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2011/11/29 04055856
2. HAZARDS IDENTIFICATION
GHS Classification GHS Label Elements Pictogram or Symbol Signal Word Hazard Risk Statement Precautionary Statement Prevention Response : Not applicable for GHS classification. : None. : None. : Not hazardous. : Avoid contact with skin and eyes. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Wash with plenty of soap and water. : Not applicable. : Not applicable. : None known.
Mixture Silicone Wt %
0.1 - 1
Component Name
Octamethylcyclotetrasiloxane
GHS Classification
Flammable liquid: Category 3 Reproductive toxicity (Inhalation - vapour): Category 2 Chronic aquatic hazard: Category 4 Flammable liquid: Category 2 Skin corrosion/irritation: Category 2 Reproductive toxicity: Category 2 Specific target organ toxicity - single exposure (Inhalation - vapour): Category 3 (narcotic effects) Specific target organ toxicity - repeated exposure (Inhalation): Category 2 (central nervous system) Aspiration hazard: Category 1 Acute aquatic hazard: Category 2
108-88-3
(3)-2
C6H5CH3
<1
Toluene
Comments
: This product contains the above chemical(s) listed by Japanese regulations and/or classified and containing not less than cut-off value by GHS.
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5. FIRE-FIGHTING MEASURES
Extinguishing Media Unsuitable Extinguishing Media Specific Hazards during Fire Specific Fire Fighting Protection for Fire-fighter : On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire exposed containers. : None established. : None. : Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool. : Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals.
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Exposure Limits
Dow Corning guide: TWA 10 ppm. Japan Association on Industrial Health Guideline (2007): TWA 50 ppm (188 mg/m3). OSHA PEL (final rule): 8-Hour TWA 200 ppm, Ceiling 300 ppm, 10 minutes maximum duration 500 ppm. ACGIH TLV: TWA 20 ppm.
Engineering Measures : None should be needed. Local Ventilation : Recommended. General Ventilation Personal Protective Equipment Personal Protective Equipment for Routine Handling : No respiratory protection should be needed. Respiratory protection : None should be needed. Suitable Respirator : No special protection needed. Hand protection : Use proper protection - safety glasses as a minimum. Eye protection : Washing at mealtime and end of shift is adequate. Skin protection : Exercise good industrial hygiene practice. Wash after handling, especially before eating, Hygiene Measures drinking or smoking. Personal Protective Equipment for Spills : No respiratory protection should be needed. Respiratory protection : Use proper protection - safety glasses as a minimum. Eye protection : Washing at mealtime and end of shift is adequate. Skin protection : Avoid eye contact. Do not take internally. Use reasonable care. Precautionary Measures : If this product is heated to > 150 degrees C, trace quantities of formaldehyde may be Comments released, and adequate ventilation is required.
Note : These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions. For further information regarding aerosol inhalation toxicity, please refer to the guidance document regarding the use of silicone-based materials in aerosol applications that has been developed by the silicone industry (www.SEHSC.com) or contact the Dow Corning customer service group.
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The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing specifications.
: Please refer to Section 3, Section 4 Health Effect and Section15 ISHL Mutagen Substance. : Please refer to Section 3, Section 4 Health Effect and Section15 ISHL Carcinogen Substance. : Please refer to Section 3 and Section 4 Health Effect. : Please refer to Section 3 and Section 4 Health Effect.
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: This product contains substances which may cause adverse effects in the aquatic environment. : This product contains substances which may cause adverse effects in the aquatic environment. : No specific information is available.
: In soil, siloxanes are degraded. : Low potential to bioaccumulate. : Siloxanes are removed from water by sedimentation or binding to sewage sludge. : No specific information is available.
Notification Component(s)
Toluene
Wt %
<1
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Not applicable. Not applicable Not applicable. Not applicable. Not applicable. 4TH GROUP, 4TH CLASS PETROLEUMS (6,000L) Not applicable. Not applicable. Not Classified as a Marine Pollutant
All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. All ingredients listed or exempt. All ingredients listed or exempt. All ingredients listed or exempt. All components are listed on ENCS/ISHL or its exempt rule. All ingredients listed, exempt or notified. All ingredients listed or exempt. All chemical substances in this material are included on or exempted from the DSL. All ingredients listed or exempt.
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2002/95/EC 2000/53/EC EC No 1272/2008, ATP1 included EU04 REACH Annex XVII [Except EU03] EC No 552/2009 EU05 REACH SVHC on the Candidate List 2011-06-20 Substances do not directly mean legally regulated. It depends on use and other conditions. For more information please refer to "How to make JAMP MSDSplus".
These data are offered in good faith as typical values and not as product specifications. They are believed accurate as of the date of this Material Safety Data Sheet based on a review of current composition and information supplied by vendors. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. This Product has been developed and manufactured for general industrial use. For medical use, or other uses where safety considerations may be required, you must in advance test and review the safety of your intended application. Moreover, this Product is not for human implant nor human injection, nor use for applications which may present risk of accumulating inside human bodies.