TIME 1 hour

INSTRUCTIONS TO CANDIDATES
Do not open this booklet until you are told to do so.
Write your name, Centre number and candidate number on the answer sheet in the spaces provided
unless this has already been done for you.
There are forty questions in this paper. Answer all questions. For each question, there are four
possible answers, A, B, C and D. Choose the one you consider correct and record your choice in soft
pencil on the separate answer sheet.
Read very carefully the instructions on the answer sheet.
INFORMATION FOR CANDIDATES
Each correct answer will score one mark. A mark will not be deducted for a wrong answer.
Any rough working should be done in this booklet.
A copy of the Periodic Table is printed on page 16.
This question paper consists of 15 printed pages and 1 blank page.
MML 2691 1/02 S30311/1
UCLES 2002 [Turn over
UNIVERSITY OF CAMBRIDGE LOCAL EXAMINATIONS SYNDICATE
Joint Examination for the School Certification
and General Certificate of Education Ordinary Level
CHEMISTRY 5070/1
PAPER 1 Multiple Choice
OCTOBER/NOVEMBER SESSION 2002
1 hour
Additional materials:
Multiple Choice answer sheet
Soft clean eraser
Soft pencil (type B or HB is recommended)
1 Which property of a gas affects the rate at which it spreads throughout a laboratory?
A boiling point
B molecular mass
C reactivity
D solubility in water
2 The graph gives the melting points of mixtures of lead and tin.
The graph shows that any mixture of lead and tin must have a melting point
A above that of tin.
B below that of lead.
C below that of both tin and lead.
D between that of tin and lead.
3 From which mixture can the underlined substance be obtained by adding water, stirring and
filtering?
A calcium carbonate and sodium chloride
B copper(II) sulphate and sodium chloride
C ethanoic acid and ethanol
D iron and magnesium
100
100 50 0
100
200 200
300 300
400 400
m.p. of
pure lead
m.p. of
pure tin
melting
point/C
% tin in the mixture
2
5070/1/O/N/02
4 An aqueous solution of a sulphate is made from a solid hydroxide, of a metal M, by the reaction:
M(OH)
2
(s) + H
2
SO
4
(aq)

MSO
4
(aq) + 2H
2
O(l)
For which hydroxide would the method not work?
A barium hydroxide
B copper(II) hydroxide
C iron(II) hydroxide
D magnesium hydroxide
5 Which ion has the most shells that contain electrons?
A Al
3+
B Be
2+
C N
3
D S
2
6 The table gives data about four substances.
Which substance could be an ionic compound?
3
5070/1/O/N/02 [Turn over
compound
A
B
C
D
melting point / C
73
32
474
805
electrical conductivity
in aqueous solution
good
poor
poor
good
7 The number of outer shell electrons for the atoms of the first 12 elements in the Periodic Table is
plotted against the proton number of the element.
Which graph is obtained?
12 11 10 9 8 7 6 5 4 3 2 1
12
11
10
9
8
7
6
5
4
3
2
1
n
u
m
b
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r

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f

o
u
t
e
r
s
h
e
l
l

e
l
e
c
t
r
o
n
s
proton number
12 11 10 9 8 7 6 5 4 3 2 1
12
11
10
9
8
7
6
5
4
3
2
1
n
u
m
b
e
r

o
f

o
u
t
e
r
s
h
e
l
l

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c
t
r
o
n
s
proton number
12 11 10 9 8 7 6 5 4 3 2 1
12
11
10
9
8
7
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4
3
2
1
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proton number
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12
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7
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3
2
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s
proton number
A B
C D
4
5070/1/O/N/02
8 The table shows the electron structures of four elements.
Which pair of atoms will form a covalent substance?
A two atoms of W
B two atoms of X
C an atom of Wand an atom of X
D an atom of Y and an atom of Z
9 Which substance contains covalent bonds, but also conducts electricity?
A brass
B graphite
C iodine
D steel
10 One mole of each of the following compounds is burnt in excess oxygen.
Which compound will produce three moles of carbon dioxide and three moles of steam only?
A C
3
H
8
B C
3
H
7
OH C C
3
H
7
CO
2
H D CH
3
CO
2
CH
3
11 When zinc reacts with dilute sulphuric acid a gas is released.
What happens to the zinc and what is the gas released?
5
5070/1/O/N/02 [Turn over
element
W
X
Y
Z
electronic structure
2, 6
2, 8
2, 8, 1
2, 8, 7
A
B
C
D
the zinc is
oxidised
oxidised
reduced
reduced
the gas is
hydrogen
sulphur dioxide
hydrogen
sulphur dioxide
12 Which pair of metals X and Y will produce the highest voltage when used as electrodes in a
simple cell?
13 Four electrolytes were electrolysed using carbon electrodes.
Which set of data is correct?
metal Y in a
solution of a
salt of Y
porous wall
metal X in a
solution of a
salt of X
6
5070/1/O/N/02
A
B
C
D
metal X
copper
magnesium
magnesium
zinc
metal Y
silver
silver
zinc
copper
A
B
C
D
electrolyte
CuSO
4
(aq)
NaCl (aq)
NaH (l)
PbBr
2
(l)
anode cathode
oxygen
chlorine
sodium
lead
copper
sodium
hydrogen
bromine
product at
14 Which pair of substances are isotopes?
A
12
6
C and
14
6
C
B carbon dioxide and carbon monoxide
C diamond and graphite
D C
2
H
4
and C
3
H
6
15 Which step in the diagram shows the process of photosynthesis?
16 Dissolving ammonium nitrate in water is endothermic.
Which graph shows how the temperature alters as the ammonium nitrate is added to water and
then the solution is left to stand?
temperature
room
temperature
time
temperature
room
temperature
time
temperature
room
temperature
time
temperature
room
temperature
time
A B
C D
carbon dioxide
in atmosphere
carbon
compounds
in plants
carbon
compounds
in animals
oil and
natural gas
A
B C
D
7
5070/1/O/N/02 [Turn over
17 If a strip of magnesium is dropped into excess hydrochloric acid an exothermic reaction occurs.
The rate of this reaction increases during the first few seconds because
A the amount of magnesium is decreasing.
B the magnesium is acting as a catalyst.
C the solution is becoming hotter.
D the surface area of the magnesium is increasing.
18 The energy profile diagrams show how adding a substance X to a reaction mixture changes the
reaction pathway.
Which change is likely to be observed when X is added to the reaction mixture?
A The reaction becomes less exothermic.
B The reaction becomes more exothermic.
C The speed of the reaction decreases.
D The speed of the reaction increases.
19 Which process does not involve either oxidation or reduction?
A formation of ammonium sulphate from ammonia and sulphuric acid
B formation of nitrogen monoxide from ammonia
C formation of sulphuric acid from sulphur
D formation of zinc from zinc blende (ZnS)
energy
reactants
with X
without X
products
reaction pathway
8
5070/1/O/N/02
20 In separate experiments, an excess of aqueous sodium hydroxide or aqueous ammonia was
gradually added to a solution X.
In both experiments, a precipitate was obtained which dissolved in an excess of the added
reagent.
What could X contain?
A copper(II) nitrate
B iron(II) nitrate
C iron(III) nitrate
D zinc nitrate
21 An excess of dilute sulphuric acid reacts with both aqueous barium hydroxide and aqueous
barium chloride. In what way are the two reactions the same?
A A gas is produced.
B An insoluble salt is produced.
C The final pH is 7.
D Water is produced.
22 Which property decides the order of the elements in the Periodic Table?
A the masses of their atoms
B the number of electrons in the outer shell
C the number of neutrons in the nucleus
D the number of protons in the nucleus
23 The proton number of indium, In, is 49.
What is the most likely formula for the oxide of indium?
A In
2
O B In
2
O
3
C InO D InO
2
24 Which element in the table is likely to be a transition metal?
element melting point colour of chloride
A high blue
B low green
C high white
D low white
9
5070/1/O/N/02 [Turn over
25 Which feature of a metals structure is responsible for it conducting electricity?
A It contains positive ions.
B It has a sea of electrons.
C Its ions are tightly packed together.
D Its positive ions attract electrons.
26 Aluminium is extracted from purified bauxite by electrolysis but iron is extracted from haematite
by reduction with coke.
Why is iron not extracted by electrolysis?
A Haematite needs to be purified but bauxite does not.
B Iron is less reactive than aluminium.
C Reduction with coke is cheaper than electrolysis.
D Reduction with coke gives a purer product than electrolysis.
27 Old steel drums corrode quickly in a damp atmosphere but aluminium cans do not.
Which of the following correct statements explains this behaviour of aluminium?
A Aluminium has only one valency.
B Aluminium has a lower density than iron.
C Aluminium is above iron in the activity series.
D Aluminium is protected by its oxide layer.
28 Caesium is a metal that is more reactive than aluminium.
Which reaction would produce caesium?
A electrolysing aqueous caesium chloride
B electrolysing molten caesium chloride
C heating caesium carbonate
D heating caesium oxide with carbon
29 Which of the following gases cannot be removed from the exhaust gases of a petrol powered car
by its catalytic converter?
A carbon dioxide
B carbon monoxide
C hydrocarbons
D nitrogen dioxide
10
5070/1/O/N/02
30 A 100 cm
3
sample of bottled gas used for diving was placed in a gas syringe in the apparatus
shown.
The gas was passed backward and forward over heated copper turnings. The results obtained
were used to plot the graph.
What is the percentage of oxygen in the bottled gas?
A 20% B 30% C 70% D 80%
31 In the Haber process, nitrogen and hydrogen react to form ammonia.
N
2
(g) + 3H
2
(g) 2 NH
3
(g) H = 92 kJ / mol
Which factor increases both the speed of reaction and the amount of ammonia produced?
A addition of a catalyst
B decreasing the temperature
C increasing the pressure
D increasing the temperature
0 2 4 6 8 10 12
50
60
70
80
90
100
volume of gas
remaining/cm
3
number of times gas is
passed over hot copper
+
+
+
+ +
+ +
100 cm
3
syringe
100 cm
3
syringe heat
glass tube full of copper turnings
11
5070/1/O/N/02 [Turn over
32 Nitrates from fertilisers used on farmland can cause pollution.
Why do nitrates pollute rivers?
A Nitrates are salts.
B Nitrates are very soluble in water.
C Nitrates contain oxygen.
D Nitrate ions are negatively charged.
33 Which representation of dilute sulphuric acid is correct?
A H
2
(aq) + SO
2
4
(aq)
B 2H
+
(aq) + SO
2
4
(aq)
C 2H
+
(aq) + SO

4
(aq)
D H
2
SO
4
(l)
34 Which statement describes what happens when hydrogen and oxygen are used in a fuel cell?
A Electricity is generated directly.
B Electricity is used to produce water.
C Hydrogen is burned to form steam.
D Hydrogen reacts to form a hydrocarbon fuel.
35 The structures of an acid and an alcohol are shown.
Which pairing of names correctly identify the two compounds?
H H H
H
H
H
H
H
C C C
O
O
O
H
H
H
H
C C
H
H
H
H
C C
acid alcohol
12
5070/1/O/N/02
A
B
C
D
acid
ethanoic
ethanoic
propanoic
propanoic
alcohol
butanol
propanol
propanol
butanol
36 Which physical property of the alkanes does not increase as relative molecular mass increases?
A boiling point
B flammability
C melting point
D viscosity
37 The structures of four organic compounds are shown.
Which compounds decolourise bromine water?
A 1 and 2 B 1, 2 and 4 C 2 and 4 D 3 and 4
38 A polymer X was hydrolysed and the two products were
and
What can be deduced about X?
A It was a condensation polymer.
B It was starch.
C It was made by addition polymerisation.
D It was Terylene.
H
H
N
H
H
N
O O
HO C C OH
H
H
H
C
H
H H
H
H
H H
C
C C
O
O
H H
H
H
H
H
C C H
H
H
H
C C C
H
H
C
1 2 3 4
13
5070/1/O/N/02
39 Which polymer has the empirical formula CH?
40 In the polymerisation of ethene to form poly(ethene), there is no change in
A boiling point.
B density.
C mass.
D molecular formula.
H
H
H
H
C C
n
H
H
H
CH
3
C C
n
H
H
H
C
2
H
5
C
6
H
5
C C
n
H
H
H
C C
n
A B C D
14
5070/1/O/N/02
BLANK PAGE
15
5070/1/O/N/02
16
5070/1/O/N/02
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2
E
u
E
u
r
o
p
i
u
m
6
3
1
5
7
G
d
G
a
d
o
l
i
n
i
u
m
6
4
1
5
9
T
b
T
e
r
b
i
u
m
6
5
1
6
2
D
y
D
y
s
p
r
o
s
i
u
m
6
6
1
6
5
H
o
H
o
l
m
i
u
m
6
7
1
6
7
E
r
E
r
b
i
u
m
6
8
1
6
9
T
m
T
h
u
l
i
u
m
6
9
1
7
3
Y
b
Y
t
t
e
r
b
i
u
m
7
0
1
7
5
L
u
L
u
t
e
t
i
u
m
7
1
1
8
4
W
T
u
n
g
s
t
e
n
7
4
1
8
6
R
e
R
h
e
n
i
u
m
7
5
1
9
0
O
s
O
s
m
i
u
m
7
6
1
9
2
I
r
I
r
i
d
i
u
m
7
7
1
9
5
P
t
P
l
a
t
i
n
u
m
7
8
1
9
7
A
u
G
o
l
d
7
9
2
0
1
H
g
M
e
r
c
u
r
y
8
0
2
0
4
T
l
T
h
a
l
l
i
u
m
8
1
2
0
7
P
b
L
e
a
d
8
2
2
0
9
B
i
B
i
s
m
u
t
h
8
3
P
o
P
o
l
o
n
i
u
m
8
4
A
t
A
s
t
a
t
i
n
e
8
5
R
n
R
a
d
o
n
8
6
F
r
F
r
a
n
c
i
u
m
8
7
2
2
6
R
a
R
a
d
i
u
m
8
8
2
2
7
A
c
A
c
t
i
n
i
u
m
8
9

1
H
H
y
d
r
o
g
e
n
1
I
I
I
I
I
I
V
V
V
I
V
I
I
0