CHEMISTRY

One hour and a half hours

Name : . Form :



SUMMATIVE ASSESSMENT
THIR TERM
ST!M
"#$%
TERENGGANU

SECTION A [ 15 marks ]
Four suggested answers labelled A& '& C and are given for each question.
Choose one correct answer.
$ A compound with the molecular formula CH
3
CHNH
!
"C##H e$i%t% in two %hape%& 'hat i%
it called(
A )%otope%&
' Ci% * tran% i%omer%&
C #ptical i%omer%&
+tructural i%omer%&

" 'hat rea,ent i% u%ed to differentiate the followin, compound% -elow(


A .romine water
' Car-on dio$ide
C Ethano/l chloride
0iluted h/drochloric acid
% 'hich reaction %how% the propa,ation %tep durin, the reaction -etween methane and
chlorine in the pre%ence of li,ht(
A H 1 Cl
!
HCl 1 Cl
' CH
2
1 Cl
1
CH
3
Cl 1 H
1
C CH
2
1 Cl
1
CH
3
1
1 HCl
CH
2
1 Cl CH
3
1 HCl
!
CH
!
#H
#H

( 'hich car-on atom can mo%t ea%il/ -e attac3ed -/ an electrophile(

A

CH
!
.r
H
3
C
0

C#CH
3
. C
) 'hich one of the followin,% will -e produced throu,h the reaction -etween phenol and
chlorine %olution(

A



'


C





3
#Cl
CH
3
#H
Cl
#H
Cl
Cl
Cl

| |
* 'hich compound can chan,e the C = # ,roup in propanone to C Cl

(
| |

A Chlorine ,a%
' 4ho%phorou% 5" chloride
C +odium chloride
0ilute h/drochloric acid
+ #ne component of -ee%wa$6 which i% u%ed a% a car poli%h6 ha% the formula
CH
3
CH
!
"
!2
C##CH
!
"
!7
CH
3
& 'hat are the product% of the acidic h/drol/%i% of thi%
component(
A CH
3
CH
!
"
!3
C##H and CH
3
CH
!
"
!7
C##H
. CH
3
CH
!
"
!2
C##H and CH
3
CH
!
"
!8
C##H
C CH
3
CH
!
"
!2
C##H and CH
3
CH
!
"
!7
#H
0 CH
3
CH
!
"
!2
#H6 CH
3
CH
!
"#H and C#
!
, 'hen -romine water i% added to phen/lamine6 the -romine water i% decolouri%ed&
'hich %tatement e$plain% the o-%er9ation a-o9e(
A 4hen/lamine o$idi%e% .r
!
into .r
:
&
' The NH
!
,roup in phen/lamine i% %u-%tituted with .r
!
&
C The NH
!
,roup phen/lamine react% with .r
!
&
.romine %u-%titute% h/dro,en in the -en;ene rin,&
2

- A%partame i% an artificial %weetener which ha% the %tructural formula a% follow%<
# #
== ==
H
!
N CH C NH CH C #CH
3
. .
CH
!
CH
!
| |
C##H

'hich functional ,roup i% no/ found in the a%partame molecule(

A E%ter ' Amino acid
C Car-o$/l ,roup Car-on/l ,roup
$# The repeatin, unit of a pol/mer i% a% follow%&

'hich of the followin, can produce the a-o9e pol/mer(
A
'
C
5

$$ 'hat are the %imilaritie% amon, %olid enantiomer% optical i%omer%"(

$ Relati9e molecular ma%%
" >eltin, point
% Chemical propertie%
A $
' $&"
C "&%
$&"&%
$" 'hat are the compound% produced when -utan:!:ol i% reflu$ed with acidified pota%%ium
man,anate5))" %olution(
$ .utanone
" .utanoic acid
% .utanol

A $
' $&"
C "&%
$&"&%
$% 'hat i% the t/pe of reaction that will occur to the compound -elow(
CH
3
C# CH
3


CH ? CHCH
3

$ Electrophilic addition
" Nucleophilic addition
% Electrophilic %u-%titution
@

A $
' $&"
C "&%
$&"&%
$( A part of a pol/mer %tructure i% a% follow%<
ANHC#CH
!
"
2
C#
!
CH
!
"
!
NHC#CH
!
"
2
C#
!
CH
!
"
!
:
'hich %tatement% are true a-out thi% pol/mer(
I )t can -e %/nthe%i%ed from C)C#CH
!
"
2
C#C1 and H#CH
!
CH
!
NH
!
&
" )t i% a pol/amide and al%o a pol/e%ter&
% )t i% re%i%tant a,ain%t al3aline h/drol/%i%&
A $
' $&"
C "&%
$&"&%


$) There are %aturated and un%aturated pol/mer%& 'hich pol/mer%" decolouri%e%" an acidified
%olution of pota%%ium man,anate 5))"(
$ 4ol/!:meth/l-uta:1 63:diene"
" 4ol/ethene"&
% 4ol/phen/lethene"
A $
' $&"
C "&%
$&"&%
B

SECTION B [15 marks]
Answer all questions in this section.
16 a" 0raw the %tructure of the maCor product of each of the followin, reaction%&
012 :'r 3 NH
%

0112 0CH
%
2
"
C'r
"
3 NaOH

01112 4CHO

[3 >ar3%]
-" The %tructural formula of an or,anic compound i% a% follow%<
H# CH
!
CHCH
3

#H
0raw the %tructural formula of the or,anic product%" formed when the compound
react% with each of the followin, rea,ent%<
i" %odium metal [1 mar3]
ii" An aDueou% %olution of %odium h/dro$ide& [1 mar3]
iii" An al3aline iodine %olution& [1 mar3]
i9" A hot acidic pota%%ium man,anate5))" %olution& [1 mar3]
8
Ethanol
i" CH
3
CH
!
>,.r
ii" H
3
#
1

17 a" Ethene react% with -romine 9ia electrophile addition mechani%m
i" 'hat i% meant -/ electrophile(
EEEEEEEEEEEEEEEEEEEEEEEEEEE&
EEEEEEEEEEEEEEEEEEEEEEEEEEE
EEEEEEEEEEEEEEEEEEEEEEEEEEEEEE
[1 mar3]
ii" 'rite a -alance eDuation for the reaction the reaction ta3in, place&
[! mar3%]
-" The formulae of pol/mer% F and G are ,i9en -elow&
i" 'rite the %tructural formulae of the monomer% of pol/mer% F and G&
[3 mar3%]

ii" +tate the t/pe% of pol/rneri%ation in9ol9ed in the formation of pol/mer% F and G&

4ol/mer F< EEEEEEEEEEEEEEEEEEEEEEEEEEEE
4ol/mer G< EEEEEEEEEEEEEEEEEEEEEEEEEEEE

[! mar3%]
7


SECTION C [30 marks]
Answer any two questions in this section.
$, a" )dentif/ the t/pe of i%omeri%m %hown -/ !:-utanol and -utenedioic acid&
E$plain wh/ the%e compound% e$hi-it i%omeri%m& 0raw the pair of i%omer% for
each compound&
[6 Marks]
-" An or,anic compound 4 ha% the molecular formulaC
5
H
1!
# 6& 4 to form H ha%
a chiral car-on atom and decolouri%e% hot6 acidified pota%%ium man,anate 5))"
%olution& .oth 4 and H form% a /ellow precipitate when reacted with an al3aline
iodine %olution& H form% a /ellow precipitate with !62:dinitrophen/lh/dra;ine&
0etermine the %tructural formula of 4 and H& E$plain the a-o9e o-%er9ation% and
write the appropriate eDuation% for the reaction%&
[9 Marks ]
$- a" i" 'rite the mechani%m of the reaction when 1:chloropropane i% reflu$ed with
aDueou% %odium h/dro$ide& Name the t/pe of reaction in9ol9ed&
[3 marks]
ii" +tate and e$plain how the rate of thi% reaction chan,e% when
1:chloropropane i% replaced -/ 1:-romopropane&
[3 marks]
iii" 'rite the eDuation% to %how how /ou would chan,e 1:chloropropane to
!:chloropropane&
[5 marks]
-" Catal/tic crac3in, i% a proce%% where lon, chained al3ane% are -ro3en into mi$ture
of %hort chained molecule%&

i" E$plain the importance of the catal/tic crac3in, proce%% in indu%trie%&
[! marks]
ii" +tate the condition% reDuired for thi% proce%%&
[! marks]
1I

"# +u,,e%t how each of the followin, con9er%ion% can -e carried out& )n each ca%e /our an%wer
%hould include %ucce%%i9e %tep% of the con9er%ion and al%o rea,ent and condition u%ed in each
%tep&
a" Ethanol to propanoic acid
[4 marks]
-" 14propanol to !4propanol
[3 marks]
c" !4-romopropane to propanone
[3 marks]
d" 4ropane414ol to !4meth/lpropanoic acid
[5
marks]
END OF QUESTION PAPER
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