UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS General Certificate of Education Ordinary Level

CHEMISTRY Paper 1 Multiple Choice Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB is recommended)

5070/11
May/June 2012 1 hour

*2940770204*

READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 16.

This document consists of 14 printed pages and 2 blank pages.

IB12 06_5070_11/3RP UCLES 2012

[Turn over

2 1 A student measured the rate of reaction between calcium carbonate and dilute hydrochloric acid. A graph showing the volume of gas produced against time is shown.

volume / cm3

time / seconds

Which apparatus was used to measure the variables shown on the graph? A B C D 2 balance and gas syringe burette and pipette gas syringe and stop watch pipette and stop watch

A mixture of two substances is spotted onto a piece of chromatography paper. The paper is inserted into a beaker containing a liquid.

chromatography paper beaker spot of mixture liquid

For separation of the substances to occur the spot of mixture must A B C D 3 be placed so that the spot is just below the level of the liquid. be soluble in the liquid. contain substances of the same Rf values. contain substances that are coloured.

Which molecule contains a total of three covalent bonds? A B C D C2H4 H2 H2O N2

5070/11/M/J/12

UCLES 2012

3 4 The addition of dilute acid to a solution containing the anion Q and the subsequent use of limewater can be used to identify the anion Q. What is Q? A B C D 5 a carbonate a chloride an iodide a sulfate

Four substances have the following electrical properties. substance W X Y Z property does not conduct under any conditions conducts only in aqueous solution conducts in both the molten and solid states conducts in both the molten and aqueous states

What are these four substances? W A B C D HCl Pb S S X S HCl HCl NaCl Y NaCl NaCl Pb HCl Z Pb S NaCl Pb

The proton number of element X is 6. The proton number of element Y is 9. What is the formula of a compound of these elements? A X2Y3 B X3Y2 C XY3 D XY4

Which ion reacts with aqueous ammonia to give a precipitate that dissolves in an excess of ammonia? A Al 3+(aq) B Fe2+(aq) C Fe3+(aq) D Zn2+(aq)

UCLES 2012

5070/11/M/J/12

[Turn over

4 8 Which statement about aqueous sodium chloride is correct? A B C D 9 It contains sodium atoms. It contains two different types of molecules. It does not conduct electricity. It forms a white precipitate when added to aqueous silver nitrate.

15.0 cm3 of 1.0 mol / dm3 potassium hydroxide just neutralise 20.0 cm3 of a solution of nitric acid. What is the concentration of the acid? A B C D 0.75 mol / dm3 1.0 mol / dm3 1.5 mol / dm3 7.5 mol / dm3

10 An atom, X, contains 16 protons. Which statement about X is correct? A B C D It cannot form an ion. It contains 6 electrons in the outer shell. It contains 6 neutrons. It has relative atomic mass of 16.

11 The equation for the burning of hydrogen in oxygen is shown. 2H2(g) + O2(g) 2H2O(g) What does this equation indicate? A B C D 2 atoms of hydrogen combine with 2 atoms of oxygen. 2 g of hydrogen combine with 1 g of oxygen. 2 moles of steam can be obtained from 0.5 mole of oxygen. 2 moles of steam can be obtained from 1 mole of oxygen.

UCLES 2012

5070/11/M/J/12

5 12 The diagram shows an apparatus used to compare rates of diffusion. At which labelled position did a white deposit of ammonium chloride form?
A B C D

source of ammonia gas

source of hydrogen chloride gas

13 Which statement about conduction of electricity is correct? A B C D Electricity is conducted in aqueous solution by electrons. Electricity is conducted in a metal wire by ions. Electricity is conducted in a molten electrolyte by electrons. Electricity is conducted in an acid solution by ions.

14 In terms of electrons, what happens when potassium combines with iodine to form a compound? A B C D The atoms of both elements each lose one electron. The atoms of both elements each gain one electron. The potassium atoms each lose one electron and the iodine atoms each gain one electron. The potassium atoms each gain one electron and the iodine atoms each lose one electron.

15 Aqueous copper(II) sulfate is electrolysed using copper electrodes. Which equation represents the reaction taking place at the anode (positive electrode) in this electrolysis? A B C D Cu(s) Cu2+(aq) + 2e SO42(aq) SO2(g) + O2(g) + 2e Cu2+(aq) + 2e Cu(s) 4OH(aq) 2H2O(l) + O2(g) + 4e

UCLES 2012

5070/11/M/J/12

[Turn over

6 16 The combustion of methane is exothermic. The equation is given below. CH4 + 2O2 CO2 + 2H2O What can be deduced from the fact that the reaction is exothermic? A B C D Fewer bonds are broken than are made. Less energy is involved in breaking bonds than is involved in making bonds. More bonds are broken than are made. More energy is involved in breaking bonds than is involved in making bonds.

17 How does a catalyst increase the speed of a reaction? A B C D by increasing the collision frequency of particles by increasing the speed of the particles by increasing the temperature of the reaction by lowering the activation energy

18 Copper(II) carbonate powder was heated. The loss in mass was plotted against time as shown on the graph.

0.4

0.3 loss in mass / g 0.2

0.1

0 0 2 4 6 time / min 8 10

During which time interval is the reaction fastest? A 0 to 2 min B 2 to 4 min C 6 to 8 min D 8 to 10 min

UCLES 2012

5070/11/M/J/12

7 19 In which equation is the underlined element reduced? A B C D CuSO4(aq) + Mg(s) Cu(s) + MgSO4(aq) 2FeCl 2(s) + Cl 2(g) 2FeCl 3(s) 2SO2(g) + O2(g) 2SO3(g) Zn(s) + H2SO4(aq) ZnSO4(aq) + H2(g)

20 A sample of air was bubbled into water. The pH of the water slowly changed from 7 to 6. Which gas in the sample caused this change? A B C D carbon dioxide carbon monoxide nitrogen oxygen

21 Which compound is insoluble in water? A B C D lead sulfate silver nitrate sodium carbonate zinc chloride

22 The following statements about dilute sulfuric acid are all correct. 1 2 3 4 Addition of Universal Indicator shows that the solution has a pH value of less than 7.0. A white precipitate is formed when aqueous barium nitrate is added. The solution reacts with copper(II) oxide, forming a blue solution. The solution turns anhydrous copper(II) sulfate from white to blue.

Which two statements confirm the acidic nature of the solution? A 1 and 2 B 1 and 3 C 2 and 4 D 3 and 4

UCLES 2012

5070/11/M/J/12

[Turn over

8 23 Pieces of material are placed in turn between P and Q in the incomplete electrical circuit shown.

P Q bulb

Which material would not cause the bulb to light? A B C D aluminium diamond magnesium zinc

24 Which of the following pairs of compounds react together to produce ammonia? 1. ammonium nitrate and calcium carbonate 2. ammonium nitrate and calcium oxide 3. ammonium sulfate and calcium hydroxide 4. ammonium sulfate and calcium nitrate A B C D 1 and 2 only 1 and 4 only 2 and 3 only 3 and 4 only

25 Which reaction occurring in the blast furnace is an acid base reaction? A B C D C + CO2 2CO C + O2 CO2 CaO + SiO2 CaSiO3 Fe2O3 + 3CO 2Fe + 3CO2

UCLES 2012

5070/11/M/J/12

9 26 An atom of which element gains three electrons when it forms an ion? A B C D aluminium iron nitrogen silicon

27 A metal X forms oxides with the formulae XO and X2O3. Where is X in the Periodic Table? A B C D in Group II in Group III the second Period in the transition elements

28 Which pair of metals are not oxidised when added to water? 1. A B C D calcium 1 and 2 1 and 3 2 and 4 3 and 4 2. copper 3. potassium 4. silver

29 Part of the Periodic Table is shown. The letters are not the symbols of the elements.

V X Y

W Z

Which statement about the elements is correct? A B C D V is more reactive than X. W is more reactive than Z. Y is in the same Group as X. Z has a lower melting point than W.

UCLES 2012

5070/11/M/J/12

[Turn over

10 30 Three different beakers are set up as shown.

1 rod of metal Z 2 rod of metal W 3 rod of metal X

aqueous metal W salt

aqueous metal X salt

aqueous metal Y salt

In beaker 1 metal W is displaced from solution. In beaker 2 metal X is displaced from solution. In beaker 3 metal Y is displaced from solution. What is the order of decreasing reactivity of the four metals? most reactive A B C D W X Z Z X Y W X Y W X W least reactive Z Z Y Y

31 Which gases are formed during the production of aluminium by electrolysis of molten aluminium oxide? A B C D carbon dioxide, carbon monoxide, oxygen carbon dioxide, carbon monoxide, sulfur dioxide carbon dioxide, oxygen, sulfur dioxide carbon monoxide, oxygen, sulfur dioxide

32 Which pair of gases could be removed from the atmosphere using calcium carbonate? A B C D CO2 and O3 CO and SO2 CH4 and NO2 NO2 and SO2

UCLES 2012

5070/11/M/J/12

11 33 In which parts of a motor car do the reactions, shown in the equations, take place? N2 + O2 2NO A B C D engine engine exhaust exhaust 2CO + 2NO 2CO2 + N2 engine exhaust engine exhaust

34 The diagrams show four monomers.

H 2N NH2 HOOC NH2 HO NH2 HO OH

How many of these monomers would react with the molecule below to form a polymer?
HOOC COOH

35 For which molecules are the empirical and molecular formulae the same? 1. methanoic acid, HCO2H 2. ethanoic acid, CH3CO2H 3. propanoic acid, C2H5CO2H 4. butanoic acid, C3H7CO2H A B C D 1, 2 and 3 only 1 and 3 only 2 and 3 only 2, 3 and 4 only

36 A compound Y is thought to be an organic acid. Which reaction shows that Y is an organic acid? A B C D It reacts with an alcohol to form an ester. It reacts with magnesium to form hydrogen. It reacts with sodium carbonate to form carbon dioxide. It turns litmus red.

UCLES 2012

5070/11/M/J/12

[Turn over

12 37 A 10 cm3 sample of a gaseous hydrocarbon is completely burnt in oxygen. The total volume of the products is 70 cm3. All gas volumes are measured at room temperature and pressure. Which equation represents the combustion of the hydrocarbon? A B C D CH4(g) + 2O2(g) CO2(g) + 2H2O(g) C2H4(g) + 3O2(g) 2CO2(g) + 2H2O(g) C3H8(g) + 5O2(g) 3CO2(g) + 4H2O(g) 2C2H6(g) + 7O2(g) 4CO2(g) + 6H2O(g)

38 The boiling points of the alcohols increase as their relative molecular mass increases. Which alcohol has the highest boiling point? A B C D butanol ethanol methanol propanol

39 Which of the following is a type of naturally occurring polymer? A B C D paraffin polyethene protein sugar

UCLES 2012

5070/11/M/J/12

13 40 Compound Q reacts with bromine to form the compound shown.

H H C Br H C Br H C H H C H H

Which is compound Q?
A H C H Br C H C H H C H H H C Br H C B H C H H C H H

C H H C H H C H H C H C H H H C H H C

D H C H C H H

UCLES 2012

5070/11/M/J/12

14 BLANK PAGE

UCLES 2012

5070/11/M/J/12

15 BLANK PAGE

UCLES 2012

5070/11/M/J/12

University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity.

UCLES 2012

DATA SHEET The Periodic Table of the Elements

Group III
1

I H
Hydrogen

II

IV

VI

VII

0
4

He
Helium

1 11 12 14 16 19

2 20

Li
Boron Carbon

Be
5 27 28 6 7

N
Nitrogen

O
Oxygen

F
Fluorine

Ne
Neon

Lithium

Beryllium

8 31 32

9 35.5

10 40

23

24

Na
Aluminium

Mg
13 51 52 55 56 59 59 64 65 70

Al
14

Si
Silicon

P
Phosphorus

S
Sulfur

Cl
Chlorine

Ar
Argon

Sodium

Magnesium

11

12

15 73 75

16 79

17 80

18 84

39

40

45

48

K
Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc

Ca
23 93 96 101 103 106 108 112 24 25 26 27 28 29 30

Sc

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zn
31

Ga
Gallium

Ge
Germanium

As
Arsenic

Se
Selenium

Br
Bromine

Kr
Krypton

Potassium

Calcium

Scandium

Titanium

19

20

21

22

32 115 119

33 122

34 128

35 127

36 131

16

85

88

89

91

Rb
Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver

Sr
41 181 195 184 186 190 192 197 42 43 44 45 46 47

Zr

Nb

Mo

Tc

Ru

Rh

Pd

Ag
48

Cd
Cadmium

In
Indium

Sn
Tin

Sb
Antimony

Te
Tellurium

I
Iodine

Xe
Xenon

5070/11/M/J/12
49 201

Rubidium

Strontium

Yttrium

Zirconium

37

38

39

40

50 204 207

51 209

52

53

54

133

137

139

178

Cs
Tantalum Iridium Tungsten Rhenium Osmium Platinum

Ba
73 77 74 75 76 78

La Ta W Re Os Pt

Hf

Ir
79

Au
Gold

Hg
Mercury

Tl
Thallium

Pb
Lead

Bi
Bismuth

Po
Polonium

At
Astatine

Rn
Radon

Caesium

Barium

Lanthanum

Hafnium

55

56

57

72

80

81

82

83

84

85

86

226

227

Fr
140 141 144 150

Ra

Ac
152 157 159 162 165 167 169 173 175

Francium

Radium

Actinium

87

88

89

*58-71 Lanthanoid series 90-103 Actinoid series Ce

Cerium Praseodymium Neodymium Promethium

Pr
59 60 238 61

Nd

Pm
62

Sm
Samarium

Eu
Europium

Gd
Gadolinium

Tb
Terbium

Dy
Dysprosium

Ho
Holmium

Er
Erbium

Tm
Thulium

Yb
Ytterbium

Lu
Lutetium

58 232

63

64

65

66

67

68

69

70

71

a = relative atomic mass

Key Th
Thorium Protactinium Uranium

X Pa
91 92

X = atomic symbol
90

U
93

Np
Neptunium

Pu
Plutonium

Am
Americium

Cm
Curium

Bk
Berkelium

Cf
Californium

Es
Einsteinium

Fm
Fermium

Md
Mendelevium

No
Nobelium

Lr
Lawrencium

b = proton (atomic) number

94

95

96

97

98

99

100

101

102

103

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).