Documente Academic
Documente Profesional
Documente Cultură
ions.
[Total: 9]
12
5070/41/M/J/10 UCLES 2010
For
Examiners
Use
10 A student investigated the rise in temperature when sulfuric acid was added to a solution
containing 1.00 mol/dm
3
sodium hydroxide, using the apparatus shown below.
burette
sulfuric
acid
thermometer
stirrer
beaker
1.00 mol / dm
3
sodium hydroxide
20.0 cm
3
of 1.00 mol/dm
3
sodium hydroxide was poured into a beaker. The temperature of
both this solution and the sulfuric acid was 25C.
Following successive additions of 5.0 cm
3
volumes of sulfuric acid from the burette, further
temperature readings were taken.
The diagrams below show parts of the thermometer stem giving the temperature after the
addition of 5.0, 15.0 and 25.0 cm
3
of sulfuric acid.
25
30
35
25
30
35
20
addition of
5.0 cm
3
of
sulfuric acid
addition of
15.0 cm
3
of
sulfuric acid
addition of
25.0 cm
3
of
sulfuric acid
25
30
13
5070/41/M/J/10 UCLES 2010 [Turn over
For
Examiners
Use
(a) Use the diagrams to complete the following table of results.
volume of sulfuric acid / cm
3
temperature / C
0.0 25
5.0
10.0 29
15.0
20.0 33
25.0
30.0 29
35.0 26
[1]
(b) Plot these results on the grid below and connect the points with two intersecting
straight lines.
volume of sulfuric acid
added / cm
3
0
25
20
30
35
5 10 15 20 25 30 35 40 45
[3]
14
5070/41/M/J/10 UCLES 2010
For
Examiners
Use
Use the graph to answer the following questions.
(c) (i) State the temperature at the intersection of the two lines (highest temperature).
.............................................. C [1]
(ii) What volume of sulfuric acid produced this temperature?
........................................... cm
3
[1]
(d) 20.0 cm
3
of 1.00 mol/dm
3
sodium hydroxide was used in the experiment.
(i) Write an equation for the reaction between sodium hydroxide and sulfuric acid.
............................................................................................................................. [1]
(ii) Using your answer to (c)(ii) calculate the concentration of the sulfuric acid.
.................................... mol/dm
3
[2]
(e) After the highest temperature was reached, explain why the temperature of the solution
decreased as more sulfuric acid was added.
..........................................................................................................................................
..........................................................................................................................................
..................................................................................................................................... [2]
[Total: 11]
15
5070/41/M/J/10 UCLES 2010
BLANK PAGE
16
5070/41/M/J/10 UCLES 2010
BLANK PAGE
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of
Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.