Documente Academic
Documente Profesional
Documente Cultură
GC Applications
......................................... 318
SUPELCO
208
Capillary GC
Equity Columns
SUPELCO
Significant improvements in the polymer chemistry are at the heart of the enhanced performance you will receive with our
uity
new Eq
Capillary GC Columns. The polymer improvements result in better cross-linking, higher thermal stability, and superior product
reproducibility.
The consistent resolution, analyte response, low bleed, and column life from one Equity column to the next will allow liably
you to re
transfer methods between sites or instruments within the same site. Also, maintain the expected column performance over
thintime wi
the same instrument when you need to replace your column. The reproducible performance Equity provides will minimize time
consuming method adjustments and troubleshooting with column changes which means more tests run with higher confidence.
The Resolution You Need
For accurate identification, reliable quantitation, and confidence For lower detection limits and less instrument downtime, you can
in your results choose Equity Capillary GC Columns. The
depend on Equity Capillary GC Columns. The reproducible
consistently high resolution you demand and the service you
analyte response you demand and the service you deserve.
deserve.
Equity-1
Equity-1
2
1
1.
2.
3.
4.
5.
Ethylbenzene
m/p-Xylene
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
6.0
7.0
G001597,98,99
Min
30m x 0.25mm ID, 0.25m
28046-U
50C to 200C @ 10C/min. (5 min.)
200C
FID, 250C
30cm/sec. @ 50C
1.0L, 100:1 split
UST Modified Gasoline Range Organics (48167)
1 2
Phase Lot 1
Min
Column:
Cat. No.:
Oven:
Inj.:
MSD Interface:
Scan Range:
Flow:
Injection:
Sample:
2
1
Phase Lot 2
Min
11
10
Column:
Cat. No.:
Oven:
Inj.:
Det.:
Flow:
Injection:
Sample:
% Response:
Equity-5
Equity-5
2
3 56
8
5.0
5
Phase Lot 3
Phase Lot 2
Phase Lot 1
Column:
Cat. No.:
Oven:
Inj.:
Det.:
Flow:
Injection:
Sample:
10
G001600 - 1602
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Gas
Chromatography
Supelcos new and improved line of capillary GC columns deliver the capillary GC column performance you demand for your general
purpose, special purpose GC/MS, or environmental applications.
20
Min
30m x 0.25mm ID, 0.25m
28046-U
110C (14 min.) to 325C (15 min) @ 15C/min.
250C
FID, 360C
30cm/sec. @ 110C
1.0L, 100:1 split
Nonpolar Column Test Mix (47300-U)
Calculated relative to the predicted hydrocarbon response at
the same retention time
2 3
1
Phase Lot 3
Min
21
Column:
Cat. No.:
Oven:
Inj.:
MSD Interface:
Scan Range:
Flow:
Injection:
Sample:
22
23
24
25
Min
Pentachlorophenol
Phenathrene
Anthracene
Benzidine
G001606
209
Capillary GC
Equity Columns
The Low Bleed You Expect
Equity-1
Response recovered well after clipping one loop from the column
Pentachlorophenol
0.4
G001616
4pA
10
Column:
Cat. No.:
Oven:
Inj.:
Det.:
Flow:
Injection:
Sample:
20
Min
30
40
G001608, 09, 10
4pA
Phase Lot 2
13
18
3pA
Phase Lot 3
Phase Lot 1
24 30 36 40
Number of Injections
48
54
60
Durability Challenge
Column:
Oven:
Inj.:
Det.:
Flow:
Injection:
Sample:
Durability Test:
The column durability and life was challenged for over 60 injections by alternating
injections of the 1L test mix followed by 5 consecutive 2L splitless injections of
the high concentration waste sample. Column maintenance was performed at the
end of the test and a final test mix was injected.
Equity-5
2pA
Phase Lot 3
5pA
Phase Lot 1
10
Column:
Cat. No.:
Oven:
Inj.:
Det.:
Flow:
Injection:
Sample:
20
Min
30
40
G001612, 13, 14
3pA
Phase Lot 2
RELATED INFORMATION
For more information on the Equity line of capillary GC columns
request T402049.
Gas
Chromatography
1.0
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Benzoic acid
SUPELCO
210
Capillary GC
SUPELCO
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Gas
Chromatography
10
Excellent
phenol peak
shapes
Great peak
shapes and
resolution
2-Methylphenol
2-Propanol
Acetone
Ethanol
Equity-1 Columns
20
30
G001692
Min
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
23. Heptanol
12. 3-Pentanol
24. Decane
13. Heptane
25. Octanol
14. 3-Methyl-1-butanol
26. Undecane
15. 2-Methyl-1-butanol
27. Dodecane
16. 3-Methyl-3-pentanol
28. Decanol
17. 4-Methyl-2-pentanol
29. Tridecane
18. Pentanol
30. Tetradecane
19. Octane
31. Pentadecane
20. 4-Methyl-1-pentanol
32. Hexadecane
21. Hexanol
22. Nonane
11,12 15
21 23 25
28
14 18
22 24 26 27 29
1
8 9
19
2
30
13
16
5
20
31
7
4
17
10
32
3
6
Methanol
Ethanol
Isopropanol
t-Butanol
Propanol
2-Butanol
Hexane
Isobutanol
Butanol
3-Methyl-2-butanol
2-Pentanol
10
Excellent peak shapes
and resolutions
20
Min
30
G001709
LENGTH (m)
0.10mm ID
15
0.20mm ID
12
25
10
0.25mm ID
30
15
30
60
15
30
60
100
0.32mm ID
30
15
30
60
30
60
100
30
30
60
0.53mm ID
15
30
15
30
15
30
15
30
60
15
30
60
15
30
60
DF (m)
BETA
CAT. NO.
0.10
250
28039-U
0.33
0.33
1.2
152
152
42
28041-U
28042-U
28043-U
0.10
0.25
0.25
0.25
1.0
1.0
1.0
1.0
625
250
250
250
63
63
63
63
28044-U
28045-U
28046-U
28047-U
28048-U
28049-U
28050-U
28052-U
0.10
0.25
0.25
0.25
1.0
1.0
1.0
2.0
5.0
5.0
800
320
320
320
80
80
80
40
16
16
28053-U
28054-U
28055-U
28056-U
28057-U
28058-U
28060-U
28061-U
28062-U
28063-U
0.10
0.10
0.5
0.5
1.0
1.0
1.5
1.5
1.5
3.0
3.0
3.0
5.0
5.0
5.0
1325
1325
265
265
133
133
88
88
88
44
44
44
27
27
27
28064-U
28065-U
28067-U
28068-U
28069-U
28071-U
28072-U
28073-U
28074-U
28075-U
28076-U
28077-U
28079-U
28081-U
28082-U
PRICE
211
Capillary GC
Equity-5 Columns
Benzo(b)fluoranthene
4-Nitrophenol
2,4-Dinitrophenol
Benzo(k)fluoranthene
Excellent peak
shapes and
resolution
276
100000
207
10
12
14
Min
16
18
20
22
24
8.
9.
10.
11.
12.
13.
14.
15.
Heptachlor epoxide
g-Chlordane
Endosulfan I
a-Chlordane
4,4-DDE
Dieldrin
Endrin
Endosulfan II
10 1112
13 16
8 9
15 18
14
16.
17.
18.
19.
20.
21.
22.
20
22
20
Min
30
G001689
21
10
35
4,4-DDD
Endrin aldehyde
Endosulfan Sulfate
4,4-DDT
Endrin ketone
Methoxychlor
Decachlorobiphenyl
(surr.)
17 19
30
25
LENGTH (m)
0.10mm ID
15
0.20mm ID
15
30
60
12
0.25mm ID
15
30
60
30
15
30
60
0.32mm ID
15
30
60
30
30
30
60
0.53mm ID
15
30
60
30
15
30
30
60
15
30
60
DF (m)
BETA
CAT. NO.
0.10
250
28083-U
0.20
0.20
0.20
0.33
250
250
250
152
28084-U
28085-U
28086-U
28087-U
0.25
0.25
0.25
0.5
1.0
1.0
1.0
250
250
250
125
63
63
63
28088-U
28089-U
28090-U
28092-U
28093-U
28094-U
28095-U
0.25
0.25
0.25
0.32
0.5
1.0
1.0
320
320
320
250
160
80
80
28096-U
28097-U
28098-U
28099-U
28195-U
28199-U
28251-U
0.5
0.5
0.5
1.0
1.5
1.5
3.0
3.0
5.0
5.0
5.0
265
265
265
133
88
88
44
44
27
27
27
28252-U
28259-U
28263-U
28264-U
28265-U
28267-U
28268-U
28269-U
28278-U
28279-U
28293-U
PRICE
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
G001611
G001687
5 nanograms
Benzo(g,h,i)perylene
(m/z 276)
Gas
Chromatography
10000
SUPELCO
212
Capillary GC
General Purpose Columns
SPB-Octyl
SPB-35
SUPELCO
BETA
CAT. NO.
250
250
63
63
24218-U
24219-U
24232
24233-U
44
25398
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Gas
Chromatography
PRICE
SPB-20
LENGTH (m)
DF (m)
0.25mm ID FUSED SILICA
30
0.25
0.32mm ID FUSED SILICA
30
0.25
0.53mm ID FUSED SILICA
30
0.50
30
1.0
BETA
CAT. NO.
250
24092
320
24094
265
133
25331
25335
PRICE
SPB-50
80% dimethylsiloxane)
50% dimethylsiloxane)
LENGTH (m)
DF (m)
0.25mm ID FUSED SILICA
30
0.2
60
0.25
30
1.0
0.32mm ID FUSED SILICA
30
0.25
60
1.0
0.53mm ID FUSED SILICA
30
0.50
30
1.0
BETA
CAT. NO.
250
250
63
24086
24087-U
24196-U
320
80
24088
24194-U
265
133
25329-U
25333
PRICE
LENGTH (m)
DF (m)
0.25mm ID FUSED SILICA
30
0.25
0.32mm ID FUSED SILICA
30
0.25
0.53mm ID FUSED SILICA
30
0.50
BETA
CAT. NO.
250
24181
320
24187
265
25363
PRICE
213
Capillary GC
General Purpose Columns
SP-2250
SPB-1701
Intermediate polarity SPB-1701 columns have a mixed functionality which provides unique elution order characteristics, relative
to the phenyl-containing silicone phases.
This column meets USP G46 requirements.
50% methylsiloxane)
86% dimethylsiloxane)
CAT. NO.
313
313
313
24009
24010
24011-U
320
320
24147
24148
PRICE
SPB-17
This bonded, crosslinked (50%-phenyl)-methylpolysiloxane,
intermediate polarity phase is excellent for confirmational
analyses.
This column meets USP G3 requirements.
BETA
CAT. NO.
250
250
250
24112
24113
24114
320
320
24184
24185
265
265
133
133
25368
25369
25366
25367
PRICE
PAG
40C to 280/300C
0.53mm ID: 40C to 260/280C
McReynolds Nos.: x y z u s = 125 169 174 253 207
LENGTH (m)
DF (m)
0.25mm ID FUSED SILICA
15
0.25
30
0.25
0.32mm ID FUSED SILICA
30
0.25
30
0.50
0.53mm ID FUSED SILICA
15
1.0
LENGTH (m)
DF (m)
0.25mm ID FUSED SILICA
15
0.25
30
0.25
60
0.25
0.32mm ID FUSED SILICA
30
0.25
60
0.25
0.53mm ID FUSED SILICA
15
0.50
30
0.50
15
1.0
30
1.0
BETA
CAT. NO.
250
250
24374-U
24380-U
320
160
24381
24376
250
25472
Less polar than polyethylene glycol phases, due to the incorporation of propylene oxide into the polymer backbone. Fills the
polarity gap between 50% phenyl columns and Carbowax-type
columns (polarity similar to UCON and Pluronics phases).
This column meets USP G18 requirements.
PRICE
LENGTH (m)
DF (m)
0.25mm ID FUSED SILICA
15
0.25
30
0.25
0.32mm ID FUSED SILICA
15
0.25
30
0.25
0.53mm ID FUSED SILICA
15
0.50
30
0.50
60
0.50
BETA
CAT. NO.
250
250
24222-U
24223
320
320
24225-U
24226
265
265
265
25422-U
25423-U
25424
PRICE
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
BETA
Gas
Chromatography
LENGTH (m)
DF (m)
0.25mm ID FUSED SILICA
15
0.20
30
0.20
60
0.20
0.32mm ID FUSED SILICA
15
0.20
30
0.20
SUPELCO
214
Capillary GC
General Purpose Columns
SUPELCOWAX 10
SPB-1000
SUPELCO
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Gas
Chromatography
LENGTH (m)
DF (m)
0.10mm ID FUSED SILICA
5
0.10
10
0.10
15
0.10
0.20mm ID FUSED SILICA
30
0.20
60
0.20
0.25mm ID FUSED SILICA
15
0.25
30
0.25
60
0.25
30
0.50
0.32mm ID FUSED SILICA
15
0.25
30
0.25
60
0.25
15
0.50
30
0.50
60
0.50
30
1.0
60
1.0
0.53mm ID FUSED SILICA
15
0.50
30
0.50
60
0.50
15
1.0
30
1.0
60
1.0
30
2.0
60
2.0
BETA
CAT. NO.
250
250
250
25025-U
25026-U
24343
250
250
24169
24170
250
250
250
125
24077
24079
24081
24284
320
320
320
160
160
160
80
80
24078
24080-U
24082
24083
24084
24085-U
24211
24212
265
265
265
133
133
133
63
63
25324
25325
25385
25300-U
25301-U
25391
25375-U
25376
PRICE
LENGTH (m)
DF (m)
0.25mm ID FUSED SILICA
30
0.25
0.32mm ID FUSED SILICA
30
0.25
0.53mm ID FUSED SILICA
30
0.50
BETA
CAT. NO.
250
24313
320
24315
265
25445
PRICE
LENGTH (m)
DF (m)
0.25mm ID FUSED SILICA
15
0.25
30
0.25
60
0.25
0.32mm ID FUSED SILICA
15
0.25
30
0.25
60
0.25
15
1.0
30
1.0
60
1.0
0.53mm ID FUSED SILICA
15
0.50
30
0.50
60
0.50
BETA
CAT. NO.
250
250
250
24106-U
24107
24108
320
320
320
80
80
80
24130
24131
24132
24206-U
24207
24208
265
265
265
25326
25327
25386
PRICE
215
Capillary GC
General Purpose Columns
SPB-225
SP-2380
methylpolysiloxane
CAT. NO.
417
250
24334
24335
533
320
24336
24337
PRICE
SP-2330
Substitution of the bis-cyanopropyl and phenyl groups on the
polymer backbone provides the phase with both polar and
polarizable characteristics. These columns (and all high
cyanopropyl-substituted polymers) are useful for both high and
low temperature separations of samples such as geometric isomers
of fatty acid methyl esters, dioxins, and aromatic compounds.
This column meets USP G8 requirements.
Operating Conditions: More susceptible to damage by oxygen, moisture, and HCI
than other silicone phases. Avoid solvents such as water and methanol when using
on-column injection techniques. Columns should not be rinsed.
Phase: nonbonded; poly(80% biscyanopropyl/
LENGTH (m)
DF (m)
0.25mm ID FUSED SILICA
15
0.20
30
0.20
60
0.20
0.32mm ID FUSED SILICA
15
0.20
30
0.20
60
0.20
BETA
CAT. NO.
313
313
313
24018
24019
24020-U
320
320
320
24102-U
24073
24074
PRICE
LENGTH (m)
DF (m)
0.25mm ID FUSED SILICA
15
0.20
30
0.20
60
0.20
0.32mm ID FUSED SILICA
30
0.20
60
0.20
0.53mm ID FUSED SILICA
30
0.20
BETA
CAT. NO.
313
313
313
24109
24110-U
24111
320
320
24116-U
24117
663
25319
PRICE
SP-2340
The highest polarity of any of the general purpose cyanosilicone
phases. As with all cyano phase columns, these columns are
useful for both high and low temperature separations of samples
such as geometric isomers of fatty acid methyl esters, dioxins, and
aromatic compounds.
This column meets USP G5 requirements.
Operating Conditions: More susceptible to damage by oxygen, moisture, and HCI
than other silicone phases. Avoid solvents such as water and methanol when using
on-column injection techniques. Columns should not be rinsed.
Phase: nonbonded; poly(biscyanopropyl siloxane)
Temp. Limits: subambient to 250C
McReynolds Nos.: x y z u s = 419 654 541 758 637
LENGTH (m)
DF (m)
0.25mm ID FUSED SILICA
15
0.20
30
0.20
60
0.20
0.32mm ID FUSED SILICA
15
0.20
30
0.20
60
0.20
BETA
CAT. NO.
313
313
313
24021
24022
24023
320
320
320
24138
24075
24076
PRICE
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
BETA
Gas
Chromatography
LENGTH (m)
DF (m)
0.25mm ID FUSED SILICA
30
0.15
30
0.25
0.32mm ID FUSED SILICA
30
0.15
30
0.25
SUPELCO
216
Capillary GC
Special Purpose Columns (Chiral)
a -DEX 120
a-DEX 120 columns provide unique selectivity for enantiomeric
p-Xylene (>99%)
SUPELCO
m-Xylene
o-Xylene
dimethylsiloxane)
BETA
CAT. NO.
250
24310
250
250
24301
24302
250
250
24304
24305-U
250
24307
PRICE
14
Column:
Cat. No.:
Oven:
Carrier:
Det.:
Inj.:
16
Min
794-0648
g-DEX 120
18
a -DEX 120,
a-DEX 120
g-DEX 120
20
Column:
Cat. No.:
Oven:
Carrier:
Det.:
Inj.:
Min
22
20
Min
22
794-0282,0283
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Gas
Chromatography
a -DEX 120 and g -DEX 120, 30m x 0.25mm ID, 0.25m film
24310 (a -DEX 120), 24307 (g -DEX 120)
130C
helium, 35cm/sec
FID, 300C
1L methylene chloride
(1mg/mL each analyte), split (100:1), 250C
217
Capillary GC
Special Purpose Columns (Chiral)
DEX-225 and DEX-325 Columns
(+)
( -)
( +)
b-DEX 325
b-DEX 225
a -DEX 225
Phase: nonbonded; 25% 2,3-di-O-acetyl-6-O-TBDMS-acyclodextrin in SPB-20 poly(20% phenyl/80%
( -)
30 Min
b -DEX 225 and b -DEX 325, 30m x 0.25mm ID, 0.25m film
24348 (b-DEX 225), 24308 (b-DEX 325)
100C
helium, 25cm/sec
FID, 300C
1L methylene chloride (1mg/mL), split 100:1, 250C
These kits provide the tools you need to perform most chiral
separations. Confirm identities of enantiomers by monitoring
elution order changes (enantioreversal) from one column to
another. In combination, the columns in the two kits span the
full range of DEX column enantioselectivity, at substantial
savings relative to purchasing individual columns.
Kit I: one 30m x 0.25mm ID, 0.25m film column of each type:
a-DEX 120, b-DEX 120, g-DEX 120.
Kit II: one 30m x 0.25mm ID, 0.25m film column of each type:
b-DEX 120, b-DEX 225, g-DEX 225, b-DEX 325.
CAT. NO.
24340
24328-U
RELATED INFORMATION
g-DEX 225
DESCRIPTION
Chiral Column Kit I
Chiral Column Kit II
PRICE
a -DEX 325
Phase: nonbonded; 25% 2,3-di-O-methyl-6-O-TBDMS-acyclodextrin in SPB-20 poly(20% phenyl/80%
dimethylsiloxane)
b -DEX 325
Phase: nonbonded; 25% 2,3-di-O-methyl-6-O-TBDMS-bcyclodextrin in SPB-20 poly(20% phenyl/80%
dimethylsiloxane)
g-DEX 325
Phase: nonbonded; 25% 2,3-di-O-methyl-6-O-TBDMS-gcyclodextrin in SPB-20 poly(20% phenyl/80%
dimethylsiloxane)
Subject
Chiral applications/selection guide
Using DEX Column Selection Kit II
LENGTH (m)
a-DEX 225
30
b-DEX 225
30
g-DEX 225
30
a-DEX 325
30
b-DEX 325
30
g-DEX 325
30
DF (m)
BETA
CAT. NO.
0.25
250
24311
0.25
250
24348
0.25
250
24312
0.25
250
24303
0.25
250
24308
0.25
250
24306
PRICE
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
b -DEX 225
797-0450
20 Min
Column:
Cat. No.:
Oven:
Carrier:
Det.:
Inj.:
dimethylsiloxane)
Gas
Chromatography
Terpinen-4-ol
SUPELCO
218
Capillary GC
Special Purpose Columns (Environmental)
93 volatile compounds separated
without subambient temperatures
in less than 20 minutes
SUPELCO
0
0
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Gas
Chromatography
G000343
Column:
Cat. No.:
Oven:
Carrier:
Det.:
Inj.:
10
15
Min
20
10
Min
12
Volatiles: VOCOL
These intermediate polarity columns, designed for volatile
organic compounds (VOCs) analysis, ensure greater retention and
resolution of the more volatile compounds. Use in direct
injection ports or coupled to purge-and-trap systems, for US EPA
volatiles methods, including 502.2, 524.2, 624, 8240, 8260, and
8021.
Temp. Limits: subambient to 250C (1.5m film) or
230C (3m film)
42
24129-U
42
42
24205-U
24154
44
27
24217-U
24157
44
44
44
25320-U
25381
25358
20
Proprietary
e
bonded phas
Volatiles: SPB-624
CAT. NO.
18
Proprietary
e
bonded phas
BETA
16
25
LENGTH (m)
DF (m)
0.20mm ID Fused Silica
10
1.2
0.25mm ID Fused Silica
30
1.5
60
1.5
0.32mm ID Fused Silica
60
1.8
60
3.0
0.53mm ID Fused Silica
30
3.0
60
3.0
105
3.0
14
PRICE
LENGTH (m)
DF (m)
0.25mm ID Fused Silica
30
1.4
60
1.4
0.32mm ID Fused Silica
60
1.8
0.53mm ID Fused Silica
30
3.0
75
3.0
BETA
CAT. NO.
44
44
24255
24256
44
24251
44
44
25430
25432
PRICE
219
Capillary GC
Special Purpose Columns (Environmental)
Resolve key compound pairs
2 45
6
10
7 9
8 12
11
13
14 16
15 18
17
10
20
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
Propazine
Atrazine
Simazine
Terbacil
Sencor
Dual
Paarlan
Prowl
Bromacil
Oxadiazon
Goal
Hexazinone
14
13
12
16
2 5 6
4
9
3
7 8 10
11
30
Min
Column:
Cat. No.:
Oven:
Carrier:
Det.:
Inj.:
Proprietary
e
bonded phas
Pesticides/Herbicides: SPB-608
For chlorinated pesticides - Specially tested with low concentrations of 18 chlorinated pesticides, with an electron capture
detector (ECD). These columns meet the criteria for minimum
breakdown of 4,4'-DDT and endrin for US EPA Methods 508,
608, 8080, 8081, and SW-Pesticides.
Temp. Limits: subambient to 300C
BETA
CAT. NO.
250
24103-U
265
265
25310-U
25312
PRICE
Column:
Cat. No.:
Oven:
Carrier:
Det.:
Inj.:
8
Min
23
18
17
21
22
15
LENGTH (m)
DF (m)
0.25mm ID Fused Silica
30
0.25
0.53mm ID Fused Silica
15
0.50
30
0.50
19,20
10
12
14
Pesticides/Herbicides: Sup-Herb
Specially tested intermediate polarity column for analyses of
herbicides, per US EPA Method 507.
Temp. Limits: subambient to 300C
LENGTH (m)
DF (m)
0.53mm ID Fused Silica
15
0.50
BETA
CAT. NO.
265
25322
PRICE
Gas
Chromatography
1. Ethyl acetate
(solvent)
2. Eptam
3. Sutan
4. Vernam
5. Tillam
6. Ordram
7. Treflan
8. Balan
9. Ro-Neet
10. Propachlor
11. Tolban
1
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Heptachlor
d-BHC
Aldrin
Heptachlor epoxide
Endosulfan I
4,4-DDE
Dieldrin
Endrin
4,4-DDD
Endosulfan II
4,4-DDT
Endrin aldehyde
Endosulfan sulfate
Methoxychlor
Endrin ketone
G000329
a-BHC
g-BHC (Lindane)
b-BHC
G000328
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
SUPELCO
220
Capillary GC
Special Purpose Columns (Environmental, Air Monitoring, High Temperature)
Key TCDD isomers resolved
1.
2.
3.
4.
750000
1,4,7,8-TCDD
2,3,7,8-TCDD
1,2,3,4-TCDD
1,2,3,7-TCDD and
1,2,3,8-TCDD
700000
4
650000
600000
550000
500000
450000
SUPELCO
350000
300000
19.0
Dioxins:
60
313
313
24257
24104-U
400
24105-U
0.20
PRICE
SPB-HAP
6
7
9
8
10
50
480
570
650 700
Boiling Point (C)
750
BETA
CAT. NO.
20
25020-U
PRICE
HT-5
C20
C30
C40
C50
C60
C70
C80
C90
C100
C110
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
450
LENGTH (m)
DF (m)
0.32mm ID Fused Silica
60
4.0
320
8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38
Min
High Temperature:
Temp
(C)
Air Monitoring:
Column:
Cat. No.:
Oven:
Carrier:
Det.:
Inj.:
BETA
150000
50000
Proprietary
ase
stabilized ph
LENGTH (m)
DF (m)
0.25mm ID Fused Silica
30
0.20
60
0.20
0.32mm ID Fused Silica
200000
100000
24105-U
200C (1 min) to 250C at 3C/min, hold 10 min
helium, 30cm/sec (set at 200C)
ECD, 270C
1L TCDD PE Mix (1.5g/mL each analyte in n-dodecane),
on-column, 200C
SP-2331
250000
G000506
18.0
Min
G000327
17.0
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Gas
Chromatography
400000
2
LENGTH (m)
DF (m)
0.32mm ID Fused Silica
12
0.10
25
0.10
0.53mm ID Fused Silica
6
0.10
12
0.15
BETA
CAT. NO.
800
800
25002
25003
1325
883
25004
25005-U
PRICE
221
Capillary GC
Special Purpose Columns (Solvents, Steroids)
Methylene chloride
Underivatized sterols
separated with minimal tailing 6
2
1.
2.
3.
4.
5.
6.
Benzene
1
Chloroform
5-a-Cholestane (IS)
Cholesterol
Brassicasterol
Campesterol
Stigmasterol
b-Sitosterol
20
Solvents:
25396
40C
helium, 35cc/min
FID, 260C
1L, direct, 140C
20
30
Steroids: SAC-5
OVI-G43
10
Min
Cat. No.:
Oven:
Carrier:
Det.:
Inj.:
PRICE
BETA
CAT. NO.
250
250
24151
24156
PRICE
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
10
Min
G000349
G000332
1,4-Dioxane
Gas
Chromatography
3
Trichloroethylene
SUPELCO
222
Capillary GC
Special Purpose Columns (Sulfur Compounds, SCOT Columns)
Resolve H2S, COS, SO2
1.
2.
3.
4.
5.
6.
7.
8.
3
COS
Hexane
n-Nonane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
o-Xylene
H 2S
SUPELCO
10
Min
15
80-324
20
24158
-10C (3min) to 300C at 10C/min
helium, 20cm/sec
sulfur chemiluminescence
0.1mL sulfur gas standard, split 10:1
6
Min
10
12
SPB-1 SULFUR
G000348
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Gas
Chromatography
SO2
BETA
CAT. NO.
20
24158
PRICE
Gases:
25521
90C
helium, 27cm/sec, set at 90C
220C
220C
Di-n-decylphthalate
25521
25538
25535
25536
PRICE
223
Capillary GC
Special Purpose Columns (Gases - PLOT Columns)
1
Min
Gases:
MAX. TEMP.
(C)
300
300
CAT. NO.
24243
25463
1.
2.
3.
4.
5.
6.
7.
5
Ambient temperature separation of
oxygen and nitrogen
3
4
7
10
Min
G000337
1. Oxygen
2. Nitrogen
3. Carbon monoxide
Gases:
Carboxen-1010 PLOT1
MAX. TEMP.
(C)
250
250
CAT. NO.
24246
25467
PRICE
PRICE
PRICE
2
2
Min
Gases:
MAX. TEMP.
(C)
250
250
Carboxen-1006 PLOT1
DIMENSIONS
(FUSED SILICA)
30m x 0.32mm ID
30m x 0.53mm ID 2
Hydrogen
Oxygen
Nitrogen
Methane
Carbon monoxide
6 Min 8
10
12
Hydrogen sulfide
Carbonyl sulfide
Methyl mercaptan
Dimethyl sulfide
Ethyl mercaptan
Carbon disulfide
Sulfur dioxide
14
Gases:
Supel-Q PLOT1
MAX. TEMP.
(C)
250
250
CAT. NO.
24242
25462
PRICE
A proprietary procedure fixes particles to the fused silica tubing and ensures they will not be dislodged in normal use. Manufactured under US patents 5,599,445;
5,607,580; 5,609,756; 5,620,603; and 5,630,937.
0.53mm ID column can be used in packed column chromatographs.
Gas
Chromatography
794-0120
1.
2.
3.
4.
5.
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Nitrogen
Carbon monoxide
Methane
Carbon dioxide
Acetylene
Ethylene
Ethane
795-0367
67
5
794-0699
1.
2.
3.
4.
5.
6.
7.
SUPELCO
224
Capillary GC
Special Purpose Columns (FAMES)
C18:1n9
8
16 17
13
14
7 91011 15 18 23
19 20
28
31
24 27
21
25 2629
22
32
40
G000344
20
30
Column:
Cat. No.:
Oven:
Carrier:
Omegawax
C22:6n3
C24:0
C23:0
C22:5n3
Min
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Gas
Chromatography
Key
resolution
C23:0
C18:4n3
C20:0
C22:0
C20:1n9
C21:5n3
C20:5n3
C18:2n6
12
2
C18:0
SUPELCO
BETA
CAT. NO.
250
24136
320
24152
265
25374
10
20
30
40
50
35
33 34
36
60
70
37
796-0582
C14:0 C16:0
80
Min
Column:
Cat. No.:
Oven:
Carrier:
Det.:
Inj.:
SPB-PUFA
PRICE
LENGTH (m)
DF (m)
0.25mm ID Fused Silica
30
0.20
0.32mm ID Fused Silica
30
0.20
BETA
CAT. NO.
313
24314
400
24323
PRICE
225
Capillary GC
Special Purpose Columns (FAMES)
Fast carbon number separation of 37 component FAME mix
16 17
18
15
3
1
2
5
1.
2.
3.
4.
5.
6.
21, 23
12
8
1011 13 14
28, 32
36
31
30
27
33 29
22 24
25
35 37 34
20 19
C18:0
C18:1 trans isomers
C18:1 cis & trans valley isomers
C18:1 isomers
5
C18:2
C20:0
1
2 3
40
Min
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
Component
(acid methyl esters)
C4:0 (Butryic)
C6:0 (Caproic)
C8:0 (Caprylic)
C10:0 (Capric)
C11:0 (Undecanoic) 2
C12:0 (Lauric)
C13:0 (Tridecanoic) 2
C14:0 (Myristic)
C14:1 (Myristoleic)
C15:0 (Pentadecanoic)
C15:1 (cis-10-Pentadecenoic)
C16:0 (Palmitic)
C16:1 (Palmitoleic)
C17:0 (Heptadecanoic)
C17:1 (cis-10-Heptadecenoic)
C18:0 (Stearic)
C18:1n9c (Oleic)
C18:1n9t (Elaidic)
C18:2n6c (Linoleic)
C18:2n6t (Linolelaidic)
C18:3n6 (g-Linolenic)
Column:
Cat. No.:
Oven:
Carrier:
Det.:
Inj.:
Weight
%
4
4
4
4
22.
23.
24.
25.
26.
4
27.
4
2
2
2
6
2
2
2
4
4
2
2
2
2
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
Component
Weight
(acid methyl esters)
%
C18:3n3 (a-Linolenic)
2
C20:0 (Arachidic)
4
C20:1n9 (cis-11-Eicosenoic)
2
C20:2 (cis-11,14-Eicosadienoic) 2
C20:3n6 (cis-8,
11,14-Eicosatrienoic)
2
C20:3n3 (cis-11,
4,17-Eicosatrienoic)
2
C20:4n6 (Arachidonic)
2
C20:5n3 (cis-5,
8,11,14,17-Eicosapentaenoic) 2
C21:0 (Henicosanoic)
2
C22:0 (Behenic)
4
C22:1n9 (Erucic)
2
C22:2 (cis-13,
16-Docosadienoic)
2
C22:6n3 (cis-4,7,10,
13,16,19-Docosahexaenoic)
2
C23:0 (Tricosanoic)
2
C24:0 (Lignoceric)
4
C24:1n9 (Nervonic)
2
795-0781
28
Column:
Cat. No.:
Oven:
Carrier:
Det.:
Inj.:
30
32
34
36
Min
38
40
42
44
SP-2560
SP-2380
BETA
CAT. NO.
313
24317
PRICE
LENGTH (m)
DF (m)
0.25mm ID Fused Silica
100
0.20
BETA
CAT. NO.
313
24056
PRICE
Gas
Chromatography
30
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
20
G000345
10
SUPELCO
226
Capillary GC
Special Purpose Columns (Petroleum - Hydrocarbons, MTBE)
MTBE
Baseline resolution of critical MTBE contaminants
34
6
SUPELCO
797-0220
10
20
30
40
Min
50
60
70
10
80
Hydrocarbons:
MTBE
8
Petrocol DH 50.2
11
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
Methanol
Isopentane
n-Pentane
trans-2-Pentene
tert-Butanol
cis-2-Pentene
2-Methyl-2-butene
tert-Butyl ethyl ether
tert-Amyl methyl ether (TAME)
2,4,4-Trimethyl-1-pentene
Triisobutylene Isomers:
11. 4,4-Dimethyl-2-neopentyl-1-pentene
12. 2,2,4,6,6-Pentamethyl-3-heptene
12
11
LENGTH (m)
DF (m)
0.20mm ID Fused Silica
50
0.50
BETA
CAT. NO.
100
24133-U
12
16
20
24
Min
28
32
36
713-0764
10 11
40
44
Petrocol DH 150
BETA
CAT. NO.
63
24155
20 Min
25
30
35
24160-U
50C (13 min) to 180C at 10C/min
helium, 20cm/sec; vent flow 140mL/min (set at 35C)
FID (310C)
1L MTBE containing 1% each analyte (MTBE Contaminants
Mix A, Cat. No. 47942) split (200:1) (250C)
Hydrocarbons:
Hydrocarbons:
15
10
Cat. No.:
Oven:
Carrier:
Det.:
Inj.:
Light Hydrocarbons
Length and film thickness provide ambient temperature separations,
including critical isobutylene/1-butene
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
PRICE
713-1329,28
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Gas
Chromatography
PRICE
Petrocol DH
For PNA, PONA, PIANO-type analyses - A highly reproducible column displaying more than 400,000 theoretical plates,
designed for detailed analyses of petroleum products. Includes an
extensive retention index data sheet of 400+ analytes.
Phase: bonded; poly(dimethylsiloxane)
Temp. Limits: -60C to 320C
LENGTH (m)
DF (m)
0.25mm ID Fused Silica
100
0.50
BETA
CAT. NO.
125
24160-U
PRICE
227
Capillary GC
Special Purpose Columns (Petroleum - Hydrocarbons, SIMDIS)
The only nonpolar methyl silicone column that
resolves benzene and toluene from common coeluters
Toluene
Benzene
Methyl cyclopentene-1
2,3,3-Trimethylpentane
C50
40
45
Min
C70
Hydrocarbons:
C30
Petrocol DH Octyl
BETA
CAT. NO.
125
24282
8 10
Min
12
14
16
18
25323
-20C to 320C at 20C/min, hold 5 min
nitrogen, 6mL/min
FID
0.1L Cat. No. 48873, direct (350C)
5" cage
BETA
CAT. NO.
265
25323
25337
50C (3min) to 380C at 15C/min
helium, 5mL/min
FID, 400C
0.2L (10mg/mL Polywax 655 in p-xylene), cool on-column
injection
Minimal Bleed
at 320C
28 minutes
PRICE
C80
PRICE
LENGTH (m)
DF (m)
0.53mm ID Fused Silica
5
0.10
BETA
CAT. NO.
1325
25337
PRICE
Gas
Chromatography
35
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
30
2110010007
25
Column:
Cat. No.:
Oven:
Det.:
Inj.:
94-0364
C60
C40
SUPELCO
228
Capillary GC
Special Purpose Columns (Amines, Aromatics)
1
1.
2.
3.
4.
5.
6.
7.
8.
9.
SUPELCO
n-Decane
Benzylamine
Octylamine
n-Undecane
2,4-Dimethylaniline
2,6-Dimethylaniline
n-Dodecane
Decylamine
n-Tridecane
9
1.
2.
3.
4.
5.
6.
7.
8.
9.
Isooctane
n-Tridecane (C13)
Toluene
Ethylbenzene
p-Xylene
Isopropylbenzene
1,2,4-Trimethylbenzene
1,2,4,5,-Tetramethylbenzene
Cyclohexanone 9
10
G000350
8
20
Min 6
G000335
Min
24277
128C
helium, 40cm/sec
FID, 220C
1L PTA-5 Test Mix (500g/mL each analyte in methyl tert butyl
ether), split (100:1), 220C
Amines: PTA-5
This column is a specially prepared, base-deactivated poly(5%
diphenyl/95% dimethylsiloxane) column designed for analyses of
amines and other basic analytes.
Phase: bonded; base-modified poly(5% diphenyl/
95% dimethylsiloxane)
Temp. Limits: -60C to 320C
LENGTH (m)
DF (m)
0.25mm ID Fused Silica
30
0.50
30
1.0
0.32mm ID Fused Silica
30
0.5
30
1.0
30
1.5
0.53mm ID Fused Silica
30
0.5
30
1.5
30
3.0
BETA
CAT. NO.
125
625
24277
24330
160
80
53
24331
24332
24333
265
88
44
25437
25438
25439
PRICE
24153
110C
helium, 20cm/sec
FID, 170C
1L TCEP test mix, split (100:1), 170C
Aromatics: TCEP
This highly polar phase offers unique polarity for certain
separations, despite its relatively low temperature limit and the
fact that it is not a bonded phase. Because many aromatic
compounds have retention indices greater than 1100 on TCEP, it
is used for analyses of aromatics in mineral spirits and impurities
in individual aromatics and oxygenates.
Phase: nonbonded; 1,2,3-tris-2-cyanoethoxypropane
Temp. Limits: subambient to 145C
McReynolds Nos.: x y z u s = 594 857 759 1031 917
LENGTH (m)
DF (m)
0.25mm ID Fused Silica
60
0.44
0.32mm ID Fused Silica
60
0.51
BETA
CAT. NO.
142
24153
157
24161
PRICE
1.
2.
3.
4.
5.
6.
7.
8.
BETA
CAT. NO.
133
133
133
25352
25353
25354
PRICE
8
Min
10
12
Propylamine
Butylamine
Pentylamine
Hexylamine
Heptylamine
Octylamine
Nonylamine
Decylamine
14
25353
50C to 200C at 8C/min, hold 10 min
helium, 20cm/sec (set at 170C)
FID, 220C
0.02L neat amines mix, split (100:1), 220C
711-0127
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Gas
Chromatography
5
6
229
Capillary GC
Other Columns
SPB-1
SPB-5
BETA
CAT. NO.
250
24338
250
250
152
152
24162
24163
24229-U
24230-U
625
250
250
250
250
63
63
63
63
24261
24026
24028
24030-U
24198
24027
24029
24031
24220-U
800
320
320
320
320
80
80
80
80
40
40
16
16
24290
24099
24044
24046
24228-U
24098-U
24045-U
24047
24213-U
24215-U
24216-U
24296
24297
1325
1325
265
265
265
133
133
88
88
88
44
44
44
27
27
27
25360
25361
25314
25315
25382
25416
25417
25302-U
25303
25388
25340
25341-U
25348
25344
25345-U
25349
PRICE
LENGTH (m)
D f (m)
0.10mm ID FUSED SILICA
15
0.10
0.20mm ID FUSED SILICA
15
0.20
30
0.20
60
0.20
12
0.33
0.25mm ID FUSED SILICA
15
0.25
30
0.25
60
0.25
15
1.0
30
1.0
60
1.0
0.32mm ID FUSED SILICA
15
0.25
30
0.25
60
0.25
30
0.50
15
1.0
30
1.0
60
1.0
0.53mm ID FUSED SILICA
15
0.50
30
0.50
60
0.50
30
1.0
15
1.5
30
1.5
60
1.5
15
3.0
30
3.0
60
3.0
15
5.0
30
5.0
60
5.0
BETA
CAT. NO.
250
24341
250
250
250
152
24165-U
24166
24167
24234-U
250
250
250
63
63
63
24032
24034
24036
24033
24035
24037
320
320
320
160
80
80
80
24101-U
24048
24050
24360
24100-U
24049
24051
265
265
265
133
88
88
88
44
44
44
27
27
27
25316
25317
25383
25420-U
25304
25305-U
25389
25342
25343
25350
25346
25347
25351
PRICE
CAT. NO.
30
0.25
250
SE-54, 0.25mm ID FUSED SILICA
24004-U
30
0.25
250
24001
PRICE
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
LENGTH (m)
D f (m)
0.10mm ID FUSED SILICA
15
0.10
0.20mm ID FUSED SILICA
15
0.20
30
0.20
12
0.33
25
0.33
0.25mm ID FUSED SILICA
30
0.10
15
0.25
30
0.25
60
0.25
100
0.25
15
1.0
30
1.0
60
1.0
100
1.0
0.32mm ID FUSED SILICA
30
0.10
15
0.25
30
0.25
60
0.25
100
0.25
15
1.0
30
1.0
60
1.0
100
1.0
30
2.0
60
2.0
30
5.0
60
5.0
0.53mm ID FUSED SILICA
15
0.10
30
0.10
15
0.50
30
0.50
60
0.50
15
1.0
30
1.0
15
1.5
30
1.5
60
1.5
15
3.0
30
3.0
60
3.0
15
5.0
30
5.0
60
5.0
Gas
Chromatography
McReynolds Nos.: x y z u s = 4 58 43 56 38
SUPELCO
230
Capillary GC
Other Columns
PTE-5/QTM - meets or exceeds performance specifications of MDN-5S - These nonpolar columns feature very low bleed, and
US EPA Methods 625, 1625, 8270, and QTM protocols. Low
excellent inertness for active compounds. High sensitivity and
bleed, recommended for use with GC/MS systems.
integrity due to a better signal-to-noise ratio.
Phase: bonded; poly(5% diphenyl/95%
dimethylsiloxane)
Temp. Limits:
SUPELCO
D f (m)
Gas
Chromatography
LENGTH (m)
PTE-5
BETA
CAT. NO.
250
24135-U
320
250
80
24143
24214
24159
265
25355
PRICE
LENGTH (m)
D f (m)
0.25mm ID Fused Silica
30
0.10
15
0.25
30
0.25
60
0.25
30
0.50
30
1.0
0.32mm ID Fused Silica
30
0.25
60
0.25
30
0.50
30
1.0
0.53mm ID Fused Silica
30
1.5
BETA
CAT. NO.
625
250
250
250
125
63
24378
24377-U
24384
24392
24379
24385-U
320
320
160
80
24386
24394
24393
24387-U
PRICE
88
25474
MDN-1 - Nonpolar methylsilicone column that separates
analytes according to boiling point. The bonded polymer matches
the polarity of nonbonded phases SE-30 and SP-2100, and of
bonded phase SPB-1.
MDN-12 - Low polarity and unique selectivity make these
Phase: bonded; poly(dimethylsiloxane)
columns ideal for confirmational analyses and for separating
Temp. Limits: -60C to 320C
active compounds, pesticides, herbicides, PCBs, and PAHs.
Similar Phases: SPB-1, DB-1, ULTRA-1, RTx-1, CP-SIL-5CB
LENGTH (m)
D f (m)
0.25mm ID Fused Silica
30
0.25
30
1.0
0.32mm ID Fused Silica
30
0.25
30
1.0
BETA
CAT. NO.
250
63
24258
24259
320
80
24299
24300-U
PRICE
BETA
CAT. NO.
250
24096
320
250
80
24097
24203
24204-U
CAT. NO.
250
250
24388
24396
320
320
80
24390-U
24398
24391
PRICE
LENGTH (m)
D f (m)
0.25mm ID Fused Silica
30
0.25
0.32mm ID Fused Silica
30
0.25
30
0.32
30
1.0
BETA
PRICE
methylpolysiloxane
50C to 340/360C
BETA
CAT. NO.
250
24382-U
320
24383-U
PRICE
Operating Conditions For All Columns On This Page:Chemically compatible with water and other injection solvents. Sensitive to strong inorganic acids and bases.
Columns can be rinsed.
231
Capillary GC
Capillary Column Equivalents
SPB-Octyl
SPB-1701
HP-1701 / DB-1701
SPB-35
HP-35 / DB-35
SP-2250
HP-50, HP-17 / DB-17
SPB-17
HP-50, HP-17 / DB-17
SPB-50
HP-50 / DB-17
PAG
ALLTECH CHROMPACK
MACHERYNAGEL
AT-1000
AT-5
AT-20
AT-1701
AT-35
AT-50
AT-50
AT-50
AT-Wax
CP-Sil5CB
CP-Sil 8CB
CP-Sil19CB
CP
-Sil 24CB
CP-Sil 24CB
CP-Sil 24CB
CP-Wax
52CB
Optima 1
Op
tima 5
Optima 1701
Optima 17
Optima 17
Permabond CW 20M
AT
-1000
AT-1000
AT-225
AT-Silar
CP-Sil 88
CP-Sil88
SGE
PACKED
COLUMN
EQUIVALENT
007-1
RTx-1
007-2
RTx-5
007-20
RTx-20
007-1701 RTx-1701
007-11
RTx-35
007-17
RTx-50
007-17
RTx-50
RTx-50
007-CW
Stabilwax
BP-1
BP-5
BP-10
BPX-35
BP-20
Squalane
SE-30, SP-2100
SE-54, SE-52, OV-73
OV-7
OV-1701
OV-11
OV-17
OV-17, SP-2250
OV-17, SP-2250
Pluronics F68
Carbowax 20M
007-FFAP
007-FFAP
007-225
007-23
BP-21
BP-21
BP-225
BPX-70
SP-1000, OV-351
SP-1000, OV-351
OV-225
SP-2330
SP-2340
QUADREX
RESTEK
Stabilwax-DA
Stabilwax-DA
RTx-225
RTx-2330
RTx-2330
RTx-2330
Chiral
-DEX
-DEX
-DEX 120
Environmental
Equity-5 / PTE-5
SP-2331
SPB-608
SPB-624
SPB-HAP
Sup-Herb
VOCOL
GC/MS
Equity-1 / MDN 1
Equity-5 / MDN-5
Equity-5 / MDN-5S
AGILENT / J&W
ALLTECH
CHROMPACK
HP Chiral /
Cyclodex-B
Chiraldex-B
CP-Chirasil
DEX CB
AT-5
CP-Sil 8CB
HP-5MS
DB-Dioxin
HP-608 / DB-608
HP-624 / DB-624,
DB-VRX
HP-VOC /
DB-502.2
HP-1MS
HP-5MS
HP-5TA / DB-5MS,
DB-625
Food & Beverage / Fatty Acids
Omegawax
SAC-5
SP-2380
HP-23 / DB-23
SP-2560
SPB-PUFA
Carboxen-1010 PLOT
Petrocol DH 50.2
HP-PONA
Petrocol DH Octyl
Petrocol EX2887
DB-2887
PTA-5
SCOT
SPB-1 Sulfur
Supel-Q PLOT
HP-PLOT Q / GS-Q
TCEP
Pharmaceutical
OVI-G43
HP-624 / DB-624
MACHERYNAGEL
QUADREX
RESTEK
SGE
LIPODEX A
HYDRODEX
RT-DEX
Cydex B
LIPODEX E
RTDEX
007-2
XTI-5
BPX-5
AT-Pesticides
AT-624
Permabond
SE-54-HKW
CP-Sil 13CB
Optima 624
007-608
007-624
RTx-624
BP608
BP624
RTx-502.2
CP-Sil 1CB MS
CP-Sil 8CB MS
Optima 1MS
Optima 5MS
RTx-5Sil MS
BPX5
CP-Sil 88
Famewax
RTx-2330
CP-Wax 51
FS-CW 20 M-AM
Stabilwax-DB
CP-MoleSieve 5A
RT-MoleSieve 13X
AT-Petro
CP-SimDist CB
CP-Sil PONA
Squalane
CP-SimDist CB
Pe
rmabond P-100
Optima-5 Amine
007-1-10V-1.0F
007-1-50-0.5F
007-1-10V-1.0F
RTx-2887
RTx1-PONA
RTx-5 Amine
AT-Sulfur
AT-624
PoraPLOT Q
TCEP
007-624
RT-Q PLOT
RTx-TCEP
RTx-624
BP-1 PONA
BP-1 PONA
BP624
Gas
Chromatography
AGILENT / J&W
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
SUPELCO
232
Capillary GC
Custom Columns
Custom Capillary GC Columns
SUPELCO
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Gas
Chromatography
SE-30
SE-54
SP-2100
SP-2250
SP-2330
SP-2331
SP-2340
SP-2380
SPB-1
SPB-1 Sulfur
SPB-5
SPB-20
SPB-50
SPB-35
SPB-225
SPB-608
SPB-624
SPB-1000
SPB-1701
SPB-Octyl
SPB-PUFA
SUPELCOWAX 10
TCEP
VOCOL
DIMENSIONS AVAILABLE
Inside diameter: Available in 0.10mm, 0.20mm, 0.25mm, 0.32mm,
0.53mm, and 0.75mm sizes.
Film thickness: Varies from 0.05m to 7.0m. Actual film thickness
will depend on the phase and column ID selected.
Column length: Varies from 1m to 100m. Actual lengths will depend
on the column ID selected and cage style selected.
Cage: The 0.10mm to 0.25mm ID columns are placed on our
standard 6/15cm cage. All others are placed on our standard 8/
20cm cage. The smaller HP6850 column cage is also available upon
request.
TCEP
UCON LB-550-X
DIMENSIONS AVAILABLE
Inside diameter: Available in .020 inch (.50mm) size.
Column length: Varies from 1 foot to 100 feet.
* Additional phases may be available. Please inquire if you require a phase not
listed.
CAT. NO.
PRICE
233
Capillary GC
Fused Silica Tubing
Fused Silica Tubing
Use as transfer lines, guard columns, or retention gaps, or to make
your own columns.
P000167
TUBING TREATMENT
Untreated
APPLICATION
MAX. TEMP
General purposes, where
360C
high inertness is not necessary
Nonpolar (methyl)
360C
Intermediate Polarity
(phenyl/methyl)
360C
UNTREATED
ID (mm)
CAT. NO.
PRICE
3 x 1-meter lengths
0.10
25700-U
0.20
0.25
24024
0.32
25702
0.53
25703
3-meter length
0.10
25715
0.20
0.25
25717
0.32
25718
0.53
25719
5-meter length
0.10
25735
0.20
0.25
25737
0.32
25738
0.53
25739
15-meter length
0.20
0.25
24059
0.32
24062
0.53
25306
30-meter length
0.20
25767
0.25
0.32
24063
0.53
25308
60-meter length
0.20
0.25
24061
0.32
24064
0.53
25781
1
260C
DEACTIVATED TUBING
NONPOLAR
CAT. NO.
PRICE
25704
24025
24058
25307
25720-U
25722
25723
25724
DEACTIVATED TUBING
INTERMEDIATE POLARITY
CAT. NO.
PRICE
25705
25706
25707
25708
25709
25726
25727
25728
25729
25740-U
25741
25742
25743
25744
25745-U
25746
25747
25748-U
25339 1
25755
25756
25757
25758
25760-U
25761
25762
25768-U
25769-U
25770-U
25771
25772
25774
25775-U
25783
25784
25785
25786
25787
25788-U
25789
DEACTIVATED TUBING
POLAR
CAT. NO.
PRICE
25710
25712
25714
25734
25752-U
25753
25763
25765
25766
25777
25778
25779
25792
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Polar (PEG)
Gas
Chromatography
SUPELCO
234
Capillary GC
Test Mixes for Capillary Columns
Column Test Mixes
After you install a column in your system, use a test mix to make sure you havent also installed some surprises, such
le or as
tubing
ferru
fragments in the column, or small leaks. Weekly tests thereafter will keep little problems from growing into big problems.
mixes
Test
are
an inexpensive aid to obtaining high quality chromatograms.
Acidity Test Mix
Methane Standard
SUPELCO
DESCRIPTION
Acidity Test Mix
2,6-Dimethylphenol
QTY.
2mL
CAT. NO.
48255-U
PRICE
Gas
Chromatography
2,6-Dimethylaniline
DESCRIPTION
QTY.
100ppm in helium
14L
Accessories for Methane Standard
Hamilton 1725N Syringe
Syringe Adapter
Pressure Regulator
CAT. NO.
307200
PRICE
20705
609010
513010
Undecane (C11)
2,6-Dimethylaniline
Dodecane (C12)
Tri decane (C13)
DESCRIPTION
Programmed Test Mix
Dodecane (C12)
2,6-Dimethylphenol
Tridecane (C13)
2,6-Dimethylaniline
Tetradecane (C14)
Octadecane (C18)
2,6-Dimethylaniline
2,6-Dimethylphenol
Eicosane (C20)
DESCRIPTION
QTY.
Isothermal Test Mix Kit
3x3mL
Nonpolar Column Test Mix
2mL
Intermediate Polarity
Column Test Mix
2mL
Polar Column Test Mix
2mL
Nonanal
Undecane
2-Ethylhexanoic acid
2,6-Dimethylan iline
C10 acid methyl ester
Dicyclohexylamine
C11 acid methyl ester
C12 acid methyl ester
CAT. NO.
47303
47300-U
47301
47302
PRICE
400g/mL
290g/mL
380g/mL
320g/mL
420g/mL
310g/mL
420g/mL
410g/mL
QTY.
2mL
CAT. NO.
47304
PRICE
235
Capillary GC
Test Mixes for Capillary Columns
Test Mixes for Specific Phases
For popular Supelco capillary columns. Each mix contains active components and inactive hydrocarbons.
COMPOSITION
500g/mL each component in methyl tert-butyl ether.
n-Octylamine
n-Nonylamine
n-Pentadecane (C15)
n-Decylamine
-DEX 120
Decane (C10)
(+)-1,2-Propanediol1
Decane (C10)
( +)-3-Methyl-2-heptanone
PRICE
1mL
48013
1mL
48028
(-)-1,2-Propanediol1
Undecane (C11)
CAT. NO.
48278
n-Octadecane (C18)
2,6-Dimethylaniline
2,4-Dimethylaniline
n-Eicosane (C20)
-DEX 120
n-Hexadecane (C16)
n-Benzylamine
n-Heptadecane (C17)
Tri-n-hexylamine
QTY.
1mL
1-Hexanol
Undecane (C11)
Omegawax2
1mL
48476
Menhaden Oil 2
PETROCOL TEST MIXES
1mL
48473
1mL
48872
Petrocol DH
Petrocol D2887
Toluene, 1%
n-Octane, 1%
m-Xyl ene, 4%
p-Xylene, 2%
n-Nonane, 1%
6 x 1mL
48889
n-Octadecane
SPB-50
1-Octanol
2,6-Dimethylphenol
2,6-Dimethylaniline
48273
1mL
48275-U
1mL
48280-U
1mL
49136
1mL
49138-U
n-Dodecane (C12)
n-Tridecane (C13)
1mL
n-Nonadecane (C19)
n-Eicosane (C20)
1-Octanol
n-Dodecane (C12)
n-Tridecane (C13)
2,6-Dimethylphenol
2,6-Dimethylaniline
n-Pentadecane (C15)
Herbicides Mix 2
1
2
Treflan (Trifluralin)
Atrazine
Terbacil
Sencor
Bromacil
Paarlan (Isopropalin)
GOAL (Oxyfluorfen)
Velpar (Hexazinone)
Vernam
Simazine
Dual
Propachlor
Propazine
Prowl
Balan
Tolban (Profluralin)
Oxadiazon
Total concentration 1000g/mL for the two isomers.
The Omegawax Column Test Mix and the Menhaden Oil standard are based on naturally occurring mixtures of fatty acids relative p eak sizes may vary from lot to lot.
O r d e r : 1 . 8 0 0 . 3 2 5 . 3 0 1 0 Te c h n i c a l S e r v i c e : 1 . 8 0 0 . 3 5 9 . 3 0 4 1 We b : w w w. s i g m a - a l d r i c h . c o m / s u p e l c o
Gas
Chromatography
SUPELCO