Documente Academic
Documente Profesional
Documente Cultură
www.elsevier.com/locate/ijhydene
Plug-in hybrid with fuel cell battery charger
G.J. Suppes
Department of Chemical Engineering, University of Missouri, W2028 EBE, Columbia, MO 65211, USA
Received 20 January 2004; received in revised form 24 March 2004; accepted 20 April 2004
Available online 17 June 2004
Abstract
A new approach on vehicular fuel cell technology uses an on-board regenerative fuel cell (RFC) stack as a battery charger.
The RFCs electrolyser capability uses grid electricity to produce hydrogen and oxygen during an overnight charging process.
By using the RFC to recharge the vehicles battery pack during the day, the size of the battery pack can be reduced by 50%.
A sensitivity analysis evaluating vehicle specication and component performances suggests that small RFC stacks (e.g.
1 kW) would be commercially viable in plug-in vehicles at prices as high as $1800/kW for the RFC stack. The combination of a
RFC stack and a battery pack would cost less than the either an appropriately sized battery pack or fuel cell stack alone. Vehicles
using so-called tribrid power systems based on the combination of RFCs, battery packs, and internal combustion engines (ICE)
could be viable decades before vehicles powered solely by fuel cells that rely on a hydrogen refueling infrastructure.
? 2004 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
Keywords: Fuel cell; Hydrogen; Recharge; Plug-in; Eciency
1. Introduction
Important industrial issues on sustainability, balance of
trade, and creation of quality domestic jobs culminate on
petroleum fuels and the US crude oil imports now exceed-
ing $150 billion each year. For decades, eorts to displace
petroleum imports have fallen short due to the high costs of
alternatives and the limited energy feed stock options large
enough to displace crude oil. Today, fuel cell technology is
receiving much attention due to its potential to change the
rules in the transportation sector. In addition, closed-loop
fuel cell systems that are recharged with grid electricity
would emit zero tail-pipe emissions and lead to signicant
reductions in municipal air pollution.
Plug-in approaches that use onboard electrolysis to pro-
duce hydrogen are particularly attractive since they do not
rely on a hydrogen-refueling infrastructure and do not re-
quire the distribution of new fuels [1]. Preferably, regener-
ative fuel cells (RFC) would be used; a RFC operates both
as an electrolyzer and fuel cell.
a
t
l
e
a
s
t
2
5
%
o
f
t
h
e
r
a
n
g
e
m
u
s
t
c
o
m
e
f
r
o
m
b
a
t
t
e
r
i
e
s
t
o
m
e
e
t
p
e
r
f
o
r
m
a
n
c
e
n
e
e
d
s
.
W
h
e
n
n
o
b
a
t
t
e
r
i
e
s
a
r
e
n
e
e
d
e
d
,
t
h
e
f
u
e
l
c
e
l
l
s
t
a
c
k
i
s
s
i
z
e
d
t
o
m
e
e
t
a
l
l
p
o
w
e
r
r
e
q
u
i
r
e
m
e
n
t
s
T
o
t
a
l
B
a
t
t
e
r
y
B
a
t
t
e
r
y
H
2
H
2
F
u
e
l
I
C
E
W
e
i
g
h
t
W
e
i
g
h
t
W
e
i
g
h
t
W
e
i
g
h
t
B
a
t
t
e
r
y
F
u
e
l
c
e
l
l
T
a
n
k
E
l
e
c
t
r
o
l
y
z
e
r
T
o
t
a
l
(
k
m
)
p
a
c
k
p
a
c
k
(
k
m
)
(
k
W
h
)
c
e
l
l
(
$
)
b
a
t
t
e
r
y
t
a
n
k
b
a
t
t
e
r
y
t
a
n
k
c
o
s
t
c
o
s
t
c
o
s
t
(
$
)
(
k
m
)
(
k
W
h
)
(
k
W
)
(
k
g
)
(
k
g
)
(
$
)
(
$
)
(
$
)
(
$
)
(
$
)
6
4
0
0
6
4
2
7
.
7
5
0
$
0
0
.
0
2
7
.
7
$
0
$
4
2
$
0
$
5
9
,
4
7
9
$
1
1
1
$
0
$
5
9
,
6
3
1
6
4
1
6
5
4
8
2
0
.
7
2
.
5
9
$
1
0
0
0
6
4
.
1
2
0
.
7
$
9
6
$
3
1
$
2
0
0
0
$
3
0
8
7
$
8
3
$
3
0
8
7
$
9
3
8
5
6
4
3
2
1
0
3
2
1
3
.
8
1
.
7
3
$
1
0
0
0
1
2
8
.
2
1
3
.
8
$
1
9
2
$
2
1
$
4
0
0
0
$
2
0
5
8
$
5
5
$
2
0
5
8
$
9
3
8
5
6
4
4
8
1
5
1
6
6
.
9
2
0
.
8
6
$
1
0
0
0
1
9
2
.
3
6
.
9
$
2
8
8
$
1
0
$
6
0
0
0
$
1
0
2
9
$
2
8
$
1
0
2
9
$
9
3
8
5
6
4
6
4
2
0
0
0
0
$
1
0
0
0
2
5
6
.
4
0
$
3
8
5
$
0
$
8
0
0
0
$
0
$
0
$
0
$
9
3
8
5
that allow 8 h to fully charge the hydrogen tank) lead to less
costly power systems; however, these systems would have
greater limitations on performance which translates to the
ICE being needed more frequently to provide power when
the fuel cell stack has not had sucient time to recharge
the batteries. In principal, this predominantly translates to
more frequent gasoline refueling stops. Low sizing fac-
tors and relatively small fuel cells (e.g. 1:72 kW) would
make excellent entry-level systems for this market. For the
PFCHEV system of Table 1, the cost of the power sys-
tem could be further reduced by use of a sizing factor less
than 0.125/h.
The PFCHEV would benet from highly ecient bat-
teries and batteries with large charge/discharge lives. This
suggests that high-capacity capacitors, ywheels, and other
ecient and robust storage means could be used to advan-
tage on the PFCHEV. Regenerative braking is also more
important in the PFCHEV than in conventional HEV ve-
hicles due to the premium paid for plug-in capabilities.
Batteries with higher power outputs would also be needed
since the specic power outputs listed in Table 3 would be
insucient.
Other parameters such as battery costs, costs for tanks,
and cost penalties for weight had relatively minor impacts
within the range of parameters. The estimated costs for the
PFCHEV power systems at the threshold fuel cell cost solu-
tions ranged from $6000 to $12,000. Electricity costs were
not considered because electricity is an operating cost. The
operating costs are discussed elsewhere [2].
Table 6 summarizes a series of analyses on the impact
of plug-in range on threshold fuel cell costs. The range
had no impact on the threshold fuel cell costs, but it did
impact the size of the fuel cell needed to meet power re-
quirements. As the size of the fuel cell stack became larger
to achieve greater ranges, the advantage over the FCHEV
diminished to a factor of 3.4 at a range of 129 km per
day.
4.2. Market entry products
The sensitivity analysis indicates that a vehicle similar to
that specied in Table 1 would be an entry-level vehicle
having a threshold fuel cell price of $1792/kW and system
price of $4773 (Table 7 summarizes entry level pricing).
This would be an ecient, light-weight vehicle with up to
48 km per day in plug-in range. The HEV version of this
vehicle would include about 10:6 km in battery capacity at
a cost of about $830 plus the ICE ($1000). A premium of
about $2957 is paid for the plug-in option with a 48 km
capacity. At $1792/kW, a 50 kW power system would cost
about $90,000.
For a hybrid car, the extra cost for the battery pack and
electronics is partially recoverable in the form of reduced
fuel consumption. Plug-in vehicles would have consider-
ably less gasoline consumption, but per-km energy costs
would be about the same as with the HEV. The fuel costs
3
G.J. Suppes / International Journal of Hydrogen Energy 30 (2005) 113121 119
Table 5
Fuel cell costs ($/kW) below which the combination of a fuel cell charger and battery pack is less expensive than use of the battery pack
alone to meet energy demands. Calculations are based on 64 km (40 miles) of plug-in range for a PFCHEV. The fuel cell kW ratings are
based on 16-km range from the batteries and 48-km range from the fuel cell stack. All energy and power units are in delivered energy. For
example the hydrogen (H
2
) in kWh must be divided by the fuel cell eciency to estimate the amount of hydrogen in the tank
FC Sizing Economy Spec. E. Cost bat Cost tank Cost Cost wt FC/PFC Total Cost FC
(kW) factor (kWh/km) energy bat (%) ($/kWh) ($/kWh) electrol. ($/kg) ($/$) ($) ($/kW)
(1/h) (Wh/kg) (% FC)
2.60 0.125 0.311 78 0.85 400 4 100% 1.5 6.3 $9385 $1184
1.72 0.083 9.5 $9385 $1782
5.19 0.25 3.2 $9385 $592
0.186 9.8 $6031 $1184
0.435 4.7 $12,738 $1184
70 6.3 $9429 $1190
80 6.3 $9375 $1182
0.8 5.6 $9385 $1051
0.9 7.1 $9385 $1336
550 6.5 $12,385 $1617
300 6.1 $7385 $895
2 6.4 $9385 $1198
6 6.3 $9385 $1182
0 12.7 $9385 $2379
2 4.2 $9385 $793
1 6.4 $9256 $1173
2 6.4 $9513 $1206
Table 6
Impact of vehicle plug-in range on threshold fuel cell prices and fuel cell power rating
Total (km) Battery (km) FC (kW) FC/PFC ($/$) Total ($) Cost FC ($/kW)
32 8 1.30 11.5 5192 1190
48 12 1.95 8.2 7288 1190
64 16 2.60 6.4 9385 1190
64 32 1.73 6.4 9385 1190
97 24 3.89 4.4 13,577 1190
129 32 5.19 3.4 17,769 1190
Table 7
Example entry level PFCHEV specications and costs
Spec.
Total kilometers 48
Battery pack (km) 16
Battery pack (kWh) 3
H
2
(km) 32
H
2
(kWh) 8.30
Fuel cell (kW) 0.69
ICE ($) 1000
Battery cost ($) 1200
Fuel cell cost ($) 1235
Electrolyzer ($) 1235
Total ($) 4773
FC ($/kW) 1792
are about $0.0155 and 0.0199/km ($0.025 and $0.032 per
mile)
2
for a gasoline ($0.25/l, no highway tax) ICE and
hydrogen produced by grid (o-peak, $0.056/kWh [11]).
Entry level vehicles will not pay for themselves at current
RFC prices based on saved fuel cost in the USin countries
where fuel prices are more than $1.00/l it is possible for
the PHEV and PFCHEV to pay for themselves based on
savings in fuel costs if they are able to tap into cheap o-peak
grid electricity.
2
Costs are based on a vehicle getting 12:75 km/l (30 mpg)
and fuel at $0.25/l (not including highway taxes). An energy con-
tent of 411; 426 kJ/l (114,500 Btu/gal) for gasoline translates to
2500 kJ/km of gasoline (3817 Btu gasoline/mile). This translates
to 450 kJ/km (687 Btu) of wheel energy per mile applied to all
fueling options.
120 G.J. Suppes / International Journal of Hydrogen Energy 30 (2005) 113121
Two potential US niche markets for the plug-in approach
are the alternative fuel markets created by Environmental
Policy Act (EPACT) regulation and consumers who are
willing to pay additional money for an automobile that dis-
places imported petroleum with electrical power produced
for indigenous feed stocks. The markets would not be huge,
but they would create additional momentum in the fuel cell
industry to further reduce costs.
At a fuel cell cost of $500/kW and a 50% premium for
reversible performance (possible by 2010), a power system
with the same economy and fuel cell sizing factor as that
of Table 7 would cost about $2750. This vehicle would re-
place about 75 l per year of imported petroleum with elec-
trical power. From a societal perspective, the benets would
warrant the additional cost. If the ICE and gasoline tank
were removed from this ICE and it were used for limited
local transit, the price of the power system could be further
reduced to about $1500 and the vehicle itself would real-
ize reduced costs due to weight reductions. Such a vehicle
would be particularly appropriate as a second vehicle in a
2-car family or as a short trip vehicle for a college student.
Vehicles with and without the backup ICE could realize sub-
stantial markets.
4.3. Evolution of fuel cell-battery-ICE tribrids
As fuel cells become less expensive, increased plug-in
ranges would become viable and the ICE would be used less.
As the ICE is used less, less expensive, lighter, and possibly
air-cooled ICEs could be used to reduce the premium prices
paid for these vehiclesthis would reduce the premium
paid for the plug-in option. When fuel cell prices are low
enough and the premium paid for the reversible aspect of
the fuel cell is low enough, the reduced ICE cost will allow
the cost PFCHEV power system to become less, eventually
being equal to the cost for HEV power systems. The greatest
attributes of the PFCHEV are its abilities to evolve into a
platform that is less expensive than ICE options and that
will be powered by indigenous fuels.
Today, PEM fuel cell costs are about $1100/kW when
used with pure oxygen and about $2200/kW [12] when used
with air. The costs are projected to be $650$1150 by 2010
[13]. The large automobile market could readily reduce the
prices to less than $500 by 2010 due to both mass production
and increased competition.
The entry level $4773 vehicle of Table 7 could be attained
by about 2007 based on projected fuel cell prices. Increased
demands for fuel cells could expedite the reductions in fuel
cell prices to the point where the $500/kW fuel cells with a
50%premiumfor reversible performance could be attainable
by 2010. The evolution from 2010 would include PFCHEV
vehicles with increased plug-in ranges both with and without
backup ICEs.
Fuel cells operated from electrolysis oxygen and hydro-
gen are considerably less complex than ICEs. Also, elec-
tronics and electric motors have the potential to be produced
Table 8
Typical operating costs for vehicle. Ranges include low end cost
of mid-sized car and upper end costs for luxury car and SUV [15]
Vehicle operating Average
cost range ($/mi) cost (%)
Depreciation 22.531.8 49.2
Insurance 6.910.5 14.3
Financing 4.88.3 12.3
Fuel 4.56.9 10.9
Maintenance, oil, tires 4.75.3 9.1
License & registration 1.43.2 4.2
Table 9
Qualitative comparison of PFCHEV approach to FCHEV relying
on hydrogen refueling
Hydrogen Plug-in &
refueling reformer
Fuel cell cost breakthroughs $$$ $$
Improved fuel cell durability $$ $
Improved hydrogen production $$ $
Hydrogen storage breakthroughs $$$ N/A
Hydrogen refueling breakthroughs $$ N/A
Hydrogen infrastructure cost $$$$$ N/A
H
2
Refueling time/anxiety/risk $$$ N/A
for lower costs and lighter weights than current mechanical
drive trains and transmissions. Fuel cell technology makes
entry of new companies into the automobile market eas-
ier than has been possible with ICEs and mechanical drive
trains. This is especially true for light-weight vehicles. Com-
petition could increase resulting in lower prices for vehicles
low-maintenance and dependable vehicles could become
available at a fraction of todays automobile prices (possible
by 2012). Table 8 summarizes the typical operating costs of
a vehicle. Substantial reductions in the cost of owning and
operating a vehicle can be achieved by reducing the vehicle
cost and those expenses like nancing, insurance, and taxes
that are related to the cost of the vehicle.
Table 9 qualitatively compares the cost of the FCHEV
using hydrogen refueling with the PFCHEV. No major cost
or technological barriers exist for the PFCHEV, while items
like the cost of a hydrogen refueling infrastructure will
make it dicult to make the transition from ICEs directly
to FCHEVs.
The PFCHEV will push the limits of battery technol-
ogy due to the high power output and the large number of
charge/recharge cycles. It is likely that large strides can be
made in power output as the power output currently does
not drive the price of batteriesprices correlate with the
energy content (kWh) of the batteries. A PFCHEV would
put a large number of cycles on the batteries, up to one
cycle for every 16 km.
G.J. Suppes / International Journal of Hydrogen Energy 30 (2005) 113121 121
A 1000-cycle battery life (see Table 2) translates to
10,000 miles before the battery pack would need to be
changed. Fortunately, EPRI reports that products like the
Saft nickel metal hydride batteries are achieving greater
than 2800 cycles [14]. In addition, through the use of ca-
pacitors, directing fuel cell power directly to the ICEs, and
accounting for backup ICE operation, a vehicle designed
for 16 km range from the battery pack could average near
32 km (20 miles) per cycle. This translates to 56,000 miles
before replacing the batteries. A single replacement of the
battery pack during the life of the vehicle is an attainable
short-term goal.
5. Conclusions
The PFCHEV approach using the fuel cell battery charger
provides for market entry vehicles that would cost ten times
less than FCHEVcounterparts using pure hydrogen and oxy-
gen. If air were used with FCHEV fuel cells, the PFCHEV
power systems would cost a factor of twenty less. Neither
does the PFCHEV rely on a hydrogen refueling infrastruc-
ture creating a commercially viable entry point for vehicles
beneting from fuel cells which is likely at least a decade
earlier than FCHEV vehicles.
The PFCHEV vehicles would use the versatility of the
electrical power grid to tap into domestic energy sources.
When wind, other renewable energy, or nuclear sources
are used, petroleum imports are displaced with technology
having near-zero carbon dioxide emissions and near-zero
tail-pipe emissions in the cities. Other than the modied ve-
hicle design, no additional infrastructure would be required
for the PFCHEV to enter the market. Increased electrical
power infrastructure would occur through private investment
in well-established supply-demand economics in providing
electrical power. The versatility to use o-peak electricity
for recharging PFCHEV will allow baseline power genera-
tion to increase, and this can be used to great advantage to
improve the electrical power grid infrastructure so that it is
more ecient and reliable.
At fuel cell costs less than about $1700/kW, the combi-
nation of fuel cells, batteries, and capacitors would be less
costly than batteries used in PHEV or BEV power systems.
Consumers that currently use BEV and EPACT-qualifying
alternative fuel vehicles should also be receptive to PFCHEV
vehicles that should become commercially competitive
starting in about 2007. It will likely be about 2010 before
fuel cells are inexpensive enough to cause growth in the tra-
ditional BEV market that will be replaced with limited range
FCHEV vehicles. The FCHEV vehicles will tend to evolve
toward use of larger fuel cell stacks and smaller battery
packs, eventually reaching fuel cell stack sizes that merge
into the FCHEV classication with backup ICEs no longer
being necessarya speculative timeframe for this is about
2020.
References
[1] Keith DW, Farrell AE. Rethinking hydrogen cars. Science
2003;301.
[2] Suppes GJ, Lopes S, Chiu CW. Plug-in fuel cell hybrids
as transition technology to hydrogen infrastructure. Int J
Hydrogen Energy 2004;29:36974.
[3] Plug-In Hybrids: The Cars We Need for the Next Ten Years,
California Cars Initiative, an activity of the International
Humanities Center, 2003 (see http://calcars.org).
[4] Renyl J, Schuurmans PJ. Policy implications of hybrid
electric vehicles-nal report to NREL, National Renewable
Energy Laboratory, Golden, CO, Report ACB-5-15337-01
(see www.ott.doe.gov/pdfs/nevcor.pdf), April 22,
1996.
[5] Mullen R. Proposed car of near-future: plug-in hybrid. New
Technology Week. Washington, DC: King Communications
Group, Inc; October 20, 2003.
[6] Graham, Bob. Plug-In Hybrid Electric Vehicles Signicant
Market Potential. see http://www.arb.ca.gov/msprog/zevprog/
2003rule/1202wkshp/graham.pdf, 2002.
[7] Vyas AD, Ng HK. Batteries for electric drive vehicles: Evalua-
tion of future characteristics and costs through a Delphi survey.
1997. http://www.transportation.anl.gov/pdfs/TA/103.pdf
[8] Your Driving Costs 1998, American Automobile Association,
based on data from Runzheimer International, see
http://www.vtpi.org/tdm/tdm66.htm Toc18284947, 2002.
[9] Hinrichs RA, Kleinbach M. Energy Its use and the
environment, 3rd ed. London: Thomas Learning Inc;
2002.
[10] Doe Solicitation Number DE-PS36-03GO93013, Grand
challenge for basic and applied research in hydrogen storage,
US Department of Energy, Golden Field Oce, 1617 Cole
Boulevard, Golden, CO 80401-3393, 2003.
[11] http://www.dcec.com/billing rate.html, 2003.
[12] Based on price of 7 kW hydrogen power generator. See
http://www.fuelcellstore.com, Item #540118. Price estimates
include 50% cost reduction for pure oxygen fuel cell stack
versus air fuel cell stack.
[13] Energy Technology Fact Sheet. Published by United Nations
Environment Program, Division of Technology, Industry,
and Economics (see http://www.uneptie.org/energy/). See
http://www.etachase.com/Alt%20Energy%20papers/
UNEP fuelcell.pdf 2003.
[14] Duvall M. Advanced batteries for electric-drive vehicles.
Preprint Report, published by EPRI, Palo Alto, CA, Version
16, 2003 (see http://www.epri.com/corporate/discover epri/
news/downloads/EPRI AdvBatEV.pdf).
[15] Anonymous, Your Driving Costs, American Automobile
Association, based on data from Runzheimer International
(see http://www.vtpi.org/tdm/tdm82.htm), 1998.