2
S and FeS which inturn
are partially oxidised
3) Limonite, haematite and magnesite are minerals of iron
4) The extraction of zinc from zincblende is achieved by roasting followed by reduction with carbon
72. Sodiumthiosulphate (Hypo) is prepared by
1) Reducing Na
2
SO
4
with H
2
S 2) Boiling Na
2
SO
3
solution with sulphur
3) Neutralising H
2
S
2
O
3
with NaOH 4) Boiling sulphur with Na
2
CO
3
73. Which of the following statement is unacceptable?
1) Among the oxoacids of chlorine, HOCl, HOClO, HOClO
2
and HOClO
3
, the weakest is HOClO
2
2) Among the halide ions, F
4) ClF
3
and BrF
3
are used to prepare UF
6
74. Which of the following statements about actinoid is incorrect?
1) Most of the actinoids are synthetic elements
2) Actinoids include the element
104
Rf
3) Actinoids have variable oxidation states ranging from +3 to +7
4) They have no reaction with alkali
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75. In Victor Mayers method, 0.2 g of an organic substance displaced 56 mL of air at STP. The molecular
mass of the compound is
1) 56 2) 112 3) 80 4) 28
76. At absolute zero
1) Only para hydrogen exists 2) Only ortho hydrogen exists
3) Both para and ortho exist in the ration 1 : 1 4) Both ortho and para exist in the ratio 3 : 1
77.
,
3
4 2 2
2 4
CH Cd
HgSO SOCl ( O)
2 2 Dil.H SO
C H (A) (B) (C) D , compound (D) is
1) Propanone 2) Butanone 3) Propanal 4) t-butyl alcohol
78. , ,
NBS Alc.KOH
3 2 2
CH CH CH CH X Y = . The compound (Y) is
1) But-3-en-2-ol 2) But-3-en-1-ol 3) 1,3-Butadiene 4) 1,2-Butadiene
79. Main product formed when benzene is alkylated with n-propyl chloride in presence of anhydrous AlCl
3
is
1) Ethyl and methyl benzene 2) n-propyl benzene
3) Isopropylbenzene 4) Chlorobenzene
80.
2
4 2 4 2
z
xClO yMnO zOH xClO yMnO H O
2
+ + + +
. In this balanced equation x, y, z are
1) 2, 3, 6 2) 1, 3, 4 3) 1, 3, 6 4) 2, 6, 6
81. Which of the following act as a sink for CO?
1) Plants 2) Haemoglobin
3) Microorganisms present in the soil 4) Oceans
82. A mixture of hydrazine (N
2
H
4
) and 58-60% solution of H
2
O
2
is used as
1) Antiseptic 2) Mild bleaching agent 3) Fentones reagent 4) Rocket fuel
83. Aluminium (III) chloride forms a dimer because
1) Higher coordination number can be achieved by Al
2) Aluminium has high ionisation enthalpy
3) Aluminium belongs to group 13
4) It cant form a trimer
84. The possible number of spectral lines when an electron jumps from 5th shell to second shell is/are
1) 4 2) 2 3) 3 4) 6
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85. The compressibility factor (Z) for 1 mol CH
4
at low pressure is
1) 1
m
a
V RT
2)
3
8
3)
m
ab
1
V RT
4)
m
a
b
V RT
STLDY CETRE
PALA
1. 3 The topmost and bottommost figures are short circuited. simple circuit is shown below
2. 3
2
1
V
P
R
=
The coil is cut into two pieces , its resistance becomes R/2. As they are in parallel,
equivalent resistance = R/4
P
2
=
2
V
R / 4
=
2
V
4
R
= 4P
1
1
2
P 1
P 4
=
3. 2 V = -kxy
x
dV
E ky
dx
= =
y
dV
E kx
dy
= =
2 2
x y
E E E = + =
2 2
k x y Kr; E r + =
4. 3
Let the potential at F and D is zero. Then the potential at E is +V
1
and potential at C is +V
2
. Also the
potential at G is -V
3
and let the potential at A is V.
Consider the junction A. Total charge of all the plates connected to a junction is zero, according to
Kirchoffs law.
1 2 3
q q q 0 + + = , , ,
1 1 2 2 3 3
V V C V V C V V C + + (
= 0
1 1 1 2 2 2 3 3 3
VC VC VC V C VC V C + + + = 0
,
1 2 3
V C C C + + =
1 1 2 2 3 3
VC V C VC + V =
1 1 2 2 3 3
1 2 3
VC V C V C
C C C
+
+ +
5. 1 At angular frequency e, the current in R.C circuit is given by
,
rms
rms
2
2
V
I (1)
1
R
C
=
+
e
Also
,
rms rms
2
2
I V
(2)
2
3
R
C
=
+
e
From (1) and (2)
2
2 2
5
3R
C
=
e
ie
c
X 3
R 5
=
6. 3
s s
p p
e N
e N
=
s
s
N 220
N 500
2200 5000
= =
7. 2
0
0
E
B
C
=
FT
14A
/AIPMT/MCD[A1] 2 STLDY CETRE
8. 3
IA F I
F P
C A C
= = =
9. 3 Energy received from sun = 2 cal cm
-2
min
-1
= 8.4 Jcm
-2
min
-1
Energy of photon , E =
34 8
19
10
hC 6.6 10 3 10
3.6 10 J
5500 10
= =
i
;
19
19
8.4
n 2.3 10
3.6 10
= =
10. 1
0 0
h h ev 6.2 5 11.2eV o= o + = + =
hc
11.2eV =
i
34 8
0
19
hc 6.6 10 3 10
1104.9A
11.2eV 11.2 1.6 10
i = = =
This incident radiation lies in ultraviolet region
11. 1
e e nh eh n
L . .
2m 2m 2 2m 2
|
= = =
|
'
=
B
n
2
; n
12. 1
2 2 2
2
h P h
P ; E
c 2M 2MC
o o
= = =
13. 3
14. 1 A
v
in dB = 10 log
10
1000 = 10 3 log
10
10 = 30 dB
15. 3
7
5 2 0 2
I 4 10 4
Bp 4 10 wbm
2R 2 0.02
= = =
;
7
5 2 0 1
I 4 10 3
Bq 3 10 wbm
2R 2 0.02
= = =
2 2 5 2
B Bp Bq 5 10 wbm
= + =
16. 2 A long straight conductor carrying I passes through O, then by symmetry, all points of the circular
paths are equivalent and hence the magnitude of magnetic field should be same at these points
0
B.d I =
}
17. 2
1 MBcos
v
2 i
o
=
v Bcos o
2
v
B
cos
o
0
1
0
2
B 400 cos 60
16: 9 3
B cos 30 225
= =
18. 1
I
T 2
MB
=
I
M
I ; M
2
2
2 I
T' 2 T
2 M B
= =
19. 1 Condition of no emergence is A > C . As angle of prism is greater than critical angle for blue and
green coloured rays, total internal reflection will take place at second surface and hence the arrangement
will separate red colour from blue and green
20. 2 The given prism is a right angled prism,
0
LMN 45 Z =
, since the rays suffering T.I.R the critical
angle is angle of incidence in denser medium for which the angle of refraction in the rarer medium is
90
0
, ie C = 45
0
FT
14A
/AIPMT/MCD[A1] 3 STLDY CETRE
By snells law
;
0
1 1
2
sin C sin 45
= = =
21. 1
D
d
i
| = | i
also
1
i
1
| i
| |
= = =
| |
' '
5
tan i
3
=
1
5
i tan
3
|
=
|
'
23.. 3 m = linear density =
M
L
(
; A = force = [MLTT
2
]
[B] =
j
j
A
M
=
2
1
MLT
ML
(
(
=
2 2
L T
(
= [latent heat]
24. 3 Velocity of the thiefs car with respect to ground is,
TG
V 10m/ s =
Velocity of police van with respect to ground ,
PG
72 5
V 72km/ hr 20m/ s
18
= = =
Velocity with which bullet will hit the target is
BT BG GT BP PG GT
V V V V V V 20 5 10 15m/ s = + = + + = + =
25 3 Both the stones will have same initial downward velocity u at the falling point. Hence they will
reach the ground with same velocity.
26. 4
2 2 2
u sin 2 3u sin
g 2g
u u
=
27. 4
1
V 30km/ h =
due north;
2
V =
due south,
2 2
| V | 30 30 42.4 A = + =
km/h towards south - west
28. 3 2 rev/s e= ; 4 rad/s ;
2
r
a r = e ;
2
0.25 16 =
;
2
4 =
29. 1 W= f = R = 0.2 10N 2N =
30. 1 Impulse and change in momentum are in the same direction
31. 4 power developed =
100
70
mgh =
100
70
05 10
60
9 8 30 3500
3
.
.
= W
32. 4
33. 3
i i
cm
i
m x M 0 M 0 M 2 2
x
m M M M 3
_ + +
= = =
_ + +
i i
cm
i
m y M 2 M 0 M 0 2
y
m M M M 3
_ + +
= = =
_ + +
FT
14A
/AIPMT/MCD[A1] 4 STLDY CETRE
Position vector of centre of mass is ,
2
i j
3
+
34. 2 By theorem of parallel axes ,
2
cm
I I Md = +
,
2
2
0 0
L ML
I I M I
2 4
= + = +
35. 4
2
1
R
g
g g
4
R R
|
= =
|
+
'
; Since
1
T
g
o
;
2
1
T
g
2
g
T
4
= =
; T
2
= 2T
36. 1 Potential at the given point = potential at the point due to the shell + potential due to the particle
=
GM 2GM
a a
=
3GM
a
37. 3
2
0 0 1
T T
2 ; 2
9 g 7 g
l
l
= = ,
2
1
2
7
9
=
l
l
38. 4
2
E a o
39. 4 Since the body floats completely immersed, density of the body = density of water.
Hence mass of the body is (100 x 1) g. So total mass = 400g + 100g = 500 g
40. 4
A
A
A
l
l
l
= = = = =
F
A
L
Y
L
L
A
A
A r
1
2
1
2
2
1
2
1
2
1
4
1
8
; ( )
41. 2 Slope at x = 0 at t = 0 is positive. ie., particle velocity is in negative y - direction, ie, particle at x = 0 is
travelling in negative y direction. So (2) is the correct option
42. 1 For fundamental mode of vibration.
4
i
=
or
4 i =
.
Now,
v f = i
ie
340 264 4 =
0.3219m 32.19cm = =
43. 4 According to wiens displacement law
1 2
1 1 2 2 2 1
2 1
T 0.26
T T ; 2, T 2T
T 0.13
i
i = i = = = =
i
By stefanss law, E =
4
T o
;
,
4 4
1 1 1
4 4
2 2
1
E T T 1
E T 16
2T
o
= = =
o
44. 4 w =Q
1
Q
2
;
1 2 1 2
1 1
Q Q T T
Q T
=
;
2
Q 4.8Kcal; w 6 4.8 1.2 = = =
45. 1 CH CH C
e t
o
= 5 7 0
2
/ ;
C
RT
m
ie
RT R
rms
= =
3 3
4
5
7
3 273
2
;
ie T = 273 K = 0
o
C
CHEMISTRY
46. 1 According to Arrhenius equation, k = Ae
Ea/RT
comparing, the given value of
k = (4.5 x 10
11
s
1
)e
28000K/T
We get
Ea 28000 K Ea
or 28000 K
RT T R
= =
Hence Ea = 28000 K x R = 28,000 K x 8.314 K
1
mol
1
= 232792 J mol
1
= 232.792 kJ mol
1
47. 4 Both
3
NO
and
2
3
CO
have 32 electrons and both are planar/triangular
48. 1 During crystallisation, molecules attain more ordered state
49. 2
0 0
cell
G nFE A = = 2 (mol)
96500 (C.mol
1
)
0.236 V = 45548 CV = 45548 J = 45.55 kJ
50. 2 pH = log ( ,
total
H
+
A) For 10
6
M, pH = 6
B) For 10
7
M, pH = log(10
7
+ 10
7
) = 6.69
C) For 10
8
M, pH = log (10
8
+ 10
7
) = 6.96
D) For 10
9
M, pH = log(10
9
+ 10
7
) = 6.9956
~
7.0
51. 3
52. 2
,
3 4 4 2
2
2 2 2 2
Co NH Cl Ma b type
Show geometrical cis & trans isomerism
AuCl Br Ma B type
(
`
)
, ,
2 3 5
5
Co NO NH Mab
+
(
type dont show isomerism
53. 4 RF and RI cant be prepared because fluorination is so fast that explosion occurs while iodination is
slowest and produces HF, a strong reducing agent which causes the reaction to proceed backward
54. 2 I.E. o
1
screening effect
55. 1 Hydration is exothermic ( H, ve) A it is spontaneous ( G, ve) A also randomness decrease
( , S, ve A
56. 2 Group 15 fluorides act as F
ion acceptor
57. 4
V
V KT V K T or K
T
A
= A = A =
A
;
V 1 1
V. T V T
A
= o o
A
So graph between
and T will be a rectangular hyperbola
58. 2
1
KE.m
i o
59. 3
60. 3
O
E
+
O
H
E
Fairly stable neutral conjugate ketone
61. 2
2 2
3
SnCl / HCl H O
3 3 3 NH
CH C N CH CH NH CH CHO
=
62. 4 The aldehydes which dont have o -hydrogen atoms show disproportionation. These may be aliphatic
aldehyde (HCHO) or aromatic aldehyde.
63. 1
64. 3
65. 2 The acidic character of an aminoacid molecule is due to
3
NH
+
group which is less acidic than
COOH group, while the basic character of an aminoacid is due to COO
CH
3
CH CH
3 + H
2
O
80. 3
2
4 2 4 2
( Z 6)
( x 1) ( y 3)
ClO 3MnO 6OH ClO 3MnO 3H O
=
= =
+ + + +
81. 3 CO is converted to CO
2
by the microorganisms present in the soil
82. 4
83. 1
84. 4 Total no. of spectral lines observed
, ,
2 1 2 1
n n n n 1
2
+
, , 5 2 5 2 1
6
2
+
=
85. 1
,
m 2
m
a
P V b RT
V
|
+ =
|
'
; At low pressure, V
m
becomes large. Hence b is neglected
m
m
a
PV RT
V
+ =
; m
m
a
PV RT
V
= =
; Z =
m
m
PV a
1
RT V RT
=
86. 2 Synthesis of a chiral compound from achiral compound in the absence of optically active agent always
produces a racemic modification
87. 2 Ceric ammonium nitrate gives test for OH group. Iodoform test is positive due to the presence of
CH
3
CH
OH
-gr o up
88. 3
, ,
fcc pc 3 3
a A
4 M 1 M
N 3 N 2
= =
;
3
fcc
Pc
4 2 32
1.18
f 1 3 27
| |
= = =
| |
' '
89. 4 sp
2
hybridised with bent shape
90. 1 Pyrophosphorous acid
P
O
H
OH O
P
O
OH
H
+3
FT
14A
/AIPMT/MCD[A1] 6 STLDY CETRE
91. 3
92. 4
93. 3
94. 2
95. 3
96. 2
97. 3
98. 2
99. 4
100. 2
101. 2
102. 2
103. 1
104. 4
105. 1
106. 4
107. 1
108. 1
109. 2
110. 2
111. 1
112. 2
113. 4
114. 2
115. 3
116. 1
117. 1
118. 2
119. 4
120. 1
121. 4
122. 3
123. 2
124. 4
125. 2
126. 3
127. 1
128. 3
129. 2
130. 2
131. 1
132. 3
133. 4
134. 2
135. 3
136. 1
137. 2
138. 4
139. 2
140. 3
141. 3
142. 3
143. 4
144. 4
145. 4
146. 4
147. 2
148. 1
149. 1
150. 1
151. 1
152. 1
153. 2
154. 2
155. 3
156. 4
157. 1
158. 2
159. 1
160. 4
161. 4
162. 3
163. 3
164. 1
165. 4
166. 3
167. 2
168. 2
169. 4
170. 4
171. 3
172. 4
173. 2
174. 2
175. 3
176. 3
177. 2
178. 3
179. 1
180. 4