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Acid-Base Titration:
Determination of the Concentration of a NaOH Solution
Objective
To determine the concentration of an unknown solution of sodium hydroxide by titration,
a volumetric method of analysis, using the known concentration of an oxalic acid
solution, which is prepared by measuring the mass of oxalic acid solid and total volume
of an aqueous solution of that solid.
Equipment
Solid oxalic acid, H
2
C
2
O
4
2, 50 mL burets
100-mL volumetric flask Weighting paper
NaOH solution, unknown concentrations Deionized water
Phenolphthalein Stirring plate
Stirring bar 250 mL Erlenmeyer flask
Safety Precautions
Wear safety glasses. Handle the sodium hydroxide solution with care, it is caustic.
Avoid spilling it on your skin or clothing. If your hands feel soapy that is from the
sodium hydroxide solution, rinse thoroughly with water in the sink.
Experiment
5
5-2
Principles
A titration is a process used to determine the quantity of one substance by adding
a measured amount of a second substance. In this experiment, you will titrate a sodium
hydroxide (NaOH) solution of unknown concentration with an oxalic acid (H
2
C
2
O
4
Figure 1) solution for which the molarity will be known from the mass of oxalic acid
added to a solution of known volume. The equation for the reaction in this experiment is:
2NaOH(aq) + H
2
C
2
O
4
(aq) Na
2
C
2
O
4
(aq) + 2 H
2
O() (1)
Note from equation 1 that it takes two moles of the NaOH to react with one mole of
H
2
C
2
O
4
.
Figure 1.Oxalic Acid
The most common unit of concentrations is molarity, M, which is defined as the
number of moles of solute present in one liter of solution:
solution of liters
solute of moles
molarity M (2)
Molarity is a convenient concentration unit because the number of moles of solute in a
solution is needed in stoichiometric calculations. Molar concentrations relate the volume
of solution (expressed in liters) to the number of moles of solute present. For example,
each liter of a 1.20 M NaOH solution will contain 1.20 moles of NaOH.
1 L NaOH soln contains 1.20 mol NaOH
Equivalencies of this type can be used to convert volume of solution (in L) to number of
moles or vice versa. For example, a 750 mL solution that is 1.20 M in NaOH
contains:
(3) NaOH of moles 0.900
soln NaOH L 1
NaOH mol 1.20
soln NaOH L 0.750
5-3
In this experiment you will determine the number of moles of NaOH contained in
a known volume of NaOH solution. The concentration of the solution can then be
calculated by dividing the number of moles of NaOH by the volume of solution. For
example if it were determined that a 100-mL solution of NaOH contained 0.35 moles of
NaOH the concentration would be:
soln. NaOH of volume
NaOH of moles
NaOH of molarity
NaOH 3.5
soln. NaOH of L 100 . 0
NaOH of mol 35 . 0
M
(4)
Therefore, the key is determining the number of moles of NaOH contained in a
known volume of NaOH solution. From Equation 1 we observe that one mole of H
2
C
2
O
4
reacts with exactly two moles NaOH producing one mole of Na
2
C
2
O
4
and two moles of
water. The reaction between an acid and a base producing a salt and water is called
neutralization. When enough NaOH (which supplies one mole of OH
-
per mole of
NaOH) is added to the solution of H
2
C
2
O
4
(which supplies two moles of H
+
per mole of
H
2
C
2
O
4
), the solution is neutralized. The point at which the stoichiometrically equivalent
amounts of the two reactants are present is called the equivalence point. At the
equivalence point the reaction stoichiometry can be used to calculate the amount of
NaOH in the sample from the measured amount and known concentration of H
2
C
2
O
4
solution. For example, what is the concentration of a NaOH solution if a 75-mL sample
required 65.0-mL of a 2.50 M H
2
C
4
O
2
solution
in order to reach the equivalence point?
As in Equation 3:
moles of H
2
C
2
O
4
=
soln O C H of L 1
O C H mol 2.50
soln O C H L 0650 . 0
4 2 2
4 2 2
4 2 2
0.162 mol of
4 2 2
O C H
From the stoichiometric relationship shown in Equation 1:
moles of NaOH = 0.162 moles of
4 2 2
O C H
O C H of mole 1
NaOH of mole 2
4 2 2
2